The role of hydrogeological setting in two Canadian peatlands investigated through 2D steady-state groundwater flow modelling

This study investigated how hydrogeological setting influences aquifer–peatland connections in slope and basin peatlands. Steady-state groundwater flow was simulated using Modflow on 2D transects for an esker slope peatland and for a basin peatland in southern Quebec (Canada). Simulations investigated how hydraulic heads and groundwater flow exported toward runoff from the peatland can be influenced by recharge, hydraulic properties, and heterogeneity. The slope peatland model was strongly dominated by horizontal flow from the esker. This suggests that slope peatlands are dependent on the hydrogeological conditions of the adjacent aquifer reservoir, but are resilient to hydrological changes. The basin peatland produced groundwater outflow to the surface aquifer. Lateral and vertical peat heterogeneity due to peat decomposition or compaction were identified as having a significant influence on fluxes. These results suggest that basin peatlands are more dependent on recharge conditions, and could be more susceptible to land use and climate changes.     

Automated calibration applied to watershed‐scale flow simulations

Complexity in simulating the hydrological response in large watersheds over long times has prompted a significant need for procedures for automatic calibration. Such a procedure is implemented in the basin‐scale hydrological model (BSHM), a physically based distributed parameter watershed model. BSHM simulates the most important basin‐scale hydrological processes, such as overland flow, groundwater flow and stream–aquifer interaction in watersheds. Here, the emphasis is on estimating the groundwater parameters with water levels in wells and groundwater baseflows selected as the calibration targets. The best set of parameters is selected from within plausible ranges of parameters by adjusting the values of hydraulic conductivity, storativity, groundwater recharge and stream bed permeability. The baseflow is determined from stream flow hydrographs by using an empirical scheme validated using a chemical approach to hydrograph separation. Field studies determined that the specific conductance for components of the composite hydrograph were sufficiently unique to make the chemical approach feasible. The method was applied to the Big Darby Creek Watershed, Ohio. The parameter set selected for the groundwater system provides a good fit with the estimated baseflow and observed water well data. Copyright © 1999 John Wiley & Sons, Ltd.     

Hydrological functions of a peatland in a Boreal Plains catchment

Streamflow response in Boreal Plains catchments depends on hydrological connectivity between forested uplands, lakes, and peatlands, and their hydrogeomorphic setting. Expected future drying of the Boreal Plains ecozone is expected to reduce hydrological connectivity of landscape units. To better understand run‐off generation during dry periods, we determined whether peatland and groundwater connectivity can dampen expected future water deficits in forests and lakes. We studied Pine Fen Creek catchment in the Boreal Plains ecozone of central Saskatchewan, Canada, which has a large, valley‐bottom, terminally positioned peatland, two lakes, and forested uplands. A shorter intensive study permitted a more detailed partitioning of water inputs and outputs within the catchment during the low flow period, and an assessment of a 10‐year data set provided insight into the function of the peatland over a range of climate conditions. Using a water balance approach, we learned that two key processes regulate flow of Pine Fen Creek. The cumulative impact of landscape unit hydrological connectivity and the peatland's hydrological functional state were needed to understand catchment response. There was evidence of a run‐off threshold which, when crossed, changed the peatland's hydrological function from transmission to run‐off generation. Results also suggest the peatland should behave more often as a transmitter of groundwater than as a generator of run‐off under a drier climate future, owing to a reduced water supply.     

A graphical approach for documenting peatland hydrodiversity and orienting land management strategies

This study focuses on the development of an approach to document the hydrological characteristics of peatlands and understand their potential influence on runoff processes and groundwater flow dynamics. Spatial calculations were performed using geographic information systems data in order to evaluate the distribution of peatlands according to (a) neighbouring hydrogeological units and (b) their position within the hydrographic network. The data obtained from these calculations were plotted in a multiple trilinear diagram (two ternary plots projected into a diamond‐shaped diagram) that illustrates the position of a given peatland within the hydrogeological environment. The data allow for the segregation of peatlands according to groups sharing similarities as well as the identification of peatlands that are most likely to have similar hydrological functions. The approach was tested in a 19,549 km² region of the southern portion of the Barlow‐Ojibway Clay Belt (in Abitibi‐Témiscamingue, Canada) and lead to a conceptual model representing the hydrological interactions between peatlands, aquifers, and surface waters. This approach allows for a geographic information systems‐based differentiation of headwater peatland complexes that are likely to interact with aquifers and to supply continuous baseflow to small streams from lowland peatland complexes of the clay plain that are isolated from surrounding aquifers but that can act as storage reservoirs within the hydrographic network. The typology is further used to discuss land management strategies aimed at preserving peatland hydrodiversity within the study region. The proposed approach relies on widely applicable hydrogeological and hydrographic criteria and provides a tool that could be used for assessing peatland hydrodiversity in other regions of the planet.     

Hydrogeological interactions between fault zones and alluvial aquifers in regional flow systems

The hydrological influence of fault zones in tectonic areas is usually difficult to depict from field data. Numerical simulation allows representation of such flow systems and an estimation of flow lines and rates. This paper reports on simulations of the groundwater flow in a range‐and‐basin area affected by a regional fault zone, which may drain or recharge an overlaying alluvial aquifer. Different hydraulic conductivity values for the range rocks, the fault‐zone, and the sedimentary infill of the basin are considered, as well as different fault‐zone widths and boundary conditions. Results show that upward and downward fluxes develop in the upper part of the fault zone, controlled by the action of the alluvial aquifer, influencing the recharge of the sedimentary basin. This paper shows the hydrological efficiency of fault zones as preferential flow; it also analyses the constraints that determine groundwater recharge to the surrounding basins. These results contribute to the understanding of hydrogeological dynamics in tectonic areas. Copyright © 2008 John Wiley & Sons, Ltd.     

Semi‐Arid Aquifer Responses to Forest Restoration Treatments and Climate Change

The purpose of this study was to develop an interpretive groundwater‐flow model to assess the impacts that planned forest restoration treatments and anticipated climate change will have on large regional, deep (>400 m), semi‐arid aquifers. Simulations were conducted to examine how tree basal area reductions impact groundwater recharge from historic conditions to 2099. Novel spatial analyses were conducted to determine areas and rates of potential increases in groundwater recharge. Changes in recharge were applied to the model by identifying zones of basal area reduction from planned forest restoration treatments and applying recharge‐change factors to these zones. Over a 10‐year period of forest restoration treatment, a 2.8% increase in recharge to one adjacent groundwater basin (the Verde Valley sub‐basin) was estimated, compared to conditions that existed from 2000 to 2005. However, this increase in recharge was assumed to quickly decline after treatment due to regrowth of vegetation and forest underbrush and their associated increased evapotranspiration. Furthermore, simulated increases in groundwater recharge were masked by decreases in water levels, stream baseflow, and groundwater storage resulting from surface water diversions and groundwater pumping. These results indicate that there is an imbalance between water supply and demand in this regional, semi‐arid aquifer. Current water management practices may not be sustainable into the far future and comprehensive action should be taken to minimize this water budget imbalance.     

Investigating hydrological regimes and processes in a set of catchments with temporary waters in Mediterranean Europe

Abstract

Seven catchments of diverse size in Mediterranean Europe were investigated in order to understand the main aspects of their hydrological functioning. The methods included the analysis of daily and monthly precipitation, monthly potential evapotranspiration rates, flow duration curves, rainfall—runoff relationships and catchment internal data for the smaller and more instrumented catchments. The results showed that the catchments were less “dry” than initially considered. Only one of them was really semi-arid throughout the year. All the remaining catchments showed wet seasons when precipitation exceeded potential evapotrans-piration, allowing aquifer recharge, “wet” runoff generation mechanisms and relevant baseflow contribution. Nevertheless, local infiltration excess (Hortonian) overland flow was inferred during summer storms in some catchments and urban overland flow in some others. The roles of karstic groundwater, human disturbance and low winter temperatures were identified as having an important impact on the hydrological regime in some of the catchments.     

Quantifying groundwater discharge to a small perennial stream in southern Ontario, Canada

A study of the interaction between groundwater and surface water was undertaken within a small agricultural watershed in southern Ontario, Canada. Groundwater contributions to streamflow were measured along a section of stream during baseflow conditions and during rainfall events. Four techniques were used to estimate the contribution of groundwater to the stream along a 450 m reach (three during baseflow and one during stormflow conditions). Under baseflow conditions, streamflow measurements using the velocity–area technique indicated that the net groundwater flux to the stream during the summer months was 10 ml s⁻¹ m⁻¹. Hydrometric measurements (i.e. hydraulic gradient and hydraulic conductivity) taken using mini-piezometers installed in the sediments beneath the stream resulted in net groundwater flux estimates that were four to five times lower. Seepage meters failed to provide any measurements of water flux into or out of the stream. Therefore, based on these results, the velocity–area technique gives the best estimate of groundwater discharge. Hydrograph separations were conducted using isotopic ratios and electrical conductivity on two large rainfall events with different antecedent moisture conditions in the catchment. Both events showed that pre-event water (generally considered groundwater) dominated streamflow and tile drain flow with 64%–80% of the total discharge contributed by pre-event water. High water table conditions within the catchment resulted in greater stream discharge and a greater contribution of event water in the streamflow than that observed under low water table conditions for similar intensity storm events. The results also showed that differences in riparian zone width, vegetation and surface saturation conditions between the upper and lower catchment can influence the relative magnitude of streamflow response from the two catchment areas.     

The influence of groundwater representation on hydrological simulation and its assessment using satellite‐based water storage variation

The interaction between surface water and groundwater is an important aspect of hydrological processes. Despite its importance, groundwater is not well represented in many land surface models. In this study, a groundwater module with consideration of surface water and groundwater dynamic interactions is incorporated into the distributed biosphere hydrological (DBH) model in the upstream of the Yellow River basin, China. Two numerical experiments are conducted using the DBH model: one with groundwater module active, namely, DBH_GW and the other without, namely, DBH_NGW. Simulations by two experiments are compared with observed river discharge and terrestrial water storage (TWS) variation from the Gravity Recovery and Climate Experiment (GRACE). The results show that river discharge during the low flow season that is underestimated in the DBH_NGW has been improved by incorporating the groundwater scheme. As for the TWS, simulation in DBH_GW shows better agreement with GRACE data in terms of interannual and intraseasonal variations and annual changing trend. Furthermore, compared with DBH_GW, TWS simulated in DBH_NGW shows smaller decreases during autumn and smaller increases in spring. These results suggest that consideration of groundwater dynamics enables a more reasonable representation of TWS change by increasing TWS amplitudes and signals and as a consequence, improves river discharge simulation in the low flow seasons when groundwater is a major component in runoff. Additionally, incorporation of groundwater module also leads to wetter soil moisture and higher evapotranspiration, especially in the wet seasons.     

Channel precipitation dynamics in a forested Pennsylvania headwater catchment (USA)

Seasonal and event variations in stream channel area and the contributions of channel precipitation to stream flow were studied on a 106‐ha forested headwater catchment in central Pennsylvania. Variations in stream velocity, flowing stream surface width and widths of near‐stream saturated areas were periodically monitored at 61 channel transects over a two‐year period. The area of flowing stream surface and near‐stream saturated zones combined, ranged from 0·07% of basin area during summer low flows to 0·60% of total basin area during peak storm flows. Near‐stream saturated zones generally represented about half of the total channel area available to intercept throughfall and generate channel precipitation. Contributions of routed channel precipitation from the flowing stream surface and near‐stream zones, calculated using the Penn State Runoff Model (PSRM, v. 95), represented from 1·1 to 6·4% of total stream flow and 2·5–29% of total storm flow (stream flow–antecedent baseflow) during the six events. Areas of near‐stream saturated zones contributed 35–52% of the computed channel precipitation during the six events. Channel precipitation contributed a higher percentage of stream flow for events with low antecedent baseflow when storm flow generated by subsurface sources was relatively low. Expansion of channel area and consequent increases in volumes of channel precipitation with flow increases during events was non‐linear, with greater rates of change occurring at lower than at higher discharge rates. Copyright © 1999 John Wiley & Sons, Ltd.     

Manganese in runoff from upland catchments: temporal patterns and controls on mobilization / Teneur en manganèse de l'écoulement en bassins versants d'altitude: variations temporelles et contrôles de la mobilisation

Abstract

Knowledge of the hydrochemical dynamics of the trace metal manganese (Mn) in upland catchments is required for water quality management. Stream water Mn and other solutes and flow were monitored in two upland catchments in northern England with different soils: one dominated by peat (HS7), the other by mineral soils (HS4). Maximum Mn concentrations occurred at different times in the two catchments: in summer baseflow at HS4 and during late summer storm events at HS7. A two-component chemical mixing model was used to identify the hydrological processes controlling Mn concentrations in stream water. This approach was more successful for HS4 than HS7, probably because of different processes of Mn release in the two catchments and also difficulties in selecting conservative solutes. Factor analysis of the stream water chemistry data set for each catchment was more useful in identifying the controls on Mn release into runoff. The factors indicate that the main source of Mn at HS4 is the hydrological pathway supplying summer baseflow, whereas at HS7 Mn is released during the rewetting of dried peat soils. Manganese concentrations in stream water in upland catchments appear to depend on soil type and antecedent moisture conditions. This has implications for the design of sampling strategies in upland catchments and also for managing the quality of water supplies from such areas.     

Identifying and linking source areas of flow and P transport in dairy‐grazed headwater catchments,North Island,New Zealand

We examined the applicability of the critical‐source area (CSA) concept to the dairy‐grazed 192‐ha Upper Toenepi catchment and its 8·7‐ha Kiwitahi sub‐catchment, New Zealand. We evaluated if phosphorus (P) transport from land into stream is dominated by saturation‐excess (SE) and infiltration‐excess (IE) runoff during stormflow and by sub‐surface (<1·5 m depth) flows during baseflow. We measured stream flow and shallow groundwater levels, collected monthly stream, tile drain (TDA) and groundwater samples, and flow‐proportional stream samples from the Kiwitahi sub‐catchment, and determined their dissolved reactive phosphorus (DRP) and total phosphorus (TP) concentrations. In the Kiwitahi sub‐catchment, during storm events, IE contributions were significant. Contributions from SE appeared significant in the Upper Toenepi catchment. However, in both catchments, sub‐surface contributions dominated stormflow and baseflow periods. Absence of water table at the surface and the water table gradient towards the stream indicated that P transport during events was not limited to surface runoff. The dynamics of the groundwater table and the occurrence of SE areas were influenced by proximity to the stream and hillslope positions. Baseflow accounted for 42% of the annual flow in the Kiwitahi sub‐catchment, and contributed 37 and 52% to the DRP and TP loads, respectively. The P transport during baseflow appeared equally important as P losses from CSAs during stormflow. The close resemblance in P levels between groundwater and stream samples during baseflow demonstrates the importance of shallow groundwater for stream flow. In the Upper Toenepi catchment, contributions from effluent ponds (EFFs) dominated P loads. Management strategies should focus on controlling P release from EFFs, and on decreasing Olsen P concentrations in soil to minimize leaching of P via sub‐surface flow to streams. Research is needed to quantify the role of sub‐surface flow as well as to expand management strategies to minimize P transfers during stormflow and baseflow conditions. Copyright © 2010 John Wiley & Sons, Ltd.     

Wetland nitrogen dynamics in an Adirondack forested watershed

Wetlands often form the transition zone between upland soils and watershed streams, however, stream–wetland interactions and hydrobiogeochemical processes are poorly understood. We measured changes in stream nitrogen (N) through one riparian wetland and one beaver meadow in the Archer Creek watershed in the Adirondack Mountains of New York State, USA from 1 March to 31 July 1996. In the riparian wetland we also measured changes in groundwater N. Groundwater N changed significantly from tension lysimeters at the edge of the peatland to piezometer nests within the peatland. Mean N concentrations at the peatland perimeter were 1·5, 0·5 and 18·6 µmol L^?1 for NH₄⁺, NO₃^? and DON (dissolved organic nitrogen), respectively, whereas peatland groundwater N concentration was 56·9, 1·5 and 31·6 µmol L^?1 for NH₄⁺, NO₃^? and DON, respectively. The mean concentrations of stream water N species at the inlet to the wetlands were 1·5, 10·1 and 16·9 µmol L^?1 for NH₄⁺, NO₃^? and DON, respectively and 1·6, 28·1 and 8·4 µmol L^?1 at the wetland outlet. Although groundwater total dissolved N (TDN) concentrations changed more than stream water TDN through the wetlands, hydrological cross‐sections for the peatland showed that wetland groundwater contributed minimally to stream flow during the study period. Therefore, surface water N chemistry was affected more by in‐stream N transformations than by groundwater N transformations because the in‐stream changes, although small, affected a much greater volume of water. Stream water N input–output budgets indicated that the riparian peatland retained 0·16 mol N ha^?1 day^?1 of total dissolved N and the beaver meadow retained 0·26 mol N ha^?1 day^?1 during the study period. Nitrate dominated surface water TDN flux from the wetlands during the spring whereas DON dominated during the summer. This study demonstrates that although groundwater N changed significantly in the riparian peatland, those changes were not reflected in the stream. Consequently, although in‐stream changes of N concentrations were less marked than those in groundwater, they had a greater effect on stream water chemistry—because wetland groundwater contributed minimally to stream flow. Copyright © 2004 John Wiley & Sons, Ltd.     

Quantifying groundwater dependency of riparian surface hydrologic features using the exit gradient

Numerical groundwater flow models necessarily are limited to subsurface flow evaluation. It is of interest, however, to examine the possibility that, for unconfined aquifer systems, they could be used to proportionately measure the magnitude of seepage they estimate when these aquifers intersect the landscape surface. Our goal in this study was to determine the degree to which an unconfined groundwater model can estimate run‐off or seepage at the land surface during winter time wet season conditions, as well as in the dry season, when evapotranspiration is a major part of the water balance, using a lowland basin‐fill example study area in the Pacific Northwest. The exit gradient is a metric describing the potential for vertical seepage at the landscape surface. We investigated the spatial relationship of mapped surface features, such as wetlands, streams and ponds, to the model‐predicted mapped exit gradient. We found that areas mapped as wetlands had positive exit gradients. During the wet season, modelled exit gradients predicted seepage throughout extensive areas of the groundwater shed, extending far beyond mapped wetland areas (355% increase), associated with previously observed increases in nitrate‐nitrogen in streams in wet season. During the dry season, exit gradients spatially corresponded with wetland areas. The increase in in‐stream nitrogen corresponds with shorter residence times in carbon‐rich wetland zones because of the onset of saturation overland flow. We present results that suggest that the exit gradient could be a useful concept in examining the groundwater–surface water linkage that is often under represented physically in watershed flow models. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.     

SULPHATE DYNAMICS IN RELATION TO GROUNDWATER–SURFACE WATER INTERACTIONS IN HEADWATER WETLANDS OF THE SOUTHERN CANADIAN SHIELD

The spatial and temporal distribution of sulphate (SO₄) concentrations in peat pore water and the outlet streams of two forested swamps was related to variations in the magnitude of upland runoff, wetland water levels and flow path. The swamps were located in headwater catchments with contrasting till depths typical of the southern Canadian Shield. Inputs of SO₄ from shallow hillslope tills and streams showed little seasonal variation in either source or concentration in both swamps. Sulphate dynamics at the outlet stream reflected hydrological and biogeochemical processes within the valley wetlands, which in turn were partly controlled by catchment hydrogeology. During high runoff, maximum water table elevations and peak surface flow in the swamps resulted in upland inputs largely bypassing anoxic peat. Consequently, SO₄ concentrations of 8–10 mg/l at the swamp outlets were similar to stream and groundwater inputs. During periods of low flow, concentrations of SO₄ at the swamp outlets declined to less than 3 mg/l. At this time lower water table elevations resulted in increased interaction of input water with anoxic peats, and therefore, SO₄ reduction. Contrasts in till depth and the nature of groundwater flow between catchments resulted in differences in SO₄ dynamics between years and swamps. In dry summers the absence of groundwater inputs to the swamp in the catchment with thin till resulted in a large water table drawdown and re-oxidation of accumulated S, which contributed to maximum SO₄ concentrations (up to 35 mg/l) during storm runoff. Continuous groundwater input to the swamp in the catchment with deeper till was critical to maintaining saturated surfaces and efficient SO₄ retention during both dry and wet summers. A conceptual model of wetland SO₄ retention and export, based on catchment hydrogeology, is developed to generalize the SO₄ dynamics of valley bottom wetlands at the landscape scale. © 1997 by John Wiley & Sons, Ltd.     

Improved vegetation parameterization for hydrological model and assessment of land cover change impacts on flow regime of the Upper Bhima basin,India

This study investigates the potential and applicability of variable infiltration capacity (VIC) hydrological model to simulate different hydrological components of the Upper Bhima basin under two different Land Use Land Cover (LULC) (the year 2000 and 2010) conditions. The total drainage area of the basin was discretized into 1694 grids of about 5.5 km by 5.5 km: accordingly the model parameters were calibrated at each grid level. Vegetation parameters for the model were prepared using temporal profile of Leaf Area Index (LAI) from Moderate-Resolution Imaging Spectroradiometer and LULC. This practice provides a methodological framework for the improved vegetation parameterization along with region-specific condition for the model simulation. The calibrated and validated model was run using the two LULC conditions separately with the same observed meteorological forcing (1996–2001) and soil data. The change in LULC has resulted to an increase in the average annual evapotranspiration over the basin by 7.8%, while the average annual surface runoff and baseflow decreased by 18.86 and 5.83%, respectively. The variability in hydrological components and the spatial variation of each component attributed to LULC were assessed at the basin grid level. It was observed that 80% of the basin grids showed an increase in evapotranspiration (ET) (maximum of 292 mm). While the majority of the grids showed a decrease in surface runoff and baseflow, some of the grids showed an increase (i.e. 21 and 15% of total grids—surface runoff and baseflow, respectively).     

Modelling hydrological processes influenced by soil,rock and vegetation in a small karst basin of southwest China

Hydrological processes in karst basins are controlled by permeable multimedia, consisting of soil pores, epikarst fractures, and underground conduits. Distributed modelling of hydrological dynamics in such heterogeneous hydrogeological conditions is a challenging task. Basing on the multilayer structure of the distributed hydrology‐soil‐vegetation model (DHSVM), a distributed hydrological model for a karst basin was developed by integrating mathematical routings of porous Darcy flow, fissure flow and underground channel flow. Specifically, infiltration and saturated flow movement within epikarst fractures are expressed by the ‘cubic law’ equation which is associated with fractural width, direction, and spacing. A small karst basin located in Guizhou province of southwest China was selected for this hydrological simulation. The model parameters were determined on the basis of field measurement and calibrated against the observed soil moisture contents, vegetation interception, surface runoff, and underground flow discharges from the basin outlet. The results show that due to high permeability of the epikarst zone, a significant amount of surface runoff is only generated after heavy rainfall events during the wet season. Rock exposure and the epikarst zone significantly increase flood discharge and decrease evapotranspiration (ET) loss; the peak flood discharge is directly proportional to the size of the aperture. Distribution of soil moisture content (SMC) primarily depends on topographic variations just after a heavy rainfall, while SMC and actual ET are dominated by land cover after a period of consecutive non‐rainfall days. The new model was able to capture the sharp increase and decrease of the underground streamflow hydrograph, and as such can be used to investigate hydrological effects in such rock features and land covers. Copyright © 2011 John Wiley & Sons, Ltd.     

A simple overland flow calculation method for distributed groundwater recharge models

A method to improve the calculation of overland flow in distributed groundwater recharge models is presented and applied to two sub‐catchments in the Thames Basin, UK. Recharge calculation studies tend to simulate the runoff flow component of river flow in a simplistic way, often as a fraction of rainfall over a particular period. The method outlined in this study intends to improve the calculation of groundwater recharge estimates in distributed recharge models but does not present an alternative to complex overland flow simulators. This method uses seasonally varying coefficients to calculate runoff for specified hydrogeological classes or runoff zones, which are used to model baseflow index variations across the basin. It employs a transfer function model to represent catchment storage. Monte Carlo simulation was applied to refine the runoff values. Decoupling the runoff zones between the two sub‐catchments produces a better match between the simulated and observed values; however, the difference between observed runoff and the simulated output indicates other factors, such as landuse and topographical characteristics that affect the generation of runoff flow, need to be taken into account when classifying runoff zones. British Geological Survey © NERC 2011. Hydrological Processes © 2011 John Wiley & Sons, Ltd.     

Simulated groundwater interaction with rivers and springs in the Heihe river basin

Surface water and groundwater in the Heihe river basin of China are interconnected and the pattern of water resources exploitation has a direct effect on the interaction of groundwater and surface water, especially on a downstream oasis. A three‐dimensional groundwater flow simulation model with eight model layers was established to simulate the regional groundwater flow in the multilayered aquifer system and the interaction among the rivers, springs, and groundwater. The model was calibrated not only with historical water levels but also with the investigated baseflow and spring flux. The simulation results of the numerical model match reasonably well with the observed groundwater levels, baseflow to rivers, and spring flux. The numerical simulation also demonstrates that the hydraulic connection between the river and the aquifers has transferred from the coupling to decoupling at some reaches. It is suggested that there is a vital need to reduce groundwater withdrawal and to rationalize the use of both groundwater and surface water in order to maintain sustainable development in the study area. Copyright © 2007 John Wiley & Sons, Ltd.     

Distinct export dynamics for dissolved and particulate phosphorus reveal independent transport mechanisms in an arable headwater catchment

This paper investigates particulate phosphorus (PP) and soluble reactive phosphorus (SRP) concentrations at the outlet of a small (5 km²) intensively farmed catchment to identify seasonal variability of sources and transport pathways for these two phosphorus forms. The shape and direction of discharge‐concentration hystereses during floods were related to the hydrological conditions in the catchment during four hydrological periods. Both during flood events and on an annual basis, contrasting export dynamics highlighted a strong decoupling between SRP and PP export. During most flood events, discharge‐concentration hystereses for PP were clockwise, indicating mobilization of a source located within or near the stream channel. Seasonal variability of PP export was linked to the availability of stream sediments and the export capacity of the stream. In contrast, hysteresis shapes for SRP were anticlockwise, which suggests that SRP was transferred to the stream via subsurface flow. Groundwater rise in wetland soils was likely the cause of this transfer, through the hydrological connectivity it created between the stream and P‐rich soil horizons. SRP concentrations were the highest when the relative contribution of deep groundwater from the upland domain was low compared with wetland groundwater. Hence, soils from non‐fertilized riparian wetlands seemed to be the main source of SRP in the catchment. This conceptual model of P transfer with distinct hydrological controls for PP and SRP was valid throughout the year, except during spring storm events, during which PP and SRP exports were synchronized as a consequence of overland flow and erosion on hillslopes. Copyright © 2015 John Wiley & Sons, Ltd.