Principles of Probabilistic Regional Mineral Resource Estimation

Five principal sources of uncertainty in quantitative mineral resource estimation are listed and illustrated by means of a simple example (mosaic model) and a case history study for large copper deposits in the Abitibi area of the Canadian Shield. Abitibi copper potential originally was estimated on the basis of 1968 estimates of production and reserves totalling 3.12 Mt Cu. This prognostication now could be evaluated on the basis of 2008 copper production and reserves totalling 9.50 Mt Cu. An earlier hindsight study performed on the basis of 1977 data (totalling 5.23 Mt Cu) showed seven new discoveries occurring either in the immediate vicinities of known deposits or on broad regional copper anomalies predicted from the 1968 inputs. By 1977, the global geographic distribution pattern of large copper deposits in the Abitibi area had stabilized. During the next 30 years, new copper was essentially found close to existing deposits, much of it deeper down in the Earth's crust. In this paper, uncertainties associated with copper ore tonnage are analyzed by comparison of 2008 data with 1968 data using (a) log-log plots of size versus rank, and (b) lognormal QQ-plots. Straight lines fitted by least squares on these plots show that 1968 slopes provide good estimates of 2008 slopes but 1968 intercepts are much less than 2008 intercepts. In each linear log-weight versus log-rank plot, the slope is related to fractal dimension of a Pareto frequency distribution, and in a lognormal QQ-plot it is determined by logarithmic variance. The difference between 2008 and 1968 intercepts represents the increase in copper ore production and reserves from 1968 to 2008. The Pareto model fits actual copper and massive sulphides increase over the past 40 years better than the lognormal frequency distribution model for 10 km×10 km cells on favorable environments in the Abitibi area.      

利用测井信息评价盐湖相烃源岩

盐湖相烃源岩富含膏、盐质成分,使其测井响应特征发生极大改变,给测井评价烃源岩带来困难。基于实测数据,分析了盐湖相烃源岩中普遍发育的纯泥岩、含膏(盐)泥岩和膏(盐)质泥岩有机碳含量的测井响应模式,发现纯泥岩和含膏(盐)泥岩TOC与AC和LogRt呈正比,与DEN呈反比,膏(盐)质泥岩TOC与DEN呈正比,与LogRt呈反比,并基于此建立了盐湖相烃源岩测井评价方法,即首先利用ΔGR区分岩性,再针对不同岩性建立TOC评价模型,最后根据实测S₁+S₂和TOC建立相关关系,就可以求取烃源岩的TOC和S₁+S₂。利用该方法对东营凹陷沙四下亚段烃源岩性质和展布进行分析,发现预测TOC与实测TOC吻合程度高,具有一定推广价值。     

中国昆明地区岩溶洞穴洞口带苔藓植物研究

为了研究中国西南岩溶洞穴植物区系与生物多样性特征, 作者曾两次对云南昆明地区12个岩溶洞穴进行了野外考察和苔藓植物标本采集工作。其中含昆明市石灰岩洞穴1个, 石林县石灰岩洞穴5个和宜良县白云岩洞穴6个。根据采自12个岩溶洞穴洞口带的164件苔藓植物标本研究, 本文首次报道昆明地区洞穴苔藓植物10科18属25种。昆明地区洞穴中分布较多的苔藓植物科有丛藓科( Po ttiaceae) 5属8种,凤尾藓科( Fi ssidentaceae ) 1属4种,柳叶藓科( Amblystegiaceae ) 3 属3 种和青藓(Brachytheciaceae ) 2属3种。溶洞中较常见的4种苔藓植物种类是萤光苔类植物光苔Cyathodiumcavernarum Kunze ( 见于6个溶洞中) , 小凤尾藓Fissidens bryoides Hedw ( 见于4个溶洞中) , 橙色净口藓Gymnostonum calcareum Nees et Ho rsch (见于3 个溶洞中)和长叶扭口藓Tortella tortuosa( Hedw ) Limp ( 见于3个溶洞中)。野外观察表明,受洞穴弱光环境生态因子的限制, 昆明地区洞穴苔藓植物主要生长于洞穴洞口0～ 26m带范围内; 2种丛集型藓类植物, 橙色净口藓Gymnostonumcalcareum Nees et Horsch, 和钩喙净口藓G.recurvirost re Hedw 参与洞口带钟乳石或石笋钙华沉积。      

Analysis on the deployment of mining research supported by the grant program of Deep Resources Exploration and Mining

The Deep Resources Exploration and Mining(DREAM) grant program, within the framework of The National Key Research and Development Program grants, is a pillar to implement China's science and technology strategy in the area of deep resources exploitation. To tackle the insufficient of theories and technologies for the 1000-meter-deep mining, a section of mining, covering the research of basic theories, general technologies and application demonstration, was arranged in the layout of DREAM under the principle of "whole chain design, integrated implementation". In the aspect of basic research, DREAM mainly focused on the deep rock mechanics and mining theory, such as the in-situ mechanical behavior of deep rock, deep high stress induction and energy regulation theory. For the general and key technologies, DREAM supported the research on the mine construction and hoisting, excavation, rock breaking, mining methods and mining safety according to the characteristics of coal and metal mines. For the demonstration application, taking green, safe and efficient as the starting point, DREAM aimed at the green, safe and high efficiency mining, and the demonstration and leading role projects such as the low-waste and high-efficiency back fill mining. Since 2016, 10 RD projects have been funded, and 122 institutional participants with a total budget of RMB 235 million from the central government and RMB 480 million from enterprises as well as local governments have been involved. It is expected that the mining section of DREAM would contribute to establishing the theory and technology system in the area of deep mining and promoting the ability of deep resource exploitation in China.     

Geology and mineralization of the Tiegelongnan supergiant porphyry-epithermal Cu (Au,Ag) deposit (10 Mt) in western Tibet,China: A review

The Tiegelongnan Cu(Au,Ag)deposit in central Tibet contains more than 10 Mt of copper ranking 29 th in the world.It is characterized by typical porphyry-epithermal alteration and mineralization.In order to improve the understanding of porphyry-epithermal copper deposit in Tibet,new zircon U-Pb age and sulfur isotope data along with published data in the Tiegelongnan are presented to investigate the formation and preservation mechanism.Ore-related intrusive rocks in the Tiegelongnan including Early Cretaceous(about 120 Ma)granodiorite porphyry and diorite porphyry are closely related to the northward subduction of Bangongco-Nujiang ocean.Sulfur mainly comes from deep magma,and ore-forming fluid is affected by both magmatic and meteoric water.The metallogenic setting of Tiegelongnan is consistent with those of Andean porphyry copper deposits in South America.The cover of the Meiriqiecuo Formation volcanic rocks,Lhasa-Qiangtang collision and India-Eurasian collision have significance in the preservation and uplift of the deposit.The formation,preservation and discovery of Tiegelongnan play an important role in exploration of ancient porphyry-epithermal deposits in Tibet.     

Application of 3D Static Modelling in Reservoir Characterization: A Case Study from the Qishn Formation in Sharyoof Oil Field, Masila Basin, Yemen

Three-dimensional(3 D)static modelling techniques are applied to the characterization of the Qishn Formation(Fm.)in the Sharyoof oil field locating within the Masila basin,southeastern Yemen.The present study was initiated by the seismic structural interpretation,followed by building a 3 D structural framework,in addition to analysing well log data and from these,3 D facies and petrophysical models are constructed.In the Sharyoof oil field,the Qishn Fm.exhibits depth values within the range of 400-780 m below sea level,with a general increase towards the SSE.A set of high dip angle normal faults with a general ENE-WSW trend dissect the rocks.The strata are also folded as a main anticline with an axis that is parallel to the fault trend,formed as a result of basement uplift.According to the facies models,the Qishn Fm.comprises 43.83% limestone,21.53% shale,21.26% sandstone,13.21% siltstone and 0.17% dolomite.The Qishn Carbonates Member has low porosity values making it a potential seal for the underlying reservoirs whereas the Upper Qishn Clastics SI A and C have good reservoir quality and SIB has fair reservoir quality.The Upper Qishn Clastics S2 and S3 also have fair reservoir quality,while the Lower Qishn Clastics zone has good reservoir quality.The water saturation decreases towards the west and east and increases towards north and south.The total original oil in-place(OOIP)of the Upper Qishn clastics is 106 million STB within the SI A,SIC and S2 zones.Drilling of development wells is recommended in the eastern study area,where good trapping configuration is exhibited in addition to the presence of a potential seal(Upper Qishn Carbonates Member)and reservoir(Qishn Clastics Member)with high porosity and low water saturation.     

印度共和国地质构造与区域成矿

印度共和国位于南亚次大陆中部,陆地面积297.32万km2(不包括印控克什米尔地区与锡金),北部为喜马拉雅高山区,海拔平均为5500m;中部是印度河-恒河-布拉马普特河(在中国境内称雅鲁藏布江)平原,平均海拔100~200m,是印度经济最发达、人口最稠密地区;南部是印度半岛高原区,西高东低,     

多年冻土环境对寒区天然气管线稳定性的影响

Field investigations of several gas mains in different geosystems were carried out in Noviy Urengoy region (Eastern Siberia) in September, 2003. There were on ground pipelines covered with peat or sand. In case of small rivers pipelines were elevated by pile support on the shores. Because pipelines were applied in cryolithozone that means special secure methods used in pipeline systems functioning and operating. There are multiple sites of natural landscapes destructed or totally destroyed during building and exploiting of the pipelines. That causes negative cryogenic processes development. The most dangerous one is the heaving, that reaches up to several meters in humid landscapes. The complex thermoerosion, thermokarst and heaving occur very often at one site. The heaving of piles leads to pipe deformations and the emergency situations to occur. It is possible to predict negative cryogenic processes development and so far to reduce an emergency risk.     

Water in coesite: Incorporation mechanism and operation condition,solubility and P-T dependence,and contribution to water transport and coesite preservation

A series of coesite,coexisting with or without a liquid phase,was synthesized in the nominal system SiO2-H2O at800-1450℃and 5 GPa.Micro-Raman spectroscopy was used to identity the crystalline phase,electron microprobe and LA-ICP-MS were employed to quantity some major and trace elements,and unpolarized FTIR spectroscopy was applied to probe the different types of hydrogen defects,explore water-incorporation mechanisms and quantify water contents.Trace amounts of A1 and B were detected in the coesite.Combining our results with the results in the literatures,we have found no positive correlation between the Al contents and the"Al"-based hydrogen concentrations,suggesting that previously proposed hydrogen-incorporation mechanism H^++Al^3+■Si^4+does not function in coesite.In contrast,we have confirmed the positive correlation between the B contents and the B-based hydrogen concentrations.The hydrogen-incorporation mechanism H^++B3^+■Si^4+readily takes place in coesite at different P-T conditions,and significantly increases the water content at both liquid-saturated and liquid-undersaturated conditions.For the SiO2-H2O system,we have found that type-Ⅰhydrogarnet substitution plays a dictating role in incorporating water into coesite at liquid-saturated condition,type-II hydrogarnet substitution contributes significantly at nearly dry condition,and both operate at conditions in between.The water solubility of coesite,as dictated by the type-Ⅰhydrogarnet substitution,positively correlates with both P and T,cH2O=-105(30)+5.2(32)×P+0.112(26)×T,with cH2O in wt ppm,P in GPa and T in℃.Due to its low water solubility and small fraction in subducted slabs,coesite may contribute insignificantly to the vertical water transport in subduction zones.Furthermore,the water solubility of any coesite in exhuming ultra-high pressure metamorphic rocks should be virtually zero as coesite becomes metastable.With an adequately fast waterdiffusion rate,this metastable coesite should be completely dry,which may have been the key factor to the partial preservation of most natural Coe.As a byproduct,a new IR experimental protocol for accurate water determination in optically anisotropic nominally anhydrous minerals has been found.Aided with the empirical method of Paterson(1982)it employs multiple unpolarized IR spectra,collected from randomly-orientated mineral grains,to approximate both total integrated absorbance and total integrated molar absorption coefficient.Its success relies on a high-level orientation randomness in the IR analyses.     

Magmatic and hydrothermal zircon growth during multiple orogenic cycles in an evolving mantle wedge

The Hongseong area of the Hongseong-Imjingang Belt in the central-western Korean Peninsula forms part of a subduction-collision system that is correlated with the Qinling-Dabie-Sulu Belt in China. Several serpentinized ultramafic bodies carrying blocks of metamorphosed mafic rocks occur in this area. Here we investigate zircon grains in serpentinites from Bibong(BB) and Wonnojeon(WNJ), and high-pressure(HP) mafic granulite from Baekdong(BD) localities based on U-Pb, REE and Lu-Hf analyses. The zircons from BD HP mafic granulite show distinct age peaks at 838 Ma, 617 Ma and 410 Ma, with minor peaks at1867 Ma, 1326 Ma and 167 Ma. The Neoproterozoic age peaks in these rocks as well as in the serpentinites suggest subduction-related melt-fluid interaction in the mantle wedge at this time. The older zircon grains ranging in age from the Early to Middle Paleoproterozoic might represent detrital grains from the basement rocks transferred to the wedge mantle through sediment subduction. The BD HP mafic granulite shows a Middle Paleozoic age peak(Devonian; 410 Ma). The 242-245 Ma age peaks in the compiled age data of zircon grains serpentinites from BB and WNJ correspond to a major Triassic event that further added melts and fluids into the ancient mantle wedge to crystallize new zircons. In the chondrite normalized rare earth element diagram, the magmatic zircon grains from the studied rocks show LREE depletion and HREE enrichment with sharply negative Eu and Pr anomalies and positive Ce and Sm anomalies. The REE patterns of hydrothermal zircons show LREE enrichment, and relatively flat patterns with negative Eu anomaly. Zircon Hf signature from the WNJ serpentinite show negative εHf(t)(-18.5 and-23.5) values indicating an enriched mantle source with TDM in the range of 1614 Ma and1862 Ma. Zircons from the BD HP mafic granulite also show slightly negative εHf(t)(average-4.3) and TDM in the range of 1365-1935 Ma. Our study provides evidence for multiple zircon growth in an evolving mantle wedge that witnessed melt and fluid interaction during different orogenic cycles.     

高岭石热转变产物^29Si、^27Al魔角旋转核磁共振研究

运用魔角旋转核磁共振结合红外光谱及X射线衍射等手段，研究了苏州高岭石的560－1600℃热转变产物，主要获得以下结论：（1）高岭石－偏高岭石－莫来石的转变系列的确存在结构上的连续性。其转变经历了几个阶段；脱羟阶段（400－600℃），偏高岭石阶段（600－800℃），相分离阶段（800－1100℃），莫来石阶段（1100－1600℃）。（2）莫来石形成过程没有出现Al2O3的大量分凝，但存在SiO2的分凝。（3）偏高岭石－莫来石转变过程的中间相为Al-Si尖晶石和准莫来石。（4）引起1000℃放热反应的主要因素是准莫来石的形成。     

倾斜断层Vzz、Vzzz的联合反问题解

本文利用两个上延高度的V_zz极值距和其中之一高度的V_zzz的零值点获得了倾斜断层的位置、埋深、断距、倾向、倾角以及断层正逆性质等的反问题解。     

饶阳凹陷大王庄地区古近系东营组三段沉积微相研究

针对大王庄地区沉积相类型判定结论不一致的问题,以区域构造演化为基础,利用钻井数据、沉积构造标志、测井数据等地质资料,探讨了东营组三段（Ed₃）沉积时期周边潜山、洼槽对大王庄地区物源方向、沉积相类型的控制作用,建立了东三段沉积模式.研究结果表明,东三段沉积时期,沉降中心位于研究区东北部,主要接受西南深泽低凸起的物源沉积.东营组沉积期间,随着断陷的抬升,湖盆面积迅速缩小,地形逐渐平坦,沉积相不断延伸,大王庄地区东三段发育曲流河相.沉积相的精细研究为储层预测提供了依据.     

污染物的固化/安定化处理的种类和研究应用现状

污染物的固化／安定化技术处理可归纳为6大类,即基于水泥的固化技术、基于石灰的固化技术、矿物吸附技术、热固技术、热塑技术和玻璃化技术等。其中有机聚合物固化剂（热固、热塑材料）一般用于处理固态有机污染物;玻璃化技术一般用于处理污染土、城市垃圾焚烧物和放射性物质。因无机胶结剂操作方便、成本低、能处理的无机污染物范围很广,因此使用频率较高（90％以上）,而有机胶结剂固化技术和废物玻璃化处理技术成本高,仅被用于特殊污染物的处理。     

邻二氮杂菲银/蒙脱石抗菌复合物的制备及表征

以X射线衍射(XRD)、傅立叶变换红外光谱(FT IR)、激光拉曼光谱(R am an)等手段对用微波辐射法制备邻二氮杂菲银/蒙脱石抗菌复合物抗菌及其热处理产物进行表征,结果显示:邻二氮杂菲与银离子所形成的络离子([A g(phen)2] )通过离子交换作用进入蒙脱石的层间形成有序插层结构,其d(001)值随热处理温度的上升呈规律性变化,复合物的热稳定性可达300℃。复合物中银离子的溶出量受热处理温度的控制。抗菌性能测试表明复合物及其热处理产物对大肠杆菌都具有良好的抗菌活性。微波辐射法较传统制备方式更为简便、快速。     

蒙脱石/醋酸氯已定抗菌复合物的制备及其表征

以2：1型粘土矿物钠基、钙基蒙脱石为栽体,醋酸氯已定为抗菌组分,利用离子交换法制备一种新型的抗菌复合物。采用X射线衍射分析（XRD）对产物进行表征,并进行了抗菌性能测试。结果表明,醋酸氯已定离子进入了蒙脱石的层间,呈单层或“绞链”状态排列。所制备的蒙脱石／醋酸氯已定抗菌复合物对大肠杆菌有良好的抗菌活性,在组分含量1CEC时即表现出抗茵活性,而且抗菌活性随组分浓度的增加而增加。     

祁漫塔格成矿带磁铁矿Fe2+/Fe3+比值测定方法对比研究

为了厘清磁铁矿成分测试过程中Fe²⁺/Fe³⁺比值分析各种方法的准确性及适用范围;采用直接测氧法、Lβ/Lα强度比值法、电价差值法、剩余氧法和穆斯堡尔谱法,对祁漫塔格成矿带中典型矿床中磁铁矿的Fe²⁺/Fe³⁺比值进行了研究,结果表明电价差值法、剩余氧法和穆斯堡尔谱法是相对比较准确的测试方法,但穆斯堡尔谱法不是原位分析方法,存在适用范围的缺陷。     

伊利石测年在焉耆盆地油气成藏时期研究中的应用

油气藏成藏时期的确定是进行油气藏勘探与评价的重要工作内容之一。也是揭示成藏过程的有效途径，利用伊利石测年确定油气成藏期，能够得出其绝对年龄，因而受到人们重视，运用自生伊利石同位素年龄测定的原理和方法及自生伊利石同位素年龄资料对焉耆盆地博湖坳陷油气藏成藏时期及油气运移时期进行了分析，最后对自生伊利石同位素测年存在的问题和措施进行了有益的探讨并克服了以往只能根据地质综合研究定性确定油气藏成藏时期及油气运移时期问题，为定量确定油气藏成藏时期以及油气运移时期提供了科学的方法。     

锆铝基柱撑蒙脱土的制备研究

以钠基蒙脱土为原料,采用共聚法合成锆铝基柱撑蒙脱土,并研究不同锆铝摩尔比例和不同NaOH的量对柱撑蒙脱土制备的影响。XRD研究表明,当锆铝摩尔比例为1：6、加入70ml0．4mol／LNaOH时,可得到（001）面网层间距达1．9343nm的锆铝基柱撑蒙脱土。通过FT—IR发现,锆铝聚合羟基阳离子进入蒙脱土层间,形成Si-O-Al和Si-O-Zr。对柱撑前后蒙脱土的比表面积和孔径结构进行分析,发现锆铝基柱撑蒙脱土具有较大的比表面积,较为均匀的孔径分布,是一种合适的催化和吸附材料。     

分离的大陆板块边缘镁铁-超镁铁岩系Th/Hf-Ta/Hf判别

本文在论述了 Th/ Hf— Ta/ Hf关系判别岩浆岩源区大地构造环境机理的基础上 ,根据世界上典型大地构造环境区岩浆岩系的 Th、Ta、Hf特征 ,提出了分离的大陆板块边缘镁铁 -超镁铁岩的 Th/ Hf— Ta/ Hf判别标志 :Th/ Ta=1.8～ 4 .0 ,Ta/ Hf>0 .1