On the attenuation of direct solar irradiance in Athens due to aerosols

Summary In this study the trend of the time sequence of the integral aerosol optical depth (k _a), as proposed by Unsworth and Monteith, was determined for clear days in summer for the period 1962–1988 in Athens. The trend was found by fitting a third degree polynomial curve and it was concluded that (k _a) showed a considerable increase (i.e. from the value of 0.18 to 0.31) in the period 1962–1976 and remained approximately constant until 1979, after which it started decreasing again slowly until 1988. The increase of (k _a) in the period 1962–1976 is likely attributable to the rapid development of the city in this period, while the decrease of (k _a) after 1979 probably reflects the efficiency of some restrictions which were imposed on the pollutant emissions during this period. In addition, an analysis of the percentage frequency distribution found that while 95% of the values of (k _a) ranged from 0.100 to 0.400 in the beginning of the period (1964–1967), in recent years (1984–1987) the same percentage of the values of (k _a) ranged from 0.100 to 0.500.With 3 Figures     

The behaviour of aerosol optical depth during clear summer days in Athens,Greece

Summary The integral aerosol optical depths (k ) at the hour of 08:20 Local Standard Time (LST), are compared with those calculated previously at 11:20 and 14:20 LST, for clear days during summer in Athens over the period 1962–1988. The mean values at 08:20 LST were consistently lower than the values at 11:20 and 14:20 LST. The influence of the vertical wind profile on the values ofk was also investigated. A comparison was made of the wind profiles at 02:00 and 14:00 LST, for days in which the 11:20 and 14:20 LST values ofk were 0.200 andk 0.350, respectively. The corresponding bulk wind shear s was also found for the period 1980–1988. The most significant results occurred with the first category of days. The resultant wind velocities from the surface to the 900 hPa level, in each hour were higher by 2–4 m·s^–1 with respect to the corresponding values for the second category. At 02:00 LST the bulk wind shear showed a considerable difference (1.8) between the two categories of days in the surface to 700 hPa layer at 02:00 LST. Finally, the associated weather conditions that appear to initiate a period of low values ofk (k 0.200) at 11:20 and 14:20 LST were examined for the period 1980–1988. Fifteen such cases were identified and it was found that they all occurred after the passage of weak cold fronts.With 6 Figures     

Aerosol optical properties during Asian dust storm episodes in South Korea

Summary ¶Aerosol optical depth (_a) is the most comprehensive variable to characterize aerosol, assess atmospheric pollution and make atmospheric corrections to satellite remotely sensed data from ground-based instruments. The aerosol optical properties in Korea peninsula observed at both Kwangju and Anmoyondo during the Asian dust period (March–May) have been presented in this study. Aerosol optical depths at all wavelengths showed a sharp increase during major dust outbreak in spring when compared with the average for the season. For example at Kwangju, aerosol optical depths increase from the spring average value of 0.43±0.02 at 501nm to values >0.70 during major dust event days in 1999 and 2001. Daily mean Ångström exponents () computed at both sites show dramatic changes from high values to low values on dust day periods with a sharp increase in the single scattering albedo. The study also revealed that the observed direct normal solar irradiance and diffuse horizontal irradiance during days with increased dust pollution levels is capable of reducing direct solar radiation by as much as 28% and a corresponding increase of 14% in diffuse solar irradiance during cloudless and windless days.     

In-situ measurements of the aerosol size distributions,physicochemistry and light absorption properties of Arctic haze

Thermal and optical techniques were used at Barrow, Alaska during AGASP II (3/20/86–4/7/86) to measure in-situ variability of major aerosol components present in Arctic Haze. The experiment provided continuous data on the concentration, size distribution and relative proportions of sulfate species and refractory aerosol for particle diameters of 0.15 to 5 m. Filter samples were also taken for determination of aerosol optical absorption due to soot (EC-elemental carbon). Although pronounced haze events were absence during this period the haze aerosol present varied in concentration between 2 and 6 g/m³ but showed little change in relative constituents. Apart from local influences, the optical data indicated a persistent fine-mode sulfate aerosol with a NH₄ ⁺/SO₄ ^– molar ratio of about 0.4 and a refractory component of somewhat less than 10% by mass. A preliminary comparison of soot estimates determined from the light absorption data with the size distributions of refractory aerosol observed independently by the optical particle counter showed good agreement during the sample period. In the absence of local pollution, values of single scatter albedo derived from light scattering and light absorption showed similar variation about the average value of 0.86 found by us during flights north of Barrow three years earlier during AGASP I.     

Measurements of the spectral aerosol optical depth using a sun photometer

Summary A sun photometer fitted with 9 narrowband interference filters from 368 nm to 1024 nm was used to determine the aerosol optical depth at 8 measuring stations in Europe. Of the 9 filters, 4 were not included in the standard equipment of the sun photometer. Given the temporal instabilities of the calibration factors of these 4 filters, meaningful results for the aerosol optical depth can be achieved only if calibration and measurements follow each other closely. Calibration was performed using the Langley plot method. For wavelengths < 500 nm, the measured aerosol optical depths were compared with the results of a high resolution spectrometer. Broadband aerosol optical depths, centred at 427 nm, were determined with an actinometer and were also used for comparison. Generally, there was good agreement of the results. To characterize the aerosol optical depths, the Ångström parameters and were used. The individual measuring stations showed a clustered distribution of and values.With 6 Figures     

Measurements of solar radiation and estimation of optical depth in the high Andes of Peru

Summary During an expedition to the high Andes of Southern Peru in June–July 1977, measurements of direct solar radiation in four spectral bands (0.270–0.530–0.630–0.695–2.900 ) were conducted at six sites in elevations ranging from sea level to 5645 m. These measurements were evaluated in Langley plots to determine total optical depths () and irradiances at the top of the atmosphere. In addition, water vapor optical depths (_wv) were calculated from the mean radiosounding over Lima during the expedition, and Rayleigh (_ray) and ozone (_oz) optical depths were obtained from published tabulations. Subtracting _ray, _oz, and _wv from yielded estimates of aerosol optical depth _aer. The components _ray and _oz decrease from the shorter towards the longer wavelength bands and from the lower towards the higher elevation sites; _aer also decreases towards the higher elevations. Particularly pronounced is the decrease of _aer and from the lowlands of the Pacific coast to the highlands of the interior, reflecting the effect of a persistent lower-tropospheric inversion and the contrast from the marine boundary layer to the clear atmosphere of the high Andes.With 4 Figures     

Spectral distribution of solar radiation in Athens

Summary A 25-year (1966–1990) record of measurements of the broadband direct solar irradiances performed in Athens, has been utilized to determine the radiant energy distribution in several spectral bands. Using these data the year-to-year trend of the time sequences of the mean values of the irradiation ratios in the various spectral intervals, viz. blue, green/orange, red, and photosynthetically active radiation (PAR) and the total direct irradiance for the whole spectrum, are evaluated.From this trend the following can be concluded: the blue spectral band (0.380–0.525 m) decreased from the beginning of the examined period until the mid-seventies and then increased gradually; the red band (0.630–0.710 m) shows similar trend but opposite in sense. The PAR band (0.380–0.710 m) decreased slightly until 1985 and then increases. In the green/orange band (0.525–0.630 m) the trend can be considered as nearly constant throughout the examined period. This trend of the irradiation ratios is related to the aerosol and gaseous pollutant content of the atmosphere, which probably reflects the urbanization, industrialization and heavy traffic conditions of the Athens area, during the last three decades.With 2 Figures     

Airborne and lidar measurements of aerosol and cloud particles in the troposphere over Alert Canada in April 1986

As a component of the Canadian Arctic Haze Study, held coincident with the second Arctic Gas and Aerosol Sampling Program (AGASP II), vertical profiles of aerosol size distribution (0.17 m), light scattering parameters and cloud particle concentrations were obtained with an instrumented aircraft and ground-based lidar system during April 1986 at Alert. Northwest Territories. Average aerosol number concentrations range from about 200 cm^–3 over the Arctic ice cap to about 100 cm^–3 at 6 km. The aerosol size spectrum is virtually free of giant or coarse aerosol particles, and does not vary significantly with altitude. Most of the aerosol volume is concentrated in the 0.17–0.50 m size range, and the aerosol number concentration is found to be a good surrogate for the SO₄ ⁼ concentration of the Arctic haze aerosol. Comparison of the aircraft and lidar data show that, when iced crystal scattering is excluded, the aerosol light scattering coefficient and the lidar backscattering coefficient are proportional to the Arctic haze aerosol concentration. Ratios of scattering to backscattering, scattering to aerosol number concentration, and backscattering to aerosol number concentration are 15.3 steradians, 1.1×10^–13 m², and 4.8×10^–15 m² sr^–1, respectively. Aerosol scattering coefficients calculated from the measured size distributions using Mie scattering agree well with measured values. The calculations indicate the aerosol absorption optical depth over 6 km to range between 0.011 and 0.018. The presence of small numbers of ice crystals (10–20 crystals 1^–1 measured) increased light scattering by over a factor of ten.     

A study of aerosol particle sizes in the atmosphere of Athens, Greece, retrieved from solar spectral measurements

This work aims at determining the aerosol particle radii in the atmosphere of Athens. Such a work is carried out in Athens for the first time. For this purpose, solar spectral direct-beam irradiance measurements were used in the spectral range 310–575 nm. To estimate the particle radius from aerosol optical depth retrieval, a minimization technique was employed based on the golden-section search of the difference between experimental and theoretical values of the aerosol optical depth. The necessary Mie computations were performed based on the algorithm LVEC.In this study, the mean particle radius of a given distribution was calculated every 30 min during cloudless days in the period November 1996 to September 1997. The largest particles were observed in the summer and the smallest during winter. The result was verified by the increased values of the aerosol optical depth and the turbidity factors calculated in the summer. The differences in the diurnal variation from season to season are attributed to the prevailing wind regime, pollutant emission and sink rates in the atmosphere of Athens.     

Analysis and trends of atmospheric turbidity parameters over Cairo

Summary This work deals with the Linke turbidity factor, based on total spectrum observations of the direct solar beam and aerosol turbidity parametersa _a , , and based on observations in broad spectral bands. Diurnal and seasonal variations of these turbidity parameters were analyzed for the period 1975 to 1991.Annual variations of these parameters show low values in winter and high values in both spring and summer. The extinction coefficients decrease with increase of both wavelength and optical airmass. Trend analysis shows an increase in aerosol extinction coefficient below 0.63 m, and a slight decrease for longer wave-lengths.Linear regression relations are also constructed to estimate botha _a and whenT _L is available. The relations show thata _a can be estimated with errors below 20%. The relation with the parameter, may give better results when it is estimated by assigning a fixed value of .Nomenclature AV Monthly and total average of the measured parameter - a Atmospheric optical thicknes - a _a Aerosol optical thickness - a _r Mean value of optical thickness of. Rayleigh atmosphere over all wavelengths - a _o Ozone optical thickness - a _o Ozone absorption coefficient - a _w Water vapor optical thickness - COR Correlation coefficient of the linear relation in percentage - Ex₁, Ex₂, Ex₃ Aerosol extinction coefficients in the bands .2–.53, .53–.63, .63–.695, respectively - I _(o) Normal incident direct solar radiation, under clear sky condition - I _o Extraterrestrial insolation at normal incidence - m _r Relative (optical) air mass - NO Number of the observations used in either making the relation or the verification - RMSE Root mean square error of the linear relation - RMSE% Percentage value of the root mean square error relative to the average measured value AV - T _L Linke turbidity factor - T Dry bulb temperature in °C - u _o Ozone layer thickness, cm - Z Zenith angle - Ångström wavelength exponent - Ångström turbidity coefficient - Wavelength - Y The year number after 1975 With 5 Figures     

Interpretation of Mauna Loa atmospheric transmission relative to aerosols,using photometric precipitable water amouts

Precipitable water measurements made coincident in time and space with direct broadband solar irradiance measurements are used in conjunction with an atmospheric transmission model to derive a parameter whose major dependence is on total aerosol extinction. Irradiance measurements are used to calculate an atmospheric transmission factor (ATF) that is independent of the instrument calibration and the extraterrestrial solar constant. The dependency of the ATF on precipitable water is determined using LOWTRAN5, an atmospheric transmission model with high spectral resolution. Precipitable water measurements are then used to adjust the measured ATF to correspond to an ATF value obtained for a constant precipitable water amount. The remaining variability in the adjusted ATF is due mostly to aerosol extinction. The technique is applied to a 6-year period (1978–1983) for clear-sky mornings at Mauna Loa, Hawaii (MLO). MLO ATF aerosol residuals are compared with independently measured monochromatic aerosol optical depth. Results show that the ATF aerosol residual is nearly equal to the 500 nm aerosol optical depth prior to the eruption of E1 Chichon, at which time a nonlinear time-dependent relationship between the two quantities is evident. ATF aerosol residuals reflect the spectrally integrated aerosol influence on transmission and, therefore, could indicate better than monochromatic optical depth the radiation balance perturbations due to aerosols. The 6-year precipitable water record for MLO, determined from a dual-channel sunphotometer, has a mean value of 0.3 cm. An annual cycle in precipitable water is evident, as is a 4-month 5-standard-deviation drought from December 1982 through March 1983.     

Surface aerosol measurements at Barrow during AGASP-II

Measurements at Barrow during the second Arctic Gas and Aerosol Sampling Program (AGASP-II), conducted in April 1986, showed no rapid long-range transport from lower-latitude source regions to Barrow, and only limited vertical transport from above the boundary layer to the surface. New aerosol size distribution measurements in the 0.005–0.1 m diameter size range using a Nuclepore-filter diffusion battery apparatus showed a median diameter of about 0.01 m during times of high condensation nucleus (CN) concentrations. Aerosol black carbon concentrations exceeding 400 ng m^–3 were detected at the surface and were more strongly correlated with CN concentrations than with aerosol scattering extinction (_sp), suggesting that aerosol carbon was generally associated with small particles rather than large particles. Measurements at Barrow during AGASP-I, conducted in March–April 1983, showed a series of aerosol events detected at the ground that were caused by rapid long-range transport paths to the vicinity of Barrow from Eurasia. These events were strongly correlated with aerosol loading in the vertical column (optical depth).     

Microwave vegetation optical depth and inverse modelling of soil emissivity using Nimbus/SMMR satellite observations

Summary A radiative transfer model has been used to determine the large scale effective 6.6 GHz and 37 GHz optical depths of the vegetation cover. Knowledge of the vegetation optical depth is important for satellite-based large scale soil moisture monitoring using microwave radiometry. The study is based on actual observed large scale surface soil moisture data and observed dual polarization 6.6 and 37 GHz Nimbus/SMMR brightness temperatures over a 3-year period. The derived optical depths have been compared with microwave polarization differences and polarization ratios in both frequencies and with Normalized Difference Vegetation Index (NDVI) values from NOAA/AVHRR. A synergistic approach to derive surface soil emissivity from satellite observed brightness temperatures by inverse modelling is described. This approach improves the relationship between satellite derived surface emissivity and large scale top soil moisture fromR ²=0.45 (no correction for vegetation) toR ²=0.72 (after correction for vegetation). This study also confirms the relationship between the microwave-based MPDI and NDVI earlier described and explained in the literature.List of Symbols f frequency [Hz] - f _i(p) fractional absorption at polarizationp - h surface roughness - h h cos² - H horizontal polarization - n _i complex index of refraction - p polarization (H orV) - R _s microwave surface reflectivity - T _B(p) brightness temperature at polarizationp - T ^* normalized brightness temperature - T polarization difference (T _v-T _H) - T _s temperature of soil surface - T _c temperature of canopy - T _max daily maximum air temperature - T _min daily minimum air temperature - V vertical polarization - soil moisture distribution factor; also used for the constant to partition the influence of bound and free water components to the dielectric constant of the mixture - empirical complex constant related to soil texture - microwave transmissivity of vegetation (=e ^–) - ^* effective transmissivity of vegetation (assuming =0) - microwave emissivity - _s emissivity of smooth soil surface - _rs emissivity of rough soil surface - _vs emissivity of vegetated surface - soil moisture content (% vol.) - K dielectric constant [F·m^–1] - K _fw dielectric constant of free water [F·m^–1] - K _ss dielectric constant of soil solids [F·m^–1] - K _m dielectric constant of mixture [F·m^–1] - K _o permittivity of free space [8.854·10^–12 F·m^–1] - high frequency limit ofK _wf [F·m^–1] - wavelength [m] - incidence angle [degrees from nadir] - polarization ratio (T _H/T _V) - b soil bulk density [gr·cm^–3] - s soil particle density [gr·cm^–3] - R surface reflectivity in red portion of spectrum - NIR surface reflectivity in near infrared portion of spectrum - _eff effective conductivity of soil extract [mS·cm^–1] - vegetation optical depth - _6.6 vegetation optical depth at 6.6 GHz - ₃₇ vegetation optical depth at 37 GHz - ^* effective vegetation optical depth (assuming =0) - single scattering albedo of vegetation With 12 Figures     

Anthropogenic aerosols and gases in the lower troposphere at Alert Canada in April 1986

During April 1986, as part of an international arctic air chemistry study (AGASP-2), ground level observations of aerosol trace elements, oxides of sulphur and nitrogen and particle number size distribution were made at Alert Canada (82.5N, 62.3W). Pollution haze was evident as indicated by daily aerosol number (size > 0.15 m diameter) and SO₄ ⁼ concentrations in the range 125 – 260 cm^–3 and 1.6 – 4.5 g m^–3, respectively. Haze and associated acidic gases tended to increase throughout the period. SO₂ and peroxyacetylnitrate (PAN) mixing ratios were in the range 140 – 480 and 370 – 590 ppt(v), respectively. About 88% of the total end-product nitrogen was in the form of PAN. In air dried to 2% relative humidity by warming to room temperature, the aerosol mass size distribution had a major mode at 0.3 m diameter and a minor one at 2.5 m. Aerosol mass below 1.5 m was well correlated with SO₄ ⁼, K⁺ and PAN. There was a steady increase in the oxidized fraction of total airborne sulphur and nitrogen oxide throughout April as the sun rose above the horizon and remained above. The mean oxidation rate of SO₂ between Eurasia and Alert was estimated as 0.25 – 0.5% h^–1. The molar ratio of total nitrogen oxide to total sulphur oxide in the arctic atmosphere (0.67±0.17) was comparable to that in European emissions. A remarkably strong inverse correlation of filterable Br and O₃ led to the conclusion that O₃ destruction and filterable Br production below the Arctic surface radiation inversion is associated with tropospheric photochemical reactions involving naturally occurring gaseous bromine compounds.     

A calculation of global radiation in The Netherlands with the aid of the relative duration of sunshine

Summary A.Ångström has assumed a linear relation between daily totals of the global radiation measured at a certain place and the corresponding daily values of the relative duration of sunshine. Other authors have applied the same relationhip, however, with a different unit of time, such as a 5-day period, a 10-day period and a month. In this paper a period of one hour is chosen as unit.Ångström's Q ₀ ^– and -values have been determined for De Bilt and for the one-hour periods L. A. T. of the mean day in each of the 60 months of the 5-year period 1954–1958. For the mean day of each of the 12 months of the year the arithmetic means of the 5Q ₀ ^– and 5 -values for the same hours have been calculated.A simple method to compute daily amounts of global radiation by means of these averageQ ₀ ^– and -values has been applied to De Bilt and Wageningen for all days of 1958. The square root of the residual variance of the thus determined daily amounts appeared to amount to 0.75 for De Bilt and to 0.82 for Wageningen compared with that computed for Wageningen fromÅngström's formula for daily amounts directly. This result shows that the average hourlyQ ₀ ^– and -values for De Bilt may be used to calculate daily amounts of global radiation for any place in the Netherlands.

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Zusammenfassung A.Ångström hat eine lineare Beziehung zwischen den Tagessummen der Globalstrahlung an einem Ort und den entsprechenden täglichen Werten der relativen Sonnenscheindauer angenommen. Andere Autoren haben dieselbe Beziehung benützt, jedoch mit verschiedenen Zeiteinheiten, wie einer Pentade, einer Dekade oder einem Monat. In der vorleigenden Untersuchung ist die Dauer einer Stunde als Einheit gewählt worden. DieÅngströmschenQ ₀ ^– und -Werte sind bestimmt worden für alle Stunden in wahrer Sonnenzeit für den mittleren Tag jedes der 60 Monate der fünfjährigen Periode 1954–1958 für De Bilt. Daraus sind die arithmetischen Mittel der 5Q ₀ ^– und der 5 -Werte für dieselben Stunden des mitteleren Tages in jedem der 12 Monate des Jahres berechnet worden.Eine einfache Methode zur Berechnung der Tagessummen der Globalstrahlung mit Hilfe der mittlerenQ ₀ ^– und -Werte wurde für De Bilt und Wageningen auf alle Tage des Jahres 1958 angewandt; dabei hat die Quadratwurzel der Restvarianz der also berechneten Tagessummen für De Bilt 0,75 mal und für Wageningen 0,82 mal den Wert der Quadratwurzel der Restvarianz der in direkter Weise mit Hilfe derÅngströmschen Formel für Wageningen berechneten Tagessummen ergeben. Daraus geht hervor, daß für jeden Ort in den Niederlanden die Tagessumme der Globalstrahlung nach der oben beschriebenen Methode mit genügender Genauigkeit berechnet werden kann.

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Résumé A.Ångström a supposé une relation linéaire entre les sommes journalières du rayonnement global observées en un lieu donné et les valuers journalières correspondantes de la durée d'insolation relative. D'autres auteurs ont admis la même relation, mais en employant des unités de temps différentes, telles que la pentade, la décade ou le mois. C'est la période d'une heure qui a été choisie ici comme unité. Les valeursQ ₀ et d'Ångström ont été déterminées pour De Bilt pour chaque heure, en temps solaire vrai, au cours d'un jour moyen de chaque mois de la période 1954–1958. Les moyennes arithmétiques de cinq valuersQ ₀ et ont été calculées pour les mêmes heures du jour moyen de chacun des douze mois de l'année.Une méthode simple de calcul des sommes journalières du rayonnement global à l'aide de ces valeurs moyennes deQ ₀ et de a été appliquée pour De Bilt et Wageningen pour tous les jours de l'année 1958. On a trouvé que le rapport de la racine carrée de la variance résiduelle des valuers journalières calculées de cette façon à celle des valeurs journalières calculées directement au moyen de la formule d'^Ångström pour Wageningen se montait à 0,75 pour De Bilt et à 0,82 pour Wageningen. Ce résultat prouve que l'on peut appliquer les valeurs horairesQ ₀ et calculées pour De Bilt au calcul des sommes journalières du rayonnement global en chaque point des Pays-Bas.

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The present investigation is treated more in detail in a Scientific Report of the Royal Netherlands Meteorological Institute No. WR-60-6.     

Surface-layer scintillation measurements of daytime sensible heat and momentum fluxes

Line-averaged measurements of the structure parameter of refractive index (C _n ² ) were made using a semiconductor laser diode scintillometer above two markedly different surfaces during hours of positive net radiation. The underlying vegetation comprised in the first instance a horizontally homogeneous, pasture sward well-supplied with water, and in the second experiment, a sparse thyme canopy in a semi-arid environment. Atmospheric stability ranged between near neutral and strongly unstable (–20). The temperature structure parameterC _T ² computed from the optical measurements over four decades from 0.001 to 2 K² m^–2/3 agreed to within 5% of those determined from temperature spectra in the inertial sub-range of frequencies. Spectra were obtained from a single fine thermocouple sensor positioned near the midway position of the 100m optical path and at the beam propagation height (1.5m).With the inclusion of cup anemometer measurements, rule-of-thumb assumptions about surface roughness, and Monin-Obukhov similarity theory, path-averaged optical scintillations allow calculation of surface fluxes of sensible heat and momentum via a simple iterative procedure. Excellent agreement was obtained between these fluxes and those measured directly by eddy correlation. For sensible heat, agreement was on average close to perfect over a measured range of 0 to 500 W m^–2 with a residual standard deviation of 30 W m^–2. Friction velocities agreed within 2% over the range 0–0.9 m s^–1 (residual standard deviation of 0.06 m s^–1). The results markedly increase the range of validation obtained in previous field experiments. The potential of this scintillation technique and its theoretical foundation are briefly discussed.     

Microphysical, chemical and optical aerosol properties in the Baltic Sea region

The microphysical structure, chemical composition and prehistory of aerosol are related to the aerosol optical properties and radiative effect in the UV spectral range. The aim of this work is the statistical mapping of typical aerosol scenarios and adjustment of regional aerosol parameters. The investigation is based on the in situ measurements in Preila (55.55° N, 21.00° E), Lithuania, and the AERONET data from the Gustav Dalen Tower (58 N, 17 E), Sweden.Clustering of multiple characteristics enabled to distinguish three aerosol types for clear-sky periods: 1) clean maritime–continental aerosol; 2) moderately polluted maritime–continental aerosol; 3) polluted continental aerosol. Differences between these types are due to significant differences in aerosol number and volume concentration, effective radius of volume distribution, content of SO₄⁻ ions and Black Carbon, as well as different vertical profiles of atmospheric relative humidity. The UV extinction, aerosol optical depth (AOD) and the Ångstrom coefficient α increased with the increasing pollution. The value α = 1.96 was observed in the polluted continental aerosol that has passed over central and eastern Europe and southern Russia. Reduction of the clear-sky UV index against the aerosol-free atmosphere was of 4.5%, 27% and 41% for the aerosol types 1, 2 and 3, respectively.     

Influence of Transport over a Mountain Ridge on the Chemical Composition of Marine Aerosols during the ACE-2 Hillcloud Experiment

Aerosol chemical composition and trace gas measurements were made at twolocations on the northeastern peninsula of Tenerife during the ACE-2HILLCLOUD experiment, between 28 June and 23 July 1997. Measurementswere made of coarse (#gt;2.5 m aerodynamic diameter) and fine (#lt; 2.5m) aerosol Cl^–, NO₃ ^–,SO₄ ^2–, non-sea saltSO₄ ^2– (NSSS),CH₃SO₃ ^– (MSA) andNH₄ ⁺, and gas phase dimethylsulphide (DMS), HCl,HNO₃, SO₂, CH₃COOH, HCOOH andNH₃. Size distributions were measured using a cascadeimpactor. Results show that in marine air masses NSSS and MSA wereformed via DMS oxidation, with additional NSSS present in air massescontaining a continental component. Using a Eulerian box model approachfor aerosols transported between upwind and downwind sites, a mean NSSSproduction rate of 4.36 × 10^–4 gm^–3 s^–1 was calculated for daytimeclear sky periods (highest insolation), with values for cloudy periodsduring daytime and nighttime of 3.55 × 10^–4 and2.40 × 10^–4 g m^–3s^–1, respectively. The corresponding rates for MSA were6.23 × 10^–6, 8.49 × 10^–6and 6.95 × 10^–6 g m^–3s^–1, respectively. Molar concentration ratios forMSA/NSSS were 8.7% (1.8–18.2%) and 1.9%(1.3–3.5%) in clean and polluted air masses, respectively.Reactions occurring within clouds appeared to have a greater influenceon rates of MSA production, than of NSSS, while conversely daytime gasphase reactions were more important for NSSS. For MSA, nighttimein-cloud oxidation rates exceeded rates of daytime gas phase productionvia OH oxidation of DMS. NSSS, MSA and ammonium had trimodal sizedistributions, with modes at 0.3, 4.0 and >10.0 m (NSSS andNH₄ ⁺), and 0.3, 1.5 and 4.0 m (MSA). Nosignificant production of other aerosol species was observed, with theexception of ammonium, which was formed at variable rates dependent onneutralisation of the aerosol with ammonia released from spatiallynon-uniform surface sources. Seasalt components were mainly present incoarse particles, although sub-micrometre chloride was also measured.Losses by deposition exceeded calculated expectations for all species,and were highest for the seasalt fraction and nitrate.     

On the stable stratification of the nocturnal lower troposphere inferred from lidar observations over Pune,India

The nocturnal structure of the lower troposphere is studied using aerosol profile data (50–2800 m AGL) obtained with a bistatic, continuous wave, Argon ion lidar system during October 1986–September 1989 at Pune (18°32 N, 73°51 E, 559m AMSL), India. The top of the nocturnal groundbased inversion is taken as the height above ground where the negative vertical gradient in aerosol concentration first reaches a maximum. During the post-sunset period over this station, this height is as low as 160m and frequently lies around 550m. Greater heights are observed in pre-monsoon months and smaller ones during the southwest monsoon season. Positive vertical gradients in aerosol concentration, indicative of stable/elevated layers, appear frequently around 750m. Temporal variations of aerosol concentration gradients in two adjacent air layers, 920–1000m and 100–1100m, provide evidence that stability increases downward in the early night hours.     

Impacts of greenhouse gases and aerosol direct and indirect effects on clouds and radiation in atmospheric GCM simulations of the 1930–1989 period

Among anthropogenic perturbations of the Earths atmosphere, greenhouse gases and aerosols are considered to have a major impact on the energy budget through their impact on radiative fluxes. We use three ensembles of simulations with the LMDZ general circulation model to investigate the radiative impacts of five species of greenhouse gases (CO₂, CH₄, N₂O, CFC-11 and CFC-12) and sulfate aerosols for the period 1930–1989. Since our focus is on the atmospheric changes in clouds and radiation from greenhouse gases and aerosols, we prescribed sea-surface temperatures in these simulations. Besides the direct impact on radiation through the greenhouse effect and scattering of sunlight by aerosols, strong radiative impacts of both perturbations through changes in cloudiness are analysed. The increase in greenhouse gas concentration leads to a reduction of clouds at all atmospheric levels, thus decreasing the total greenhouse effect in the longwave spectrum and increasing absorption of solar radiation by reduction of cloud albedo. Increasing anthropogenic aerosol burden results in a decrease in high-level cloud cover through a cooling of the atmosphere, and an increase in the low-level cloud cover through the second aerosol indirect effect. The trend in low-level cloud lifetime due to aerosols is quantified to 0.5 min day^–1 decade^–1 for the simulation period. The different changes in high (decrease) and low-level (increase) cloudiness due to the response of cloud processes to aerosols impact shortwave radiation in a contrariwise manner, and the net effect is slightly positive. The total aerosol effect including the aerosol direct and first indirect effects remains strongly negative.