模拟暴雨条件下农田磷素迁移特征

开展三次重复人工暴雨试验,研究太湖流域平原河网区农田磷素在暴雨径流过程中的迁移输出特征,结果表明,地表径流是暴雨径流过程农田磷素迁移的主要途径,地表径流水相和侵蚀相磷素迁移量分别占总磷输出量的58.50%和34.69%;随壤中水流输移的磷素仅占总磷输出量的6.81%,磷素迁移以颗粒态为主,约占总磷输出量的60.73%,溶解态磷素以无机磷酸盐输出为主,溶解态磷素更易于在土壤中运动,地表径流与壤中流磷素输出特征对比分析显示,土壤对磷素具有较强的滤减作用,尤其对总颗粒态附着磷浓度的消减效果明显,可达80%以上,尽管暴雨径流过程中磷素迁移以地表径流为主,然而在降雨丰富的太湖地区,一般降雨条件下壤中流是产流的主要形式,同时壤中流溶解态磷流失占有较大的比例,对区域水环境恶化具有重要贡献,因此加强壤中流溶解态磷素输移和控制研究具有重要意义.     

基于SWAT模型的南四湖流域非点源氮磷污染模拟

本文利用SWAT模型结合实测数据,对南四湖流域2001-2010年年均非点源氮磷污染进行模拟,分析了南四湖流域非点源氮磷负荷空间分布特征,计算各河流流域对南四湖湖区污染的贡献率,并对非点源氮磷污染严重的关键区进行识别.研究表明:(1)先模拟湖东和湖西的两个典型小流域的非点源氮磷污染,并将模型推及整个南四湖流域,该方法不仅提高了计算效率,且得到了较好的模拟结果.通过对比发现,湖东的模拟效果要好于湖西,一定程度上说明SWAT模型在起伏较大的地区能取得更高的精度.(2)南四湖流域非点源氮磷污染严重,几乎所有区域的氮负荷超标,40%以上的区域磷负荷超标严重.湖东非点源氮磷污染较湖西严重,其中洸府河流域是南四湖湖区非点源氮磷污染的主要贡献者.(3)通过对径流量、泥沙负荷、氮负荷、磷负荷的相关分析可以得出,南四湖流域非点源氮负荷以溶解态为主,随径流进入水体;非点源磷负荷以吸附态为主,随泥沙进入水体.     

[专稿]长江上游水库改变干流磷通量、效应与修复对策

磷主要随河川径流循环,是水域重要营养或污染物质,是长江及河口浮游生物限制因子.在自然与人类活动作用下,磷循环规律及变化对水生态环境具有重要作用.本文根据实测资料、理论和模型系统分析了长江磷自然循环属性、水库作用及可能的环境影响.长江磷以颗粒态为主,与泥沙关系密切,受水库影响大量沉积;颗粒磷的潜在生物有效磷(BAP)较高,总量超过人类排放;自然背景下磷与淡水系统关系较小,到河口及周边海域释放BAP是这里生态系统关键的营养资源;水库拦截使在底泥沉积并在缺氧环境释放的BAP成为河流上游潜在污染源.水库拦沙也破坏了下游河流泥沙的磷缓冲机制,增加环境脆弱性,降低污染承受能力,抬高水库下泄背景溶解磷浓度和河口碳、氮的相对程度,增加干流最下游大型水库污染和水华风险.另一方面,实测资料对比研究表明,我国河流地表水环境监测规范中的磷分析方法存在问题,采用"澄清样"方法使磷大量漏测,上下游、河湖库及汛枯期间磷通量监测口径不同、标准不一,很难适应流域一体化管理要求;依此监测的评估也会严重低估水库作用,忽视其拦磷和抬高背景溶解磷等机制,误导污染源解析,影响环境管理与决策.流域水库改变泥沙、磷及循环规律是当前长江干流环境条件的实质性改变,是长江保护生态面临的主要问题和修复重点之一,建议在大型水库持续挖泥用以功能性修复河流物质通量和消除上游潜在污染内源.     

长江中下游湖泊沉积物生物可利用磷分布特征

利用化学提取方法对太湖6个样点,巢湖4个样点和龙感湖3个样点的表层沉积物和沉积物柱样进行了生物可利用磷(BAP)测定．北太湖表层沉积物的平均含量为259．5mg／kg,而西部湖区平均含量为114 6mg／kg,湖心区平均含量为40．6 mg/kg,而东太湖平均含量为50．7 mg／kg,呈显著北高南低的特点．巢湖西部湖区表层沉积物的BAP平均含量为 254．2 mg／kg,而东部湖区BAP含量降低为101．9mg／kg．龙感湖表层沉积物BAP平均含量为67．8 mg／kg．显著表明污染程度较高的湖区沉积物的BAP相应较高．BAP在沉积物中随深度呈指数降低,显示生物可利用磷在沉积作用下向稳定的非活性磷转化．夏季沉积物中的BAP由于生物活性的增强向溶解态活性磷转化过程增强,显示为较低的BAP含量．BAP 含量与水体溶解态活性磷呈正相关关系,且该相关性在BAP含量较低的样点好于高BAP的样点．     

贵州红枫湖沉积物生物可利用磷分布特征及其与粒径的关系

应用化学提取法分析了红枫湖主要出入湖河口及湖心沉积物生物可利用磷(BAP)的含量,并探讨了BAP空间分布与总磷(TP)和粒度组成之间的关系.研究结果表明,各形态BAP含量顺序为:藻类可利用磷(AAP)NaHCO3可提取磷(Olsen-P)水溶性磷(WSP)易解吸磷(RDP).沉积物柱芯中BAP迅速降低,剖面变化比TP更为明显.各形态BAP与TP显著相关,除RDP与AAP外,其它形态BAP之间也显著相关.Olsen-P是评价红枫湖沉积物磷的生物有效性的最佳指标.红枫湖沉积物颗粒组成以粘土及粉砂为主,湖心沉积物比河口粒度小.表层(0-5cm)沉积物中Olsen-P和AAP的含量与细组分(粘土)的比例呈正相关,而RDP、WSP与细组分呈负相关性,表明沉积物细组分对深水湖泊富营养化的重要性.     

红壤农田小流域径流组分对氮素流失动态的影响

明确关键带中农田流域水文过程对氮负荷的影响,对于理解关键带中的物质迁移过程,尤其是农业面源污染中氮素的迁移转化具有重要意义.文章以红壤关键带丘陵区孙家农田小流域为对象,在2017年3月至2018年2月水文年对流域降水、土壤水、地下水及径流进行了较为系统的水量和水质监测,借助端元混合模型,探究了径流组分动态对氮素流失的影响.结果表明,流域不同水体之间氮素浓度差异显著.土壤水和地下水的氮素浓度最高,约为降水和灌溉水的3～5倍,流域径流氮素浓度的2倍.红壤农田流域氮素负荷较高.孙家小流域全氮(TN)年净流失量占总氮肥投入的15%.雨季是氮流失的高风险期,仅降水量最为丰沛的6月氮素流失就占到全年总流失量的1/3以上.地下径流是农田小流域氮素流失的重要途径,其径流量占到流域径流量的25%左右.径流组分的改变是径流氮素浓度变化的重要因素,且径流组分可以用来预测水田与旱地生态系统交错存在的小流域的氮素负荷,其预测结果与实测结果的线性决定系数达到0.9左右(p0.001).本研究的结果对于提高红壤农田小流域的水肥管理水平和加深对红壤关键带水氮耦合关系均具有重要指导价值.     

梯级筑坝下小型山区河流水体碳氮磷的时空特征及富营养化风险

梯级筑坝对河流水环境演化的影响是国内外关注的热点.小型山区河流高密度梯级开发对水体生源要素的空间格局以及水环境演化的累积影响特征尚不清楚.以重庆市五布河为研究对象,对流域内8个“河流-水库-下泄水”交替系统中表层水体理化因子及碳（C）、氮（N）、磷（P）形态组成进行季节性监测,探讨了梯级筑坝对小型河流生源要素空间格局及水体富营养化风险影响的累积特征及驱动机制.结果表明：梯级水电开发对五布河流域水生生境和生源要素空间分配的影响具有潜在的累积效应,各库区水体碳氮磷浓度均呈逐级增加的空间规律;水库段的有机碳及不同形态的氮、磷浓度均高于入库河流,因此水体养分浓度呈现出河段尺度（即单个河流-水库-下泄水系统）和流域尺度（即上游至下游）耦合的空间变异模式.上游水库中溶解性氮、磷的再释放及下泄输移能够补给下游库区,加之下游水库泥沙对氮、磷的吸附-沉积作用的减弱,导致水体氮、磷总量及溶解性氮、磷的占比沿程增加,呈现梯级筑坝对水环境演化的累积影响.梯级筑坝影响下河流碳氮磷总量的相关性减弱,而溶解性养分间的相关性增强,形成了特殊的养分协同演化;水库群之间水力滞留时间的差异与水体碳氮磷浓度具有较好的线性关系,是影响流域养分分配的关键因素.五布河流域水体均为高富营养化风险,由于梯级筑坝下水体溶解性养分的逐级增加,下游水库水华风险更大;水力滞留时间与水体富营养化指数及叶绿素a浓度呈显著正向关,结合氮磷比特征的分析,本研究认为外源磷输入控制及水力滞留时间的调节是五布河梯级水库富营养化防控的有效途径.     

三峡水库对长江N、P营养盐截留效应的模型分析

在长江流域干支流NP营养盐现场观测资料的基础上利用模式分析的方法分析了三峡水库对上游营养盐的截流效应. 三峡水库投入使用后发育出的水库生态系统可将上游输入的2%-7%溶解态无机氮和13%-42%的溶解态无机磷固定于浮游生物中库区水体中生物有机碳总量可保持在0.84109-2.65109mol的范围. 相应地三峡工程可减缓长江下游及长江口区的富营养化趋势但却在一定程度上加剧了长江中下游营养盐N/P比上升的趋势.     

长江流域水库"过滤器效应"对入海溶解硅通量的影响

根据1960-2000年间长江大通水文站记录的水、沙以及硅、氮、磷等数据,结合1954-2006年间长江流域库容大于10⁸ m³的162座水库的库容、上游径流量、总磷等数据,利用Vollenweider模型分析了水库"过滤器效应"对入海溶解硅(DSi)通量的影响.结果表明:1)1990s相比1960s,长江入海DSi通量下降了约1.85×10⁶ t/a,减少了大约25.3%;入海DSi通量的下降与流域径流波动、入海悬沙通量下降以及溶解无机氮通量的增加紧密相关.2)流域水库明显改变径流的自然过程,增加径流的滞留时间,流域90%以上的水库对上游径流的滞留时间超过0.05年,水库产生显著的DSi"生物过滤器"效应.模型计算显示流域大型水库对DSi的累计滞留量可达0.85×10⁶ t/a,占年均入海DSi通量(1990-2000年)5.4×10⁶ t的15.7%,是入海DSi通量减少量(1.85×10⁶ t/a)的45.9%.3)根据保守估计,流域162座大型水库内泥沙累计淤积量达6.75×10⁸ t/a,不仅使悬沙入海通量显著下降,而且造成大量颗粒吸附的外源和内源DSi颗粒沉淀,这对入海DSi通量减少也起到重要贡献.但目前对水库"泥沙过滤器"的滞留机理并不清楚,需要展开进一步的研究.     

沉水植物水槽对农村水体净化效果与机制的模拟

实验设计中试水槽装置,模拟研究2种沉水植物轮叶黑藻(Hydrilla nerticillata)和苦草(Vallisneria natans)对农村水体的净化效果,并探讨沉水植物在水体氮、磷去除中的作用.结果显示,沉水植物系统均能显著降低水体中总氮、铵态氮、硝态氮和磷酸盐浓度,去除率分别达到50.5%、84.4%、41.9%和64.6%,且轮叶黑藻组选择20 g/m2,苦草组选择40 g/m2为适种密度.水体流经各串联单元时氮、磷去除负荷存在显著差异,其中总氮、硝态氮、磷酸盐浓度在有植物单元高于无植物单元,铵态氮浓度相反,结合单元内溶解氧浓度、硝化与反硝化细菌总数表明,有植物单元可显著发生反硝化作用,无植物单元可显著发生硝化作用,有无植物串联单元更有利于氮的去除.     

Phosphorus storage,transport and export dynamics in the Foron River watershed

Phosphorus (P) export from the Foron River watershed was intensively monitored. Water was analysed for total P, soluble total P, soluble orthophosphate and suspended solids. Watershed soils and river sediments were sampled and the size fraction <0·2 mm analysed for total P, water extractable P, bioavailable P, 1 minute exchangeable P and P fixation capacity. Interstitial waters were analysed for soluble total P. Four hydrological conditions recurred, two during low river flows and two during increased flow. The first occurs in dry weather with a constant or decreasing flow over at least seven days and when there is no surface runoff. Exported phosphorus, predominately soluble and bioavailable, is from point sources. Phosphorus inputs exceed P export so P accumulates in the river. The second condition occurs when a small storm flow increases the average seven-day flow to exceed the preceding weekly average. Phosphorus export exceeds P inputs and originates from urban runoff, point sources and release of P stored in the river. Exported P is largely particulate but highly bioavailable. The third condition is when substantial runoff follows at least a seven-day period of constant or decreasing flow. Phosphorus export is from diffuse urban runoff. All the P stored is exported. Exported P is highly bioavailable. High concentrations and fluxes of P export are often seen. The fourth condition happens when the soils are wet and increased flow is from both urban and agricultural runoff. Phosphorus export from diffuse agricultural runoff predominates and is largely not bioavailable. Phosphorus concentrations are low but export fluxes are high when flows are high. These hydrological conditions, when integrated with concepts of mass balance define a phosphorus export typology comprising four regimes. These regimes explain total phosphorus (TP) storage, transport and export patterns, changes in P speciation and allow identification of probable sources of TP in the Foron river watershed. © 1998 John Wiley & Sons, Ltd.     

EVALUATION OF EROSION PRODUCTIVITY IMPACT CALCULATOR （EPIC） MODEL FOR MIDDLE MOUNTAIN REGION OF NEPAL

This study verifies the applicability of EPIC model for an erosion plot (61 .2 m~2) and an uplandterraced watershed (72 ha) using a total of 94 rainfall events over a study period of two years. Inorder to analyze the effect of storm size on runoff and soil loss processes, rainfall events aredivided into three groups: small (<25mm), moderate (25--50mm) and large (>50mm). Resultsindicate that the model could predict reasonably well the runoff and soil loss from the erosion plotand the watershed for the moderate and large rainfall events. However, the runoff and soil lossprediction for the small rainfall events is found to be poor. On annual basis, both surface runoff andsoil loss predictions match well the observations. In ligh of the importance of the moderate andlarge rainfall events in producing most of the annual runoff and soil loss in the study area, the EPICmodel is applied to assess the impacts of erosion on agricultural productivity and to evaluatemanagement practices to protect watersheds in the     

Using hydrogeochemical signatures of stream water to assess pathways for rainfall events: towards a predictive model

Thanks to its simple division into agricultural and forestry land use, the Corbeira catchment (Galicia, Spain) is used as a case study to build a predictive model using hydrogeochemical signatures. Stream data acquired under recessional flow conditions over a one year period were obtained from a sampling station near the downstream end of the catchment, and using principal component analysis, it is shown that some of the analytical parameters are covariant, and some are negatively correlated. These findings support inferences about the pathways of rainfall in the catchment. Specific signatures may be associated with the dominant hydrological source, either surface runoff or subsurface waters: additionally, the dominant land use in that part of the catchment, where the flow originated, can also be predicted. The dominant runoff shows a strong covariance between suspended solids (SS) and particulate phosphorus (PP), with a clear negative correlation with pH. Dissolved organic carbon (DOC) data are associated with this covariant set when these compounds are available in the soils in question. Dissolved phosphorus, total organic nitrogen and dissolved nitrates are also associated with the same covariant set when the runoff flows through areas of extensive agricultural use. The SS ? PP covariance is less significant at lower flows. Typical base flow regimes show a significant covariance between salinity and pH, with a marked negative correlation with SS ? PP set, confirming the dominance of subsurface waters in the baseflow, as expected. Seasonally divergent DOC ? SS behaviour proves to be a useful tracer for rainfall regimes. The DOC trend shows a sinusoidal annual variation in amplitude, determined by the rainfall regime. As a result, flow from the catchment is dominated by surface water whenever there is synchronicity between the peaks of DOC and SS. Copyright © 2013 John Wiley & Sons, Ltd.     

Modeling the sediment yield and the impact of vegetated filters using an event‐based soil erosion model—a case study of a small Canadian watershed

This paper presents the first application of the event‐based MHYDAS‐Erosion model to a small agricultural watershed under temperate climate conditions (Quebec, Canada). Simulation results based on observed and synthetic rainfall events revealed a bimodal behaviour of sediment yield. During high‐intensity rainfall events, most of the sediments reaching the watershed outlet originate from cropland. Meanwhile, during low‐intensity events, most of the sediments come from the drainage network. Furthermore, simulation results show that implementation of 5‐m and 20‐m wide vegetated filters throughout the watershed or at the edge of the most problematic fields (4% of the total fields) could reduce soil loss by 52% and 31%, respectively. The modeling framework could be used for the design and location of beneficial management practices such as grass strips and riparian zones Copyright © 2016 John Wiley & Sons, Ltd.     

Incremental distributed modelling investigation in a small agricultural catchment: 2. Erosion and phosphorus transport

Distributed physically based erosion and phosphorus (P) transport models, run by the overland flow model described in Taskinen and Bruen (2006. Hydrological Processes 20 : this issue), are described. In the erosion model, the additional components to the basic model were the outflow of the particles by infiltration and a new model component, i.e. deposition when rainfall stops. Two ways of calculating the shielding factor due to the flow depth were compared. The P transport model had both dissolved P (DP) and particulate P (PP) components. The processes included in the DP model were desorption from the soil surface, advection, storage in the overland flow and infiltration. The PP model accounted for advection, storage in the flow, infiltration, detachment from the soil surface by flow and rainfall and deposition both when transport capacity of suspended solids (SS) is exceeded and when rainfall ceases. When the models were developed and validated in small agricultural fields of cohesive soil types in southern Finland, comparisons were made between corresponding processes and the significance of added components were estimated in order to find out whether increased model complexity improves the model performance. The sedigraphs were found to follow the dynamics of rainfall, emphasizing the importance of the rainfall splash component. The basic model was too slow to react to changes in rainfall and flow rates, but infiltration and deposition that acts during the cessation in rainfall improved the model significantly by enabling the modelled SS to fall sharply enough. The shielding effect of flow depth from the splash detachment was found to play a significant role. Transport capacity should also be included in erosion models when they are applied to cohesive soils. In this study, the Yalin method worked well. A strong correlation was obvious between the measured SS and total P concentrations, indicating that the main form of P in runoff is PP. This emphasizes the importance of a good sediment transport model in P transport modelling. The submodel used for DP desorption from the soil surface produced plausible results without any calibration. Copyright © 2006 John Wiley & Sons, Ltd.     

A study on rainfall,runoff,and soil loss relations at different landuses-A case in Hilkot watershed in Pakistan

Reliable field data for all hydrologic parameters are often unavailable for watersheds even for those intensively monitored.In the absence of reliable such data,verified mathematical relations for an area can be used for other areas with same hydrologic and climatic regimes.The objectives of this research were:1) to assess the total runoff and sediment loss,and 2) to develop rainfall,runoff and soil loss relations for four prominent landuses(including degraded,pasture,forest and agriculture lands) in the Hilkot watershed(Pakistan).Four experimental natural runoff plots were established on the landuses (degraded,pasture,forest and agriculture land).The field study and data collection were conducted in the Hilkot watershed from 1999 to 2005.Regression analysis was conducted to establish relations among rainfall,runoff and soil loss for all landuses using.Regression analysis indicated good correlation with field data.     

Nitrogen and phosphorus dynamics during runoff events over a transition from grassland to shrubland in the south‐western United States

During the last 150 years, land degradation across the semi‐arid grasslands of the south‐western United States has been associated with an increase in runoff and erosion. Concurrent with this increase in runoff and erosion is a loss of nitrogen (N) and phosphorus (P), which are plant‐essential nutrients. This study investigates the runoff‐driven redistribution and loss of dissolved and particulate‐bound N and P that occurs during natural runoff events over a trajectory of degradation, from grassland to degraded shrubland, in central New Mexico. Runoff‐driven nutrient dynamics were monitored at four stages over a transition from grassland to shrubland, for naturally occurring rainfall events over 10 × 30 m bounded runoff plots. Results show that particulate‐bound forms of N and P are responsible for most of N and P lost from the plots due to erosion occurring during runoff events. Results suggest that for high‐magnitude rainfall events, the output of N and P from the plots may greatly exceed the amount input into the plots, particularly over shrub‐dominated plots where erosion rates are higher. As these results only become apparent when monitoring these processes over larger hillslope plots, it is important to recognize that processes of nutrient cycling related to the islands of fertility hypothesis may have previously been overstated when observed only at smaller spatial scales. Thus, the progressive degradation of semi‐arid grassland ecosystems across the south‐western United States and other semi‐arid ecosystems worldwide has the potential to affect N and P cycling significantly through an increase in nutrient redistribution and loss in runoff. Copyright © 2010 John Wiley & Sons, Ltd.     

天目湖流域丘陵山区典型土地利用类型氮流失特征

天目湖丘陵山区农业综合开发持续推进,大量林地转变为茶园,迫切需要认识茶园扩张对流域氮流失的影响.本研究选取茶园、次生马尾松林和毛竹林开展自然降雨条件下的径流小区实验,分析天目湖丘陵山区典型用地类型径流氮流失规律,为评估丘陵山区综合开发的水环境影响提供实测参数.研究表明:茶园、次生马尾松林和毛竹林地表径流TN浓度分别为11.25、2.83和3.60 mg/L,均以溶解态为主;壤中流TN浓度分别为27.16、3.59和1.06 mg/L,茶园和次生马尾松林均以溶解性无机氮(尤其是硝态氮)为主,毛竹林以溶解性有机氮为主;茶园、次生马尾松林和毛竹林的小区尺度地表径流系数均不到0.03,壤中流是丘陵山区径流的主要来源;茶园开发加剧了丘陵山区的氮素流失,茶园径流TN流失强度高达103.08 kg/(hm²·a),分别是次生马尾松林和毛竹林的7.6和23.2倍,壤中流贡献了流失总量的86.7%~99.7%.防治茶园径流氮流失需重点关注壤中流输出,在减量施肥的基础上,采取坡脚构建毛竹林生态缓冲带/在小流域出口布设塘坝等原位拦截措施,实现流域氮流失综合防控.     

Hydrological modelling of a small watershed using generated rainfall in the soil and water assessment tool model

An adequately tested soil and water assessment tool (SWAT) model was applied to the runoff and sediment yield of a small agricultural watershed in eastern India using generated rainfall. The capability of the model for generating rainfall was evaluated for a period of 18 years (1981–1998). The watershed and subwatershed boundaries, drainage networks, slope, soil series and texture maps were generated using a geographical information system (GIS). A supervised classification method was used for land‐use/cover classification from satellite imageries. Model simulated monthly rainfall for the period of 18 years was compared with observations. Simulated monthly rainfall, runoff and sediment yield values for the monsoon season of 8 years (1991–1998) were also compared with their observed values. In general monthly average rainfall predicted by the model was in close agreement with the observed monthly average values. Also, simulated monthly average values of surface runoff and sediment yield using generated rainfall compared well with observed values during the monsoon season of the years 1991–1998. Results of this study revealed that the SWAT model can generate monthly average rainfall satisfactorily and thereby can produce monthly average values of surface runoff and sediment yield close to the observed values. Therefore, it can be concluded that the SWAT model could be used for developing a multiple year management plan for the critical erosion prone areas of a small watershed. Copyright © 2004 John Wiley & Sons, Ltd.     

Distribution and origin of biologically available phosphorus in the water of the Meiliang Bay in summer

The investigation and continuous monitoring with an innovative iron oxide embedded cellulose acetate membrane (FeO/CAM) on the concentrations of biologically available phosphorus (BAP) were conducted in the Meiliang Bay of the Taihu Lake during summer in 2004. The results showed that the concentrations of dissolved (FeO-DP), particulate (FeO-PP) and total bioavailable phosphorus (FeO-P) had similar horizontal distribution. The BAP concentrations were the highest in those estuaries in the northern bay. With the decrease of the distance to the estuary or long shore, there was little difference between BAP concentrations in an open lake area. During the observation period, algal blooms occurred in most waters of the northern bay, which was reflected from the high concentrations of chlorophyll a (Chl-a). While they were not highest in the estuarine waters of those major rivers, this is the case for the BAP concentrations. The concentrations of Chl-a had a significantly positive correlation with those of bioavailable phosphorus in the open area of the Meiliang Bay. With the sediment resuspension induced by wind and wave, BAP concentrations increased in a short-term, indicating that the riverine P inputs mainly contribute to the concentrations of BAP in the estuarine water while internal P release was the major source of BAP in the open lake area. In the eutrophic shallow lake, the blooms of alga may cause pH increase and further result in internal P release. The above results showed that the new membrane of FeO/CAM can be used to monitor the concentrations of BAP and provide the scientific justifications for the control strategy of the lake eutrophication.