扎河坝蛇绿混杂岩内富铌玄武(安山)岩的地球化学特征及其地质意义

在新疆北部东准噶尔的扎河坝蛇绿混杂岩中发现的富铌玄武（安山）岩,其SiO₂含量介于46.71%~57.65%,TiO₂含量为1.00%~1.76%,与太古代绿岩带内富铌玄武（安山）岩相似,Na₂O含量为3.86%~6.64%,P₂O₅为0.34%~0.82%,明显高于太古代绿岩带富铌玄武（安山）岩。扎河坝富铌玄武岩铌含量介于7.22×10^-6~21.91×10^-6之间,大于7×10^-6,与典型的富铌玄武岩相同。该岩石轻重稀土元素分馏较明显,其分布模式为无明显铕至弱负铕异常的右倾曲线。尽管铌的绝对含量较高,但由于钍和轻稀土元素更加富集,在微量元素蛛网图中扎河坝富铌玄武（安山）岩仍表现为铌的明显亏损,同时高场强元素Zr、Hf及Ti也表现出一定程度的亏损。微量元素地球化学特征显示,扎河坝蛇绿混杂岩内富铌玄武（安山）岩形成于古亚洲洋的洋内弧,它是被埃达克质岩浆交代的地幔楔橄榄岩部分熔融的产物,同时大洋沉积物及俯冲板块释放的流体对成岩作用也有一定的贡献。富铌玄武（安山）岩作为弧前增生楔定位在扎河坝蛇绿混杂岩体内,与早前报道的超高压变质岩共存表明,该蛇绿混杂岩体至少记录了两次性质不同的古亚洲洋洋壳俯冲,这更进一步证实新疆北部晚古生代新增陆壳是古亚洲洋多次俯冲作用的产物。     

西天山特克斯北中酸性火成岩地球化学特征及成因意义

新疆西天山特克斯县城北部伊特公路沿线和库勒萨依出露大量中酸性火成岩,伊特公路沿线为石英钠长斑岩,库勒萨依为石英闪长斑岩和花岗闪长斑岩。岩石地球化学和同位素组成研究表明,前者为典型的岛(陆)弧带火成岩,而后者具有埃达克岩的成分特征,两者均为古亚洲洋壳在俯冲过程中岩浆活动的产物。早先俯冲的较冷洋壳板片在深处脱水诱发上覆地幔楔熔融,熔体上升并经历壳幔相互作用等过程引发伊特公路一带弧岩浆活动; 由于洋壳持续俯冲,后来新形成的靠近洋脊的年轻板片由于高热在较浅处直接发生部分熔融形成埃达克岩浆,并上侵至库勒萨依一带。库勒萨依斑岩体SIMS锆石 U-Pb年龄为342.5±2.3Ma,属于早石炭世。两组中酸性火成岩的地球化学特征表明,古亚洲洋(南天山洋)在早石炭世还未完全闭合,洋壳向北的持续俯冲过程造成伊犁-中天山板块南缘广泛的岩浆活动,此时西天山陆壳增生方式主要为侧向增生,增生物质主要为洋壳板片(埃达克岩)和洋壳板片流体交代的地幔楔成分。     

Age and petrogenesis of late Mesozoic intrusions in the Huoluotai porphyry Cu-(Mo) deposit,northeast China: Implications for regional tectonic evolution

Multi-stage igneous rocks developed in the recently discovered Huoluotai Cu-(Mo) deposit provide new insights into the controversial late Mesozoic geodynamic evolution of the northern segment of the Great Xing’an Range (NSGXR). Zircon U-Pb dating suggests that the monzogranite, ore-bearing granodiorite porphyry, diorite porphyry, and granite porphyry in the deposit were emplaced at 179.5 ± 1.6, 148.9 ± 0.9, 146.1 ± 1.3, and 142.2 ± 1.5 Ma, respectively. The Re-Os dating of molybdenite yielded an isochron age of 146.9 ± 2.3 Ma (MSWD = 0.27). The Jurassic adakitic monzogranite and granodiorite porphyry are characterized by high SiO₂ and Na₂O contents, low K₂O/Na₂O ratios, low MgO, Cr, and Ni contents, low zircon ε_Hf(t) values relative to depleted mantle, and relatively high Th contents. They were produced by partial melting of a subducted oceanic slab, with involvement of marine sediments in the magma source and limited interaction with mantle peridotites during magma ascent. The Late Jurassic diorite porphyry is characterized by moderate SiO₂ contents, high MgO, Cr, and Ni contents, and positive dominated ε_Hf(t) values, indicating it was produced by partial melting of a subduction-modified lithospheric mantle wedge and underwent limited crustal contamination during magma ascent. The early Early Cretaceous adakitic granite porphyry shows high SiO₂ and K₂O contents and K₂O/Na₂O ratios, low MgO, Cr, and Ni contents, enriched Sr–Nd isotopic compositions, and slightly positive zircon ε_Hf(t) values, suggesting it was produced by partial melting of thickened mafic lower crust. The NSGXR experienced a tectonic history that involved flat-slab subduction (200–160 Ma), and tearing and collapse (150–145 Ma) of the Mongol–Okhotsk oceanic lithosphere. The period of magmatic quiescence from ca. 160 to 150 Ma was a response to flat-slab subduction of the Mongol–Okhotsk oceanic lithosphere. Crustal thickening in the NSGXR (145–133 Ma) was due to the collision between the Amuria Block and the Siberian Craton.     

甘肃北山460金矿埃达克质石英闪长岩地球化学特征及意义

460金矿石英闪长岩产出于塔里木板块北缘红石山深大断裂带中。通过对其岩石化学组成的研究表明,主量元素SiO2、Al2O3和MgO的含量分别为56.01%~66.96%、14.54%~16.71%和0.88%~5.70%,微量元素Y、Yb和Sr的含量分别为(4.55~13.7)×10-6(、0.61~1.58)×10-6和(428~884)×10-6,LREE为富集型和Eu为正异常,这些特征反映石英闪长岩为埃达克质岩。综合分析认为是基性下地壳在一定的物理化学条件下部分熔融后直接侵位于近地表而形成的。与本区埃达克岩金矿化存在密切的时空关系。     

滇西剑川始新世富碱岩浆岩锆石U-Pb年代学与Sr-Nd-Hf同位素地球化学及其对岩石成因的制约

滇西剑川富碱岩浆岩位于青藏高原东南缘的三江南段,是金沙江-红河富碱岩浆岩带的重要组成部分。剑川富碱岩浆岩包括花岗岩和正长岩两类岩石,前者主要有花岗斑岩和石英二长斑岩,后者主要是正长斑岩和粗面岩。本文对剑川富碱岩浆岩进行了主微量元素、锆石U-Pb年代学和Sr-Nd-Hf同位素特征研究。锆石U-Pb测年结果显示,剑川花岗岩结晶年龄为35. 1～36. 1Ma,正长岩结晶年龄为35. 7～35. 8Ma,均形成于始新世。花岗斑岩和石英二长斑岩的SiO_2含量为67. 92%～69. 93%,K_2O/Na_2O比值介于0. 86～1. 22,具有高钾钙碱性特征;正长斑岩和粗面岩的SiO_2含量为53. 94%～63. 51%,K_2O/Na_2O比值介于1. 30～2. 68,属于钾玄质岩石系列。两类岩石都富集轻稀土元素(LREE)和大离子亲石元素(LILE),相对亏损高场强元素(HFSE)。其中,花岗斑岩和石英二长斑岩有着较高的Sr、Sr/Y、La/Yb值和低的Y、Yb含量,具有埃达克质岩浆属性。结合Sr-Nd-Hf同位素研究认为,滇西剑川地区花岗岩起源于增厚的镁铁质新生下地壳部分熔融,正长岩是由交代富集的岩石圈地幔熔融产生的基性岩浆演化而来的产物。滇西剑川新生代富碱岩浆活动是对印度与欧亚板块晚碰撞阶段,岩石圈地幔发生对流减薄和软流圈物质上涌过程的响应。     

Origin of LateTriassic high-Mg adakitic granitoid rocks from the Dongjiangkou area,Qinling orogen,central China: Implications for subduction of continental crust

The origin of high-Mg adakitic granitoids in collisional orogens can provide important information about the nature of the lower crust and upper mantle during the orogenic process. Late-Triassic high-Mg adakitic granite and its mafic enclaves from the Dongjiangkou area, the Qinling orogenic belt, central China, were derived by partial melting of subducted continental crust and underwent interaction with the overlying mantle wedge peridotite. Adakitic affinity of the different facies of the Dongjiangkou granite body are: high Sr, Ba, high La/Yb and Sr/Y, low Y,Yb, Yb/Lu and Dy/Yb, and no significant Eu anomalies, suggesting amphibole + garnet and plagioclase-free restite in their source region. Evolved Sr-Nd-Pb isotopic compositions [(⁸⁷Sr/⁸⁶Sr)_i = 0.7050 to 0.7055,ε_Nd(t) = –6.6 to –3.3; (²⁰⁶Pb/²⁰⁴Pb)_i = 17.599 to 17.799, (²⁰⁷Pb/²⁰⁴Pb)_i = 15.507 to 15.526, (²⁰⁸Pb/²⁰⁴Pb)_i = 37.775 to 37.795] and high K₂O, Rb, together with a large variation in zircon Hf isotopic composition (ε_Hf(t) = ?9.8 to + 5.0), suggest that the granite was derived from reworking of the ancient lower continental crust. CaO, P₂O₅, K₂O/Na₂O, Cr, Ni, Nb/Ta, Rb/Sr and Y increase, and SiO₂, Sr/Y and Eu/Eu* decrease with increasing MgO, consistent with interaction of primitive adakitic melt and overlying mantle peridotite. Zircons separated from the host granites have U-Pb concordia ages of 214 ± 2 Ma to 222 ± 2 Ma, compatible with exhumation ages of Triassic UHP metamorphic rocks in the Dabie orogenic belt. Mafic microgranular enclaves and mafic dykes associated with the granite have identical zircon U-Pb ages of 220 Ma, and are characterized by lower SiO₂, high TiO₂, Mg# and similar evolved Sr-Nd-Pb isotopic composition. Zircons from mafic microgranular enclaves (MMEs) and mafic dykes also show a large variation in Hf isotopic composition with ε_Hf(t) between ?11.3 and + 11.3. It is inferred that they were formed by partial melting of enriched mantle lithosphere and contaminated by the host adakitic granite magma.In combination with the regional geology, high-Mg# adakitic granitoid rocks in the Dongjiangkou area are considered to have resulted from interaction between subducted Yangtze continental crust and the overlying mantle wedge. Triassic continental collision caused detachment of the Yangtze continental lithosphere subducted beneath the North China Craton, at ca. 220 Ma causing asthenosphere upwelling and exhumation of the continental crust. Triassic clockwise rotation of the Yangtze Craton caused extension in the Dabie area which led to rapid exhumation of the subducted continental lithosphere, while compression in the Qinling area and high-P partial melting (amphibole ± garnet stability field) of the subducted continental crust produced adakitic granitic magma that reacted with peridotite to form Mg-rich hybrid magma.     

Transition from oceanic subduction to continental collision recorded in the Bangong-Nujiang suture zone: Insights from Early Cretaceous magmatic rocks in the north-central Tibet

The transition from oceanic subduction to continental collision is a key stage in the evolution of ancient orogens. We present new data for Early Cretaceous diorite and granite porphyry from north–central Tibet to constrain the evolution of the Bangong–Nujiang Tethyan Ocean (BNTO). The diorites have moderate SiO₂ and high MgO contents, similar to high-Mg andesites. Zircon grains yield U–Pb ages of 128–124 Ma and positive ε_Hf(t) values between +13.2 and + 16.3, corresponding to Hf depleted-mantle model ages (T_DM) of 281–131 Ma. The high-Mg diorite was probably formed by partial melting of hydrous mantle wedge fluxed by slab-derived fluids in an oceanic subduction setting. The granite porphyries yield zircon U–Pb ages of 117–115 Ma and zircon ε_Hf(t) values ranging from +0.1 to +4.5. Most samples have high SiO₂ and Fe₂O₃^T contents, variable FeO^T/MgO and Ga/Al ratios, and are depleted in Ba, Sr, P, and Ti, similar to I- and A-type granites. The granite porphyries were most likely derived from partial melting of juvenile dioritic or granodioritic crust due to break-off of the BNTO lithosphere following collision between the Lhasa and Qiangtang blocks. The Early Cretaceous high-Mg diorite and A-type granite porphyry thus record the Early Cretaceous transition from oceanic subduction to continental collision along the Bangong–Nujiang suture zone (BNSZ).     

Geochemistry and Petrogenesis of Granitoids at Sharang Eocene Porphyry Mo Deposit in the Main‐Stage of India‐Asia Continental Collision,Northern Gangdese,Tibet

The Sharang porphyry Mo deposit is the first discovered Mo porphyry‐type deposit in the Gangdese Metallogenic Belt. The orebody is hosted by the Eocene multi‐stage composite intrusive complex which is emplaced in the Upper Permian Mengla Formation and cut by the Miocene dykes. Granite porphyry is recognized as the ore‐bearing porphyry in the complex, which consists of quartz diorite, quartz monzonite, granite, prophyritic granite and post‐mineral lamprophyre. Granodiorite porphyry and dacite porphyry intrude the granite porphyry. Geochemical data indicate that Sharang complex has a High‐K calc‐alkalinc to shoshonitic, metaluminous to slightly peraluminous composition. The Sharang complex rocks are enriched in large ion lithophile elements, depleted in high‐field strength elements, Nb, Sr, P and Ti. REE patterns show slight enrichments in light REE relative to heavy REE and weak negative Eu anomalies. All rocks in this complex have a wide range of initial ⁸⁷Sr/⁸⁶Sr ratios (0.705605～0.712496) and lower ε_Nd(t) values (?0.61～?7.80). The geochemical data suggest highly oxidized‐evolved magma and old continental materials may have been the magma source for the Sharang intrusive complex that host porphyry Mo mineralization. Eocene pre‐ore and ore‐forming rocks at Sharang may have formed by partial melting of mantle wedge and by mixing with old continental crust at the lower crust level. In contrast the post‐ore rocks may have formed by partial melting of enriched lithospheric mantle.     

Chronology and Geochemistry of the Nadingcuo Volcanic Rocks in the Southern Qiangtang Region of the Tibetan Plateau: Partial Melting of Remnant Ocean Crust along the Bangong-Nujiang Suture

<正>The Nadingcuo high-K calc-alkaline rocks mainly composed of trachyte and trachyandesite are the largest outcrop area of volcanic rocks in southern Qiangtang terrane in the Tibetan plateau. However,their exact source and peterogenesis are still debated.~(40)Ar-~(39)Ar and LAM-ICPMS zircon U-Pb isotopic dating confirm that these rocks erupted in Eocene.In addition,the Nadingcuo volcanic rocks are characterized by high Sr/Y content ratios,similar with the adakite derived from partial melting of oceanic crust.They can be further classified as high Mg~#(Mg~#=48-57) and low Mg~# (Mg~#=33-42) subtypes.The Nadingcuo adakitic rocks have relatively low(~(87)Sr/~(86)Sr)_i and highε_(Nd)(t), showing a trend of similarity to the Dongcuo ophiolite present in the Bangong-Nujiang oceanic crust. Simple modeling indicates that the Nadingcuo adakitic rocks are a mix resulting from the basalt of Bangong-Nujiang Ocean with 10%-20%crustal material of Lhasa terrane.On these bases we suggest that the low Mg~# Nadingcuo adakitic rocks are the product of partial melting of remnant oceanic crust with small sediment,and the high Mg~# rocks are the result of reaction between rising melt of remnant oceanic crust with subducted sediment and mantle wedge.Therefore,the origin of Nadingcuo adakitic rocks may be related to intracontinental subduction triggered by collision of India-Asia during Cenozoic.     

俯冲带复杂的壳幔相互作用

俯冲带除俯冲板片脱水形成的富大离子亲石元素流体、交代地幔楔形成的岛弧钙碱性玄武岩安山岩-英安岩-流纹岩及相应侵入岩组合外，还存在由俯冲扳片熔融形成的埃达克质熔体交代地慢楔形成的埃达克岩-富铌玄武岩-富镁安山岩组合，从而构成了俯冲带的流体交代与熔体交代两大类壳慢相互作用体系及相应的岩石组合。熔体交代作用的显著特点是Mg、高场强元素Nb、Ti、P等含量增加，Nd／Sr值增高，而Si、K、Na及La／Yb降低。洋壳板片或洋脊俯冲、玄武质岩浆底侵使地壳增厚，或板片断离、撕裂等作用均可产生埃达克质熔体并随之产生熔体交代作用。流体和熔体与地幔橄揽岩的相互作用构成了俯冲带复杂的地球化学体系。     

Petrogenesis of Rabor-Lalehzar magmatic rocks (SE Iran): Constraints from whole rock chemistry and Sr-Nd isotopes

The Urumieh-Dokhtar magmatic arc (UDMA) of Central Iran has been formed during Neotethyan Ocean subduction underneath Eurasia. The Rabor-Lalehzar magmatic complex (RLMC), covers an area ～1000?km² in the Kerman magmatic belt (KMB), SE of UDMA. RLMC magmatic rocks include both granitoids and volcanic rocks with calc-alkaline and adakitic signatures but with different ages.Miocene adakitic rocks are characterd by relatively enrichmented in incompatible elements, high (Sr/Y)_(N) (>40), and (La/Yb)_(N) (>10) ratios with slightly negative Eu anomalies (Eu_N/Eu*≈ 0.9), depletion in HFSEs, and relatively non-radiogenic Sr isotope signatures (⁸⁷Sr/⁸⁶Sr?=?0.7048–0.7049). In contrast, the Oligocene granitoids exhibit low Sr/Y (<20) and La/Yb (<9) ratios, negative Eu anomalies (Eu_N/Eu*?≈?0.5), and enrichment in HFSEs and radiogenic Sr isotope signatures (⁸⁷Sr/⁸⁶Sr?=?0.7050–0.7052), showing affinity to the island arc rocks. Eocene volcanic rocks which crusscut the younger granitoid rocks comprise andesites and dacites. Geochemically, lavas show calc-alkaline character without any Eu anomaly (Eu_N/Eu*?≈?1.0). Based on the geochemical and isotopic data we propose that melt source for both calc-alkaline and adakitic rocks from the RLMC can be related to the melting of a sub-continental lithospheric mantle (SCLM). Basaltic melts derived from a metasomatized mantle wedge might be emplaced at the mantle-crust boundary and formed the juvenile mafic lower crust. However, some melts fractionated in the shallow magma chambers and continued to rise forming the volcanic intermediate-mafic rocks at the surface. On the other hand, the assimilation and fractional crystallization in the shallow magma chambers of may have been responsible for the development of Oligocene granitoids with calc-alkaline affinity. In the mid-Late Miocene, following the collision between Afro-Arabia and Iranian block the juvenile mafic crust of UDMA underwent thickening and metamorphosed into garnet-amphibolites. Subsequent upwelling of a hot asthenosphere during Miocene was responsible for partial melting of thickened juvenile crust of the SE UDMA (RLM complex). The adakitic melts ascended to the shallow crust to form the adakitic rocks in the KMB.     

俯冲型和碰撞型含矿斑岩地球化学组成的差异

Cu-Mo-Au含矿斑岩不仅可以形成于与洋壳俯冲相联系的弧环境,而且也产于碰撞造山带内。通过对比俯冲型和碰撞型含矿斑岩的地球化学特征,发现它们特别在微量元素上具有较大差别,暗示它们有着不同的物源区组成或形成机制。同冈底斯带碰撞型含矿斑岩相比,太平洋东岸俯冲型含矿斑岩有着明显高的HREE和Y含量,低的Sr/Y、(La/Yb)_N以及(Dy/Yb)_N比值,表明其物质源区不含或含有少量的石榴子石并可能以角闪石组成为主。统计发现这些俯冲型含矿斑岩部分样品具有埃达克岩地球化学特征,但大部分样品却显示出具有与正常岛弧系列火山岩相似的特征,它们很可能是板片释放流体交代地幔楔形成的熔体并在后期经历MASH过程的产物。冈底斯带碰撞型含矿斑岩具有典型埃达克岩地球化学特征,指示其形成条件达到了石榴子石相变,可能形成于增厚的下地壳,其物质源区很可能与前期的洋壳俯冲有着密切的联系。普朗-雪鸡坪含矿斑岩具有与俯冲型含矿斑岩十分相似的地球化学特征,它们有可能是西向俯冲的甘孜-理塘洋发生断离,进而诱发前期俯冲流体交代的富集地幔楔发生部分熔融的产物,而并非是俯冲洋壳直接发生部分熔融的产物。     

Late Cretaceous magmatic activity in the southern Lhasa terrane: insights from the Dazhuqu hornblende gabbro and the Xietongmen granite porphyry

ABSTRACT

The mechanisms triggering the emplacement of Cretaceous magmatic rocks related to Neo-Tethyan subduction in the southern Lhasa subterrane (SLT) remain controversial because geochronological, geochemical, and isotopic data from the Cretaceous magmatic rocks in the western portion of the SLT are lacking. This paper provides the first report indicating that the Dazhuqu hornblende gabbro and Xietongmen granite porphyry were generated in the Late Cretaceous (ca. 100 Ma and ca. 68 Ma, respectively) in the western portion of the SLT. The Dazhuqu hornblende gabbro is characterized by high MgO, Na₂O, Cr, Co, and Mg^# values, enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs), and depletion in high field strength elements with no Eu anomalies. The Xietongmen granite porphyry displays high SiO₂, low MgO, Mg^#, Cr, Co, and Ni, enrichment in LREEs and LILEs, flat heavy rare earth element (HREE) patterns and negative Eu anomalies. Zircons from the Dazhuqu hornblende gabbro and Xietongmen granite porphyry display high positive ε_Hf(t) ranges from 11.79 to 14.91 and from 9.05 to 12.38, respectively. The Dazhuqu hornblende gabbro was produced by the partial melting of 12–15% garnet peridotite in the depleted mantle that was metasomatized by fluids released from the dehydrating subducted Neo-Tethyan oceanic slab. This magma was then emplaced at an upper crustal depth of 5.3–7.0 km. The Xietongmen granite porphyry was generated by the partial melting of underplated basaltic crust during the subduction of the Neo-Tethyan oceanic crust and formed in the presence of pyroxene, plagioclase, and minor hornblende in its magmatic source. In combination with previously published data from Cretaceous magmatic rocks in the SLT, our data suggest that the petrogenesis of the Dazhuqu hornblende gabbro was related to flat or low-angle slab subduction of the Neo-Tethyan oceanic crust during 109–97 Ma and that the formation of the Xietongmen granite porphyry was related to lithospheric delamination in the western portion of the SLT after ca. 68 Ma.     

冀东晚古生代东湾子岩体的岩石成因研究

冀东晚古生代东湾子岩体由角闪石岩、少量辉石岩和辉长岩组成.典型的堆晶结构、全岩和镁铁质矿物(透辉石、角闪石)的上凸型稀土分布模式、相容元素含量低且变化范围大(如:角闪石岩中V=296×10-6～673×10-6)的特征表明了岩体的堆晶成因.计算得到的与辉石岩中的透辉石相平衡的熔体具有很高的稀土含量,轻重稀土分馏较为明显,富集大离子亲石元素(如:Sr,Ba,K),亏损高场强元素(如:Nh,Zr,Ti),具有典型的弧岩浆特征.透辉石和角闪石的矿物成分也具有弧岩浆的特征.高钙透辉石、大量的角闪石与黑云母的存在说明母岩浆富水.透辉石在高PH2O的状态下与熔体反应,生成角闪石的结构特征也证明了这一点.结合岩体的球化学特征,认为岩浆来源于富集的含有角闪石的尖晶石橄榄岩的部分熔融,母岩浆具有富水的特征(>3%).考虑到岩体形成时代(～300Ma;Zhao et al.,2007)和地质背景,认为东湾子岩体与位于华北北缘的其它晚石炭-早二叠世的岩体形成于同一构造背景下,都是晚古生代时期古亚洲洋向华北板块之下俯冲的产物.     

俯冲带部分熔融

俯冲带是地幔对流环的下沉翼,是地球内部的重要物理与化学系统。俯冲带具有比周围地幔更低的温度,因此,一般认为俯冲板片并不会发生部分熔融,而是脱水导致上覆地幔楔发生部分熔融。但是,也有研究认为,在水化的洋壳俯冲过程中可以发生部分熔融。特别是在下列情况下,俯冲洋壳的部分熔融是俯冲带岩浆作用的重要方式。年轻的大洋岩石圈发生低角度缓慢俯冲时,洋壳物质可以发生饱和水或脱水熔融,基性岩部分熔融形成埃达克岩。太古代的俯冲带很可能具有与年轻大洋岩石圈俯冲带类似的热结构,俯冲的洋壳板片部分熔融可以形成英云闪长岩-奥长花岗岩-花岗闪长岩。平俯冲大洋高原中的基性岩可以发生部分熔融产生埃达克岩。扩张洋中脊俯冲可以导致板片窗边缘的洋壳部分熔融形成埃达克岩。与俯冲洋壳相比,俯冲的大陆地壳具有很低的水含量,较难发生部分熔融,但在超高压变质陆壳岩石的折返过程中可以经历广泛的脱水熔融。超高压变质岩在地幔深部熔融形成的熔体与地幔相互作用是碰撞造山带富钾岩浆岩的可能成因机制。碰撞造山带的加厚下地壳可经历长期的高温与高压变质和脱水熔融,形成S型花岗岩和埃达克质岩石。     

Geochemistry and Petrogenesis of the Tongshankou and Yinzu Adakitic Intrusive Rocks and the Associated Porphyry Copper-Molybdenum Mineralization in Southeast Hubei, East China

Abstract. The late Jurassic Tongshankou and Yinzu plutons in southeast Hubei have been investigated for their contrasting metal mineralization features. The former is closely associated with porphyry Cu‐Mo mineralization, while the latter is barren of metal mineralization, althouth both are located very close to each other. The Tongshankou granodiorite porphyries and the Yinzu granodiorites are geochemically similar to adakites, e.g., high Al₂O₃ and Sr contents and La/Yb and Sr/Y ratios, enriched in Na₂O, depleted in Y and Yb, very weak Eu anomalies and positive Sr anomalies. However, different geochemi‐cal characteristics exist between the two plutons: the Tongshankou adakitic rocks (1) are relatively enriched in SiO₂, K₂O, MgO, Cr, Ni, and Sr and depleted in Y and Yb; (2) have higher degree REE differentiation; (3) have positive Eu anomalies in contrast with very weak negative or unclear Eu anomalies in the Yinzu rocks; and (4) isotopically have relatively higher eP_Nd(t) values (‐5.19 to ‐5.38) and lower initial ⁸⁷Sr/⁸⁶Sr ratios (0.7060 to 0.7062), while the Yinzu adakitic rocks have relatively lower eP_Nd(t) values (‐7.22 to ‐8.67) and higher initial ⁸⁷Sr/⁸⁶Sr ratios (0.7065 to 0.7074). The trace element and isotopic data demonstrate that the Tongshankou adakitic rocks were most probably originated from partial melting of delaminated lower crust with garnet being the main residual mineral whereas little or no plagioclase in the source. On the contrary, the Yinzu adakitic rocks were likely derived from partial melting of thickened lower crust, with residual garnet and a small quantity of plagioclase and hornblende in the source. Interactions between the adakitic magmas and mantle peridotites possibly took place during the ascent of the Tongshankou adakitic magmas through the mantle, considering that MgO, Cr, and Ni contents and eP_Nd(t) values of the adakitic magmas were possibly elevated and initial ⁸⁷Sr/⁸⁶Sr ratios were possibly lowered due to the contamination of mantle peridotites. In addition, the Fe₂O₃ of the adakitic magmas was likely released into the mantle and the oxygen fugacities (?_o2) of the latter were obviously possibly raised, which made metallic sulfide in the mantle oxidized and the chalcophile elements such as Cu were incorporated into the adakitic magmas. The ascent of the adakitic magmas enriched in Cu and Mo will lead to the formation of porphyry Cu‐Mo deposit. Nevertheless, the Yinzu adakitic magmas were possibly lack of metallogenetic materials due to not interacting with mantle peridotite, and thus unfavorable to metal mineralization.     

Petrogenesis of Ore‐Related Granodiorite Porphyry in the Jiande Copper Deposit,SE China: Implications for the Tectonic Setting and Mineralization

Adakitic rocks and related Cu–Au mineralization are widespread along eastern Jiangnan Orogen in South China. Previous studies have mainly concentrated on those in the Dexing area in northeastern Jiangxi Province, but information is lacking on the genesis and setting of those in northwestern Zhejiang Province. The Jiande copper deposit is located in the suture zone between the Yangtze and Cathaysia blocks of South China. This paper presents systematic LA–ICP–MS zircon U–Pb dating and element and Sr–Nd–Hf isotopic data of the Jiande granodiorite porphyry. Zircon dating showed that the Jiande granodiorite porphyry was produced during the Middle Jurassic (ca. 161 Ma). The Jiande granodiorite porphyry is characterized by adakitic geochemical affinities with high Sr/Y and La_N/Yb_N ratios but low Y and Yb contents. The absence of a negative Eu anomaly, extreme depletion in Y and Yb, relatively low MgO contents, and relatively high ²⁰⁷Pb/²⁰⁴Pb ratios, indicated that the Jiande granodiorite porphyry was likely derived from partial melting of the thickened lower continental crust. In addition, the Jiande granodiorite porphyry shows arc magma geochemical features (e.g., Nb, Ta and Ti depletion), with bulk Earth‐like ε_Nd (t) values (?2.89 to ?1.92), ε_Hf (t) values (?0.6 to +2.8), and initial ⁸⁷Sr/⁸⁶Sr (0.7078 to 0.7105). However, a non‐arc setting in the Middle Jurassic is indicated by the absence of arc rocks and the presence of rifting‐related igneous rock associations in the interior of South China. Combined with the regional Neoproterozoic Jiangnan Orogeny, it indicates that these arc magma geochemical features are possibly inherited from the Neoproterozoic juvenile continental crust formed by the ancient oceanic crust subduction along the Jiangnan Orogen. The geodynamic environment that is responsible for the development of the Middle Jurassic Jiande granodiorite porphyry is likely a localized intra‐continental extensional environment along the NE‐trending Jiangshan‐Shaoxing Deep Fault as a tectonic response to far‐field stress at the margins of the rigid South China Plate during the early stage of the paleo‐Pacific plate subduction. In terms of Cu mineralization, we suggest that the metal Cu was released from the subducted oceanic slab and reserved in the juvenile crust during Neoproterozoic subduction along the eastern Jiangnan Orogen region. Partial melting of the Cu rich Neoproterozoic juvenile crust during the Middle Jurassic time in the Jiande area caused the formation of adakitic rocks and the Cu deposit.     

Geochronological and geochemical studies of adakites from Tethyan Belt,Western Pakistan: A clue to geodynamics and Cu-Au mineralization

ABSTRACT

Large porphyry Cu-Au deposits are associated with Early Miocene intrusive rocks in Tethyan belt, discovered along Chagai magmatic arc in Western Pakistan, adjacent to Southeast Iran. Two types of rocks were discriminated as granodiorite and monzodiorite from Saindak area. The granodiorites are associated with regional large Cu-Au mineralization, while the monzodiorites are mostly ore-barren. LA-ICP-MS U-Pb dating yielded weighted mean ²⁰⁶Pb/²³⁸U ages of 22.16–24.2 Ma for granodiorites and ca. 22.6 Ma for a monzodiorite. These intrusive rocks in the Saindak area are all calc-alkaline rocks, with enriched LILEs and depleted HFSEs, and without Eu negative anomalies. The felsic granodiorites are characterized by high Sr contents and Sr/Y ratios, with intermediate to high (La/Yb)_N ratios that identify them as typical high-silica adakites. In contrast, the basaltic-andesitic monzodiorites are just normal arc-related rocks, showing less fractionated REE patterns than the granodiorites, with systematically lower LREE and higher MREE and HREE. Low K₂O/Na₂O ratios and decoupled Sr/Y-(La/Yb)_N ratios indicate the characteristics of slab-derived adakites for the granodiorites, most likely originated through partial melting of the subducted Neotethys oceanic crust beneath Eurasian continent followed by subsequent mantle interaction. The almost simultaneously melting of subcontinental lithospheric mantle induced by dehydration of Neotethys plate gave rise to the formation of the barren monzodiorites. These intrusive rocks in the Saindak area are characterized by similar Sr-Nd-Pb isotopes with high ⁸⁷Sr/⁸⁶Sr_i ratios, slightly negative εNd(t) values and radiogenic Pb isotopes, plotting in the field between the MORB and EM-II mantle endmembers or the Average Cadomian Lower Crust, suggesting subducting sediments or old continental crustal materials have contributed into the compositions of these rocks by source enrichment or crustal contamination. The slab-melting derived adakite is favourable for regional massive Cu-Au mineralization in the Saindak area.     

The adakite connection of the Tuwu–Yandong copper porphyry belt, eastern Tianshan, NW China: trace element and Sr-Nd-Pb isotope geochemistry

The Tuwu–Yandong porphyry copper belt lies in the eastern Tianshan mountains, eastern section of the Central Asian orogenic belt. The copper mineralization is mainly hosted in plagiogranite porphyries intruded into early Carboniferous volcanic rocks of the Paleozoic Dananhu island arc between the Tarim and Siberian plates. The plagiogranite porphyries have contents of 65–73 wt% SiO₂, 14–17 wt% Al₂O₃, 0.9–2.2 wt% MgO, 3–16 ppm Y, 0.4–1.40 ppm Yb, 347–920 ppm Sr, and positive Eu anomalies. The rocks also exhibit positive ɛ _Nd(t) values (+5.0 to +9.4) and low initial ⁸⁷Sr/⁸⁶Sr values (0.70316–0.70378). Such features are similar to those of adakites derived from partial melting of a subduction-related oceanic slab. The mineralization age is early Carboniferous (350–320 Ma), which is close to that of the porphyries. The close relationship between the Cu mineralization and the porphyry is also indicated by their similar Sr-Nd-Pb isotopic compositions. We suggest that the copper porphyry (magma) system in the Dananhu island arc was formed by direct melting of an obliquely subducting early Carboniferous oceanic slab.     

中甸弧西斑岩带印支期中酸性侵入岩成因与成矿意义

位于义敦岛弧带南端的中甸弧广泛发育印支期中-酸性浅成-超浅成复式杂岩及与之有关的斑(玢)岩型矿床;在其西斑岩带内,主要分布有阿热、春都、雪鸡坪和烂泥塘等4个斑(玢)岩体。阿热岩体的特征与埃达克岩相似:SiO2>58.06%,平均58.64%,高Al2O3(14.77%~17.29%)、Sr(490×10-6~1409×10-6)、Sr/Y(37.44~83.79)和La/Yb(4.62~31.48,平均28.51)值,低Y(13.1×10-6~16.82×10-6)和Yb(1.20~1.61)值,δEu为0.90~1.02,REE球粒陨石配分曲线呈平滑的右倾形态,富集轻稀土,严重亏损重稀土,具较高的MgO(0.91%~3.77%)及Mg#(37.84~70.00)值,与其他含矿岩体特征基本一致。通过对主量和稀土及Sr元素研究对比表明,研究区岩石可能由于俯冲的甘孜—理塘洋壳发生断离,先后引发地幔楔及洋壳部分熔融,初始熔浆与地壳发生不同混染叠加并随区域性收缩沿现今格咱断裂东侧短时间内多次脉动侵位形成具岛弧岩石向埃达克质岩石过渡特征的线性串珠状岩体,其源区残留组合有石榴石+单斜辉石+角闪石,初始熔浆上侵过程中受到地壳不同程度的混染叠加可能是导致该带成矿差异性的原因之一。