中国西部雪冰中的黑碳及其辐射强迫

 在中国西部的青藏高原和新疆地区的若干条冰川区域采集雪和冰芯样品,分析了雪冰样品中的黑碳,并模拟了雪冰黑碳产生的辐射强迫。我国西部雪冰黑碳的平均浓度为63 ng/g,高于北半球其他地区的实测结果。影响雪样黑碳浓度空间分布格局的主因是周边的排放源。模拟结果显示,黑碳在中国西部冰川雪表的沉降产生的平均辐射强迫为（+4.0±2.0) W/m²。喜马拉雅山中段的东绒布冰芯记录揭示黑碳主要来源于南亚,经印度夏季风输送;1951年以来黑碳的平均浓度为16 ng/g,产生的月平均辐射强迫在2001年夏季超过了+4.5 W/m²。南亚排放的黑碳可能抵达青藏高原南部腹地,对青藏高原的冰川表面能量平衡有一定影响。     

近千年东亚季风变化统计动力反演与驱动机制研究

利用观测数据和非线性统计-动力学方法,构建了东亚季风变化的动力方程。量化了单因子强迫及各因子间相互作用在东亚季风演化中的相对贡献率,为东亚季风驱动机制研究提供了量化参考。研究发现:（1）过去千年东亚季风是多种因子共同作用下的复杂非线性动力系统。有些因子以起驱动作用为主,则有些以反馈调节作用为主,因子间交互作用与东亚季风演化存在耦合效应机制。（2）季风的驱动力主要来源于副热带太平洋海表温度、青藏高原动力热力强迫、CO₂和N₂O交叉项、太阳辐射和N₂O交叉项、CO₂与CH₄交叉项等的耦合作用机制;调节作用主要是石笋δ18O指代的地理位置、单因子CO₂浓度、太阳辐射变化、CH₄与N₂O交叉项、太阳辐射与ENSO交叉项等的耦合作用机制。温室气体（CO₂、CH₄与N₂O）浓度对东亚季风演化的驱动与调节作用贡献较大。（3）通过动力反演机制推论副热带太平洋和热带西太平洋对东亚季风均有驱动作用,但主要驱动力来自副热带太平洋,即驱动东亚季风变化的主源地在副热带太平洋海区,次源地在热带西太平洋海区。（4）由海-陆温差对季风演变贡献大小推测石笋δ18O指代的也主要是夏季风信息。      

喜马拉雅山南坡冬季暴雪对高原南部冰芯中稳定同位素记录的影响

聂拉木气象站降水中 δ18O的变化表明 ,夏季降水中 δ18O为一低值阶段 ;冬季降水中 δ18O总的来说为一高值阶段 ,但冬季暴风雪中δ18O的值和夏季强的季风活动中降水的δ18O一样很低。由于该地区冬季降水十分活跃 ,冬季降水中 δ18O的变化对该地区冰芯记录将产生重要的影响。首先是用δ18O的季节变化来对冰芯定年产生一定的困难 ,其次喜马拉雅山中段冰芯中的δ18O记录不仅包括了夏季季风活动的强弱信息 ,而且冬季强的暴风雪过程也记录在内。     

珠穆朗玛峰北坡冰川表面不同季节气象特征分析

在极端高海拔地区获取定点的气象观测资料对于研究山地冰川与气候变化的关系极为重要。2005年5月1日-7月22日（春末夏初）和2007年10月2日-2008年1月19日（秋冬）在珠峰地区海拔6560m的东绒布冰川积累区进行了包括气温、湿度、风向风速和气压在内的气象要素观测。对观测资料的分析表明,气温和湿度与附近较低海拔定日气象站的变化趋势基本一致,证明了在极端环境下获得的气象观测资料的合理性。春末夏初月平均气温从5月的-11．3℃上升到7月的-3．4℃,秋冬季月平均气温则从10月的-11．3℃下降到次年1月的-19．0℃。在春末夏初受印度季风影响,湿度呈持续增加趋势,月平均湿度混合比从5月的1．4g／kg增加到7月的5．4g／kg;而在西风环流控制下的秋冬季湿度呈缓慢降低,月平均湿度混合比从10月的1．4g／kg降低到次年1月的0．5g/kg。春末夏初主要以阴天为主,秋冬季则是晴天占据主导地位。西风环流控制时东绒布冰川盛行西北风,风速较大,极端最大风速可达35m／s。而受印度季风影响时东绒布冰川以南风为主,风速相对较小。     

南海-西北太平洋季风槽强度的变化特征及其与热带气旋活动的关系

利用1979—2005年NCEP/DOE AMIP-Ⅱ再分析逐日平均资料,根据西北太平洋季风槽的特点,研制了能较好表征季风槽活动的强度指数和位置指数,并分三段描述不同区域季风槽的活动特征及其对生成于南海-西北太平洋季风槽的热带气旋（MTTC）活动的影响,结果表明：（1） 季风槽强度指数和位置指数呈正相关关系,季风槽强度越强,其位置越偏北。（2） 季风槽强度存在明显的年际变化,1994年前以4～5年的变化周期较为显著,1994年后2～3年的周期较明显。（3） 不同区域季风槽强度的影响因子不同。前期海温场的异常将导致大气环流异常,致使不同区域的季风槽强度异常。（4） 季风槽强度与MTTC频数异常密切相关,3个不同区域的季风槽以南海季风槽强度与MTTC频数异常的关系最为密切。MTTC异常偏少年大多出现在季风槽总体偏弱,各区域季风槽也偏弱的年份;MTTC异常偏多年可能出现在季风槽偏强的年份,也可能出现在季风槽总体偏弱但南海季风槽偏强的年份,且后者出现的概率更大一些。（5） 季风槽强度的季节内变化能为TC的生成和发展提供有利条件,季风槽同时处于30～60天振荡和准双周10～20天振荡的活跃期时,有利于MTTC的生成。     

冰（雪）晶生长微物理过程的风洞实验研究

该文简要介绍了（１）风洞实验研究的科学意义及应用前景；（２）冰（雪）晶增长微物理实验的研究的概况；（３）新研制的冰（雪）晶增长小型垂直过冷云风洞及其测试系统；（４）主要实验研究结果，包括风洞实验模拟出的冰（雪）晶，含水量对冰（雪）晶增长的影响，风洞中冰（雪）晶的运动方式，初始晶胚特性及运用实验结果指导象灾害的预测及防治。     

2016—2017年中国中东部本底地区PM10化学特性

对中国中东部3个区域大气本底观测站2015年12月—2017年12月PM₁₀质量浓度及其化学成分空间分布与季节变化特征进行研究,结果显示:研究期间龙凤山站、临安站和金沙站平均PM₁₀质量浓度分别为57.5,62.2 μg·m-3和57.6 μg·m-3。其中临安站和金沙站2017年PM₁₀质量浓度较2016年有所下降,但龙凤山站有所上升。与2013年相比,临安站和金沙站平均PM₁₀质量浓度分别降低29.3%和26.2%。临安站SO₄2-,NO₃-和NH₄+平均质量浓度分别为9.9,8.2 μg·m-3和3.7 μg·m-3,金沙站分别为10.2,6.7 μg·m-3和2.6 μg·m-3,均高于龙凤山站的5.9,4.9 μg·m-3和2.1 μg·m-3,其中龙凤山站和临安站的NO₃-与SO₄2-质量浓度比值较高（0.9和0.8）,金沙站较低（0.6）。龙凤山站的有机碳（OC）和元素碳（EC）质量浓度分别为10.1 μg·m-3和2.7 μg·m-3,临安站为6.7 μg·m-3和3.1 μg·m-3,金沙站为4.7 μg·m-3和2.3 μg·m-3,即龙凤山站OC最高,金沙站最低,3个站点的EC基本相当,临安站略高。与2013年相比,研究期间临安站SO₄2-,NH₄+和OC分别下降38.1%,26.0%和55.6%,金沙站分别下降46.3%,51.9%和44.7%,但临安站和金沙站的NO₃-分别上升12.3%和15.5%;临安站EC下降27.9%,金沙站EC上升4.5%。3个站点夏季PM₁₀,NO₃-,EC质量浓度及NO₃-与SO₄2-质量浓度比值均最低。     

南海夏季风爆发与热带海洋海温和大气环流异常变化关系的研究

用合成和相关分析方法及SVD技术研究了南海夏季风爆发早、晚年份4～6月季风建立时期季风环流的异常及其与热带太平洋-印度洋海温的关系。结果表明,南海夏季风爆发与热带大气环流和海温变异密切相关。（1）当热带中、东太平洋—印度洋（主要在西南部）及南海海温低（高）,西太平洋—澳洲邻近海域海温高（低）时,南海夏季风爆发早（晚）。不同区域海温对季风的影响有明显的季节差异,印度洋主要为晚春至初夏（4～6月）,南海为5～6月,而热带太平洋从前冬一直持续到夏季。（2）不同的海温异常产生不同的季风环流型,南海夏季风爆发早、晚年大气环流的异常变化基本相反。南海夏季风的活动主要受印度季风环流变化的影响,与前期冬春季西太副高的强弱及位置变化密切相关。西太副高弱时,南海夏季风爆发早;反之,爆发晚。（3）热带太平洋—印度洋海温异常引起季风环流和Walker环流的异常变化可能是影响南海夏季风爆发早、晚的物理过程。     

中国南海夏季风强、弱年多尺度相互作用能量学特征

中国南海夏季风为东亚季风的主要系统之一,其具有多重尺度特征,除季节平均环流场外,低频（季节内振荡）和高频（天气尺度）扰动也十分活跃,各尺度系统存在明显的年际变化。该研究使用ERA-Interim和NCEP/NCAR两套再分析资料,从季风平均动能（MKE）诊断的角度出发,探讨了1979-2010年中国南海夏季风环流年际变化的能量来源及其和扰动场的相互作用过程。结果表明:中国南海夏季风对流活跃年份,中国南海南部（12°N以南）及中南半岛一带为季风平均动能显著增强区,此与南亚季风区西风急流的增强并向东延伸有关;中国南海北部（12°N以北）及西太平洋为气旋性环流盘踞,季风槽加深。中国南海南部季风平均动能增强的能量源自于扰动动量通量与平均环流的相互作用,强季风年,平均环流失去较少的动能给扰动场（亦即平均环流保留较多的动能）。通过进一步探讨高频（<10 d）及低频（10-90 d）扰动场与平均环流不同分量的（散度、涡度、风垂直切变）相互作用过程,发现季风平均动能的增长主要来自于<10 d扰动与季风平均散度和涡度的相互作用。中国南海北部季风槽区季风平均动能的维持来自于大气热源和平均上升运动的相互作用,但同时有较多的季风平均动能向扰动动能转换,有利于扰动的成长。因此,强季风年,中国南海北部热带气旋生成数目增多,夏季北传的季节内振荡也增强,导致中国南部沿海及华南地区出现较多的灾害天气。      

保定市大气颗粒物中含碳组分粒径分布

北京-天津-河北地区工业城市保定大气颗粒物(Particulate matter,PM)污染严重,保定大气颗粒物尤其是细粒子和超细粒子污染严重,其中含碳组分具有重大贡献,PM1.1、PM2.1和PM2.1-9.0中含碳气溶胶总量(total carbonaceous aerosols,TCA)分别占到(49±20)%、(45±19)%和(19±7)%。PM9.0中的含碳气溶胶主要富集在PM2.1乃至PM1.1中。颗粒物浓度谱分布及含碳气溶胶富集量呈显著季节变化,由于采暖过程秋冬季各粒径段有机碳(organic carbon,OC)和元素碳(elemental carbon,EC)的浓度均增加,秋、冬季节细颗粒物中OC浓度可高达44.0±38.3、78.5±30.2μg m-3,EC浓度分别为3.5±1.6、8.5±6.8μg m-3。各个季节OC和EC在总悬浮颗粒物(total suspended particulate,TSP)中的几何平均直径(geometric mean diameter,GMD)均集中在较小粒径段。粗颗粒物中OC的GMD在春夏季较高,秋季减少,而冬季最低。而粗颗粒物中EC的GMD则是冬季最高,夏季最低。保定0.4μm的颗粒物中OC/EC比值4个季节的水平较为稳定,春、夏、秋、冬季OC/EC比值分别为5.2、3.5、4.1和5.4,来源主要为交通和燃煤。其余几个粒径段的颗粒物的来源更为复杂,其来源主要为燃煤、木材和生物质。     

Carbonaceous and inorganic species in PM<Subscript>10</Subscript> during wintertime over Giridih,Jharkhand (India)

Ambient concentrations of organic carbon (OC), elemental carbon (EC) and water soluble inorganic ionic components (WSIC) of PM₁₀ were studied at Giridih, Jharkhand, a sub-urban site near the Indo Gangatic Plain (IGP) of India during two consecutive winter seasons (November 2011–February 2012 and November 2012–February 2013). The abundance of carbonaceous and water soluble inorganic species of PM₁₀ was recorded at the study site of Giridih. During winter 2011–12, the average concentrations of PM₁₀, OC, EC and WSIC were 180.2?±?46.4; 37.2?±?6.2; 15.2?±?5.4 and 18.0?±?5.1 μg m^?3, respectively. Similar concentrations of PM₁₀, OC, EC and WSIC were also recorded during winter 2012–13. In the present case, a positive linear trend is observed between OC and EC at sampling site of Giridih indicates the coal burning, as well as dispersed coal powder and vehicular emissions may be the source of carbonaceous aerosols. The principal components analysis (PCA) also identifies the contribution of coal burning? +?soil dust, vehicular emissions?+?biomass burning and seconday aerosol to PM₁₀ mass concentration at the study site. Backward trajectoy and potential source contributing function (PSCF) analysis indicated that the aerosols being transported to Giridih from upwind IGP (Punjab, Haryana, Uttar Pradesh and Bihar) and surrounding region.     

Seasonal characteristics and sources of carbonaceous components and elements of PM10 (2010–2019) in Delhi,India

In this study we present the seasonal chemical characteristics and potential sources of PM₁₀ at an urban location of Delhi, India during 2010?2019. The concentrations of carbonaceous aerosols [organic carbon (OC), elemental carbon (EC), water soluble organic carbon (WSOC) and water insoluble organic carbon (WIOC)] and elements (Al, Fe, Ti, Cu, Zn, Mn, Pb, Cr, F, Cl, Br, P, S, K, As, Na, Mg, Ca, B, Ni, Mo, V, Sr, Zr and Rb) in PM₁₀ were estimated to explore their possible sources. The annual average concentration (2010–2019) of PM₁₀ was computed as 227?±?97 µg m^?3 with a range of 34?734 µg m^?3. The total carbonaceous aerosols in PM₁₀ was accounted for 22.5% of PM₁₀ mass concentration, whereas elements contribution to PM₁₀ was estimated to be 17% of PM₁₀. The statistical analysis of OC vs. EC and OC vs. WSOC of PM₁₀ reveals their common sources (biomass burning and/or fossil fuel combustion) during all the seasons. Enrichment factors (EFs) of the elements and the relationship of Al with other crustal metals (Fe, Ca, Mg and Ti) of PM₁₀ indicates the abundance of mineral dust over Delhi. Principal component analysis (PCA) extracted the five major sources [industrial emission (IE), biomass burning?+?fossil fuel combustion (BB?+?FFC), soil dust, vehicular emissions (VE) and sodium and magnesium salts (SMS)] of PM₁₀ in Delhi, India. Back trajectory and cluster analysis of airmass parcel indicate that the pollutants approaching to Delhi are mainly from Pakistan, IGP region, Arabian Sea and Bay of Bengal.

     

太原冬季PM2.5中有机碳和元素碳的变化特征

2005年12月—2006年2月在太原市区持续观测了气溶胶细粒子PM_2.5, 并应用Sunset碳分析仪进行了有机碳 (organic carbon, OC) 和元素碳 (elemental carbon, EC) 的测定。结果表明:太原冬季PM_2.5, OC和EC浓度均较高, 其中PM_2.5日平均浓度变化范围为25.4~419.0 μg/m3, 日平均浓度为193.4±102.3 μg/m3, OC平均浓度为28.9±14.8 μg/m3, EC平均浓度为4.8±2.2 μg/m3, OC/EC平均比值是7.0±3.9, 即太原市冬季PM_2.5和碳气溶胶污染严重。OC在PM _2.5中占18.6%, EC占2.9%, 这表明碳气溶胶是太原大气细粒子污染控制的关键组分。在太原市冬季, 采暖燃烧的煤是OC和EC的主要贡献源, 造成OC大大高于EC, 从而使OC/EC比值增大。各种气象条件对PM_2.5, OC, EC和OC/EC比值的变化都有不同程度的影响, 特别是大雾天气、相对湿度、风速和降雪是影响碳气溶胶浓度变化的重要因素。     

Chemical composition of PM2.5 at an urban site of Chengdu in southwestern China

PM2.5 aerosols were sampled in urban Chengdu from April 2009 to January 2010, and their chemical compositions were characterized in detail for elements, water soluble inorganic ions, and carbonaceous matter. The annual average of PM2.5 was 165g m－3, which is generally higher than measurements in other Chinese cities, suggesting serious particulate pollution issues in the city. Water soluble ions contributed 43.5% to the annual total PM2.5 mass, carbonaceous aerosols including elemental carbon and organic carbon contributed 32.0%, and trace elements contributed 13.8%. Distinct daily and seasonal variations were observed in the mass concentrations of PM2.5 and its components, reflecting the seasonal variations of different anthropogenic and natural sources. Weakly acidic to neutral particles were found for PM2.5. Major sources of PM2.5 identified from source apportionment analysis included coal combustion, traffic exhaust, biomass burning, soil dust, and construction dust emissions. The low nitrate: sulfate ratio suggested that stationary emissions were more important than vehicle emissions. The reconstructed masses of ammonium sulfate, ammonium nitrate, particulate carbonaceous matter, and fine soil accounted for 79% of the total measured PM2.5 mass; they also accounted for 92% of the total measured particle scattering.     

泰山PM10及其中化学成分变化特征

为研究华北平原区域背景气溶胶成分及其变化特征,2010年6月至2011年7月在泰山顶采集了64个PM10滤膜样品,分析了样品的PM10及其中无机盐离子和有机碳（OC）、元素碳（EC）的质量浓度,并对各成分相关性等进行了分析。泰山PM10年均质量浓度约为68.4 mg/m³,其中无机盐离子约占总质量的64.8%,碳气溶胶约占17.4%。无机盐离子的质量浓度从春季逐渐增大,夏季达到峰值,秋季下降,冬季最小;OC质量浓度从春季至秋季逐渐增高,冬季最低,EC变化类似,但夏秋两季差别不大。二次有机碳（SOC）与OC的比值四季均在50%以上,年均值约为58.5%。通过后向轨迹聚类分析发现,在经过城市的较短轨迹以及南方较短混合轨迹的影响下,泰山PM10质量浓度较高,而西北长距离传输气团PM10浓度均较低。     

Chemical Characteristics of Carbonaceous Aerosols During Dust Storms over Xi'an in China

Characterization of carbonaceous aerosols including CC （carbonate carbon）, OC （organic carbon）, and EC （elemental carbon） were investigated at Xi＇an, China, near Asian dust source regions in spring 2002. OC varied between 8.2 and 63.7μgm^- 3, while EC ranged between 2.4 and 17.2 μ m^-3 during the observation period. OC variations followed a similar pattern to EC and the correlation coefficient between OC and EC is 0.89 （n=31）. The average percentage of total carbon （TC, sum of CC, OC, and EC） in PM2.5 during dust storm （DS） events was 13.6%, which is lower than that during non-dust storm （NDS） periods （22.7%）. CC, OC, and EC accounted for 12.9%, 70.7%, and 16.4% of TC during DS events, respectively. The average ratio of OC/EC was 5.0 in DS events and 3.3 in NDS periods. The OC-EC correlation （R^2=0.76, n=6） was good in DS events, while it was stronger （R^2=0.90, n=25） in NDS periods. The percentage of watersoluble OC （WSOC） in TC accounted for 15.7%, and varied between 13.3% and 22.3% during DS events. The distribution of eight carbon fractions indicated that local emissions such as motor vehicle exhaust were the dominant contributors to carbonaceous particles. During DS events, soil dust dominated the chemical composition, contributing 69% to the PM2.5 mass, followed by organic matter （12.8%）, sulfate （4%）, EC （2.2%）, and chloride （1.6%）. Consequently, CC was mainly entrained by Asian dust. However, even in the atmosphere near Asian dust source regions, OC and EC in atmospheric dust were controlled by local emission rather titan the transport of Asian dust.     

Chemical composition of the background aerosol at two sites in southwestern and northwestern China: potential influences of regional transport

Concentrations of organic carbon (OC), elemental carbon (EC), selected trace elements and water-soluble (WS) ions were determined for samples collected from August 2004 to February 2005 to assess the aerosol background at two remote sites in China. The OC and EC concentrations in PM₁₀ from near the Tibetan Plateau at Zhuzhang (ZUZ) were comparable with other background sites, averaging 3.1 and 0.34 μg m⁻³, respectively, with no pronounced seasonality. At Akdala (AKD) on northern margin of the Zhungaer Basin, the average concentrations were similar (mean OC = 2.9 μg m⁻³ and EC = 0.35 μg m⁻³), but the concentrations were higher in winter. The aerosol mass at both sites was dominated by OC and SO₄²⁻, but a stronger contribution from soil dust was observed at AKD. At ZUZ, NO₃⁻ showed a unique weather-related fluctuation in PM₁₀ with a periodicity of ∼1 week. Anthropogenic sources in the Sichuan Basin and southeastern Yunnan Province evidently influence ZUZ in summer and autumn while pollutants from Russia and the China–Mongolia border affect AKD nearly all year. The identification of these upwind sources demonstrates that transboundary transport needs to be taken into account when assessing air quality in remote parts of China.     

北京乡村地区分粒径气溶胶OC及EC分析

利用北京上甸子区域大气本底站2004年观测的分粒径大气气溶胶资料,分析了气溶胶中有机碳 (OC) 及元素碳 (EC) 的质量浓度水平、季节变化、尺度分布特征、OC与EC比值及其相关性。结果显示:上甸子站总悬浮颗粒物 (TSP) 中OC平均质量浓度为7.5~31.5 μg·m-3,EC质量浓度为1.4~6.6 μg·m-3;PM_2.1(粒径小于2.1 μm) 中OC质量浓度为4.0~19.1 μg·m-3,EC质量浓度大约为0.8~4.3 μg·m-3。冬季OC及EC质量浓度明显高于其他季节,其中冬、夏、秋季OC及EC峰值粒径出现为0.65~2.1 μm,但在春季峰值粒径移至2.1~4.7 μm。观测期间,OC与EC质量浓度比值平均为4~6,该比值略高于文献报道的我国一些城市地区的观测结果。     

Seasonal and annual trends of carbonaceous species of PM<Subscript>10</Subscript> over a megacity Delhi,India during 2010–2017

PM₁₀ samples were collected to characterize the seasonal and annual trends of carbonaceous content in PM₁₀ at an urban site of megacity Delhi, India from January 2010 to December 2017. Organic carbon (OC) and elemental carbon (EC) concentrations were quantified by thermal-optical transmission (TOT) method of PM₁₀ samples collected at Delhi. The average concentrations of PM₁₀, OC, EC and TCA (total carbonaceous aerosol) were 222?±?87 (range: 48.2–583.8 μg m^?3), 25.6?±?14.0 (range: 4.2–82.5 μg m^?3), 8.7?±?5.8 (range: 0.8–35.6 μg m^?3) and 54.7?±?30.6 μg m^?3 (range: 8.4–175.2 μg m^?3), respectively during entire sampling period. The average secondary organic carbon (SOC) concentration ranged from 2.5–9.1 μg m^?3 in PM₁₀, accounting from 14 to 28% of total OC mass concentration of PM₁₀. Significant seasonal variations were recorded in concentrations of PM₁₀, OC, EC and TCA with maxima during winter and minima during monsoon seasons. In the present study, the positive linear trend between OC and EC were recorded during winter (R²?=?0.53), summer (R²?=?0.59) and monsoon (R²?=?0.78) seasons. This behaviour suggests the contribution of similar sources and common atmospheric processes in both the fractions. OC/EC weight ratio suggested that vehicular emissions, fossil fuel combustion and biomass burning could be the major sources of carbonaceous aerosols of PM₁₀ at the megacity Delhi, India. Trajectory analysis indicates that the air mass approches to the sampling site is mainly from Indo Gangetic plain (IGP) region (Uttar Pradesh, Haryana and Punjab etc.), Thar desert, Afghanistan, Pakistan and surrounding areas.