Constraints from monazite and xenotime growth modelling in the MnCKFMASH‐PYCe system on the P–T path of a metapelite from Shillong‐Meghalaya Plateau: implications for the Indian shield assembly

The Palaeo‐Mesoproterozoic metapelite granulites from northern Garo Hills, western Shillong‐Meghalaya Gneissic Complex (SMGC), northeast India, consist of resorbed garnet, cordierite and K‐feldspar porphyroblasts in a matrix comprising shape‐preferred aggregates of biotite±sillimanite+quartz that define the penetrative gneissic fabric. An earlier assemblage including biotite and sillimanite occurs as inclusions within the garnet and cordierite porphyroblasts. Staurolite within cordierite in samples without matrix sillimanite is interpreted to have formed by a reaction between the sillimanite inclusion and the host cordierite during retrogression. Accessory monazite occurs as inclusions within garnet as well as in the matrix, whereas accessory xenotime occurs only in the matrix. The monazite inclusions in garnet contain higher Ca, and lower Y and Th/U than the matrix monazite outside resorbed garnet rims. On the other hand, matrix monazite away from garnet contains low Ca and Y, and shows very high Th/U ratios. The low Th/U ratios (<10) of the Y‐poor garnet‐hosted monazite indicate subsolidus formation during an early stage of prograde metamorphism. A calculated P–T pseudosection in the MnCKFMASH‐PYCe system indicates that the garnet‐hosted monazite formed at <3 kbar/600 °C (Stage A). These P–T estimates extend backward the previously inferred prograde P–T path from peak anatectic conditions of 7–8 kbar/850 °C based on major mineral equilibria. Furthermore, the calculated P–T pseudosections indicate that cordierite–staurolite equilibrated at ~5.5 kbar/630 °C during retrograde metamorphism. Thus, the P–T path was counterclockwise. The Y‐rich matrix monazite outside garnet rims formed between ~3.2 kbar/650 °C and ~5 kbar/775 °C (Stage B) during prograde metamorphism. If the effect of bulk composition change due to open system behaviour during anatexis is considered, the P–T conditions may be lower for Stage A (<2 kbar/525 °C) and Stage B (~3 kbar/600 °C to ~3.5 kbar/660 °C). Prograde garnet growth occurred over the entire temperature range (550–850 °C), and Stage‐B monazite was perhaps initially entrapped in garnet. During post‐peak cooling, the Stage‐B monazite grains were released in the matrix by garnet dissolution. Furthermore, new matrix monazite (low Y and very high Th/U ≤80, ~8 kbar/850–800 °C, Stage C), some monazite outside garnet rims (high Y and intermediate Th/U ≤30, ~8 kbar/800–785 °C, Stage D), and matrix xenotime (<785 °C) formed through post‐peak crystallization of melt. Regardless of textural setting, all monazite populations show identical chemical ages (1630–1578 Ma, ±43 Ma). The lithological association (metapelite and mafic granulites), and metamorphic age and P–T path of the northern Garo Hills metapelites and those from the southern domain of the Central Indian Tectonic Zone (CITZ) are similar. The SMGC was initially aligned with the southern parts of CITZ and Chotanagpur Gneissic Complex of central/eastern India in an ENE direction, but was displaced ~350 km northward by sinistral movement along the north‐trending Eastern Indian Tectonic Zone in Neoproterozoic. The southern CITZ metapelites supposedly originated in a back‐arc associated with subducting oceanic lithosphere below the Southern Indian Block at c. 1.6 Ga during the initial stage of Indian shield assembly. It is inferred that the SMGC metapelites may also have originated contemporaneously with the southern CITZ metapelites in a similar back‐arc setting.     

Exhumation of the Main Central Thrust from Lower Crustal Depths, Eastern Bhutan Himalaya

Geothermometry and mineral assemblages show an increase of temperature structurally upwards across the Main Central Thrust (MCT); however, peak metamorphic pressures are similar across the boundary, and correspond to depths of 35–45 km. Garnet‐bearing samples from the uppermost Lesser Himalayan sequence (LHS) yield metamorphic conditions of 650–675 °C and 9–13 kbar. Staurolite‐kyanite schists, about 30 m above the MCT, yield P‐T conditions near 650 °C, 8–10 kbar. Kyanite‐bearing migmatites from the Greater Himalayan sequence (GHS) yield pressures of 10–14 kbar at 750–800 °C. Top‐to‐the‐south shearing is synchronous with, and postdates peak metamorphic mineral growth. Metamorphic monazite from a deformed and metamorphosed Proterozoic gneiss within the upper LHS yield U/Pb ages of 20–18 Ma. Staurolite‐kyanite schists within the GHS, a few metres above the MCT, yield monazite ages of c. 22 ± 1 Ma. We interpret these ages to reflect that prograde metamorphism and deformation within the Main Central Thrust Zone (MCTZ) was underway by c. 23 Ma. U/Pb crystallization ages of monazite and xenotime in a deformed kyanite‐bearing leucogranite and kyanite‐garnet migmatites about 2 km above the MCT suggest crystallization of partial melts at 18–16 Ma. Higher in the hanging wall, south‐verging shear bands filled with leucogranite and pegmatite yield U/Pb crystallization ages for monazite and xenotime of 14–15 Ma, and a 1–2 km thick leucogranite sill is 13.4 ± 0.2 Ma. Thus, metamorphism, plutonism and deformation within the GHS continued until at least 13 Ma. P‐T conditions at this time are estimated to be 500–600 °C and near 5 kbar. From these data we infer that the exhumation of the MCT zone from 35 to 45 km to around 18 km, occurred from 18 to 16 to c. 13 Ma, yielding an average exhumation rate of 3–9 mm year^?1. This process of exhumation may reflect the ductile extrusion (by channel flow) of the MCTZ from between the overlying Tibetan Plateau and the underthrusting Indian plate, coupled with rapid erosion.     

The timing of migmatization in the northern Arabian–Nubian Shield: Evidence for a juvenile sedimentary component in collision‐related batholiths

Collision‐related granitoid batholiths, like those of the Hercynian and Himalayan orogens, are mostly fed by magma derived from metasedimentary sources. However, in the late Neoproterozoic calcalkaline (CA) batholiths of the Arabian–Nubian Shield (ANS), which constitutes the northern half of the East African orogen, any sedimentary contribution is obscured by the juvenile character of the crust and the scarcity of migmatites. Here, we use paired in situ LASS‐ICP‐MS measurements of U–Th–Pb isotope ratios and REE contents of monazite and xenotime and SHRIMP‐RG analyses of separated zircon to demonstrate direct linkage between migmatites and granites in the northernmost ANS. Our results indicate a single prolonged period of monazite growth at 640–600 Ma, in metapelites, migmatites and peraluminous granites of three metamorphic suites: Abu‐Barqa (SW Jordan), Roded (S Israel) and Taba–Nuweiba (Sinai, Egypt). The distribution of monazite dates and age zoning in single monazite grains in migmatites suggest that peak thermal conditions, involving partial melting, prevailed for c. 10 Ma, from 620 to 610 Ma. REE abundances in monazite are well correlated with age, recording garnet growth and garnet breakdown in association with the prograde and retrograde stages of the melting reactions, respectively. Xenotime dates cluster at 600–580 Ma, recording retrogression to greenschist facies conditions as garnet continued to destabilize. Phase equilibrium modelling and mineral thermobarometry yield P–T conditions of ~650–680°C and 5–7 kbar, consistent with either water‐fluxed or muscovite‐breakdown melting. The expected melt production is 8–10 vol.%, allowing a melt connectivity network to form leading to melt segregation and extraction. U–Pb ages of zircon rims from leucosomes indicate crystallization of melt at 610 ± 10 Ma, coinciding with the emplacement of a vast volume of CA granites throughout the northern ANS, which were previously considered post‐collisional. Similar monazite ages (c. 620 Ma) retrieved from the amphibolite facies Elat schist indicate that migmatites are the result of widespread regional rather than local contact metamorphism, representing the climax of the East African orogenesis.     

Phase equilibria modelling and LASS monazite petrochronology: P–T–t constraints on the evolution of the Priest River core complex,northern Idaho

Phase equilibria modelling, laser‐ablation split‐stream (LASS)‐ICP‐MS petrochronology and garnet trace‐element geochemistry are integrated to constrain the P–T–t history of the footwall of the Priest River metamorphic core complex, northern Idaho. Metapelitic, migmatitic gneisses of the Hauser Lake Gneiss contain the peak assemblage garnet + sillimanite + biotite ± muscovite + plagioclase + K‐feldspar ± rutile ± ilmenite + quartz. Interpreted P–T paths predict maximum pressures and peak metamorphic temperatures of ~9.6–10.3 kbar and ~785–790 °C. Monazite and xenotime ²⁰⁸Pb/²³²Th dates from porphyroblast inclusions indicate that metamorphism occurred at c. 74–54 Ma. Dates from HREE‐depleted monazite formed during prograde growth constrain peak metamorphism at c. 64 Ma near the centre of the complex, while dates from HREE‐enriched monazite constrain the timing of garnet breakdown during near‐isothermal decompression at c. 60–57 Ma. Near‐isothermal decompression to ~5.0–4.4 kbar was followed by cooling and further decompression. The youngest, HREE‐enriched monazite records leucosome crystallization at mid‐crustal levels c. 54–44 Ma. The northernmost sample records regional metamorphism during the emplacement of the Selkirk igneous complex (c. 94–81 Ma), Cretaceous–Tertiary metamorphism and limited Eocene exhumation. Similarities between the Priest River complex and other complexes of the northern North American Cordillera suggest shared regional metamorphic and exhumation histories; however, in contrast to complexes to the north, the Priest River contains less partial melt and no evidence for diapiric exhumation. Improved constraints on metamorphism, deformation, anatexis and exhumation provide greater insight into the initiation and evolution of metamorphic core complexes in the northern Cordillera, and in similar tectonic settings elsewhere.     

Two successive phases of ultrahigh temperature metamorphism in Rogaland,S. Norway: Evidence from Y‐in‐monazite thermometry

In Rogaland, South Norway, a polycyclic granulite facies metamorphic domain surrounds the late‐Sveconorwegian anorthosite–mangerite–charnockite (AMC) plutonic complex. Integrated petrology, phase equilibria modelling, monazite microchemistry, Y‐in‐monazite thermometry, and monazite U–Th–Pb geochronology in eight samples, distributed across the apparent metamorphic field gradient, imply a sequence of two successive phases of ultrahigh temperature (UHT) metamorphism in the time window between 1,050 and 910 Ma. A first long‐lived metamorphic cycle (M1) between 1,045 ± 8 and 992 ± 11 Ma is recorded by monazite in all samples. This cycle is interpreted to represent prograde clockwise P–T path involving melt production in fertile protoliths and culminating in UHT conditions of ~6 kbar and 920°C. Y‐in‐monazite thermometry, in a residual garnet‐absent sapphirine–orthopyroxene granulite, provides critical evidence for average temperature of 931 and 917°C between 1,029 ± 9 and 1,006 ± 8 Ma. Metamorphism peaked after c. 20 Ma of crustal melting and melt extraction, probably supported by a protracted asthenospheric heat source following lithospheric mantle delamination. Between 990 and 940 Ma, slow conductive cooling to 750–800°C is characterized by monazite reactivity as opposed to silicate metastability. A second incursion (M2) to UHT conditions of ~3.5–5 kbar and 900–950°C, is recorded by Y‐rich monazite at 930 ± 6 Ma in an orthopyroxene–cordierite–hercynite gneiss and by an osumilite gneiss. This M2 metamorphism, typified by osumilite paragenesis, is related to the intrusion of the AMC plutonic complex at 931 ± 2 Ma. Thermal preconditioning of the crust during the first UHT metamorphism may explain the width of the aureole of contact metamorphism c. 75 Ma later, and also the rarity of osumilite‐bearing assemblages in general.     

Behaviour of geochronometers and timing of metamorphic reactions during deformation at lower crustal conditions: phase equilibrium modelling and U–Pb dating of zircon,monazite, rutile and titanite from the Kalak Nappe Complex,northern Norway

This study investigates the behaviour of the geochronometers zircon, monazite, rutile and titanite in polyphase lower crustal rocks of the Kalak Nappe Complex, northern Norway. A pressure–temperature–time–deformation path is constructed by combining microstructural observations with P–T conditions derived from phase equilibrium modelling and U–Pb dating. The following tectonometamorphic evolution is deduced: A subvertical S1 fabric formed at ~730–775 °C and ~6.3–9.8 kbar, above the wet solidus in the sillimanite and kyanite stability fields. The event is dated at 702 ± 5 Ma by high‐U zircon in a leucosome. Monazite grains that grew in the S1 fabric show surprisingly little variation in chemical composition compared to a large spread in (concordant) U–Pb dates from c. 800 to 600 Ma. This age spread could either represent protracted growth of monazite during high‐grade metamorphism, or represent partially reset ages due to high‐T diffusion. Both cases imply that elevated temperatures of >600 °C persisted for over c. 200 Ma, indicating relatively static conditions at lower crustal levels for most of the Neoproterozoic. The S1 fabric was overprinted by a subhorizontal S2 fabric, which formed at ~600–660 °C and ~10–12 kbar. Rutile that originally grew during the S1‐forming event lost its Zr‐in‐rutile and U–Pb signatures during the S2‐forming event. It records Zr‐in‐rutile temperatures of 550–660 °C and Caledonian ages of 440–420 Ma. Titanite grew at the expense of rutile at slightly lower temperatures of ~550 °C during ongoing S2 deformation; U–Pb ages of c. 440–430 Ma date its crystallization, giving a minimum estimate for the age of Caledonian metamorphism and the duration of Caledonian shearing. This study shows that (i) monazite can have a large spread in U–Pb dates despite a homogeneous composition; (ii) rutile may lose its Zr‐in‐rutile and U–Pb signature during an amphibolite facies overprint; and (iii) titanite may record crystallization ages during retrograde shearing. Therefore, in order to correctly interpret U–Pb ages from different geochronometers in a polyphase deformation and reaction history, they are ideally combined with microstructural observations and phase equilibrium modelling to derive a complete P–T–t–d path.     

A window into the Early to mid‐Cretaceous infrastructure of the Yukon‐Tanana terrane recorded in multi‐stage garnet of west‐central Yukon,Canada

Amphibolite facies metasedimentary schists within the Yukon‐Tanana terrane in the northern Canadian Cordillera reveal a two‐stage, polymetamorphic garnet growth history. In situ U‐Th‐Pb Sensitive High Resolution Ion Microprobe dating of monazite provide timing constraints for the late stages of garnet growth, deformation and subsequent decompression. Distinct textural and chemical growth zoning domains, separated by a large chemical discontinuity, reveal two stages of garnet growth characterized in part by: (i) a syn‐kinematic, inclusion‐rich stage‐1 garnet core; and (ii) an inclusion‐poor, stage‐2 garnet rim that crystallized with syn‐ to post‐kinematic staurolite and kyanite. Phase equilibria modelling of garnet molar and compositional isopleths suggest stage‐1 garnet growth initiated at ~600 °C, 8 kbar along a clockwise P–T path. Growth of the compositionally distinct, grossular‐rich, pyrope‐poor inner portion of the stage‐2 overgrowth is interpreted to have initiated at higher pressure and/or lower temperature than the stage‐1 core along a separate P–T loop, culminating at peak P–T conditions of ~650–680 °C and 9 kbar. Stage‐2 metamorphism and the waning development of a composite transposition foliation (S_T) are dated at c. 118 Ma from monazite aligned parallel to S_T, and inclusions in syn‐ to post‐S_T staurolite and kyanite. Slightly younger ages (c. 112 Ma) are obtained from Y‐rich monazite that occurs within resorbed areas of both stage‐1 and stage‐2 garnet, together with retrograde staurolite and plagioclase. The younger ages obtained from these texturally and chemically distinct grains are interpreted, with the aid of phase equilibria calculations, to date the growth of monazite from the breakdown of garnet during decompression at c. 112 Ma. Evidence for continued near‐isothermal decompression is provided by the presence of retrograde sillimanite, and cordierite after staurolite, which indicates decompression below ~4–5 kbar prior to cooling below ~550 °C. As most other parts of the Yukon‐Tanana terrane were exhumed to upper crustal levels in the Early Jurassic, these data suggest this domain represents a tectonic window revealing a much younger, high‐grade tectono‐metamorphic core (infrastructure) within the northern Cordilleran orogen. This window may be akin to extensional core complexes identified in east‐central Alaska and in the southeastern Canadian Cordillera.     

Separating metamorphic events in the Fosdick migmatite–granite complex,West Antarctica

The Fosdick migmatite–granite complex in West Antarctica records evidence for two high‐temperature metamorphic events, the first during the Devonian–Carboniferous and the second during the Cretaceous. The conditions of each high‐temperature metamorphic event, both of which involved melting and multiple melt‐loss events, are investigated using phase equilibria modelling during successive melt‐loss events, microstructural observations and mineral chemistry. In situ SHRIMP monazite and TIMS Sm–Nd garnet ages are integrated with these results to constrain the timing of the two events. In areas that preferentially preserve the Devonian–Carboniferous (M₁) event, monazite grains in leucosomes and core domains of monazite inclusions in Cretaceous cordierite yield an age of c. 346 Ma, which is interpreted to record the timing of monazite growth during peak M₁ metamorphism (～820–870 °C, 7.5–11.5 kbar) and the formation of garnet–sillimanite–biotite–melt‐bearing assemblages. Slightly younger monazite spot ages between c. 331 and 314 Ma are identified from grains located in fractured garnet porphyroblasts, and from inclusions in plagioclase that surround relict garnet and in matrix biotite. These ages record the growth of monazite during garnet breakdown associated with cooling from peak M₁ conditions. The Cretaceous (M₂) overprint is recorded in compositionally homogeneous monazite grains and rim domains in zoned monazite grains. This monazite yields a protracted range of spot ages with a dominant population between c. 111 and 96 Ma. Rim domains of monazite inclusions in cordierite surrounding garnet and in coarse‐grained poikiloblasts of cordierite yield a weighted mean age of c. 102 Ma, interpreted to constrain the age of cordierite growth. TIMS Sm–Nd ages for garnet are similar at 102–99 Ma. Mineral equilibria modelling of the residual protolith composition after Carboniferous melt loss and removal of inert M₁ garnet constrains M₂ conditions to ～830–870 °C and ～6–7.5 kbar. The modelling results suggest that there was growth and resorption of garnet during the M₂ event, which would facilitate overprinting of M₁ compositions during the M₂ prograde metamorphism. Measured garnet compositions and Sm–Nd diffusion modelling of garnet in the migmatitic gneisses suggest resetting of major elements and the Sm–Nd system during the Cretaceous M₁ overprint. The c. 102–99 Ma garnet Sm–Nd ‘closure’ ages correspond to cooling below 700 °C during the rapid exhumation of the Fosdick migmatite–granite complex.     

Monazite in a Variscan mylonitic paragneiss from the Münchberg Metamorphic Complex (NE Bavaria) records Cadomian protolith ages

Small oval‐shaped, unshielded monazite grains found in a Variscan garnet–muscovite‐bearing mylonitic paragneiss from the Liegendserie unit of the Münchberg Metamorphic Complex in the northwestern Bohemian Massif, central Europe, yield only pre‐Variscan ages. These ages, determined with the electron microprobe, have maxima at c. 545, 520 and 495 Ma and two side‐maxima at 455 and 575 Ma, and are comparable with previously determined ages of detrital zircon reported from paragneisses elsewhere in the NW Bohemian Massif. The pressure (P)–temperature (T) history of this mylonitic paragneiss, determined from contoured P–T pseudosections, involved an initial stage at 6 kbar/600 °C, reaching peak P–T conditions of 12.5 kbar/670 °C with partial melting, followed by mylonitization and retrogression to 9 kbar/610 °C. The monazite, representing detrital grains derived from igneous rocks of a Cadomian provenance between 575 and 455 Ma, has survived these Variscan metamorphic/deformational events unchanged because this mineral has probably never been outside its P–T stability field during metamorphism.     

Palaeoproterozoic evolution of the Challenger Au deposit, South Australia, from monazite geochronology

Monazite in granulite facies metatexite migmatites (Christie Gneiss) hosting the Challenger Au deposit, South Australia, records a series of growth and resorption stages over a c. 60 Myr period between 2470 and 2410 Ma. A combination of electron microprobe X‐ray mapping and in situ ion‐microprobe dating was used to delineate and date five compositional domains. The oldest prograde metamorphic components are preserved in granoblastic gneisses surrounding the deposit, and as small high‐Y cores in large monazite grains in Au‐bearing migmatites. In metatexite leucosomes, these cores were partially resorbed prior to the growth of large high‐Th monazite domains that crystallized during partial melting and stromatic migmatite development at c. 2443 Ma. Subsequent heating to biotite dehydration conditions (c. 850 °C at 7 kbar) caused further partial melting roughly 10–15 Myr later, giving rise to c. 2428 Ma domains surrounding partly resorbed 2443 Ma grains that were entrained in the higher‐temperature melts. This period of partial melting coincided with isoclinal folding culminating in dextral transpression and represents the most likely window for remobilization of Au‐bearing polymetallic sulphide melts into low‐strain domains. Localized reaction of residual melt with the granulite facies assemblage during cooling gave rise to narrow high‐Y rims dated at 2414 ± 7 Ma. Although monazite from unmineralized granoblastic gneisses and migmatitic ore zones display the same range of U‐Pb dates, monazite in migmatites displays a higher overall Ca + Th + U content, indicating that compositional heterogeneities between ore zones and host rocks developed prior to 2470 Ma, perhaps a consequence of the hydrothermal alteration inferred to have accompanied gold mineralization.     

Late Miocene movement within the Himalayan Main Central Thrust shear zone, Sikkim, north-east India

In the Sikkim region of north‐east India, the Main Central Thrust (MCT) juxtaposes high‐grade gneisses of the Greater Himalayan Crystallines over lower‐grade slates, phyllites and schists of the Lesser Himalaya Formation. Inverted metamorphism characterizes rocks that immediately underlie the thrust, and the large‐scale South Tibet Detachment System (STDS) bounds the northern side of the Greater Himalayan Crystallines. In situ Th–Pb monazite ages indicate that the MCT shear zone in the Sikkim region was active at c. 22, 14–15 and 12–10 Ma, whereas zircon and monazite ages from a slightly deformed horizon of a High Himalayan leucogranite within the STDS suggest normal slip activity at c. 17 and 14–15 Ma. Although average monazite ages decrease towards structurally lower levels of the MCT shear zone, individual results do not follow a progressive younging pattern. Lesser Himalaya sample KBP1062A records monazite crystallization from 11.5 ± 0.2 to 12.2 ± 0.1 Ma and peak conditions of 610 ± 25 °C and 7.5 ± 0.5 kbar, whereas, in the MCT shear zone rock CHG14103, monazite crystallized from 13.8 ± 0.5 to 11.9 ± 0.3 Ma at lower grade conditions of 525 ± 25 °C and 6 ± 1 kbar. The P–T–t results indicate that the shear zone experienced a complicated slip history, and have implications for the understanding of mid‐crustal extrusion and the role of out‐of‐sequence thrusts in convergent plate tectonic settings.     

A geochronological and petrological study of anatectic paragneiss and associated granite dykes from the Day Nui Con Voi metamorphic core complex,North Vietnam: constraints on the timing of metamorphism within the Red River shear zone

The Red River shear zone (RRSZ) is a major left‐lateral strike‐slip shear zone, containing a ductilely deformed metamorphic core bounded by brittle strike‐slip and normal faults, which stretches for >1000 km from Tibet through Yunnan and North Vietnam to the South China Sea. The RRSZ exposes four high‐grade metamorphic core complexes along its length. Various lithologies from the southernmost core complex, the Day Nui Con Voi (DNCV), North Vietnam, provide new constraints on the tectonic and metamorphic evolution of this region prior to and following the initial India–Asia collision. Analysis of a weakly deformed anatectic paragneiss using P–T pseudosections constructed in the MnO–Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (MnNCKFMASHTO) system provides prograde, peak and retrograde metamorphic conditions, and in situ U–Th–Pb geochronology of metamorphic monazite yields texturally controlled age constraints. Tertiary metamorphism and deformation, overprinting earlier Triassic metamorphism associated with the Indosinian orogeny and possible Cretaceous metamorphism, are characterized by peak metamorphic conditions of ~805 °C and ~8.5 kbar between c. 38 and 34 Ma. Exhumation occurred along a steep retrograde P–T path with final melt crystallizing at the solidus at ≥~5.5 kbar at ~790 °C. Further exhumation at ~640–700 °C and ~4–5 kbar at c. 31 Ma occurred at subsolidus conditions. U–Pb geochronological analysis of monazite from a strongly deformed pre‐kinematic granite dyke from the flank of the DNCV provides further evidence for exhumation at this time. Magmatic grains suggest initial emplacement at 66.0 ± 1.0 Ma prior to the India–Asia collision, whereas grains with metamorphic characteristics indicate later growth at 30.6 ± 0.4 Ma. Monazite grains from a cross‐cutting post‐kinematic dyke within the core of the DNCV antiform provide a minimum age constraint of 25.2 ± 1.4 Ma for the termination of fabric development. A separate and significant episode of monazite growth at c. 83–69 Ma is suggested to be the result of fluid‐assisted recrystallization following the emplacement of magmatic units.     

A curious case of agreement between conventional thermobarometry and phase equilibria modelling in granulites: New constraints on P–T estimates in the Antarctica segment of the Musgrave–Albany–Fraser–Wilkes Orogen

The Windmill Islands region in Wilkes Land, east Antarctica, preserves granulite facies metamorphic mineral assemblages that yield seemingly comparable P–T estimates from conventional thermobarometry and mineral equilibria modelling. This is uncommon in granulite facies terranes, where conventional thermobarometry and phase equilibria modelling generally produce conflicting P–T estimates because peak mineral compositions tend to be modified by retrograde diffusion processes. In situ U–Pb monazite geochronology and calculated metamorphic phase diagrams show that the Windmill Islands experienced two phases of high thermal gradient metamorphism during the Mesoproterozoic. The first phase of metamorphism is recorded by monazite ages in two widely separated samples and occurred at c. 1,305 Ma. This event was regional in extent, involved crustally derived magmatism and reached conditions of ~3.2–5 kbar and 690–770°C corresponding to very high thermal gradients of >150°C/kbar. The elevated thermal regime is interpreted to reflect a period of extension or increased extension in a back‐arc setting that existed prior to c. 1,330 Ma. The first metamorphic event was overprinted by granulite facies metamorphism at c. 1,180 Ma that was coeval with the intrusion of charnockite. This event involved peak temperatures of ~840–850°C and pressures of ~4–5 kbar. A phase of granitic magmatism at c. 1,250–1,210 Ma, prior to the intrusion of the charnockite, is interpreted to reflect a phase of compression within an overall back‐arc setting. Existing conventional thermobarometry suggests conditions of ~4 kbar and 750°C for M₁ and 4–7 kbar and 750–900°C for M₂. The apparent similarities between the phase equilibria modelling and existing conventional thermobarometry may suggest either that the terrane cooled relatively quickly, or that the P–T ranges obtained from conventional thermobarometry are sufficiently imprecise that they cover the range of P–T conditions obtained in this study. However, without phase equilibria modelling, the veracity of existing conventional P–T estimates cannot be evaluated. The calculated phase diagrams from this study allow the direct comparison of P–T conditions in the Windmill Islands with phase equilibria models from other regions in the Musgrave–Albany–Fraser–Wilkes Orogen. This shows that the metamorphic evolution of the Wilkes Land region is very similar to that of the eastern Albany–Fraser Orogen and Musgrave Province in Australia, and further demonstrates the remarkable consistency in the timing of metamorphism and the thermal gradients along the ~5,000 km strike length of this system.     

Alpine metamorphism of low-grade schists from the Slavonian Mountains (Croatia): new P-T and geochronological constraints

Low-grade schists from the Slavonian Mountains (Tisia Mega-Unit, Mt Papuk, Croatia), previously assigned to Precambrian to Lower Palaeozoic metamorphism, have been subjected to geochemical investigations, P-T modelling, and in situ age dating of monazite. The studied fine-grained metasediments consist of chlorite (5–15 vol.%), K white-mica (40–55 vol.%), quartz (20–35 vol.%), feldspar (albite 15–20 vol.%), opaques (<2 vol.%), and accessory minerals. According to their whole-rock geochemistry, the detritus of the former sediments came from upper crustal felsic rocks as they occur, for instance, at Mt Papuk. The schists show a complex microtectonic fabric, including well-developed schistosity systems. P-T pseudosections in the system MnNCKFMASHTO, constructed for typical schists of the study area, resulted in peak P-T conditions of 445–465 °C and 4.6–6.0 kbar for a sample from Kutjevo (eastern part of the study area) and 450–460 °C and 5.2–6.0 for a Vranovo sample (western part). Electron microprobe (EMP) dating of monazite in the schists gave a weighted average age of 109.0 ± 13.1 Ma (2σ) eventually with three subgroups of ages at 225 ± 63 (two analyses), 114 ± 24 and 83 ± 22 Ma. We conclude that the metamorphism of the studied schists at depths of c. 20 km is due to an Alpine collisional event.     

Geochronology in migmatites a SmNd, UPb and RbSr study from the Proterozoic Damara belt (Namibia): implications for polyphase development of migmatites in high-grade terranes

Sm–Nd (garnet), U–Pb (monazite) and Rb–Sr (biotite) ages from a composite migmatite sample (Damara orogen, Namibia) constrain the time of high‐grade regional metamorphism and the duration of regional metamorphic events. Sm–Nd garnet whole‐rock ages for a strongly restitic melanosome and an adjacent intrusive leucosome yield ages of 534±5, 528±11 and 539±8 Ma. These results provide substantial evidence for pre‐500 Ma Pan‐African regional metamorphism and melting for this segment of the orogen. Other parts of the migmatite yield younger Sm–Nd ages of 488±9 Ma for melanosome and 496±10, 492±5 and 511±16 Ma for the corresponding leucosomes. Garnet from one xenolith from the leucosomes yields an age of 497±2 Ma. Major element compostions of garnet are different in terms of absolute abundances of pyrope and spessartine components, but the flat shape of the elemental patterns suggests late‐stage retrograde equilibration. Rare earth element compositions of the garnet from the different layers are similar except for garnet from the intrusive leucosome suggesting that they grew in different environments. Monazite from the leucosomes is reversely discordant and records ²⁰⁷Pb/²³⁵U ages between 536 and 529 Ma, indicating that this monazite represents incorporated residual material from the first melting event. Monazite from the mesosome MES 2 and the melanosome MEL 3 gives ²⁰⁷Pb/²³⁵U ages of 523 and 526 Ma, and 529 and 531 Ma, respectively, which probably indicates another thermal event. Previously published ²⁰⁷Pb/²³⁵U monazite data give ages between 525 and 521 Ma for composite migmatites, and 521 and 518 Ma for monazite from neosomes. Monazite from granitic to granodioritic veins indicates another thermal event at 507–505 Ma. These ages are also recorded in ²⁰⁷Pb/²³⁵U monazite data of 508 Ma from the metasediment MET 1 from the migmatite and also in the Sm–Nd garnet ages obtained in this study. Taken together, these ages indicate that high‐grade metamorphism started at c. 535 Ma (or earlier) and was followed by thermal events at c. 520 Ma and c. 505 Ma. The latter event is probably connected with the intrusion of a large igneous body (Donkerhoek granite) for which so far only imprecise Rb–Sr whole‐rock data of 520±15 Ma are available. Rb–Sr biotite ages from the different layers of the migmatite are 488, 469 and 473 Ma. These different ages indicate late‐stage disturbance of the Rb–Sr isotopic system on the sub‐sample scale. Nevertheless, these ages are close to the youngest Sm–Nd garnet ages, indicating rapid cooling rates between 13 and 20°C Ma^?1 and fast uplift of this segment of the crust. Similar Sm–Nd garnet and U–Pb monazite ages suggest that the closure temperatures for both isotopic systems are not very different in this case and are probably similar or higher than the previously estimated peak metamorphic temperatures of 730±30°C. The preservation of restitic monazite in leucosomes indicates that dissolution of monazite in felsic water‐undersaturated peraluminous melts can be sluggish. This study shows that geochronological data from migmatites can record polymetamorphic episodes in high‐grade terranes that often contain cryptic evidence for the nature and timing of early metamorphic events.     

P–T–t evolution of granulite facies metamorphism and partial melting in the Winding Stair Gap,Central Blue Ridge,North Carolina,USA

The Winding Stair Gap in the Central Blue Ridge province exposes granulite facies schists, gneisses, granofelses and migmatites characterized by the mineral assemblages: garnet–biotite–sillimanite–plagioclase–quartz, garnet–hornblende–biotite–plagioclase–quartz ± orthopyroxene ± clinopyroxene and orthopyroxene–biotite–quartz. Multiple textural populations of biotite, kyanite and sillimanite in pelitic schists support a polymetamorphic history characterized by an early clockwise P–T path in which dehydration melting of muscovite took place in the stability field of kyanite. Continued heating led to dehydration melting of biotite until peak conditions of 850 ± 30 °C, 9 ± 1 kbar were reached. After equilibrating at peak temperatures, the rocks underwent a stage of near isobaric cooling during which hydrous melt ± K‐feldspar were replaced by muscovite, and garnet by sillimanite + biotite + plagioclase. Most monazite crystals from a pelitic schist display patchy zoning for Th, Y and U, with some matrix crystals having as many as five compositional zones. A few monazite inclusions in garnet, as well as Y‐rich cores of some monazite matrix crystals, yield the oldest dates of c. 500 Ma, whereas a few homogeneous matrix monazites that grew in the main foliation plane yield dates of 370–330 Ma. Culling and analysis of individual spot dates for eight monazite grains yields three age populations of 509 ± 14 Ma, 438 ± 5 Ma and 360 ± 5 Ma. These data suggest that peak‐temperature metamorphism and partial melting in the central Blue Ridge occurred during the Salinic or Taconic orogeny. Following near isobaric cooling, a second weaker thermal pulse possibly related to intrusion of nearby igneous bodies resulted in growth of monazite c. 360 Ma, coinciding with the Neoacadian orogeny.     

Crustal growth during back‐arc closure: Cretaceous exhumation history of Cordillera Darwin,southern Patagonia

The Cordillera Darwin metamorphic complex is unique in the Andes in exposing kyanite–staurolite schist north of the Beagle Channel in southern Patagonia. Garnet in amphibolite facies pelitic schists from Bahía Pia has patchy textures whereby some grains consist of clear, grossular‐rich garnet with fine‐grained S1 inclusion trails truncated by regions of turbid spessartine–pyrope‐rich garnet with biotite, muscovite, plagioclase and quartz inclusions. Micron‐scale aqueous inclusions in turbid garnet are consistent with recrystallization facilitated by fluid ingress; S2 inclusion trails indicate this was broadly contemporary with the growth of kyanite and staurolite in the matrix. Pseudosection modelling in Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (NCKFMASHTO) is used to infer a P–T path dominated by decompression from 12 to 9 kbar at T ≈ 620 °C, coupled with garnet mode decreasing from ～5% to <1%. U–Th–Pb in situ dating of S2 monazite indicates that staurolite and kyanite growth and thus exhumation was underway before 72.6 ± 1.1 Ma. Contact aureoles developed adjacent to late granite intrusions include sillimanite‐bearing migmatites formed at P ≈ 6 kbar after 72 Ma. Metamorphism of southern Cordillera Darwin induced by continental underthrusting beneath the arc, related to closure of the Rocas Verdes back‐arc basin, was terminated by thrusting‐controlled exhumation, with the rocks at P ≈ 9 kbar by c. 73 Ma and 6 kbar by c. 70 Ma.     

Stable staurolite–cordierite assemblages in K‐poor metapelitic schists in Aston and Hospitalet gneiss domes of the central Pyrenees (France,Andorra)

Staurolite–cordierite assemblages are common in mica schists of the Aston and Hospitalet gneiss domes of the central Axial Zone, Pyrenees (France, Andorra). Within a 200 m wide zone, staurolite, cordierite and andalusite porphyroblasts contain inclusion trails that preserve the same stage of development of a crenulation cleavage, strongly suggesting that all three phases are contemporaneous. Their syntectonic growth occurred during a short period at the beginning of the formation of the dominant schistosity (S₂) of the domes. Staurolite and cordierite touching each other further indicates an equilibrium relationship. Whole‐rock analyses show that some staurolite–cordierite schists are depleted in K₂O compared to post‐Archean shales (PAAS) and amphibolite facies pelites. Analysis of the st‐crd paragenesis in K‐poor schists without muscovite using KFMASH and MnNCKFMASH petrogentic grids, pseudosections and AFM compatibility diagrams predicts stable conditions at pressures of ~3.5 kbar at 575 °C. For metapelites with intermediate X_Mg values (0.7 >  X_Mg >0.48) a ‘muscovite‐out window’ exists from 550–650 °C at 3.5 kbar in the KFMASH system. Conventional thermobarometry (GB‐GASP, AvT‐AvP) and petrogenetic grids show an isobaric P–T path to peak temperatures of ~650 °C, supported by the presence of sillimanite‐K‐feldspar gneiss and migmatites. LP‐HT metamorphism in the Aston dome is related to early Carboniferous (c. 339 Ma) granitic intrusions into the dome core. As metamorphism is directly linked with the formation of the main S₂ schistosity, the temporal relations demonstrated in this study conflict with previous studies which constrained LP‐HT metamorphism and the development of flat‐lying schistosity to the late Carboniferous (315–305 Ma) – at least in the eastern Axial Zone.     

Using monazite and zircon petrochronology to constrain the P–T–t evolution of the middle crust in the Bhutan Himalaya

The growth and dissolution behaviour of accessory phases (and especially those of geochronological interest) in metamorphosed pelites depends on, among others, the bulk composition, the prograde metamorphic evolution and the cooling path. Monazite and zircon are arguably the most commonly used geochronometers for dating felsic metamorphic rocks, yet crystal growth mechanisms as a function of rock composition, pressure and temperature are still incompletely understood. Ages of different growth zones in zircon and monazite in a garnet‐bearing anatectic metapelite from the Greater Himalayan Sequence in NW Bhutan were investigated via a combination of thermodynamic modelling, microtextural data and interpretation of trace‐element chemical ‘fingerprint’ indicators in order to link them to the metamorphic stage at which they crystallized. Differences in the trace‐element composition (HREE, Y, Eu_N/Eu*_N) of different phases were used to track the growth/dissolution of major (e.g. plagioclase, garnet) and accessory phases (e.g. monazite, zircon, xenotime, allanite). Taken together, these data constrain multiple pressure–temperature–time (P–T–t) points from low temperature (<550 °C) to upper amphibolite facies (partial melting, >700 °C) conditions. The results suggest that the metapelite experienced a cryptic early metamorphic stage at c. 38 Ma at <550 °C, ≥0.85 GPa during which plagioclase was probably absent. This was followed by a prolonged high‐T, medium‐pressure (~600 °C, 0.55 GPa) evolution at 35–29 Ma during which the garnet grew, and subsequent partial melting at >690 °C and >18 Ma. Our data confirm that both geochronometers can crystallize independently at different times along the same P–T path and that neither monazite nor zircon necessarily provides timing constraints on ‘peak’ metamorphism. Therefore, collecting monazite and zircon ages as well as major and trace‐element data from major and accessory phases in the same sample is essential for reconstructing the most coherent metamorphic P–T–t evolution and thus for robustly constraining the rates and timescales of metamorphic cycles.     

Polymetamorphism in garnet micaschists of the Saualpe Eclogite Unit (Eastern Alps,Austria), resolved by automated SEM methods and EMP–Th–U–Pb monazite dating

Polymetamorphic garnet micaschists from the Austroalpine Saualpe Eclogite Unit (Kärnten, Austria, Eastern Alps) display complex microstructural and mineral–chemical relationships. Automated scanning electron microscopy routines with energy dispersive X‐ray (EDX) spectral mapping were applied for monazite detection and garnet mineral–chemical characterization. When the Fe, Mg, Mn and Ca element wt% compositions are used as generic labels for garnet EDX spectra, complex zonations and porphyroblast generations can be resolved in complete thin sections for selective electron‐microprobe analyses. Two garnet porphyroblast generations and diverse monazite age populations have been revealed in low‐Ca and high‐Al‐metapelites. Garnet 1 has decreasing Mn, constant Ca and significantly increasing Mg from cores to rims. Geothermobarometry of garnet 1 assemblages signals a crystallization along a M1 prograde metamorphism at ~650 °C/6–8 kbar. Sporadic monazite 1 crystallization started at c. 320 Ma. Subsequent pervasive 300–250 Ma high‐Y and high‐Gd monazite 1 formation during decompression coincided with the intrusion of Permian and Early Triassic pegmatites. Monazite 1 crystallized along the margin of garnet 1. Coronas of apatite and allanite around the large 320–250 Ma monazite signal a retrogressive stage. These microstructures suggest a Carboniferous‐to‐Early‐Permian age for the prograde M1 event with garnet 1. Such a M1 event at an intermediate‐P/T gradient has not yet been described from the Saualpe, and preceded a Permo‐Triassic low‐P stage. The M2 event with garnet 2 postdates the corona formation around Permian monazite. Garnet 2 displays first increasing X_Ca at decreasing X_Mg, then increasing X_Ca and X_Mg, and finally decreasing X_Ca with increasing X_Mg, always at high Ca and Mg, and low Mn. This records a P–T evolution which passed through eclogite facies conditions and reached maximum temperatures at ~750 °C/14 kbar during decompression‐heating. A monazite 2 population (94–86 Ma) with lower Y and Gd contents crystallized at decreasing pressure during the Cretaceous (Eo‐Alpine) metamorphism M2 at a high‐P/T gradient. The Saualpe Eclogite Unit underwent two distinct clockwise metamorphic cycles at different P–T conditions, related to continental collisions under different thermal regimes. This led to a characteristic distribution pattern of monazite ages in this unit which is different from other Austroalpine basement areas.