与煎茶岭金矿有关超基性岩体地球化学特征

煎茶岭金矿与煎茶岭超基性岩体有密切的成因联系.岩体的主量元素分析成果表明:SiO2含量为27.38%～41.88%,MgO含量为25.16%～39.27%,(Na2O K2O)含量为0.02%～1.67%,m/f比值为(5.35～9.75).煎茶岭岩体属镁质、超镁铁质岩石.全碱-硅投影显示煎茶岭岩体原岩岩性为纯橄榄岩、斜方辉橄岩;微量元素分析成果显示成矿元素Au、Pb、As含量较高;稀土元素球粒陨石标准化曲线显示轻稀土富集而重稀土亏损;δEu值介于0.43～1.48之间,说明岩体有一定的分异演化,但程度不均匀.结合矿床地质特征,推测煎茶岭金矿成矿流体和成矿物质主要来自岩浆,在热液充填交代和氧化淋滤复合作用下,促使热液流体中的金沉淀成矿.     

内蒙古边家大院铅锌银矿床花岗斑岩及辉石闪长岩特征及对成矿的指示

边家大院铅锌银矿床位于中亚造山带东段,属于大兴安岭主峰锡、铅、锌、铜成矿带。通过对边家大院矿区中花岗斑岩和辉石闪长岩进行LA-ICP-MS锆石U-Pb定年、主量元素、微量元素和钠长石电子探针分析,结果表明花岗斑岩与辉石闪长岩锆石U-Pb年龄分别为(138.2±0.8)Ma、(137.4±0.7)Ma,为早白垩世岩浆活动的产物。辉石闪长岩SiO2含量为50.99%～52.89%,CaO含量为7.47%～7.51%,MgO含量为3.64%～4.68%,全碱Na2O+K2O含量为4.91%～5.36%,位于高钾钙碱性系列与钙碱性系列交界线上;花岗斑岩具有晶洞构造、镜下鉴定显示长石全部为碱性长石,新鲜无矿化的花岗斑岩高硅(SiO2=70.34%～74.49%)、富碱(Na2O+K2O=4.83%～9.42%)、A/CNK值为1.13～2.40,属于过铝质花岗岩、贫钙(CaO=0.16%～1.04%),属于高钾钙碱性-钾玄岩系列,稀土元素配分图显示轻稀土富集,具强烈的Eu负异常(δEu=0.12～0.32),富集大离子亲石元素Rb、Th、U、K,明显亏损高场强元素Ta、Nb、P、Ti和过渡元素Sr、Ba等,钠长石An(0.03～4.64)远小于10,显示无矿化花岗斑岩具有高演化的A2型造山后碱长花岗岩特征,推断花岗斑岩岩浆来源于地壳,形成于张性环境中。结合地质特征和前人研究成果,认为边家大院花岗斑岩为成矿地质体,矿区西部深处仍有较大成矿潜力。     

安徽铜陵杨冲里金矿床成矿流体特征与成矿模式探讨

杨冲里金矿床是长江中下游成矿带铜陵矿集区内舒家店矿区新发现的新类型金矿床(破碎带蚀变岩型),矿体主要赋存于二长闪长岩与志留纪地层接触带外围的碎裂岩中。流体包裹体测温显示该矿床均一温度范围在220. 1～445. 3℃(平均值为328. 3℃),盐度介于0. 18%～8. 00%NaCleqv之间(平均值为2. 52%NaCleqv),属于中高温-低盐度-低密度成矿流体。激光拉曼包裹体成分分析显示包裹体气相成分主要为CO_2和H_2O,而液相成分主要为H_2O,可能含极少量的CO_2。H、O同位素测试结果表明成矿流体的δD值为-85‰～-50‰,δ~(18)O_水值为0. 76‰～3. 76‰,落于岩浆热液与大气降水之间,受大气降水作用影响明显。矿区内出露两个侵入岩体,岩性分别为辉石闪长岩与二长闪长岩,前人的年代学研究及两者之间的穿插关系表明,辉石闪长岩的侵位时间略早于二长闪长岩;区内两个矿床的流体包裹体特征显示,杨冲里金矿与舒家店铜矿的流体包裹体具备相似的温度,但盐度相对较低,根据不混溶流体成矿机制,杨冲里金矿成矿流体物理化学条件的变化,是成矿物质淀积的主要形成因素。结合前人对于矿区内S、Pb等同位素的研究,我们认为杨冲里金矿与舒家店铜矿为同一区域的两次成矿事件,杨冲里金矿为该成矿系统的末端成矿。     

青海省果洛龙洼金矿区年代学研究与流体包裹体特征

青海省都兰县果洛龙洼金矿床位于东昆仑造山带东段, 昆中断裂南侧。利用40Ar/39Ar测年法,获得成岩年龄介于201.8~229.3Ma,集中在202.2~204.6Ma。平均年龄为202.7±1.5Ma。成矿流体均一温度主要集中在126℃～280℃,盐度一般为6.8～17.5(wt%),成矿流体特征表明金的成矿作用与岩浆热液关系密切,属于中温岩浆热液矿床。流体包裹体气相成分主要为H2O和CO2,还有含有一定量的CH4和少量H2。液相成分中,阳离子以Na+和K+为主,阴离子以SO42-、Cl-为主。所有样品中,Na+>K+含量,Cl->SO42-含量。成矿溶液属于CO2－Na+(K+,Ca+)－Cl-（SO42-,F-)－H2O体系。后期的热液活动存在明显的H2O和CO2的分离作用,对金矿成矿起到了改造富集作用。流体包裹体成分测量表明,成矿流体属于偏碱性的富硫流体,流体中大多数是Na+>K+,这与整个东昆仑成矿带中岩体的Na20高于K2O的现象一致,流体中富Ca2+贫Mg2+。     

金厂沟梁金矿区暗色脉岩的成因和意义:主要和微量元素地球化学证据

金厂沟梁金矿区中与成矿伴生的暗色脉岩主要是细晶闪长岩-石英闪长岩、闪长玢岩-英安斑岩类.细晶闪长岩-石英闪长岩的ALK值为5.47%～5.88%,K2O/Na2O值为0.455～0.496,属钙碱性岩系,并具有Ⅱ型Adakite岩的性质;闪长玢岩-英安斑岩的ALK值为7.83%～8.28%,K2O/Na2O值为1.100～1.747,属粗安岩系.元素地球化学特征显示:细晶闪长岩-石英闪长岩的岩浆源于富集地幔或洋壳俯冲脱水交代的下地壳,地壳增厚过程产生并就位;闪长玢岩-英安斑岩类的岩浆就位相对晚,来源具有上地壳性质或被地壳物质强烈混染,地壳减薄过程形成;这种特征暗示金厂沟梁金矿形成的地球动力学背景是在地壳挤压增厚转化为伸展减薄过程.     

吉林六批叶沟金矿床流体包裹体研究

通过对金矿石石英内的原生、假次生包裹体的系统研究,查明流体包裹体主要是NaCl-H2O型,其次是CO2型.测温结果显示成矿流体温度为100℃～352℃;盐度(ω(NaCl))=0.88%～8.55%,密度为0.356～0.997g/cm3,估算成矿压力为48.83～71.29MPa,成矿深度为1.62～2.34km,属中深中温热液金矿床.成矿流体液相成分富含Na 、K 、Cl-、SO2-4及少量Mg2 和F-;气相成分以H2O为主,其次是CO2和少量的CH4、C2H6、N2及微量的H2S和Ar.依据成矿流体Na /K =1.32、Na /(Ca2 Mg2 )=100.61以及矿床与侵入体的关系进行判定,成矿流体主要来源于初始混合岩浆水,并有变质水及大气降水叠加.     

铜陵地区朝山矽卡岩型金矿床及含矿岩体的成因:40 Ar/39 Ar年龄、元素地球化学及多元同位素证据

位于铜陵地区狮子山矿田的朝山金矿是长江中下游成矿带少有的矽卡岩型独立金矿床,成矿与白芒山辉石闪长岩有关,绝大多数金矿体产于白芒山辉石闪长岩与中三叠统南陵湖组灰岩的接触带上.辉石闪长岩中三个角闪石单矿物样品的40Ar/39Ar激光阶段加热分析给出了很好的坪年龄,年龄值介于139.7±0.3～138.3±0.6Ma(2σ),代表白芒山岩体冷却到500～550℃(氩同位素在角闪石中的封闭温度)的年龄.根据角闪石40Ar/39Ar年龄和前人获得的SHRIMP锆石U-Pb年龄(142.9Ma)以及Ar同位素和U-Pb体系在角闪石和锆石中的封闭温度,计算出白芒山岩体冷却速率大约为100℃/Ma.由于氢同位素在角闪石中的封闭温度与朝山金矿的成矿温度非常接近,因此,上述40Ar/39Ar年龄可以代表朝山金矿的成矿年龄.白芒山辉石闪长岩具有富碱、高钠、准铝质、富集轻稀土元素和大离子亲石元素、亏损重稀土元素和高场强元素的地球化学特点,其Sr-Nd同位素组成((87Sr/86Sr)I=0.706598～0.707460,εNd(t)=-7.78～-8.12)与铜陵及邻区同时代或稍晚时候的辉长岩和玄武岩非常相似.以上地球化学和Sr-Nd同位素特征暗示白芒山辉石闪长岩起源于富集岩石圈地幔的部分熔融,并经历了一定程度的分离结晶和地壳混染作用.矿石矿物的硫同位素组成(δ34S= 6.2‰～ 9.3‰)呈偏离零值的塔式分布,富集34S,可能是岩浆硫与中石炭统和/或中三叠统膏盐层混合的产物.矿石中脉石矿物方解石的C-O同位素与矿区三叠系海相碳酸盐明显不同,而与地幔原始碳酸岩相似,反映成矿流体中碳(主要是CO2的形式)的来源以深源为主,与含矿岩体成因研究得出的认识一致.对区域成岩成矿年代学及岩浆活动与成矿作用特点的分析认为,朝山金矿形成于岩石圈伸展的构造背景;强烈的岩石圈伸展及玄武质岩浆底侵为铜陵矿地区大规模岩浆活动及成矿作用提供了必要的动力学环境,也为成矿作用带来了丰富的热能、流体及金属成矿元素.     

内蒙乌拉山金矿床钾长石的矿物化学及有序度的分析

采用电子探针显微分析(EMPA)和粉末X射线衍射(XRD)分析了采自乌拉山金矿床含金钾长石石英脉、石英脉以及其他类型岩石中的10 0多个钾长石样品的化学成分和结果状态,并采用R和Q模式聚类分析、Spearman等级相关分析方法对实验数据进行了统计分析。结果表明,含金矿脉、岩浆热液脉和蚀变花岗岩中的钾长石为中等到最大微斜长石,其特征为K2 O含量高,但相对而言,Na2 O、CaO和BaO的含量低。其他岩石类型中的钾长石的化学成分和结果状态变化很大,可以从透长石、正长石到微斜长石,其特征为K2 O的含量相对较低,但Na2 O、CaO和BaO的含量相对较高。含金样品中的钾长石通常更富K2 O ,表明金的成矿作用与富钾的热液流体和碱质交代作用有关。乌拉山金矿床的成矿作用分为两个阶段,主要的含金钾长石石英脉中的钾长石富K2 O ,形成温度为30 7～379℃,平均为35 3℃;第二阶段含金石英脉中的钾长石含K2 O较低,形成温度为2 6 0～318℃,平均为2 81℃。这些结果表明成矿流体与岩浆热液作用有关,流体朝温度降低、K2 O含量降低的方向演化,K2 O含量高的热液流体和2 6 0～380℃的形成温度有利于金的成矿作用。     

安徽铜陵朝山金矿床流体包裹体研究

朝山金矿床是狮子山矿田内的热液交代型金矿床,在成因上与燕山期的白芒山辉石闪长岩有关.通过采集发育在不同深度下的含金黄铁矿-石英一方解石脉样品,进行流体包裹体岩相学观察和显微测温发现,石英和方解石中均捕获了富气相、富液相的两相水溶液包裹体和含子晶的三相水溶液包裹体,以上三种类型包裹体的均一温度统计峰值分别出现于315～335℃和255～275℃,盐度的统计峰值出现于17.50%～22.50%NaCl eq.和32.50%～37.50%NaCl eq.之间.激光拉曼探针分析表明,石英中流体包裹体的气相成分以水蒸汽为主,伴有少量CO2,可能含有CH4.流体的H、O同位素组成具确岩浆水特征.上述研究表明.朝山金矿成矿流体经历了相态变化,发生了不均匀捕获.受燕山期岩浆作用影响,狮子山矿田内的铜、金成矿在时空上具有一定联系,成矿流体运移的过程中,主要发生了相分离、气相液化和减压沸腾作用,可能是形威铜、金矿化分带的重要原因.     

东准噶尔北缘老山口矿区花岗质岩体 地球化学特征

东准噶尔北缘老山口铁铜金矿区花岗质岩体主要有石英闪长岩、黑云母闪长岩、二长花岗岩、正长斑岩和闪长(玢)岩.对黑云母闪长岩和正长斑岩进行了岩石地球化学研究,结果表明:黑云母闪长岩SiO2含量介于54.43％～55.10％,Al2O3和CaO含量分别为16.92％～17.64％和5.35％ ～ 5.94％,Mg#值为(51.95 ～55.96),富碱(K2O+ Na2O =9.0％ ～9.43％)和高钾(K2O/Na2O=1.32～1.74);与之相比,正长斑岩的SiO2 (59.96％ ～63.60％)、Al2O3(18.15％ ～ 19.13％)和Mg#(30.16 ～ 48.20)、全碱(K2O+Na2O=11.81％～13.17％)含量偏高,CaO含量(1.13％ ～2.47％)和K2O/Na2O比值(1.1 ～1.53)偏低.它们属钾玄质系列岩石.所有岩石富集LREE和Rb、K、Pb、Sr和Zr,相对亏损Nb、Ta和Ti,是晚古生代准噶尔古大洋俯冲的产物.黑云母闪长岩是俯冲板片熔体和富含钾的地幔楔熔体深侵位的产物,正长斑岩为黑云母闪长岩原始岩浆经角闪石和辉石的分离结晶后又经钾长石堆晶和角闪石残余岩浆浅侵位的产物.     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.     

PALEONTOLOGY

正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)     

GEOCHEMICAL EXPLORATION

正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)     

MICROPALAEONTOLOGY

正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)     

PETROLOGY

正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,     

ENVIRONMENTAL GEOLOGY

正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an