Lunar materials: Their mineralogy,petrology and chemistry

The manned Apollo 11, 12, 14 and 15 and the automated Luna 16 lunar missions have provided us with lunar rock and regolith (soil) samples from a number of geologically distinct sites. The mare regions were sampled by Apollo 11, 12 and Luna 16, whereas Apollo 14 landed on a terrain with more relief, the Fra Mauro Formation which represents an ejecta blanket from the Imbrian Basin, and Apollo 15 touched down near the lunar highlands. The samples collected consist of a mixture, mainly of basalt, breccia and regolith (soil-particulate matter, generally < 1 cm in size). The basalts show considerable variation in texture, mineralogy and chemistry and probably represent fragments from various parts of relatively thin and extensive lava flows in the maria. The breccias represent regolith material which was indurated to varying degrees by impact events. The regolith is a product of the breakdown, again by impact, of coherent rock masses of basalt and breccia.     

月球典型撞击坑溅射物研究及对月球地质编图的意义

撞击坑是月表最典型的地质单元,其溅射物作为撞击坑的坑外组成部分可分布到距离坑中心10个直径距离之外的区域,因此撞击溅射物也是月球地质编图中最重要的表达要素之一。本文使用月球勘测轨道器(LRO)的激光高度计(LOLA)数据、广角相机(WAC)影像、窄角相机(NAC)影像以及Clementine的UVVIS多光谱数据,研究了哥白尼纪正面月海区直径31km的Kepler撞击坑和背面月陆区直径30km的Necho撞击坑。哥白尼纪撞击坑溅射沉积物可以分为三个相:连续溅射沉积相(CE)、不连续溅射沉积相(DE)和辐射纹(CR)。连续溅射沉积相分布在最大约2.6个半径范围之内,不连续溅射沉积相分布在最大近11个半径范围之内,辐射纹分布在最大近29个半径范围之内。本文强调了多源数据结合在识别撞击坑溅射沉积物中的作用,对Kepler坑和Necho坑溅射沉积物进行了填图,不对称分布的特征表明这两个坑可能形成于倾斜撞击。     

Hypervelocity collisions into continental crust composed of sediments and an underlying crystalline basement: comparing the Ries (∼24 km) and Chicxulub (∼180 km) impact craters

The Chicxulub and Ries impact craters were excavated from layered continental terrains that were composed of carbonate-bearing sedimentary sequences and underlying crystalline silicate basement materials. The Chicxulub and Ries impact events were sufficiently large to produce complex peak-ring impact craters. The walls of transient craters and excavation cavities, with diameters of 12-16 km for the Ries and 90-100 km for Chicxulub, collapsed to form final crater diameters of ∼24 and ∼180 km, respectively. Debris from both the sedimentary and crystalline layers was ejected during crater formation, but the bulk of the melting occurred at depth, in the silicate basement. The volume of melt and proportion of melt among shock-metamorphosed debris was far larger at Chicxulub, producing a central melt sheet ∼3 km in depth. The central melt sheet was covered with melt-bearing polymict breccias and, at the Ries, similar breccias (crater suevites) filled the central cavity. Also at the Ries (and presumably at Chicxulub), large hill-size megablocks of crystalline basement material were deposited near the transient crater rim. Blocks and megablocks of sedimentary lithologies were ejected into the modification zone between the peak ring and final crater rim, while additional material was slumping inward during crater growth, and buried beneath a fallout deposit of melt-bearing polymict breccias. The melt and surviving clasts in the breccias are dominantly derived from the deeper, basement lithologies. At greater distances, however, the ejecta is dominated by near-surface sedimentary lithologies, large blocks of which landed with such high energy that they scoured and eroded the pre-existing surface. The excavation and ejecta pattern produced lithological and chemical variations with radial distance from the crater centers that evolve from basement components near the crater centers to sedimentary components far from the crater centers. In addition, carbonate (and anhydrite in the case of Chicxulub) was vaporized, producing environmentally active gases. The vaporized volume produced by the Ries impact event was too small to dramatically alter the evolution of life, but the vaporized volume produced by the Chicxulub impact event is probably a key factor in the Cretaceous-Tertiary boundary mass extinction event.     

Foreign meteoritic material of howardites and polymict eucrites

Howardites and polymict eucrites are fragments of regolith breccias ejected from the surface of a differentiated (eucritic) parent body, perhaps, of the asteroid Vesta. The first data are presented demonstrating that howardites contain, along with foreign fragments of carbonaceous chondrites, also fragments of ordinary chondrites, enstatite meteorites, ureilites, and mesosiderites. The proportions of these types of foreign meteoritic fragments in howardites and polymict eucrites are the same as in the population of cosmic dust particles obtained from Antarctic and Greenland ice. The concentrations of siderophile elements in howardites and polymict eucrites are not correlated with the contents of foreign meteoritic particles. It is reasonable to believe that cosmogenic siderophile elements are concentrated in howardites and polymict eucrites mostly in submicrometer-sized particles that cannot be examined mineralogically. The analysis of the crater population of the asteroid Vesta indicates that the flux of chondritic material to the surface of this asteroid should have been three orders of magnitude higher than the modern meteoritic flux and have been comparable with the flux to the moon’s surface during its intense meteoritic bombardment. This provides support for the earlier idea about a higher meteoritic activity in the solar system as a whole at approximately 4 Ga. The lithification of the regolith (into regolith breccia) of the asteroid Vesta occurred then under the effect of thermal metamorphism in the blanket of crater ejecta. Thus, meteorite fragments included in howardites provide record of the qualitative composition of the ancient meteorite flux, which was analogous to that of the modern flux at the Earth surface.     

月表典型区撞击坑形态分类及分布特征

月球表面环形构造主要有撞击坑、火山口和月海穹窿3种,其中撞击坑分布最广泛,是研究月表环形构造的主要内容。由于月表撞击坑数量大、种类多及其形成伴随着整个月球地质的演化过程,因此这种月表地形地貌比较完整地记录了月球表面地貌随时间的改造过程以及改造类型。文中通过研究撞击坑遥感影像及形貌特征,总结归纳为简单型、碗型、平底型、中央隆起型、同心环型、复杂型及月海残留型7种撞击坑类型,用来描述月表典型区域撞击坑的形态特征。从结构和物质两方面进行了月表典型区域撞击坑的形态地貌参数提取,综合利用嫦娥一号CCD 影像数据、LROC数据,得到了该区域撞击坑形态数据(坑底、坑唇、坑壁、坑缘、溅射物覆盖层、中央峰)和形态测量数据(直径、深度、地理位置)。研究发现,LQ 4地区的撞击坑分布可分为月陆区和月海区,月陆区的撞击坑多以中小型撞击坑为主,其分布密度极高,形成年代较早,月海区撞击坑多为年轻的撞击坑,分化程度较低,分布密度也较低。     

Tooting crater: Geology and geomorphology of the archetype large,fresh, impact crater on Mars

The 27.2 km diameter Tooting crater is the best preserved young impact crater of its size on Mars. It offers an unprecedented opportunity to study impact-related phenomena as well the geology of the crust in the Amazonis Planitia region of Mars. For example, the nearly pristine condition enables the partial reconstruction of the sequence of events for crater formation, as well as facilitates a comparison to deposits seen at the Ries crater in Germany. High-resolution images taken by the High Resolution Imaging Science Experiment (HiRISE) and Context Camera (CTX) on the Mars Reconnaissance Orbiter spacecraft have revealed a wealth of information on the distribution of features within the crater and beyond the rim: a large central peak, pitted material on the floor and terrace blocks, lobate flows interpreted to be sediment flows, impact melt sheets, four discrete layers of ejecta, and an asymmetric secondary crater field. Topographic data derived from the Mars Orbiter Laser Altimeter (MOLA) and stereo HiRISE and CTX images show that the central peak is ～1100 m high, the lowest point of the crater floor is 1274 m below the highest part of the rim, and the crater rim has ～600 m of variability around its perimeter. Layering within the cavity walls indicates ～260 m of structural uplift of the target material, which constitutes ～35% of the total relief of the rim. Abundant evidence is found for water flowing down the cavity walls, and on the surface of the ejecta layers, both of which took place sometime after the impact event. Thickness measurements of the ejecta layers reveal that the continuous blanket is remarkably thin (～3–5 m) in some places, and that the distal ramparts may be ～60 m high. Crater counts made on the ejecta layers indicate a model age of <3 Ma for the formation of Tooting crater, and that the target rocks have a model age of ～240–375 Ma. It is therefore possible that this may be the source of certain basaltic shergottite meteorites ejected at ～2.8 Ma that have crystallization ages which are comparable to those of the basaltic lava flows that formed the target materials for this impact event. The geology and geomorphology of Tooting crater may help in the interpretation of older large impact craters on Mars, as well as the potential role of target volatiles in the impact cratering process.     

Lunar surface geochemistry: Global concentrations of Th, K, and FeO as derived from lunar prospector and Clementine data

Accurate estimates of global concentrations of Th, K, and FeO have an important bearing on understanding the bulk chemistry and geologic evolution of the Moon. We present empirical ground-truth calibrations (transformations) for Lunar Prospector gamma-ray spectrometer data (K and Th) and a modified algorithm for deriving FeO concentrations from Clementine spectral reflectance data that incorporates an adjustment for TiO₂ content. The average composition of soil samples for individual landing sites is used as ground-truth for remotely sensed data. Among the Apollo and Luna sites, Apollo 12 and 14 provide controls for the incompatible-element-rich compositions, Apollo 16 and Luna 20 provide controls for the feldspathic and incompatible-element-poor compositions, and Apollo 11, 15, and 17, and Luna 16 and 24 provide controls for Fe-rich compositions. In addition to these Apollo and Luna sample data we include the composition of the feldspathic lunar meteorites as a proxy for the northern farside highlands to extend the range of the calibration points, thus providing an additional anorthositic end-member composition. These empirical ground-truth calibrations for Lunar Prospector Th and K provide self consistency between the existing derived data and lunar-sample data. Clementine spectral-reflectance data are used to construct a TiO₂-sensitive FeO calibration that yields higher FeO concentrations in areas of high-Fe, low-Ti, mare-basalt-rich surfaces than previous FeO algorithms. The data set so derived is consistent with known sample compositions and regolith mixing relationships.     

Antarctic lunar meteorites Yamato-793169, Asuka-881757, MIL 05035, and MET 01210 (YAMM): Launch pairing and possible cryptomare origin

The Antarctic lunar meteorite Meteorite Hills (MET) 01210 is a polymict regolith breccia, dominantly composed of mare basalt components. One relatively large (2.7 × 4.7 mm) basalt clast in MET 01210 (MET basalt) shows remarkable mineralogical similarities to the lunar-meteorite crystalline mare basalts Yamato (Y)-793169, Asuka (A)-881757, and Miller Range (MIL) 05035. All four basalts have similar rock texture, mineral assemblage, mineral composition, pyroxene crystallization trend, and pyroxene exsolution lamellae. The estimated TiO₂ contents (∼2.0 wt%) of the MET basalt and MIL 05035 are close to the bulk-rock TiO₂ contents of Y-793169 and A-881757. These similarities suggest that Y-793169, A-881757, MIL 05035, and the MET basalt came from the same basalt flow, which we designate the YAMM basalt. The source-basalt pairing of the YAMM is also supported by their similar REE abundances, crystallization ages (approx. 3.8-3.9 Ga), and isotopic compositions (low U/Pb, low Rb/Sr, and high Sm/Nd). The pyroxene exsolution lamellae, which are unusually coarse (up to a few microns) by mare standards, imply a relatively slow cooling in an unusually thick lava and/or subsequent annealing within a cryptomare. Reported noble gas and CRE data with close launch ages (∼1 Ma) and ejection depths (deeper than several meters) among the four meteorites further indicate their simultaneous ejection from the moon. Despite the marginally close terrestrial ages, pairing in the conventional Earth-entry sense seems unlikely because of the remote recovery sites among the YAMM meteorites.The high abundance (68%) of mare components in MET 01210 estimated from a two-component mixing model calculation could have resulted from either lateral mixing at a mare-highland boundary or vertical mixing in a cryptomare. The proportion of mare materials in MET 01210 is greater than in Apollo core samples at the mare-highland boundary. The burial depth (>several meters deep) inferred from the lack of surface irradiation of MET 01210 exceeds the typical mare regolith thickness (a few meters). Thus, the source of the YAMM meteorites is likely a terrain of locally high mare-highland mixing within a cryptomare. We searched for a possible source crater of the YAMM meteorites within the well-defined cryptomare, based on the multiple constraints obtained from this study and published data. An unnamed 1.4 km-diameter crater (53°W, 44.5°S) on the floor of the Schickard crater is the most suitable source for the YAMM meteorites.The ²³⁸U/²⁰⁴Pb (μ) value of the YAMM basalts is extremely low, relative to those of the Apollo mare basalts, but comparable to those of the Luna 24 very low-Ti basalts. The low-μ source indicates a derivation from a less differentiated mantle with a lack of KREEP components. Although the chemical sources of materials and heat source of melting might be independent, the heat source that generated the source magma of the YAMM and Luna 24 basalts may not be related to KREEP, unlike the case of the Apollo basalts. The distinct chemical and isotopic compositions of mantle sources between the Apollo basalts and the YAMM/Lunar 24 basalts imply differences in mantle composition and thermal evolution between the Procellarum KREEP Terrane (PKT) and non-PKT regions of the nearside.     

Feldspathic lunar meteorites Pecora Escarpment 02007 and Dhofar 489: Contamination of the surface of the lunar highlands by post-basin impacts

PCA (Pecora Escarpment) 02007 and Dhofar 489 are both meteorites from the feldspathic highlands of the Moon. PCA 02007 is a feldspathic breccia consisting of lithified regolith from the lunar surface. It has concentrations of both incompatible and siderophile elements that are at the high end of the ranges for feldspathic lunar meteorites. Dhofar 489 is a feldspathic breccia composed mainly of impact-melted material from an unknown depth beneath the regolith. Concentrations of incompatible and siderophile elements are the lowest among brecciated lunar meteorites. Among 19 known feldspathic lunar meteorites, all of which presumably originate from random locations in the highlands, concentrations of incompatible elements like Sm and Th tend to increase with those of siderophile elements like Ir. Feldspathic meteorites with high concentrations of both suites of elements are usually regolith breccias. Iridium derives mainly from micrometeorites that accumulate in the regolith with duration of surface exposure. Micrometeorites have low concentrations of incompatible elements, however, so the correlation must reflect a three-component system. We postulate that the correlation between Sm and Ir occurs because the surface of the Feldspathic Highlands Terrane has become increasingly contaminated with time in Sm-rich material from the Procellarum KREEP Terrane that has been redistributed across the lunar surface by impacts of moderate-sized, post-basin impacts. The most Sm-rich regolith breccias among feldspathic lunar meteorites are about 3× enriched compared to the most Sm-poor breccias, but this level of enrichment requires only a few percent Sm-rich material typical of the Procellarum KREEP Terrane. The meteorite data suggest that nowhere in the feldspathic highlands are the concentrations of K, rare earths, and Th measured by the Lunar Prospector mission at the surface representative of the underlying “bedrock;” all surfaces covered by old regolith (as opposed to fresh ejecta) are at least slightly contaminated. Dhofar 489 is one of 15 paired lunar-meteorite stones from Oman (total mass of meteorite: 1037 g). On the basis of its unusually high Mg/Fe ratio, the meteorite is likely to have originated from northern feldspathic highlands.     

Big returns on small samples: Lessons learned from the analysis of small lunar samples and implications for the future scientific exploration of the Moon

Samples returned from the surface of planetary bodies are both complementary to orbital and in situ observations and provide a unique perspective for understanding the nature and evolution of that body. This unique perspective is based on the scale the sample is viewed (mm-Å), the ability to manipulate the sample, the capability to analyze the sample at high precision and accuracy, and the ability to significantly modify experiments as logic and technology dictates over an extended period of time (decades). Unlike the Apollo missions, robotic sample return missions in the next decade will result in the return of relatively small sample mass. Such robotically returned samples are scientifically more valuable if they can be placed within a planetary context through orbital observations and if information concerning planetary-scale processes and conditions can be extracted from them. Conversely, samples give remotely sensed data ground truth. That is, they act as a “calibration standard” for these data allowing a much enhanced global view to be constructed.The Moon is an example that illustrates how information can be extracted from small samples and then extended to planetary and solar system scales. Three examples from the Moon illustrate this point. First, multi-analytical and experimental studies of minute (10-500 μm) glass beads representing near-primary magmas provide constraints on the composition and condition of the lunar mantle, the style of early planetary differentiation, the history and character of early mantle dynamics and melting, and the isolation of the lunar mantle from late-stages of lunar accretion. Second, trace element analysis of individual mineral grains via ion microprobe and isotopic analysis of small rock fragments representing some of the oldest and youngest periods of lunar magmatism illustrate their usefulness for both fingerprinting distinct episodes of lunar magmatism and reconstructing the evolution of lunar magmatism. Third, mechanisms for primitive planetary mantles degassing and volatile transport on airless bodies can be understood by the analysis of volatile coatings on glass and mineral fragments in the lunar regolith.As many of our insights about the Moon are based on samples that primarily were collected within a limited lunar terrain, our understanding of the Moon is somewhat biased. Future scientifically strategic sampling targets are young mare basalts (Roris basalt in Oceanus Procellarum), far-side mare basalts (Mare Moscoviense), large pyroclastic deposits and potential mantle xenoliths (Aristarchus plateau, Rima Bode) major unsampled crustal lithologies outside the Procellarum KREEP terrane (central peak in Tsiolkovsky crater, South-pole Aitken basin), basin and crater melt sheets (South-pole Aitken basin, Giordano Bruno) and H deposits in permanently shaded areas (South-pole Aitken basin). Sampling these locations would further our understanding of processes at work during the early evolution of the terrestrial planets, provide a comprehensive history of endogenous (e.g., primary volcanic degassing) and exogenous (e.g., solar wind, galactic cosmic rays, volatiles from comets) volatile reservoirs and volatile transport and would provide unique historical information about events and processes that affected the entire inner solar system, a record obscured on the Earth and Mars.     

Feldspathic Mare Basalts at the Apollo 17 Landing Site, Taurus-Littrow

The basalt target rocks that have been converted to regolithacross the lunar maria are everywhere more feldspathic and lessmafic than the basalt hand specimens recovered from four Apollolanding sites, an effect not due to either horizontal or verticalmixing with adjacent highland materials. These crushed targetrocks need to be characterized by direct chemical and petrographicanalysis of the lithic fragments of basalt in the regolithsand by determination of the phase equilibria in and adjacentto these compositions at low pressure. Such data are availablefor the basalts of Mare Crisium and Mare Nubium (Luna 16, 24)and for Very Low Titanium basalt, first defined by three lithicfragments from the Apollo 17 core. These are all feldspathicbasalts, as are those from the Mare Tranquillitatis and OceanusProcellarum soils (Apollo 11, 12). Such data are lacking forthe principal basalt components at Mare Imbrium and Mare Serenitatis(Apollo 15, 17). The thoroughly investigated Apollo 17 landingsite at Taurus–Littrow, SE Mare Serenitatis, providesan example where other published information may be used toarrive at estimates of the composition of the feldspathic marebasalt that was the principal target material for regolith formation.This crushed basalt composition is that of a liquid close tobeing in simultaneous equilibrium with all of olivine, plagioclase,calcium-rich pyroxene, spinel, armalcolite and ilmenite at lowpressure. The simplest explanation would be that the basaltthat dominated the formation of the regolith comes from a differentflow unit than the hand specimens, but it strains credulitythat not a single hand specimen can be positively assigned tothat upper unit, and not a single soil sample can be positivelyidentified as having formed principally from the unit that providesthe hand specimens. KEY WORDS: cotectic; lithic fragment; lunar; target rock; regolith     

Holocene records of eolian dust deposition from high-elevation lakes in the Uinta Mountains,Utah, USA

Radiocarbon-dated sediment cores from subalpine lakes were used to investigate post-glacial dust deposition in the Uinta Mountains (Utah, USA). Lake sediments were geochemically characterized with ICP-OES, ICP-MS and XRF core scanning. Collections from passive samplers constrain the properties of modern dust, and samples of regolith constrain properties of the local material within the watershed. Ca and Eu are more abundant in dust, whereas Ti and Zr are more abundant in local regolith. As a result, the Ca/Ti and Eu/Zr ratios are indices for the dust content of lake sediment. In all records, the dust index rises in the early Holocene as watersheds became stabilized with vegetation, reducing the influx of local material. After this point, values remained above average through the middle Holocene, consistent with an increased dust content in the sediment. Dust index values drop in the late Holocene in most lakes, suggesting a decrease in dust abundance. Generally synchronous shifts in dust index values in cores from lakes in different parts of this mountain range are evidence of enhanced dust deposition in this region during the middle Holocene, and are consistent with a variety of records for increased aridity in the south-western USA at this time.     

松辽盆地三肇凹陷葡萄花油层局部构造控油模式探讨

利用近4000口开发井初期产能资料,结合构造、测井解释、沉积微相和报废井类型等静态地质资料,对松辽盆地三肇凹陷葡萄花油层的油水分布规律进行了系统分析。研究表明,三级构造内单个的局部构造或单个的局部构造群控制油气的最终成藏,三级构造内油水分布受单个的局部（构造、岩性）圈闭控制,单个的局部（构造、岩性）圈闭内具有统一的油水分布规律,相邻的不同单个的局部（构造、岩性）圈闭具有不同的油水分布规律;储层的发育特征控制了油水的分布层位,断层与砂体的空间配置控制油水的分布边界。在相近的条件下,地垒型断块构造油藏〖FY〗反向正断层—鼻状构造油藏“人”字型反向正断层组合油藏断层—微幅度油藏断层—岩性油藏岩性油藏其它类型油藏,控油能力逐渐减弱。     

CZChemDB and EarthChem: Advancing management and access of critical zone geochemical data

Multiple Critical Zone Observatories (CZO) have been established in recent years in the USA and other international settings to conduct collaborative research on processes that occur at and near Earth’s surface, also known as the Critical Zone (CZ). Data documentation and data sharing are two persistent problems facing the CZOs that impede the ability for cross-site comparisons and integrated analysis. In this study, a relational database was developed for CZ rock and regolith geochemical data – CZChemDB. There are a total of 24 interrelated tables in the database, each representing different aspects of CZ features. The main data group includes tables of locations, sites, samples, subsamples, preparation/treatments, laboratory-analysis and data values. The meta-data group includes tables of methods, references, and data quality. Lookup tables (variables, units, etc.) contain lists of “controlled” vocabularies. The CZChemDB is currently implemented in the MS Access database management system. It is expected to be integrated into the EarthChem portal by summer of 2011 for broader online accessibility and usability. This integration also complements the EarthChem’s global geochemistry database with CZ regolith data. The structure of the CZChemDB is simple, straightforward, and flexible so that it has potential to accommodate other chemical data collected from CZOs, such as pore fluid data. Furthermore, the development of CZChemDB represents the first attempt toward the standardization of geochemical data documentation and data sharing among CZOs. This effort will establish a model to bridge the connections between data acquisition, data management, data sharing, and data searching/discovering that are all essential but weak in terms of linkages within most geoscience research projects.     

Imbrium provenance for the Apollo 16 Descartes terrain: Argon ages and geochemistry of lunar breccias 67016 and 67455

In order to improve our understanding of impact history and surface geology on the Moon, we obtained ⁴⁰Ar-³⁹Ar incremental heating age data and major + trace element compositions of anorthositic and melt breccia clasts from Apollo 16 feldspathic fragmental breccias 67016 and 67455. These breccias represent the Descartes terrain, a regional unit often proposed to be ejecta from the nearby Nectaris basin. The goal of this work is to better constrain the emplacement age and provenance of the Descartes breccias.Four anorthositic clasts from 67016 yielded well-defined ⁴⁰Ar-³⁹Ar plateau ages ranging from 3842 ± 19 to 3875 ± 20 Ma. Replicate analyses of these clasts all agree within measurement error, with only slight evidence for either inheritance or younger disturbance. In contrast, fragment-laden melt breccia clasts from 67016 yielded apparent plateau ages of 4.0-4.2 Ga with indications of even older material (to 4.5 Ga) in the high-T fractions. Argon release spectra of the 67455 clasts are more variable with evidence for reheating at 2.0-2.5 Ga. We obtained plateau ages of 3801 ± 29 to 4012 ± 21 Ma for three anorthositic clasts, and 3987 ± 21 Ma for one melt breccia clast. The anorthositic clasts from these breccias and fragments extracted from North Ray crater regolith (Maurer et al., 1978) define a combined age of 3866 ± 9 Ma, which we interpret as the assembly age of the feldspathic fragmental breccia unit sampled at North Ray crater. Systematic variations in diagnostic trace element ratios (Sr/Ba, Ti/Sm, Sc/Sm) with incompatible element abundances show that ferroan anorthositic rocks and KREEP-bearing lithologies contributed to the clast population.The Descartes breccias likely were deposited as a coherent lithologic unit in a single event. Their regional distribution suggests emplacement as basin ejecta. An assembly age of 3866 ± 9 Ma would be identical with the accepted age of the Imbrium basin, and trace element compositions are consistent with a provenance in the Procellarum-KREEP Terrane. The combination of age and provenance constraints points toward deposition of the Descartes breccias as ejecta from the Imbrium basin rather than Nectaris. Diffusion modeling shows that the older apparent plateau ages of the melt brecia clasts plausibly result from incomplete degassing of ancient crust during emplacement of the Descartes breccias. Heating steps in the melt breccia clasts that approach the primary crystallization ages of lunar anorthosites show that earlier impact events did not completely outgas the upper crust.     

Single crystal U-Pb zircon age and Sr-Nd isotopic composition of impactites from the Bosumtwi impact structure, Ghana: Comparison with country rocks and Ivory Coast tektites

The 1.07?Myr old Bosumtwi impact structure (Ghana), excavated in 2.1-2.2?Gyr old supracrustal rocks of the Birimian Supergroup, was drilled in 2004. Here, we present single crystal U-Pb zircon ages from a suevite and two meta-graywacke samples recovered from the central uplift (drill core LB-08A), which yield an upper Concordia intercept age of ca. 2145?±?82?Ma, in very good agreement with previous geochronological data for the West African Craton rocks in Ghana. Whole rock Rb-Sr and Sm-Nd isotope data of six suevites (five from inside the crater and one from outside the northern crater rim), three meta-graywacke, and two phyllite samples from core LB-08A are also presented, providing further insights into the timing of the metamorphism and a possibly related isotopic redistribution of the Bosumtwi crater rocks. Our Rb-Sr and Sm-Nd data show also that the suevites are mixtures of meta-greywacke and phyllite (and possibly a very low amount of granite). A comparison of our new isotopic data with literature data for the Ivory Coast tektites allows to better constrain the parent material of the Ivory Coast tektites (i.e., distal impactites), which is thought to consist of a mixture of metasedimentary rocks (and possibly granite), but with a higher proportion of phyllite (and shale) than the suevites (i.e., proximal impactites). When plotted in a Rb/Sr isochron diagram, the sample data points (n?=?29, including literature data) scatter along a regression line, whose slope corresponds to an age of 1846?±?160?Ma, with an initial Sr isotope ratio of 0.703?±?0.002. However, due to the extensive alteration of some of the investigated samples and the lithological diversity of the source material, this age, which is in close agreement with a possible "metamorphic age" of ～?1.8-1.9?Ga tentatively derived from our U-Pb dating of zircons, is difficult to consider as a reliable metamorphic age. It may perhaps reflect a common ancient source whose Rb-Sr isotope systematics has not basically been reset on the whole rock scale during the Bosumtwi impact event, or even reflect another unknown geologic event.     

东海陆架EA01孔沉积物常微量元素变化及其意义

以EA01孔为研究对象，运用元素地球化学数据并辅以古生物、矿物等指标探讨东海中陆架北部的地层划分及物质来源。首先在前人工作的基础上研究常微量元素垂向变化，发现EA01孔沉积物元素地球化学地层学信息可以作为指示地层和古气候信息的良好指标；同时运用因子分析，La/Yb—Ni/Co—Cr/V三角图和U/Th—(Zr+Hf)/(Al2O3+TiO2)散点图等多种方法分析了EA01孔沉积物的物质来源，认为EA01孔沉积物主要来源于长江，其物质成分可能部分受到古气候和沉积环境的影响。     

Geochemistry, petrology and ages of the lunar meteorites Kalahari 008 and 009: New constraints on early lunar evolution

Kalahari 008 and 009 are two lunar meteorites that were found close to each other in Botswana. Kalahari 008 is a typical lunar anorthositic breccia; Kalahari 009 a monomict breccia with basaltic composition and mineralogy. Based on minor and trace elements Kalahari 009 is classified as VLT (very-low-Ti) mare basalt with extremely low contents of incompatible elements, including the REE. The Lu-Hf data define an age of 4286 ± 95 Ma indicating that Kalahari 009 is one of the oldest known basalt samples from the Moon. It provides evidence for lunar basalt volcanism prior to 4.1 Ga (pre-Nectarian) and may represent the first sample from a cryptomare. The very radiogenic initial ¹⁷⁶Hf/¹⁷⁷Hf (εHf = +12.9 ± 4.6), the low REE, Th and Ti concentrations indicate that Kalahari 009 formed from re-melting of mantle material that had undergone strong incompatible trace element depletion early in lunar history. This unusually depleted composition points toward a hitherto unsampled basalt source region for the lunar interior that may represent a new depleted endmember source for low-Ti mare basalt volcanism. Apparently, the Moon became chemically very heterogeneous at an early stage in its history and different cumulate sources are responsible for the diverse mare basalt types.Evidence that Kalahari 008 and 009 may be paired includes the similar fayalite content of their olivine, the identical initial Hf isotope composition, the exceptionally low exposure ages of both rocks and the fact that they were found close to each other. Since cryptomaria are covered by highland ejecta, it is possible that these rocks are from the boundary area, where basalt deposits are covered by highland ejecta. The concentrations of cosmogenic radionuclides and trapped noble gases are unusually low in both rocks, although Kalahari 008 contains slightly higher concentrations. A likely reason for this difference is that Kalahari 008 is a polymict breccia containing a briefly exposed regolith, while Kalahari 009 is a monomict brecciated rock that may never have been at the surface of the Moon.Altogether, the compositions of Kalahari 008 and 009 permit new insight into early lunar evolution, as both meteorites sample lunar reservoirs hitherto unsampled by spacecraft missions. The very low Th and REE content of Kalahari 009 as well as the depletion in Sm and the lack of a KREEP-like signature in Kalahari 008 point to a possible source far from the influence of the Procellarum-KREEP Terrane, possibly the lunar farside.     

Lunar crater Copernicus: search for debris of impacting body at Apollo 12 site

In an attempt to characterize meteoritic material at the Apollo 12 site, 4 KREEP concentrates from soil 12033 have been analyzed by neutron activation analysis. These contain a meteoritic component in which siderophile Ir, Re and Sb are depleted by about a factor of 2, while volatile Se, Zn, Ag and Bi are depleted by a factor of more than 5 relative to Au. This pattern does not closely resemble any major chondrite or iron meteorite group, but is very similar to that observed in high-alkali samples from Apollo 14. The meteoritic component in KREEP at both sites is therefore predominantly derived from Imbrian ejecta. However, a second, small component of primitive composition seems to be present in Apollo 12 KREEP, judging from the slight, uniform enrichments in Ir, Re, Sb, Se and Zn relative to Au. This component does not seem to be due to micrometeorites. If it is attributed to the Copernican projectile, the crater Copernicus may have been formed by a cometary nucleus, 4 km in diameter, with an impact velocity of 30–40 km/sec. These conclusions depend critically on the assumption that the meteoritic component in Apollo 12 KREEP is representative of the entire impact.     

海拉尔盆地含火山岩地层复杂岩性剖面构建技术

海拉尔盆地是中新生代断陷盆地,盆地内断裂发育、物源多且近、地层相带变化快、纵向多层位。这些地质特征导致海拉尔盆地岩性剖面结构复杂,不仅存在着火山熔岩和一般陆源沉积岩,且广泛发育火山过渡岩性。在岩石岩性多样纷杂、录井取心标定资料有限的前提下,如何构建合理的复杂岩性剖面已成为该盆地储层评价的关键。尽管常规测井资料在一定程度上可反映出岩层岩石颗粒成分及分布状况,同时又可提供岩层纵向上的连续变化趋势,但若给出高精度的纵向岩层岩性剖面,仍存在两项关键问题： 1）各测井项目对复杂岩性的反映能力问题, 2）沉积厚度薄、成分复杂的过渡岩性的识别问题。本文将岩层地质沉积信息作为测井资料识别岩性的约束条件,系统建立岩性剖面的有约束连续模式识别技术,实现了海拉尔盆地复杂岩性剖面的高精度构建。经过取心井的验证,综合岩性判别符合率达到80％以上。