青藏高原羌塘南部晚古生代地幔柱?——来自基性-超基性岩的地球化学证据

羌螗南部地区大面积出露基性一超基性火成岩.基性岩墙和玄武岩沿龙木错-双湖板块缝合带的南侧呈近东西向分布,大地构造位置位于冈瓦纳大陆北缘,分布范围西起国境线,东到双湖地区,总长约800km,形成时代集中在晚石炭世-早二叠世(284～318Ma),反映出岩浆的快速侵位-喷溢的过程.基性岩墙和玄武岩主要为碱性系列岩石,少数为亚碱性系列,Ti和Fe的含量均比较高,Mg#比较低,表明它们都是原始岩浆经不同程度分异结晶后的残余熔体.基性岩墙和玄武岩的稀土元素、微量元素、形成环境等均与板内玄武岩或典型的地幔柱成因玄武岩具有相似的特点.另外,苦橄质岩石多与基性岩墙和玄武岩一起产出.主要为单斜辉石橄税岩和二辉橄榄岩,矿物成分贫挥发性组分,主量、稀土和微量元素的特点反映出其很可能代表了地幔柱原始岩浆结晶的产物而非岩浆捕获体,而且其源区很可能为石榴子石二辉橄榄岩.由此,初步认为羌塘南部基性岩墙和玄武岩为地幔柱的头部减压熔融的产物,而苦橄质岩石为地幔柱尾柱通道熔融的产物.     

藏南亚东地区片麻状黑云花岗闪长岩LA-ICP-MS锆石U-Pb测年青藏高原羌塘南部晚古生代地幔柱?——来自基性—超基性岩的地球化学证据

羌塘南部地区大面积出露基性—超基性火成岩。基性岩墙和玄武岩沿龙木错-双湖板块缝合带的南侧呈近东西向分布,大地构造位置位于冈瓦纳大陆北缘,分布范围西起国境线,东到双湖地区,总长约800km,形成时代集中在晚石炭世—早二叠世(284~318Ma),反映出岩浆的快速侵位-喷溢的过程。基性岩墙和玄武岩主要为碱性系列岩石,少数为亚碱性系列,Ti和Fe的含量均比较高,Mg#比较低,表明它们都是原始岩浆经不同程度分异结晶后的残余熔体。基性岩墙和玄武岩的稀土元素、微量元素、形成环境等均与板内玄武岩或典型的地幔柱成因玄武岩具有相似的特点。另外,苦橄质岩石多与基性岩墙和玄武岩一起产出,主要为单斜辉石橄榄岩和二辉橄榄岩,矿物成分贫挥发性组分,主量、稀土和微量元素的特点反映出其很可能代表了地幔柱原始岩浆结晶的产物而非岩浆捕获体,而且其源区很可能为石榴子石二辉橄榄岩。由此,初步认为羌塘南部基性岩墙和玄武岩为地幔柱的头部减压熔融的产物,而苦橄质岩石为地幔柱尾柱通道熔融的产物。     

青藏高原羌塘南部晚古生代地幔柱？——来自基性—超基性岩的地球化学证据

羌塘南部地区大面积出露基性—超基性火成岩。基性岩墙和玄武岩沿龙木错-双湖板块缝合带的南侧呈近东西向分布,大地构造位置位于冈瓦纳大陆北缘,分布范围西起国境线,东到双湖地区,总长约800km,形成时代集中在晚石炭世—早二叠世（284～318Ma）,反映出岩浆的快速侵位-喷溢的过程。基性岩墙和玄武岩主要为碱性系列岩石,少数为亚碱性系列,Ti和Fe的含量均比较高,Mg#比较低,表明它们都是原始岩浆经不同程度分异结晶后的残余熔体。基性岩墙和玄武岩的稀土元素、微量元素、形成环境等均与板内玄武岩或典型的地幔柱成因玄武岩具有相似的特点。另外,苦橄质岩石多与基性岩墙和玄武岩一起产出,主要为单斜辉石橄榄岩和二辉橄榄岩,矿物成分贫挥发性组分,主量、稀土和微量元素的特点反映出其很可能代表了地幔柱原始岩浆结晶的产物而非岩浆捕获体,而且其源区很可能为石榴子石二辉橄榄岩。由此,初步认为羌塘南部基性岩墙和玄武岩为地幔柱的头部减压熔融的产物,而苦橄质岩石为地幔柱尾柱通道熔融的产物。     

四川木里地区二叠纪苦橄岩和玄武岩成因及源区性质

前人对峨眉山玄武岩的研究已经取得大量的研究成果,但对于一些关键科学问题如岩浆源区组成、源区温压条件等还存在分歧,或有待进一步探讨。本文报道了四川木里地区二叠纪苦橄岩和相关玄武岩的岩石学、地球化学和Sr-Nd同位素特征,并进一步探讨了苦橄岩和相关玄武岩的岩浆源区性质、岩浆形成条件。研究表明:四川木里地区二叠纪火成岩主要岩石类型为苦橄岩、高钛玄武岩和低钛玄武岩;苦橄质岩浆来源于地幔柱头部中心的高温区域(地幔柱轴部),岩浆主要起源于石榴石稳定域;高钛和低钛玄武质岩浆来源于地幔柱尾部,高钛玄武质岩浆主要起源于石榴石稳定域,而低钛玄武质岩浆起源于石榴石稳定域和尖晶石稳定域的过渡带;苦橄质和玄武质岩浆在上升过程中都不同程度混染了大陆岩石圈地幔物质,其中低钛玄武质岩浆可能有少量地壳物质的混染。     

峨眉山大火成岩省中发现二叠纪苦橄质熔岩

峨眉山大火成岩省是当前研究的热点,尽管早有报道在峨眉山大火成岩省中存在苦橄岩,但是是否存在真正的二叠纪苦橄质熔岩一直有争论,笔者等对前人报道的“苦橄岩”产地进行了详细的野外地质调查发现,前人报道的所谓“苦橄岩”,不是喷出的熔岩,而是呈侵入状态的苦橄玢岩。这些呈侵入状态的苦橄玢岩在区内分布较多,约有数十个,出露面积一般为50×100～200×700m~2。最大可达8km~2。这些苦橄玢岩除了侵入于峨眉山玄武岩外,部分还侵入于上三叠统白云质灰岩中。由此推测部分苦橄玢岩应晚于晚三叠世。尽管目前还没有可靠的同位素年龄数据,但根据区域对比,一般认为这些苦橄玢岩形成于喜马拉雅期,与峨眉山玄武岩系无关。需要指出的是,在这些报道所谓“苦橄岩”的论文中均没     

青藏高原东南木里地区二叠纪苦橄岩的Os-Sr-Nd同位素地球化学研究

本文报道了在青藏高原东南木里地区发现的二叠纪苦橄岩和与其共生玄武岩的主微量元素地球化学特征以及Os-Sr-Nd同位素组成。苦橄岩和与其共生玄武岩受地壳混染作用影响较小。根据苦橄岩的Ti/Y比值和初始的Os同位素组成,将木里苦橄岩分为两类:高Ti/Y型苦橄岩和低Ti/Y型苦橄岩,其中高Ti/Y型苦橄岩具有高的γ_(Os)= 5.3～ 10.7和ε_(Nd)= 5.9～ 6.4,与全球典型洋岛玄武岩的Os和Nd同位素组成接近,代表了地幔柱源区的同位素特征;而低Ti/Y型苦橄岩具有低的γ_(Os)=-4.1～ 1.2和ε_(Nd)= 3.2～ 5.0,可能表明受到了SCLM(大陆岩石圈地幔)源区物质的混染。与其共生的玄武岩具有低的γ_(Os)=-3.5～-1.6和ε_(Nd)=-0.6～ 0.7,表明其来自于不同于低Ti/Y型苦橄岩也有异于高Ti/Y型苦橄岩的地幔源区,但是也可能受到了SCLM物质的混染。基于Nd-Os同位素的地幔柱与SCLM的二端元混合模型显示:低Ti/Y型苦橄岩可能是SCLM物质组分与地幔柱起源的苦橄质原始岩浆混合形成的;与苦橄岩共生的玄武岩可能是由地幔柱来源的玄武质岩浆与SCLM小比例熔融的熔体混合形成的。     

一种判别原始岩浆的方法--以苦橄岩和碱性玄武岩为例

在前人工作基础上，利用橄榄石和熔浆的Fe—Mg分配乐数，重新制作了MgO—Fo—FeO图解，该图解的优点在于其适用范围更宽，既可用于超基性的苦橄岩，也可用于一般的玄武岩或橄榄玄粗岩系。同时介绍了该图解运用的方法，并且以峨眉山大火成岩省中苦橄岩和黑龙江镜泊湖地区全新世碱性玄武岩为例，说明如何应用该图解来恢复原始岩浆以及解释岩石的成因。研究结果表明，峨眉山大火成岩省中的苦橄岩部分代表了原始岩浆，部分有过剩橄榄石的加入，部分为演化的岩浆形成。与苦橄岩密切共生的辉斑玄武岩是苦橄质岩浆通过橄榄石的分离结晶作用形成的，而在峨眉山大火成岩省中占绝对优势的温流玄武岩则不是苦橄质岩浆简单的分离结晶作用形成。镜泊湖地区的碱性玄武岩均为演化的岩浆，而碧玄岩演化程度较低，碱玄岩则是原始岩浆高度演化的产物。     

科马提岩与苦橄岩的区别及对若干晚古生代“科马提岩”的质疑

以往学术界更多的关注科马提岩和苦橄岩的相似性,忽略其差异。通过全数据模式,采集数据库内全球的太古宙科马提岩、后太古宙低/高钛苦橄岩数据,对比三者之间的差异发现,科马提岩更富MgO、Cr、Ni、Cs、Pb、Co和Zn,其次为低钛苦橄岩(除Co和Zn),其余主量、微量元素的含量由高至低依次为高钛苦橄岩、低钛苦橄岩、科马提岩。依据元素间的差异(如Cr/Ga、MgO/Ga、MnO/Zr、Cr/Zr等),采用密度分布函数(Density Distribution)在Matlab软件中绘制出可有效区分3类岩石的等密度判别图,并用该图对若干晚古生代"科马提岩"的岩性重新厘定。结合岩相学和地球化学特征研究表明,晚古生代"科马提岩"中,印度东部为高钛苦橄岩,越南为化学成分与科马提岩类似的低钛苦橄岩,印度拉达克地区为低钛苦橄岩。     

阿尔泰山南缘中泥盆世苦橄岩中单斜辉石的成分特征及其地质意义

岛弧苦橄岩非常稀少,但在阿尔泰山南缘却分布有世界上罕见的中泥盆世厚大苦橄岩层。本文对该地区苦橄岩及其共生的玄武岩中单斜辉石的矿物化学成分进行了电子探针分析,结果表明,苦橄岩中的单斜辉石全部为透辉石,玄武岩中的单斜辉石种属有普通辉石和透辉石两类,但玄武岩中的单斜辉石成分呈连续演化关系。根据单斜辉石-熔体平衡原理计算了苦橄岩中单斜辉石斑晶形成的温度和压力,其变化范围主要集中在1350～1387℃和16.6～21.3kPa,相应的深度为55～70km,大致代表了苦橄岩岩浆房的深度。与此不同的是,玄武岩中单斜辉石斑晶结晶的深度较苦橄岩浅,为37～41km,暗示玄武岩浆是在相对低压条件下分离结晶后形成的演化岩浆。基于单斜辉石的成分和演化,确定了该地区火山岩属亚碱性系列,其构造背景为岛弧环境。     

峨眉山大火成岩省西部苦橄岩及其共生玄武岩的地球化学：地幔柱头部熔融的证据

丽江地区的苦橄岩位于峨眉山大火成岩省的西部，其与辉斑玄武岩、无斑玄武岩和玄武质火山碎屑岩共生。苦橄岩中的斑晶主要为富镁橄榄石，其F0含量最高达91．6％，CaO含量最高达0．42％，其内含有少量玻璃包裹体，指示了橄榄石是在熔体中结晶形成的。苦橄岩中的铬尖晶石具有高的Cr#值（73-75）。计算的初始岩浆的MgO含量大约为22wt％，初始熔融的温度为1630-1680℃。研究结果表明，玄武质岩石是苦橄质岩浆通过橄榄石和单斜辉石分离结晶形成的。苦橄岩和玄武岩的Nd-Sr-Pb同位素比值差别不大，只落在一个很小的范围内（如εNd（t）=-1．3 to＋4．0）。高的εNd（t）值以及抗蚀变不相容元素的原始地幔标准化图解与洋岛玄武岩相似，并且其重稀土元素特征指示了源区有石榴子石的残余，而且是低部分熔融的产物。同位素比值与抗蚀变不相容元素比值（如Nb／La）的相关性表明，岩浆形成过程中有少量的大陆地壳物质或者相对低εNd（t）组分的大陆岩石圈地幔的混染。因此，总体上，苦橄岩的地球化学特征的研究结果支持了峨眉山大火成岩省是地幔柱头部熔融的成因模型。     

徐州白露山含金刚石橄榄玄武岩地球化学特征及其岩浆演化特征

江苏徐州地区位于华北克拉通的东南部,其区内及周边广泛发育碱性超基性岩-基性岩,其中不乏含金刚石母岩,但是主要为金伯利岩。笔者在苏北寻找金刚石原生矿的过程中,在徐州白露山地区发现了含金刚石的橄榄玄武岩。本区橄榄玄武岩SiO₂含量为42.64%~51.13%,K₂O+Na₂O为2.57%~5.93%,Al₂O₃为10.48%~13.53%,MgO含量变化范围较大,为3.11%~19.34%。以主量元素做TAS图解可以看出本区基性岩的投影点基本都落于玄武岩范围,属于高钾钙碱性。微量元素特征显示白露山的样品靠近OIB和火山弧区域。富集端元明显偏高的Ba/Th比值暗示玄武岩中含有大陆下地壳物质。而白露山橄榄玄武岩元素地球化学特征及组成变化范围大并不是主要由地壳混染引起的,而是因为源区含有残留的再循环大陆下地壳。这些地球化学特征说明徐州白露山橄榄玄武岩与辽宁、山东地区金伯利岩具有一定的成因联系,为该区金刚石找矿提供了有利线索。     

新疆天山地区榆树沟-铜花山蛇绿岩特征和构造背景

榆树沟-铜花山蛇绿岩出露于南天山北缘,属哈萨克斯坦-伊犁板块和塔里木板块之间的缝合带。蛇绿岩已被构造肢解,主要由超镁铁岩、堆晶岩、熔岩类组成。超镁铁岩以方辉橄榄岩为主,显示典型的亏损地幔岩特征,橄榄石为富镁型,Fo为90;斜方辉石为顽火辉石,En为90,单斜辉石含量少;副矿物铬尖晶石属低铬型,Cr^#值(＝Cr/(Cr+Al)×100)16~28,Mg^#值(=Mg/(Mg+Fe)×100)63~75,反映了深海橄榄岩特征。归一化后榆树沟超镁铁岩MgO含量38.84%~44.53%,Al₂O₃为1.51%~3.63%,CaO为0.42%~5.77%,成分近于大洋二辉橄榄岩;铜花山的超镁铁岩叠加碳酸岩化,LREE强烈富集,可能经历了俯冲洋壳流体改造。熔岩类在榆树沟和铜花山均有较大规模产出,其中榆树沟玄武岩为主,铜花山安山岩和英安岩较多。熔岩多已遭受绿片岩相海底热液蚀变。榆树沟玄武岩的REE含量总体比铜花山的低,稀土配分模式均为轻稀土富集型;玄武岩的微量元素特征表明其源区可能遭受过流体作用影响。铜花山三个高镁火山岩化学成份具有SiO₂(32%~36%)含量很低、MgO(20.12%~28.50%)含量高、K₂O+Na₂O(0.06%~0.46%)含量小于2%的特征,综合分析可归为苦橄岩类。堆晶岩通常以构造小岩块产在超镁铁岩块中或基性熔岩中,以辉长岩为主,有少量橄榄辉石岩等,岩石蚀变、构造变形强烈。堆晶岩的成分接近玄武岩,存在LREE富集和略亏损平坦两种类型。岩石地球化学特征表明榆树沟和铜花山的蛇绿岩形成于MOR构造环境,但具有受俯冲带流体改造特征,并伴生有岛弧火山岩。     

羌北-昌都地块那益雄组火山岩锆石U-Pb年代学及地球化学特征

本文对青藏高原羌北-昌都地块阿布日阿加措地区的晚二叠世那益雄组火山岩进行了年代学和地球化学研究。该火山岩主要由玄武岩、安山玄武岩、安山岩、流纹岩、凝灰岩组成,具有碱性玄武岩到酸性熔岩的特征。锆石U-Pb年代学研究表明该火山岩的形成时代为251. 1±4. 8～249. 6±1. 3 Ma之间。地球化学分析结果表明,该地区的流纹岩具有高的Si O2(74. 85%～77. 55%)和Na2O+K2O(5. 40%～6. 61%)含量,较低的MgO、K2O和Ca O含量,Al2O3含量低且稳定,里特曼指数平均为1. 15,小于3. 3。安山岩Si O2含量55. 13%～56. 28%,Na2O+K2O含量4. 13%～6. 15%,里特曼指数平均为2. 20,小于3. 3,属于钙碱性安山岩。碱性玄武岩Si O2含量51. 49%,Na2O+K2O含量6. 34%,里特曼指数为4. 73,属于碱性系列。稀土元素配分曲线为富集LREE的右倾型。另外,富集大离子亲石元素(LILE) Th、U,亏损高场强元素(HFSE) Nb、Ta等特征,均说明羌北-昌都地块阿布日阿加措地区的火山岩形成于陆缘岛弧环境。     

Meimechites, porphyritic alkaline picrites, and melanephelinites of Siberia: Conditions of crystallization, parental magmas, and sources

The investigation of rocks, minerals, and melt inclusions showed that porphyritic alkaline picrites and meimechites crystallized from different parental magmas. At a similar ultrabasic composition, the alkaline picrite melts were enriched in K₂O relative to Na₂O, and contained up to 0.12–0.13 wt % F and less Cr, Ni, and H₂O (only 0.01–0.16 wt % H₂O, versus 0.6–1.6 wt % in the meimechite melts) compared with the meimechite magmas. The crystallization of alkaline picrite melts occurred under stable conditions at relatively low temperatures without abrupt changes: olivine and clinopyroxene crystallized at 1340–1285 and 1230–1200°C, respectively, as compared with 1600–1450 and 1230–1200°C in the meimechites. The alkaline picrite melts evolved toward melanephelinite, nephelinite, tephrite, and trachydolerite; whereas the meimechite magmas gave rise to subalkaline picritic rocks. The partitioning of vanadium between olivine and melt suggests that the meimechite magma crystallized under more oxidizing conditions compared with the alkaline picrite melts: the K_DV values for the meimechite melts (0.011–0.016) were three times lower than those for the alkaline picrite melts (0.045–0.052). The parental magmas of the alkaline picrites and meimechites were enriched in trace elements relative to mantle levels by factors of tens to hundreds. The alkaline picrite magma showed lower LILE and LREE contents compared with the meimechite magma. The magmas had also different indicator ratios of incompatible elements, including those immobile in aqueous fluids. It was concluded that the meimechite and alkaline picrite melts were derived from different mantle sources. The former were generated at lower degrees of melting of an undepleted mantle source, and the meimechite melts were produced by high-degree melting of a probably lherzolite-harzburgite source.     

Basalt contamination by continental crust: Some experiments and models

Chemical interaction between molten basalt and felsic minerals of the continental crust (quartz, K-feldspar, and oligoclase) was examined in static and dynamic experiments at 1,200°–1,400° C. Under circumstances of continuous stirring at 1,400°, -quartz dissolves in tholeiite melt at a rate of 3.3×10^–6 g/s per cm² of contact area; at 1,300°, the solution rate is 1.5×10^–6 g/cm{cm2}s. The feldspars are molten at the experimental conditions, and interact with contacting basalt melt by diffusion in the liquid state. This is a complex process characterized by rapid initial diffusion of alkalies to establish a distribution between felsic melt and basalt similar to that observed in cases of actual two-liquid equilibrium (both alkalies reach concentrations in the felsic melt 1.5–3 times those in the basalt). Alkali diffusion may be uphill or downhill, depending on which direction of net flux is required to produce a two-liquid type distribution. Once this distribution is attained, subsequent diffusion of all melt species is slow and apparently limited by the diffusivity of SiO₂, which is 10^–9-l0^–10 cm²/s at 1,200° C. Interdiffusion experiments involving molten basalt and synthetic granite confirm the behavior illustrated by the feldspar/basalt results, and give similar SiO₂ diffusivities.The solution rates and interdiffusion data can be used to model basalt contamination processes likely to occur in the continental crust. For the restricted case of solid quartzitic xenoliths, the uptake of SiO₂ in a well-mixed basalt magma is quite fast: appreciable SiO₂ contamination may occur over exposure times of only days to years. If basalt magma induces local melting of crustal rocks, the assimilation process becomes one of liquid-state interdiffusion. In this case, the varying diffusivities of ions and their differing preferences for silicic relative to basaltic melts can produce marked selective contamination effects. Selective contamination of ascending basaltic magmas is particularly likely in the case of K₂O, which may be introduced in substantial amounts even when other elements remain unaffected. The Na₂O content of mantle-derived magmas is buffered against contamination by crustal materials, and K₂O is buffered against further increases once it reaches a level of 1–1.5 wt.%.     

The Late Neoproterozoic rift-related metarhyolite–basalt association of the Glushikha trough (Yenisei Ridge): petrogeochemical composition,age, and formation conditions

New data are presented on the petrogeochemical composition, age, and formation conditions of the Late Neoproterozoic metarhyolite–basalt association of the Glushikha trough (Yenisei Ridge). The association is localized within the subaerial and shallow-water terrigenous-carbonate sediments of the Orlovka Group, which overlies Proterozoic rocks with unconformity. The felsic volcanics are essentially potassic and enriched in Rb, U, Th, and Fe. They show a weakly fractionated REE pattern with a prominent negative Eu anomaly. The basalts and picrite basalts have higher contents of Ti, Fe, P, HFSE, REE, U, Th, Ba, and Sr, and their spidergrams show no Nb or Ta depletion with respect to Th and LREE. These rocks have the petrochemical parameters of intraplate magmatic associations in continental rift zones. New geochronological data (SHRIMP II) on single zircon grains from the felsite porphyry of the metarhyolite–basalt association (717 ± 15 Ma) indicate Late Neoproterozoic volcanism in the Yenisei part of the Central block of the Trans-Angara region. According to Sm–Nd isotopic data, the rhyolites originate from Paleoproterozoic crust (T_Nd(DM) = 1757 Ma; T_Nd(DM-2st) = 1651 Ma; ∑ _Nd(T) = ? 2.7). The Orlovka volcanosedimentary rocks are rift-related, as evidenced by the following facts: (1) localization of the volcanosedimentary rocks in a narrow fault-line trough; (2) bimodal rhyolite-basaltic composition of the volcanics; and (3) petrology and geochemistry of the picrite basalts and basalts, typical of intraplate environments. The studies show that Late Neoproterozoic rifting and intraplate plume magmatism took place not only in the Tatarka–Ishimba fault zone but also in the Yenisei fault zone of the Yenisei Ridge.     

Al_2O_3/Ti:风化与蚀变过程中的原岩示踪

Al_2O_3和Ti在风化和热液蚀变等地球化学过程中通常被认为是不活动元素,两者的比值Al_2O_3/Ti常被用来指示地球化学作用过程。通过对中国157件火成岩样品元素含量平均值的统计发现,火成岩样品中Al_2O_3/Ti与SiO_2含量值之间存在着较好的幂函数关系:ln(Al_2O_3/Ti)=0.073×SiO_2-0.89,式中Al_2O_3和SiO_2和Ti含量单位均为%。本文基于得到的经验方程和TAS图解构建了一个新的判别岩石类型的图解——Al_2O_3-Ti图解。该图解可以区分酸性岩、中酸性岩、中性岩、中基性岩-基性岩四类岩性。通过对三个火成岩风化剖面的研究发现,花岗岩风化剖面从新鲜基岩到风化形成的土壤在Al_2O_3-Ti图解中均落在酸性岩区,花岗闪长岩风化剖面从新鲜基岩到风化形成的土壤样品均落在中酸性岩区,玄武质安山岩风化剖面从新鲜基岩到风化形成的土壤样品均落在中基性岩-基性岩区。不同风化程度的风化产物与其母岩在Al_2O_3-Ti图解中所在的区域一致,即Al_2O_3-Ti图解可以用来追溯火成岩风化产物的母岩岩性。通过对胶东焦家金矿和豫西牛头沟金矿两个矿区岩石的研究发现,黑云母花岗岩从新鲜岩石到其蚀变岩及其形成矿石的样品在Al_2O_3-Ti图解中均落在酸性岩区。玄武质安山岩从新鲜岩石到其蚀变岩及其形成矿石的样品在Al_2O_3-Ti图解中均落在中基性岩-基性岩区。即不同蚀变程度的蚀变产物与其原岩在Al_2O_3-Ti图解中所在的区域一致,这表明新构建的Al_2O_3-Ti图解可以用来示踪蚀变岩的原岩性质。     

Melting and phase relations in the plane tholeiite-lherzolite-nepheline basanite to 40 kilobars with geological implications

Six crystalline mixtures, picrite, olivine-rich tholeiite, nepheline basanite, alkali picrite, olivine-rich basanite, and olivine-rich alkali basalt were recrystallized at pressures to 40 kb, and the phase equilibria and sequences of phases in natural basaltic and peridotitic rocks were investigated.The picrite was recrystallized along the solidus to the assemblages (1) olivine+orthopyroxene+ clinopyroxene +plagioclase+spinel below 13 kb, (2) olivine+orthopyroxene+clinopyroxene+spinel between 13 kb and 18 kb, (3) olivine+orthopyroxene+clinopyroxene+ garnet+spinel between 18 kb and 26 kb, and (4) olivine+clinopyroxene+garnet above 26 kb. The solidus temperature at 1 atm is slightly below 1,100° and rises to 1,320° at 20 kb and 1,570° at 40 kb. Olivine is the primary phase crystallizing from the melt at all pressures to 40 kb.The olivine-rich tholeiite was recrystallized along the solidus into the assemblages (1) olivine+ clinopyroxene+plagioclase+spinel below 13 kb, (2) clinopyroxene+orthopyroxene+ spinel between 13 kb and 18 kb, (3) clinopyroxene+garnet+spinel above 18 kb. The solidus temperature is slightly below 1,100° at 1 atm, 1,370° at 20 kb, and 1,590° at 40 kb. The primary phase is olivine below 20 kb but is orthopyroxene at 40 kb.In the nepheline basanite, olivine is the primary phase below 14 kb, but clinopyroxene is the first phase to appear above 14 kb. In the alkali-picrite the primary phase is olivine to 40 kb. In the olivine-rich basanite, olivine is the primary phase below 35 kb and garnet is the primary phase above 35 kb. In the olivine-rich alkali basalt the primary phase is olivine below 20 kb and is garnet at 40 kb.Mineral assemblages in a granite-basalt-peridotite join are summarized according to reported experimental data on natural rocks. The solidus of mafic rock is approximately given by T=12.5 P _Kb+1,050°. With increasing pressure along the solidus, olivine disappears by reaction with plagioclase at 9 kb in mafic rocks and plagioclase disappears by reaction with olivine at 13 kb in ultramafic rocks. Plagioclase disappears at around 22 kb in mafic rocks, but it persists to higher pressure in acidic rocks. Garnet appears at somewhat above 18 kb in acidic rocks, at 17 kb in mafic rocks, and at 22 kb in ultramafic rocks.The subsolidus equilibrium curves of the reactions are extrapolated according to equilibrium curves of related reactions in simple systems. The pyroxene-hornfels and sanidinite facies is the lowest pressure mineral facies. The pyroxene-granulite facies is an intermediate low pressure mineral facies in which olivine and plagioclase are incompatible and garnet is absent in mafic rocks. The low pressure boundary is at 7.5 kb at 750° C and at 9.5 kb at 1,150° C. The high pressure boundary is 8.0 kb at 750° C and 15.0 kb at 1,150° C. The garnet-granulite facies is an intermediate high pressure facies and is characterized by coexisting garnet and plagioclase in mafic rocks. The upper boundary is at 10.3 kb at 750° C and 18.0 kb at 1,150° C. The eclogite facies is the highest pressure mineral facies, in which jadeite-rich clinopyroxene is stable.Compositions of minerals in natural rocks of the granulite facies and the eclogite facies are considered. Clinopyroxenes in the granulite-facies rocks have smaller jadeite-Tschermak's molecule ratios and higher amounts of Tschermak's molecule than clinopyroxenes in the eclogite-facies rocks. The distribution coefficients of Mg between orthopyroxene and clinopyroxene are normally in the range of 0.5–0.6 in metamorphic rocks in the granulite facies. The distribution coefficients of Mg between garnet and clinopyroxene suggest increasing crystallization temperature of the rocks in the following order: eclogite in glaucophane schist, eclogite and granulite in gneissic terrain, garnet peridotite, and peridotite nodules in kimberlite.Temperatures near the bottom of the crust in orogenic zones characterized by kyanitesillimanite metamorpbism are estimated from the mineral assemblages of metamorphic rocks in Precambrian shields to be about 700° C at 7 kb and 800° C at 9 kb, although heat-flow data suggest that the bottom of Precambrian shield areas is about 400° C and the eclogite facies is stable.The composition of liquid which is in equilibrium with peridotite is estimated to be close to tholeiite basalt at the surface pressure and to be picrite at around 30 kb. The liquid composition becomes poorer in normative olivine with decreasing pressure and temperature.During crystallization at high pressure, olivine and orthopyroxene react with liquid to form clinopyroxene, and a discontinuous reaction series, olivine orthopyroxene clinopyroxene is suggested. By fractional crystallization of pyroxenes the liquid will become poorer in SiO₂. Therefore, if liquid formed by partial melting of peridotite in the mantle slowly rises maintaining equilibrium with the surrounding peridotite, the liquid will become poorer in MgO by crystallization of olivine, and tholeiite basalt magma will arrive at the surface. On the other hand, if the liquid undergoes fractional crystallization in the mantle, the liquid may change in composition to alkali-basalt magma and alkali-basalt volcanism may be seen at a late stage of volcanic activity.Publication No. 681, Institute of Geophysics and Planetary Physics, University of California, Los Angeles.     

四川昭觉县中部乡镇表层土壤硒地球化学特征

硒元素是人体必需的微量元素之一,食用富硒农产品是人体获取和补充硒元素的主要途径,调查区域硒地球化学特征是有效地利用富硒土地资源以及开发富硒农副产品的重要依据。本文选择四川省昭觉县域内较为重要的农耕乡镇采集表层土壤样品,采用原子荧光光谱法、X射线荧光光谱法、电感耦合等离子体质谱/发射光谱法等方法测定1328件土壤、19件玉米及20件土豆中硒等地球化学指标含量,利用相关分析与统计学等方法,结合距离加权反比插值法,探讨研究区硒含量、分布和影响因素等地球化学特征,评价土壤与作物的富硒情况及安全性。结果表明：(1)研究区表层土壤硒含量范围为0.04～1.50mg/kg,平均值为0.33mg/kg,划定富硒土壤面积为7.23km~2,占全区土壤面积的30.31%,玄武岩发育的土壤硒含量最高,平均值为0.4mg/kg,表明区内地质背景与土壤硒含量密切相关,区内富硒土壤主要受含玄武岩夹苦橄岩、凝灰质砂泥岩的峨眉山玄武岩组地层控制;(2)不同的用地类型和土壤类型对硒元素的富集能力不同,人为农业活动导致土壤对硒的吸附能力下降,黄棕壤土层中黏粒或铁氧化物等易与硒结合富集;酸性土壤中硒含量与pH值成反比;土壤...     

Petrogenesis of rhyolites and trachytes from the Deccan Trap: Sr,Nd and Pb isotope and trace element evidence

Trachytes and rhyolites from Salsette Island, north of Bombay, have distinctive trace element and isotope features which mark them out from typical crustal melts. Their highly incompatible trace element and Sr-, Nd and Pb isotope ratios are similar to those of the associated Deccan flood basalts. Thus the rhyolites and trachytes are closely related to the basalts, and a striking compositional gap between 50 and 65% SiO₂ suggests that the high SiO₂ rocks evolved by 10–15% partial melting followed by variable amounts of fractional crystallisation. The source material could have been basalt within the Deccan Trap, or related gabbroic rocks in deep crustal sill complexes. The rhyolites yield an Rb-Sr whole rock age of 61.5±1.9 Ma, with a slightly high initial ⁸⁷Sr/⁸⁶Sr=0.7085±18. It is argued that crustal extension provides a suitable regime for the generation of acid magmas by partial melting of associated basic rocks.