吐哈盆地南缘古生代“天窗”卡拉塔格铜金矿化区的发现及其成矿潜力

新疆吐哈盆地南缘古生代天窗新发现的卡拉塔格高品铜金蚀变化区，位于土屋－延东斑岩铜矿带以北50余千米处，属大南湖－突苏泉岛弧 的组成部分，该区泥盆系钙碱性火山－侵入岩发育，矿化区火山岩组合复杂，浅成－超浅成岩脉，岩墙发育，热液蚀变呈环带状分布，黄铁矿化普遍发育，浅部显示以胆矾，氯铜矿，硫磺为主的强烈氧化矿化，外围还分布有多处铜金化探异常，经初步踏查有蚀变矿化显示，综合分析本区具有大型斑岩－次火山岩铜金矿的找矿潜力，该区所取得的铜金找矿矿突破，将大大拓宽土层－延乐斑岩铜矿带的找矿空间。     

新疆土屋斑岩铜矿床火山-侵入杂岩体、 成矿岩石及其蚀变

土屋斑岩铜矿床位于新疆东天山晚古生代大南湖-头苏泉岛弧中.矿区出露地层为石炭系企鹅山群火山-沉积岩.文章提出矿区出露的火山-沉积岩以及浅成侵入岩为一火山-侵入杂岩体,发育2个旋回4个岩相:第一旋回包括溢流相玄武岩和安山岩、爆发相集块角砾熔岩和爆发-沉积相凝灰岩;第二旋回包括次火山相闪长玢岩和玄武玢岩.斜长花岗斑岩侵入到火山机构断裂系中.矿体赋存于斜长花岗斑岩和闪长玢岩中.斜长花岗斑岩为成矿斑岩,次火山岩相闪长玢岩为容矿岩石,火山岩为围岩.土屋斑岩铜矿床可分为前成矿期和主成矿期.前成矿期形成于火山活动的晚期,发育青磐岩化;主成矿期形成于斜长花岗斑岩侵位时期,发育钾硅酸盐蚀变、绿泥石-绢云母蚀变和黄铁绢英岩化蚀变及与之有关的矿化,形成了土屋斑岩型矿化的主体.矿化阶段包括钾硅酸盐阶段、绿泥石-绢云母阶段和黄铁绢英岩化阶段等.     

与陆相火山岩有关的铁、铜、金矿床成矿地质特征及矿床成因

文章对与陆相火山岩有关的浅成低温金矿、斑岩铜矿和玢岩铁矿产出的大地构造背景、火成岩性质和矿化蚀变特征、成矿流体以及成矿物质来源等方面进行了综述.三类矿床在成矿地质条件上各具特色,表现在:成矿构造背景上,斑岩铜矿和浅成低温金矿均以岛弧和活动大陆边缘为主,其次是陆内环境;而长江中下游玢岩铁矿的形成环境可能为陆内似裂谷环境.浅成低温金矿、斑岩铜矿及玢岩铁矿的主要围岩分别为中、酸性火山岩系、中酸性次火山岩及中基性次火山岩;围岩蚀变分别以硅化、钾化、钠化为特征.浅成低温金矿床成矿流体以低盐度、低温(200～300℃)为主;而斑岩铜矿中则主要是高温(400～800℃)高盐度的流体;玢岩铁矿成矿温度介于两者之间.从低硫亚类浅成热液矿床、高硫亚类浅成热液矿床到斑岩型矿床,流体中大气水含量逐渐减少,岩浆水含量逐渐增多.成矿物质来源上,Fe主要来源于赋矿的火山-次火山岩或原始岩浆,Cu,Au,S和Na等成矿物质的来源更为复杂,还可能来源于与岩浆无关的围岩,其他的可能还包括Cu,S的岩浆混合来源以及Na的高盐卤水来源.一些特殊的岩石类型,如埃达克岩、橄榄玄粗岩及碱性岩与陆相火山岩矿床有密切联系.     

内蒙古介拉斯台盆地铀成矿条件分析与找矿预测

介拉斯台盆地处于扎兰屯火山岩型铀成矿远景带中段，是国内中生代火山岩最为发育地区之一，多期次断裂、火山活动强烈发育，铀成矿地质背景优越。文章通过对介拉斯台中生代火山岩盆地的大地构造背景、基底和盖层的含铀性、潜火山岩、断裂、火山机构、热液蚀变、铀矿化等铀成矿地质条件研究，并结合航放、化探及遥感找矿信息进行综合分析，认为介拉斯台中生代火山岩盆地具有较好的铀成矿潜力，圈定成矿远景区5处。     

黑龙江永新金矿地质特征及成因

黑龙江永新金矿床的发现是多宝山矿集区外围地质找矿取得的一项新成果.矿床赋存在早白垩世火山盆地与古生代糜棱岩带接触地带的一个浅成相和潜火山岩相小侵入体及岩脉密集分布地段.潜火山相的潜英安岩、潜流纹岩等形成于成矿前或成矿期,受蚀变矿化;浅成相的花岗斑岩、闪长玢岩等形成于成矿后,破坏矿体.金矿体及矿化主要赋存在隐蔽爆破作用形成的蚀变角砾岩体中,其次赋存在蚀变角砾岩体外侧的糜棱岩类围岩中.该矿床的发现显示在黑龙江省西部的古生代糜棱岩带中存在与早白垩世火山作用有关的潜火山热液型金矿,也表明黑龙江多宝山斑岩铜矿老矿区的外围仍具有找矿潜力.     

青藏高原两个斑岩-浅成低温热液矿床成矿亚系列及其"缺位找矿"之实践

斑岩_浅成低温热液型铜金矿床是西藏最新发现的组合矿床类型,其具有巨大的找矿潜力。笔者在西藏多龙矿集区铁格隆南铜金矿床、雄村矿集区主要矿体系统地质编录、综合研究的基础上,对其矿床地质背景、矿体形态产状、矿物组合、蚀变特征、成岩成矿年龄等进行了系统的总结,在前人研究的基础上,提出班怒成矿带与早白垩世岛弧型中_酸性火山岩_浅成岩组合有关的铜、金、银、铅锌矿床成矿亚系列,以及冈底斯成矿带与早侏罗世—晚侏罗世岛弧型中_酸性火山岩_浅成岩组合有关的铜、金、银、铅锌矿床成矿亚系列,是西藏最重要的寻找斑岩型_浅成低温热液型铜金矿的矿床成矿系列。依据"缺位找矿"理论,预测多龙矿集区尕尔勤、地堡那木岗、铁格隆山是浅成低温热液型铜金矿床的进一步勘查评价区,色那、拿顿角砾岩筒是寻找独立高硫化型浅成低温热液金矿床的重要靶区。铁格隆南浅成低温热液矿体叠加在斑岩型矿体之上,高硫化型浅成低温热液矿床浅部发育多孔状硅帽和明矾石_地开石_高岭石蚀变组合,金属矿物以硫砷铜矿_铜蓝_蓝辉铜矿_黝铜矿_黄铜矿_斑铜矿_黄铁矿等铜硫二元体系矿物组合为主,其中黄铁矿_黄铜矿_斑铜矿形成较早,矿床规模可突破1200万吨。雄村铜金矿集区发育低硫化型浅成低温热液多金属金矿体,矿体呈脉状,或在火山机构边缘构造中独立产出,或叠加于斑岩型铜金矿体之上产出,以绢云母化、叶蜡石化、伊利石化发育,闪锌矿、黝铜矿、磁黄铁矿_黄铁矿为主要金属矿物组合为特征,洞嘎、普钦木_哑达是低硫化型浅成低温热液矿床的勘查评价区,深部有找到斑岩型铜金矿的可能。上述2套矿床成矿系列亚系列都与燕山期斑岩铜金矿床的流体演化有关,具有特殊的蚀变矿物、金属矿物组合,寻找独立的浅成低温热液型金矿是下一步需要重视的找矿方向。     

满洲里地区的浅成低温热液矿床

满洲里中生代火山-次火山岩发育区,发现了一系列浅成低温热液矿床,矿种有Au、Ag、Cu、Pb、Zn等.这些矿床可分为高硫化型和低硫化型,且都具有典型的围岩蚀变、蚀变分带等矿床特征.通过对额仁陶勒盖银（金）矿床和大坝金铜矿床两典型浅成低温热液矿床的对比性研究,总结其成矿规律及成矿模式.     

北祁连山西段金矿床新类型

西安地质矿产研究所在承担国土资源部“九五”资源攻关项目 ( 95 - 0 2 - 0 0 4 )期间 ,杨建国、李智佩、宋忠宝、任有祥等通过对北祁连山西段构造蚀变岩型、蚀变超基性岩型和石英脉型 3种重要类型金矿床进行研究 ,于该区确立了首例与斑岩有关的碲 -铋 -金型矿床 ,以车路沟金矿床为代表。该类金矿床主要成矿地质特征是 ,矿床位于北祁连山早古生代岛弧火山岩带 ,直接赋存于钙碱性次火山 -中浅成英安斑岩内 ,其成矿背景为碰撞造山环境 ;矿床受区域断裂裂隙、同建造期古火山穹窿边缘继承性断裂裂隙 ,尤其是次火山岩体边缘节理、裂隙及接触破碎…     

胶东栖霞香夼铅锌多金属矿床地质特征及成因

胶东栖霞香夼铅锌多金属矿床是目前山东省内发现的规模较大的铅锌矿床.通过对该矿床的地质背景、矿体和矿石特征、围岩蚀变特征、矿床成因等进行了综合研究分析,认为该矿床的火山活动存在着中性-中酸性-酸性的演化规律,其成矿系统有明显的垂直分带现象:浅部为铅锌矿体,中部为铜硫矿体,深部为铜钼矿化,不同类型矿体是在不同阶段形成的,与不同类型岩浆作用有关.蚀变作用及蚀变岩发育广泛,既具有"面型"蚀变特征,又表现出一定的分带性,矿区热液作用的阶段性非常明显,铅锌矿床成矿流体的盐度值是很高,成因为斑岩型铅锌矿床.     

富金斑岩型铜矿床的基本特征、成矿物质来源与成矿高氧化岩浆-流体演化

第三纪富金斑岩型铜矿床主要发育于板块汇聚边缘与俯冲作用相关的火山-岩浆弧以及陆缘弧中,而大多数较古老的富金斑岩型铜矿床则主要发育于向大陆边缘增生的岛弧环境中.含矿斑岩的岩性变化范围从低钾钙碱性闪长岩、石英闪长岩和英云闪长岩到高钾钙碱性石英二长岩到碱性的二长岩及正长岩,通常侵位于地壳浅部l～2km处,与同期的火山岩密切共生,并常见热液爆破角砾岩.其围岩蚀变从早到晚依次可分为Ca-Na硅酸盐蚀变、K硅酸盐蚀变、中级泥质蚀变、绢云母化、高级泥质蚀变,而浅部的高级泥质蚀变可以与早期K硅酸盐蚀变同期形成.Cu、Au矿化主要发育在K硅酸盐蚀变带中,矿化与A型脉密切相关,贫钼而富铂族元素.控制富金斑岩型铜矿床形成的几个关键过程包括：（1）源区有大量的Cu、Au等成矿元素;（2）能使Cu、Au等成矿物质有效进入岩浆熔体的机制;（3）合成矿元素的岩浆熔体在从地幔上升到地壳高侵位而形成斑岩体的过程中没有Cu、Au等成矿物质损失;（4）在岩浆上升演化过程中,岩浆挥发份能有效的逸出,并且逸出的时间越早,对成矿越有利;（5）Cu、Au等成矿元素能有效进入岩浆挥发份;（6）在成矿斑岩体上部发育有利的相对封闭机制,阻止岩浆挥发份的逃逸;（7）含Cu、Au成矿流体的有效沉淀机制;（8）具有一个地壳上部的岩浆房,能够不断提供成矿物质和驱动热液循环的热能.要形成大型矿床一般需要多期岩浆脉动侵位与多期矿化热液蚀变事件的叠加.现多倾向认为交代的地幔楔可能是其主要物质来源.而有利于富金斑岩型铜矿床形成的岩浆有钾质钙碱性岩浆、埃达克质岩浆、碱性弧岩浆.俯冲板片脱水形成的流体或者熔融产生熔体提供了上覆地幔楔熔融的高氧逸度条件,这种高氧逸度特征是地幔源区Cu、Au成矿元素能否进入岩浆熔体的重要条件之一.最近研究表明流体的冷却可能是Cu、Au沉淀成矿最主要的因素.本文扼要介绍了富金斑岩型铜矿的矿床地质特征、矿床成因等方面的研究进展,分析了存在的主要问题并对其发展趋势作了展望.     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.