中子和密度测井找气方法的更新

中子和密度测井在复杂岩性地层中找气,如果只用中子和密度孔隙度差异性质指示气层,由于复杂岩性的干扰,容易出现多解性。本文建立的测井找气模型、刻度公式、气层下限值、指示和验证气层法则,更新了中子和密度测并找气方法,能够压制复杂岩性的干扰,排除多解性。文中给出的测井找气实例表明,采用更新后的测井找气方法指示低孔隙度复杂岩性气层,提高了中子和密度测井指示气层的分辨率、直观性和准确性,从而获得了更好的找气效果。     

致密砂岩气层的测井评价--以鄂尔多斯盆地大牛地山西组一段气田为例

大牛地气田山西组一段储层的孔隙度和渗透率均低、孔隙结构复杂、非均质性强，具有低压、低产的特征。利用测井资料，采用人工神经网络技术对致密砂岩的岩性进行了识别，共识别出中—粗粒岩屑砂岩、岩屑石英砂岩两种岩性，结合三种孔隙度测井方法进行了孔隙度和渗透率的预测，利用岩电实验资料，建立了储层微观孔隙结构与胶结指数、饱和度指数、岩石弹性力学参数之间的统计关系，获得了有效的饱和度评价参数，提高了饱和度的解释精度。并以压汞、相渗等岩芯分析资料进行了束缚水饱和度的解释，并采用多种交绘图技术，有效地识别了致密砂岩气层。该方法的特点是充分放大测井信息对天然气的响应特征，增强了气层和干层的判别差异。实践表明，上述方法对于鄂尔多斯盆地大牛地气田致密砂岩气层测井评价的符合率达到95％以上。     

来凤地区龙马溪组含气页岩测井识别——以WY1井为例

湖北龙马溪组海相页岩是除四川盆地外可能实现页岩气勘探突破点之一,测井技术是一种十分成熟的油气勘探开发研究手段,本文以来凤地区WY1井的测井为基础,对龙马溪组含气页岩层段测井响应特征进行系统研究。结果表明,WY1井龙马溪组含气页岩层段具有高自然伽马、高铀、高钍、高补偿中子、高声波时差及低密度的测井响应特征,深、浅侧向电阻率低于下伏宝塔组碳酸盐岩,高于砂质页岩,且正差异反映岩层中发育高角度裂缝的层段。通过测井曲线叠合以及交会图版分析发现,含气页岩层自然伽马—岩性密度测井叠合曲线及声波时差—岩性密度测井叠合曲线具有明显的正差异,而自然伽马—补偿中子和声波时差—补偿中子呈现明显的负差异,且声波时差—岩性密度叠合测井曲线对于含气层段的指示作用最为准确;声波时差—补偿中子测井交会图、补偿中子—自然伽马测井交会图以及深侧向电阻率—补偿中子测井交会图对于富有机质含气页岩的识别作用最明显。     

宣达地区中、下三叠统含杂卤石蒸发岩测井响应及岩性识别

钾盐主要用于农业中钾肥的生产,中国是钾盐消费和进口大国,但中国钾资源少、产量低,因此钾盐勘探对中国粮食安全有重要意义。四川盆地是中国找钾的重要区域,文章运用岩芯样品、测井等资料,通过X射线粉晶衍射、元素含量测试等实验对宣达地区中、下三叠统嘉陵江组-雷口坡组含盐系典型矿物特征及岩石测井响应特征进行分析,并基于测井解释方法原理对杂卤石进行识别。结果表明,研究区钾盐矿物包括氯化盐矿物、硫酸盐矿物、碳酸盐矿物3类,固态钾盐矿物主要为杂卤石,常与石盐、硬石膏共存,具有高电阻率、高密度、高伽马、高K的特征,主要分布于T₁j^4-2、T₁j^5-2层段。     

碎屑岩地区低矿化度气田的气,水层识别方法—以十屋断陷八层 …

在松辽盆地十屋断陷八屋气田,由于气田水的矿化度低,使得利用电阻率曲线不能将气层与水层区分开。为了解决这个问题,作者依据中子测井的“挖掘效应”原理,提出一种识别气、水层的新方法：首先,采用声波和中子孔隙度之间的差值合成一种新的曲线－声波中子合成曲线;然后,利用自然伽马曲线等划分出砂岩储层段;最后,利用所合成的声波中子合成曲线进行判别,凡大于零者为气层,小于零则为水层。     

淡水储层中低阻油气层识别技术

相对于咸水储层的常规电阻率油气层,淡水泥质砂岩储层中的低阻油气层识别难度较大,其成因类型复杂多样,可归纳为5类,即高束缚水、高阳离子交换量、盐水泥浆侵入、砂泥岩间互和油层与水层矿化度的差异,而低阻油气层大多是多成因的。针对多成因低阻油气层,采用交会图、测井新技术、常规测井信息的有效合理分析等方法进行识别,通过合理选取泥质砂岩饱和度模型定量评价。由此确定的淡水储层中低阻油气层识别评价思路,在渤海湾地区的油气勘探中得到了很好应用,而且正在发挥着重要作用,低阻油气层识别评价是一种经济、实用、可靠的勘探开发技术。     

小波分析在致密砂岩气层识别中的应用

致密砂岩储层孔隙度低、渗透率低、非均质性强,气层所对应的测井响应特征较为复杂,气层识别和评价难度较大,多解性突出.以三水模型、岩心、地质和试气资料为基础,采用能量谱峰值与能量加权累计法定量分析致密砂岩气层的电阻率与自由流体孔隙度组合曲线的小波多尺度能谱特征,以及小波包能量谱特征.组合曲线的多尺度小波能量谱分析方法在致密砂岩气层识别中气层的能量谱与水层的能量谱明显不同,并用其识别苏里格地区的致密砂岩气层.结果表明识别致密砂岩气层能量加权累计法定量分析比小波能量峰分析效果更好.      

低渗低阻产水气藏气水层识别:以广安气田须家河组为例

广安气田上三叠统须四段和须六段气藏发育了构造气藏、构造-岩性气藏和岩性气藏.储层具有低孔、低渗、低阻和高束缚水饱和度特征.空间上,储层孔渗相关关系变化大,气水分布复杂,气水层识别困难.根据岩心对测井的标定,研究了须四段和须六段四性关系,认识到储层为细砂岩、中砂岩和粗砂岩,具有低自然伽马、低补偿密度、低电阻率和高声波时差特征,而物性与含气性无明显相关性.采取了分层、分区块建立储层孔隙度、渗透率模型,提高了物性解释精度.不同气藏类型具有不同的气水分布,应用阵列感应、核磁共振和综合判识3种方法进行了气水层识别,提高了广安气田气水层识别精度.这些方法在广安气田的应用表明可以准确识别构造气藏和构造-岩性气藏的气、水层,但对构造幅度低的岩性气藏识别精度不高,因为在这些岩性气藏中气水分异不彻底,气层与气水同层、水层含水饱和度是渐变的.      

CO2气综合识别技术及应用

CO₂气藏由于其物理、化学性质的特殊性,CO₂气勘探与烃类气既有相同又有区别,综合应用多种资料和多种技术方法是识别CO₂气(层)藏的有效手段。利用区域地质分析、地球物理和地球化学勘探方法综合评价非烃气的分布,提出钻探目标,通过非烃色谱测量法和红外线CO₂气体浓度测量法实现CO₂气层钻井现场动态检测,利用气体色谱检测相关录井参数资料、核测井密度中子孔隙度差值综合解释CO₂气层,有效地识别CO₂气。主要介绍CO₂气藏综合勘探技术的关键的新技术方法,如地球化学方法、录井和测井综合识别的关键技术方法等。     

青海木里三露天天然气水合物钻孔岩性测井识别

三露天井田具有断层发育、地层缺失和重复明显、岩性种类较多等特点,岩性识别难度较大。为此,专门利用测井资料对三露天井田地层岩性进行了岩性识别研究。通过对14个天然气水合物钻孔不同岩性的测井响应特征分析,优选了自然伽马、中子和密度测井作为岩性识别敏感参数,并采用交会图技术制作了岩性识别图版,建立岩性划分标准,对三露天井田地层岩性进行识别与划分。利用测井资料能够识别7种主要岩性,包括砂岩、粉砂岩、泥质粉砂岩、粉砂质泥岩、泥岩、油页岩和煤等。根据岩性测井识别结果,三露天井田岩性分布特征在横向上表现为东部砂岩物性好,西部地区泥岩较为发育;纵向上表现为木里组地层砂泥比为4.48,含有煤层204.5 m;江仓组地层砂泥比为0.84,泥岩和油页岩较为发育,更有利于水合物赋存。测井岩性识别结果为寻找三露天井田天然气水合物有利储层奠定了基础。     

东海泥质区单体正构烷烃的碳同位素组成及物源分析 *

利用气相色谱(GC)和气相色谱/同位素比值质谱(GC/IRMS)对东海近岸泥质区、济州岛西南泥质区和冲绳海槽北部表层沉积物中正构烷烃的单体碳同位素组成及分布进行了分析。结果显示东海不同泥质区典型海洋藻类源正构烷烃C₁₉同位素组成基本相似,在-27.4 ‰ ~-28.0 ‰ 之间,平均为-27.7 ‰ 。典型海洋水生植物源C₂₃同位素组成在-28.5 ‰ ~-31.6 ‰ 之间,平均为-30.5 ‰ ,碳同位素组成从近岸泥质区到冲绳海槽北部逐渐变重,表明海槽区与陆架区海洋水生植物种类有所不同。陆架区长链正构烷烃(C₂₅~C₃₁)部分随着碳数的增加,其同位素组成逐渐变轻,但海槽区这一变化不大,显示陆架区的陆源高等植物蜡具有相似的物源,而冲绳海槽北部由于黑潮主干区和黑潮分支(对马暖流)对陆架沉积物进入深海的控制性阻隔作用,其物源与陆架区区别较大。现代输入东海的陆源植物以C₃植物为显著优势,C₃植物对近岸泥质区北部、近岸泥质区南部、远端济州岛西南泥质区和冲绳海槽北部陆源植物的贡献分别为83 % ,95 ％,75 % 和70 % 。     

Well-based hydraulic and geochemical monitoring of the above zone of the CO2 reservoir at Ketzin, Germany

In order to detect hydraulic and geochemical impact on the groundwater directly above the CO₂ storage reservoir at the Ketzin pilot site continuous monitoring using an observation well is carried out. The target depth (446 m below ground level, bgl.) of the well is the Exter formation (Upper Triassic, Rhaetian) which is the closest permeable stratigraphic overlying formation to the CO₂ storage reservoir (630–636 m bgl. at well location). The monitoring concept comprises evaluation of hydraulic conditions, temperature, water chemistry, gas geochemistry and δ¹³C values. This is achieved by a tubing inserted inside the well with installed pressure sensors and a U-tube sampling system so that pumping tests or additional wireline logging can be carried out simultaneously with monitoring. The aquifer was examined using a pump test. The observation well is hydraulically connected to the regional aquifer system and the permeability of about 1.8 D is comparatively high. Between Sept. 2011 and Oct. 2012, a pressure increase of 7.4 kPa is observed during monitoring under environmental conditions. Drilling was carried out with drilling mud on carbonate basis. The concentration of residual drilling mud decreases during the pump test, but all samples show a residual concentration of drilling mud. The formation fluid composition is recalculated with PHREEQC and is comparable to the literature values for the Exter formation. The gas partial pressure is below saturation at standard conditions and the composition is dominated by N₂ similar to the underlying storage reservoir prior to CO₂ injection. The impact of residual drilling mud on dissolved inorganic carbon and the respective δ¹³C values decreases during the monitoring period. The pristine isotopic composition cannot be determined due to calcite precipitation. No conclusive results indicate a leakage from the underlying CO₂ storage reservoir.     

歧口凹陷沙河街组成岩史分析和成岩阶段预测

渤海湾盆地歧口凹陷超压对有机质热演化、有机酸生成和水岩反应具有明显的抑制作用。在化学动力学模型中加入超压因子增加反应活化能,即可用于超压条件下有机质热演化和成岩作用的模拟。歧口凹陷深层(>3500m)主要为沙河街组(始新—渐新世)。在沙河街组沉积末期沙河街组三段(沙三段)就进入晚成岩阶段A₁期,烃源岩开始生烃,生、储、盖层发育史与圈闭发育史匹配良好,油气藏开始形成。在东营组沉积时期(渐新世)—新近纪,沙河街组大部分地层处于晚成岩阶段A₁—A₂期,是其主要成藏期。现今沙河街组一段、二段和三段的上部仍处于晚成岩阶段A₁—A₂期,有利于油气藏的形成。然而,沙三段的下部在歧口凹陷的北部地区已进入晚成岩阶段BC期,镜质组反射率Ro≥1.3%,烃源岩处于高过成熟阶段,储层物性较差,不利于成藏,但在南部地区的沙三段下部还处于晚成岩阶段A₁-A₂期,生、储、盖层发育,是油气聚集的有利地区。     

昭通示范区黄金坝气田五峰—龙马溪组页岩气储层地质特征

昭通国家级页岩气示范区黄金坝气田是继礁石坝和长宁—威远之后中国又一个在页岩气勘探、开发领域实现重大突破的地区,为了系统地展示黄金坝气田页岩气资源富集的储层条件,为未来的勘探工作提供参考,以五峰—龙马溪组页岩气储层为研究对象,从区域地质条件、储层岩石学、物性和地球化学4个方面对该页岩气储层进行了综合研究。结果表明稳定的区域构造和良好的顶底板条件是黄金坝地区页岩气资源富集的关键,良好的保存条件使储层维持了较高的压力(压力系数1);较高的孔隙度(平均4%)和TOC含量(目的层2%)提供了良好的储集空间,使储层具有较高的含气量(1.35~3.48 cm3/g,平均2.50 cm3/g);天然气地球化学数据表明,区内天然气主要成分为CH4(97%),其次还含有少量的C2H6、C3H8和CO2;天然气同位素数据表明烃类C同位素组成发生了倒转,表明储层具有良好的封闭性。但储层孔隙系统较为复杂,且非均质性极强,从而导致渗透率较低,在储层改造施工过程中应予以充分考虑。总体上,黄金坝气田具有较好的开发前景,生产测试表明,区内直井压裂产量为0.5×104~3.5×104m3/d/井,水平井压裂产量可达12×104~40×104m3/d/井。     

A geochemical study on mud volcanoes in the Junggar Basin, China

A comprehensive study was performed to characterize, for the first time, the mud, water, and gases released from onshore mud volcanoes located in the southern margin of the Junggar Basin, northwestern China. Chemical compositions of mud, along with the geology of the basin, suggest that a source of the mud is Mesozoic or Cenozoic shale. Oxygen and H isotope compositions of the released water suggest a local meteoric origin. Combined with the positive Eu anomalies of the water, a large ¹⁸O shift of the water suggests extensive interaction with rocks. Gases discharged from the mud volcanoes are predominantly thermogenic hydrocarbons, and the high δ¹³C values (>+20‰ VPDB) for CO₂ gases and dissolved carbonate in muddy water suggest secondary methanogenesis with CO₂ reduction after oil biodegradation.The enrichments of Eu and ¹⁸O in water and the low thermal gradient of the area suggest that the water-rock interactions possibly occur deeper than 3670 ± 200 m. On the other hand, considering the relationship to the petroleum reservoir around the mud volcanoes, the depth of the gases can be derived from about 3600 m, a depth that is greater than that generally estimated for reservoirs whose gas is characterized by ¹³C-enriched CO₂. Oil biodegradation with CO₂ reduction likely occurs at a shallower depth along the seepage system of the mud volcano. The results contribute to the worldwide data set of gas genesis in mud volcanoes. Moreover, they further support the concept that most terrestrial mud volcanoes release thermogenic gas produced in very deep sediments and may be early indicators of oil biodegradation, an important problem in the petroleum industry.     

Trinidad mud volcanoes: where do the expelled fluids come from?

In order to establish the origin of fluids expelled from mud volcanoes in Trinidad, we analyzed their major-element, trace-element, and isotopic (H, O, Sr) compositions. The mineralogical, chemical, and Sr isotope compositions of associated expelled muds were also determined.On the basis of their chemical and Sr isotope compositions, the fluids were divided into two groups—those southwest and northeast of a major right lateral wrench fault (the Los Bajos fault) that both controls the chemical quality of the fluids and acts as a drain. Strontium isotopes were derived via mixing between a radiogenic source (0.71135) and a nonradiogenic source (≤0.70671) for both southwest and northeast groups. However, the nonradiogenic source possibly feeding the northeast group showed a lower Sr concentration than that of the southwest group. H and O isotope data show that the fluids became enriched in δ¹⁸O through interaction with wall rocks. The fluids were originally oceanic, but their properties were subsequently modified by diagenesis as evidenced by chemical data, and mixing between fluids issued from two deep-seated reservoirs and surface aquifer end-members.The gas phase expelled with the mud and the fluid through the mud volcanoes is composed mainly of methane with minor carbon dioxide. The amount of expelled gas seems the same in samples from both sides of the Los Bajos fault. The almost unique methane content of the gas phase and the large positive δ¹⁸O shifts of the reservoir end-member, as well as B, Li, and Ba contents, reveal that the fluids from the deep-seated reservoirs inherited their chemical compositions at high-temperature fluid–rock interactions. Estimates of equilibrium temperatures of the two deep-seated reservoirs suggest that, to acquire the estimated higher temperature (150°C), the mud volcanoes must have been fed partly by a reservoir located at a depth of more than 3 km. This depth corresponds to previous geologic information, which located the deep-seated reservoir in Miocene sediments at such a comparable depth. The mixing of the original fluids with a less deep-seated reservoir and meteoric waters on the ascending path suggests the presence of a recharge mechanism and contributes to the dynamics of the expulsion itself.     

The first offshore natural gas hydrate production test in South China Sea

Natural gas hydrates (NGH) is one of key future clean energy resources. Its industrialized development will help remit the huge demand of global natural gas, relieve the increasing pressure of the environment, and play a vital role in the green sustainable growth of human societies. Based on nearly two decades’ studying on the reservoir characteristics in the South China Sea (SCS) and the knowledge of reservoir system, the China Geological Survey (CGS) conducted the first production test on an optimal target selected in Shenhu area SCS in 2017. Guided by the “three-phase control” exploitation theory which focused on formation stabilization, technologies such as formation fluid extraction, well drilling and completing, reservoir stimulating, sand controlling, environmental monitoring, monitoring and preventing of secondary formation of hydrates were applied. The test lasted for 60 days from May 10^th when starting to pump, drop pressure and ignite to well killing on July 9^th, with gas production of 3.09×10⁵ m³ in total, which is a world record with the longest continuous duration of gas production and maximal gas yield. This successful test brings a significant breakthrough on safety control of NGH production.     

Structure of the sedimentary cover of the Pugachevo mud volcano area in Sakhalin: Evidence from geophysical modeling

The geological-geophysical data on the Pugachevo mud volcano group located in the zone of the submeridional Central Sakhalin Fault (CSF) are analyzed. The results of the density and geothermal modeling along two orthogonal profiles passing through the central part of the Pugachevo area are examined. It is found that the Late Cretaceous sequence of this fault-related area contains a subvertical narrow anomalous deconsolidation cone-shaped zone widening from 1 km on the surface to 4 km at its base (at the depths more than 6 km). The density of the deconsolidation blocks is 2.20–2.22 g/cm³, whereas that of the adjacent blocks reaches around 2.4–2.5 g/cm³. The largest deconsolidation block is located in the Lower Cretaceous Ai Formation, where a vast reservoir zone with mainly hydrocarbon gas (HC) is inferred at depths of more than 4400 m with temperatures of more than 140°C. The modeling results showed that the main reservoir of gases periodically ejected from the Pugachevo mud volcano is localized in the Ai Formation sequence in the tectonically weakened zone of the CSF at depths of 4.5–5.6 km. The overlying sequences contain smaller intermediate reservoirs. The Pugachevo area is promising for economic hydrocarbon reservoirs.     

利用测井资料进行天然气储层产能的评价与预测

以鄂尔多斯某区块石盒子组第一段为主要研究层段,以测井数据体为实际利用资料,通过对测井数据资料的聚类分析,建立了对应产层的评价参数,以多参数聚类分析方法建立了天然气储层产能评价和预测的标准模式,从而达到从定性到定量对天然气储层的产能进行评价和预测的目的.分析结果表明,该区块目的层段的产能级别可分为两类,一类的产能级别较差,其无阻流量小于5 000 m3/d,达不到国家工业气流标准,无开采价值;而另一类的产能级别较好,其无阻流量大于5 000 m3/d,多在10 000 m3/d以上,具备一定的开采价值.研究验证该方法是一种行之有效的方法.     

天然气水合物成因探讨

天然气水合物是未来的能源资源。其分布于极地地区、深海地区及深水湖泊中。在海洋里,天然气水合物主要分布于外大陆边缘和洋岛的周围,其分布与近代火山的分布范围具有一致性。同位素组成表明天然气水合物甲烷主要是由自养产甲烷菌还原CO₂形成的。典型的大陆边缘沉积物有机碳含量低（＜0．5％～1．0％）,不足以产生天然气水合物带高含量的甲烷。赋存天然气水合物的沉积物时代主要为晚中新世-晚上新世,具有一定的时限性,并且天然气水合物与火山灰或火山砂共存,表明其形成与火山-热液体系有一定联系。火山与天然气水合物空间上的一致性表明,天然气水合物甲烷的底物可能主要是由洋底火山喷发带来的CO2。由前人研究结果推断 HCO^－₃在脱去两个O原子的同时,可能发生了亲核重排,羟基 H原子迁移到 C原子上,形成了甲酰基（HCO^－）,使甲烷的第一个 H原子来源于水。探讨了甲烷及其水合物的形成机制,提出了天然气水合物成因模型。