浙东地区东园花岗岩体年代学、地球化学特征及其地质意义

浙东地区岩浆岩广泛分布,受区域构造控制较明显,总体沿北东向余姚-丽水断裂带分布。本文对东园花岗岩体开展了详细的年代学和岩石地球化学研究。东园岩体主要由二长花岗岩、石英二长岩和少量花岗岩组成,主岩体二长花岗岩的LA-ICP-MS锆石U-Pb年龄为235.6±0.7 Ma(MSWD=0.97,2σ),花岗岩为238.1±0.8 Ma(MSWD=1.3,2σ),均属中三叠世产物。二长花岗岩和石英二长岩为准铝质-弱过铝质的钙碱性花岗岩,具高硅(62.94%~75.29%)、富碱(Na_2O+K_2O=8.17%~9.34%)且富钾(K_2O=4.54%~5.63%)的特征,轻重稀土分馏明显,具有较强的Eu正异常(δEu=0.94~2.43),明显亏损高场强元素(HFSE)Nb、P、Ti,而相对富集Th、Hf,富集轻稀土元素(LREE)和大离子亲石元素(LILE)Rb,相对贫Ba。岩体属高(-中等)分异I型花岗岩,岩浆来源于具弧属性的加厚地壳部分熔融,形成于同碰撞向后碰撞阶段转变的大地构造环境,可能与太平洋板块向华南板块俯冲作用事件有关。     

湖南锡田矿田花岗岩时空分布与钨锡成矿关系:来自锆石U-Pb年代学与岩石地球化学的约束

锡田钨锡多金属矿田位于南岭成矿带中段,发育多期次岩浆活动与钨锡成矿. 为了厘清花岗岩与钨锡成矿的时空关系,采用野外调查、显微鉴定、锆石U-Pb同位素定年与岩石地球化学的方法对矿田内多期次花岗岩岩体（脉）的空间分布、岩石类型、成岩时代、地球化学组成等进行了研究. 结果表明,锡田矿田发生了三期岩浆事件,分别为加里东期（435~441 Ma）、印支期（220~230 Ma）、燕山期（141~160 Ma）;三期花岗岩普遍富集大离子亲石元素Rb、K、U、Th等,亏损Ti、P、Sr、Ba等微量元素,具明显的负Eu异常,其中加里东期花岗岩与印支期花岗岩为S型花岗岩,而燕山期花岗岩为A型花岗岩;不同时期花岗岩中的成矿元素从加里东期→印支期→燕山期逐渐升高,特别是W、Sn元素在燕山期白云母与二云母花岗岩中最为富集,这与华南地区燕山期钨锡大爆发的时间是一致的;印支期岩体接触带发育少量矽卡岩型Fe-Cu-W多金属矿床,燕山期岩体接触带也发育矽卡岩型W-Sn多金属矿床,并在附近陡倾的张裂隙中发育多个中大型石英脉型W-Sn矿床,而加里东期岩体附近尚未发现钨锡矿化. 因此,锡田矿田的多期次花岗岩与钨锡多金属成矿是时空耦合的,且成矿以燕山期矽卡岩型与石英脉型钨锡矿为主.      

Zircon LA-ICP-MS dating and geochemical characteristics of I-type granitoids from the Yanhu area,west segment of the Bangongco-Nujiang suture (western Tibet): Petrogenesis and implications for the southward subduction of the Tethyan Ocean

The Yanhu granitoids are located in the west segment of the Bangongco-Nujiang suture in the western Tibetan Plateau. The main rock types of the granitoids are diorite porphyry, quartz diorite, granodiorite, granite and granite porphyry. Here, their zircon LA-ICP-MS U-Pb ages and petrogeochemical data are reported. Three groups of magmatic events can be distinguished from the Yanhu area: group 1 includes samples AK01 and ZK01 of diorite porphyry, and sample D3658 of quartz diorite that yield mean zircon U-Pb ages of 121.0 ± 2.7 Ma, 116.6 ± 2.0 Ma and 116.0 ± 3.9 Ma, respectively; group 2 includes sample D0050 of diorite porphyry, samples D1393 and D3660 of granodiorite and sample D3065 of granite porphyry that yield mean zircon U-Pb ages of 104.9 ± 2.0 Ma, 105.4 ± 3.8 Ma, 104.2 ± 1.9 Ma and 104.2 ± 1.9 Ma, respectively; group 3 includes sample D3093 of granite that yields mean zircon U-Pb ages of 93.6 ± 1.5 Ma. The zircon LA-ICP-MS U-Pb ages suggest that the Yanhu granitoids were emplaced at 121.0–93.6 Ma, representing Cretaceous magmatism in the west segment of the Bangongco-Nujiang suture. The granitoids are composed of SiO₂ (56.57 to 76.98 wt.%), Al₂O₃ (12.20 to 17.90 wt.%), Na₂O (3.61 to 4.98 wt.%), K₂O (2.06 to 4.71 wt.%) and CaO (0.27 to 5.74 wt.%). The Yanhu granitoids exhibit enrichment in LREE (light REE) and LILE (large ion lithophile elements) such as Rb, Th, U, Pb and K and depletion of HREE (heavy REE), P, Ti, Nb, Ta and Zr. Their A/CNK ratios of 0.85-1.06 are <1.1, implying that they are high-K, metaluminous-weakly peraluminous I-type granites. TheYanhu granitoids were generated mainly by partial melts of the meta-igneous lower crust and some arc-related materials. The Yanhu granitoids probably formed in VAG and syn-COLG tectonic settings related to the southward subduction of the Tethyan Ocean. Diorite porphyry and quartz diorite magmatism from 121.0 Ma to 116.0 Ma may be associated with the southward Bangongco–Nujiang Tethys oceanic crust subduction. Diorite porphyry, granodiorite, and granite porphyry magmatism from 105.4 Ma to 104.2 Ma may be associated with the rising asthenosphere induced by the slab breakoff. Granite magmatism from 93.6 Ma may be related to the crustal thickening induced by the final amalgamation of the Lhasa Terrane and the Qiangtang Terrane.     

福建政和地区加里东期花岗岩的厘定及其大地构造意义

福建政和地区林屯石英闪长岩和富美花岗岩原定为燕山早期岩体,通过对其进行锆石LA-ICP-MS U-Pb同位素测年分析,获得的年龄分别为林屯岩体433±7 Ma,富美岩体369±4 Ma。林屯岩体全岩微量元素具有明显的Ti、Nb、Ta负异常和Pb正异常,轻稀土富集,重稀土配分曲线较为平缓,不具明显的Eu负异常,为I型花岗岩,具有板块边缘幔源岩浆的特征。富美岩体全岩微量元素具有明显的Ba、Sr、P、Ti负异常和Rb、Pb、Th、U正异常,轻稀土富集,Eu负异常明显,具有板内S型花岗岩的特征。两个岩体的同位素测年及元素地球化学分析结果证明,这两个岩体为加里东期形成,反映了武夷山地区存在加里东期构造?岩浆事件,也为武夷山加里东构造运动的性质和时限提供了精确约束。     

东天山哈尔里克地区早石炭世A型花岗岩年代学、地球化学及地质意义

A型花岗岩对研究天山造山带壳幔相互作用和构造演化具有重要意义.对东天山哈尔里克地区的碱长花岗岩和正长花岗岩进行了详细的岩石学、地球化学和年代学研究,旨在阐明其成因及构造意义.其中碱长花岗岩的LA-ICP-MS锆石U-Pb年龄为350.7±2.0 Ma和351.8±2.0 Ma,表明该花岗岩体形成于早石炭世早期.岩石含大量碱性长石,暗色矿物以黑云母为主,见钠铁闪石等碱性暗色矿物.岩石高硅、富碱、贫钙镁,富集Rb、Th、K等大离子亲石元素和Zr、Hf等高场强元素,而强烈亏损元素Ba、Sr、Eu,具弱右倾“Ⅴ”字型的稀土分配曲线（（La/Yb）_N=3.23~5.55,δEu=0.19~0.28）.这些矿物学和地球化学特征表明哈尔里克早石炭世花岗岩属高钾准铝质-弱过铝质花岗岩,为典型的A型花岗岩.花岗岩正的ε_Nd（t）值（+4.2~+4.8）和新元古代的二阶段Nd模式年龄（t_DM2=0.71~0.75 Ga）,表明其源区可能为新生年轻地壳,源岩可能是亏损地幔来源的下地壳中基性岩和少量大洋沉积物.结合前人对东天山岩浆活动和构造环境的研究,认为早石炭世哈尔里克与博格达处于同一构造背景下,早石炭世早期A型花岗岩可能形成于博格达弧后裂谷的伸展早期阶段.      

广西苍梧社洞钨钼矿床花岗岩类岩石的地球化学特征及其与成矿关系

广西苍梧社洞钨钼矿是与花岗岩类有关的矿床。矿区主要花岗岩类包括加里东期花岗闪长岩、花岗闪长斑岩和燕山晚期花岗斑岩。加里东期花岗闪长岩、花岗闪长斑岩具有低Si、K,富Na、Al和基性组分特征,属于强过铝质的正常钙碱性系列岩石;稀土总量低,轻重稀土分馏明显,弱负Eu异常(δEu=0.62~0.70);Ti、Nb、Ta亏损,Th、U、Pb、Zr、Hf富集,Rb/Sr平均值为0.78,明显富集W、Cu、Mo,属于I型花岗岩,为陆内造山带碰撞早期挤压背景下岩浆活动的产物,表现为对钨、钼、铜的成矿专属性。燕山晚期花岗斑岩具有高Si、K,贫Na、Ca和基性组分,属于强过铝质的高钾-中钾钙碱性系列岩石;稀土总量高,轻重稀土分馏不明显,强负Eu异常(δEu=0.03~0.06);Ti、Ba、K、Eu亏损,Th、U、Sm、Dy、Y、Ho、Yb、Lu富集程度更高,Rb/Sr平均值为7.56,明显富集Sn、Bi,属于燕山晚期岩浆演化程度较高的S型花岗岩,为碰撞后伸展环境的板内花岗岩,表现为对锡、金的成矿专属性。     

内蒙古乌日尼图花岗岩的年代学、地球化学及其地质意义

乌日尼图隐伏岩体位于内蒙古自治区苏尼特左旗查干敖包镇西北乌日尼图地区,主要岩石类型为细粒-中细粒花岗岩、二长花岗岩。岩相学及地球化学特征研究表明,乌日尼图花岗岩体属于高钾钙碱性岩系,SiO₂含量为74.85%～78.10%,K₂O/Na₂O比值介于1.45～3.08之间,铝指数A/CNK=1.00～1.21,属过铝质岩石。主微量稀土元素分析表明,该岩体富集Rb、Th、U等元素而Ba、Nb、Sr、P和Ti强烈亏损,Eu为负异常(δEu= 0.22～0.39),总体呈现轻稀土富集的右倾“V”形分布配分模式。LA-ICP-MS锆石U-Pb定年表明,乌日尼图花岗岩体形成于早白垩世(139 Ma),为燕山运动晚期的产物。乌日尼图花岗岩体属A型花岗岩,形成于伸展的大地构造环境,且源区成分不均一,源岩可能主要由富黏土的泥质岩夹杂少量砂屑岩变质形成。     

拉萨地体北部永珠地区早白垩世岩浆岩地球化学、锆石U-Pb年代学、Hf同位素组成及其地质意义

拉萨地体北部出露大面积早白垩世岩浆岩,对它们的成因和形成机制的研究,有助于揭示拉萨地块白垩纪时期的岩浆作用过程及动力学背景.通过岩石学、地球化学和同位素地质学方法对拉萨地体北带永珠地区早白垩世中-酸性岩浆岩进行了研究.结果显示黑云母二长花岗岩、流纹岩和安山岩的锆石LA-ICP-MS U-Pb年龄分别为118±1.0 Ma、121±0.8 Ma和115±0.8 Ma,代表了其侵入和喷出时代.黑云母二长花岗岩、花岗斑岩和流纹岩为高钾钙碱性过铝质-强过铝质岩浆岩（A/CNK=1.01~1.35）,亏损高场强元素Nb、P、Ti和大离子亲石元素Ba、Sr,富集大离子亲石元素Rb、K和放射性元素U、Th;稀土配分图显示LREE富集,HREE近平坦,Eu明显负异常,为形成于大陆边缘的岛弧岩浆岩特征.黑云母二长花岗岩和流纹岩的锆石Hf初始比值ε_Hf（t）分别为-1.21~3.01和-0.68~5.35,对应的两阶段模式年龄分别为0.99~1.26 Ga和0.84~1.22 Ga,为壳幔混源岩浆.安山岩为高钾钙碱性,亏损Nb、Ta、P、Ti、U和Sr,富集Rb、K和Th,稀土配分图显示LREE富集,HREE近平坦,Eu轻微负异常,为形成于大陆边缘弧的岩浆岩.结合前人研究成果,分析认为永珠地区早白垩世岩浆岩形成于班公湖-怒江特提斯洋壳南向俯冲作用下的大陆边缘弧环境,由俯冲的班公湖-怒江中特提斯洋板片在深部脱水熔融,进而诱发上覆地幔楔部分熔融形成基性岩浆上涌,导致下地壳物质发生部分熔融形成酸性岩浆,它们在上升过程中按不同比例混合,形成中性和酸性岩浆侵入到地下或喷出地表,形成侵入岩和火山岩.      

东天山东段国宝山晚二叠世—中三叠世花岗质岩石成因与构造意义——年代学和地球化学约束

东天山—北山地区是中国重要的金属成矿带,对于其晚二叠世—中三叠世构造演化的认识,仍存在较大分歧.东天山东段国宝山地区出露有一系列晚二叠世—中三叠世花岗质岩石,包括花岗闪长岩、二长花岗岩、石英正长岩、正长花岗岩和天河石花岗岩.该系列岩体整体以富硅、富碱为特征,其中花岗闪长岩、二长花岗岩和石英正长岩具有钾质和富镁特征,轻稀...     

An early Palaeozoic double-subduction model for the North Qilian oceanic plate: evidence from zircon SHRIMP dating of granites

The North Qilian Orogenic Belt (NQOB), which consists of ophiolitic mélange and island-arc assemblages containing many granites, blueschists, and eclogites, lies between the Alax and Qilian terranes in northwestern China. The Minleyaogou and Niuxinshan granitoids occur at the northern and southern margins, respectively, in the middle segment of the NQOB. The Minleyaogou pluton is granodiorite in composition, whereas the Niuxinshan pluton consists mainly of red granite with minor grey quartz diorite. Geochemically, the Minleyaogou granite differs from the Niuxinshan granite in that it contains a smaller range in SiO₂, has lower total alkalis, and is more peraluminous. Both granitoids are magnesian but the Niuxinshan granite is alkali-calcic, whereas the Minleyaogou granodiorite is calcic. Both granitoids have similar chondrite-normalized rare earth element patterns with light rare earth element enrichment and negative Eu anomalies. They have pronounced negative Ba, Nb, Sr, P, and Ti anomalies indicating that they have an affinity to island-arc or active continental margin magmatism. SHRIMP U–Pb dating of zircons from the granitoids yields a formation age of 477 Ma for the Niuxinshan granite and 463 Ma for the Minleyaogou granodiorite. These ages, combined with the geochemistry and locations of the plutons, suggest that they formed by the double subduction of the North Qilian oceanic plate during early Palaeozoic time. Formation of the Niuxinshan granite may be related to southward subduction under the Qilian terrane at 477 Ma, whereas the Minleyaogou granodiorite was formed by northward subduction at 463 Ma under the Alax terrane.     

鄂东南程潮铁矿床花岗质岩和闪长岩的岩体时代、成因及地质意义——锆石年龄、地球化学和Hf同位素新证据

利用LA-ICP-MS锆石U-Pb法测得程潮矿区花岗岩成岩年龄为（128.8±0.5） Ma,石英二长斑岩成岩年龄为（128.3±0.5） Ma,闪长岩成岩年龄为（140.0±0.3） Ma,辉绿玢岩成岩年龄为(125.5±0.5) Ma,皆形成于早白垩世。地球化学分析结果显示：花岗质岩为高钾准铝质I型系列;闪长岩和辉绿玢岩为高钾钙碱性系列。各岩体的稀土元素总量较高,轻稀土强烈富集,轻、重稀土元素分异明显,无明显的负铕异常。花岗质岩的微量元素以富集Rb、Th、U、La等元素,贫Ba、Nb、Sr等元素为特点。闪长岩和辉绿玢岩具有相似的微量元素特征,表现为K、La、Nd富集和Ta、Nb、Sr、P、Ti亏损的特点。根据岩体的锆石Hf同位素组成和地球化学特征可知,程潮矿区各岩体可能是岩石圈地幔在部分熔融过程中,混入了不同数量古老下地壳物质的产物。矿区花岗质岩的成岩年龄与程潮Fe矿床的成矿年龄相近,暗示其与矿体有着密切的联系。     

Early Carboniferous (Viséan) emplacement of the collisional Kłodzko–Złoty Stok granitoids (Sudetes, SW Poland): constraints from geochemical data and zircon U–Pb ages

Sensitive high-resolution ion microprobe zircon U–Pb dating and geochemical data of igneous rocks from the composite K?odzko–Z?oty Stok (KZS) Granite Pluton, Sudetic Block, indicate that the granitoids represent an Early Carboniferous Viséan phase of Variscan metaluminous, high-K, I-type, syn-collisional granite magmatism within the Saxothuringian Zone of the Central European Variscides. Igneous zircon records hypabyssal magmatism that produced various granitoids and lamprophyre (spessartite) emplaced from ca. 340 to 331 Ma. The KZS granitoids have compositions ranging from granodiorite to monzonite, low A/CNK ratios (<1), and are associated with abundant mafic members. Most of them are alkaline, highly potassic, and moderately evolved. The major and trace element contents of the KZS granitoids suggest geochemical heterogeneity, and the hybrid nature of magmas derived from a range of sources in the middle crust, with a strong input of material from the upper mantle. Mixing of magmas of mantle origin with high-K material from partly melted continental crust was probably a more important factor than fractional crystallization, in controlling the evolution of the magmas. The mean Pb–U ages of the main population of igneous zircon from a quartz monzodiorite (?elazno) and hornblende monzonite (Droszków) are 340.2 ± 2.5 Ma and 339.5 ± 3.1 Ma, respectively. A slightly younger biotite-hornblende granodiorite from Chwalis?aw, 336.7 ± 2.5 Ma, was cut by a spessartite dyke at 333.1 ± 3.1 Ma. This indicates that mafic magmas were immediately intruded into fractured, probably incompletely solidified, granodiorites. The lamprophyric dyke also contains igneous zircon of Neoproterozoic age, 566.3 ± 6.4 Ma, typical of the crust in the Saxothuringian Zone. Tonalite from Ptasznik Hill near Droszków is of similar age to the spessartite, 331.5 ± 2.6 Ma. High REE contents in the tonalite and its igneous zircon indicate advanced differentiation of granitic magma, producing a more leucocratic melt associated with post-magmatic activity including abundant late crosscutting pegmatites and quartz veins, and contact metasomatic mineralization. The KZS granitoids have rather similar petrographic and geochemical characteristics to granitoids from other parts of the Central European Variscides, where a thickened orogenic root caused a substantial rise in crustal temperatures, producing granitoid magmas closely correlated with regional tectonic activity between the Saxothuringian and Brunovistulia Terranes at the NE margin of the Bohemian Massif.     

大兴安岭中段早白垩世花岗质岩石锆石U-Pb年龄及地球化学特征

大兴安岭地区显生宙花岗岩分布广泛,但区内中生代花岗岩的研究相对薄弱.通过对大兴安岭中段扎兰屯以西的毕家店岩体和神山岩体进行年代学和地球化学研究,探讨了本区早白垩世花岗岩的成因及构造背景.其中毕家店岩体主要由正长花岗岩和花岗斑岩组成,神山岩体主要由碱长花岗岩组成.毕家店岩体的锆石U-Pb年龄为136±3 Ma、139.5±0.9 Ma和128.1±0.8 Ma,神山岩体为119.3±0.8 Ma,均形成于早白垩世.地球化学特征上,两岩体均呈现高硅、低钙、富碱、Eu负异常等特征,亏损Nb、Ta,富集Rb、Th和U,属于弱过铝质高钾钙碱性系列,为岩浆演化晚期的高分异I型花岗岩.两岩体具有活动大陆边缘构造属性,结合大兴安岭地区同时期I型、A型花岗岩特征,认为早白垩世花岗质岩石的形成与太平洋板块俯冲背景下的拆沉作用密切相关.     

Late Jurassic–Early Cretaceous tectonic evolution of the Great Xing’an Range: geochronological and geochemical evidence from granitoids and volcanic rocks in the Erguna Block,NE China

ABSTRACT

The late Mesozoic magmatic record within the Erguna Block is critical to evaluate the tectonic history and geodynamic evolution of the Great Xing’an Range, NE China. Here, we provide geochronological and geochemical data on Late Jurassic–Early Cretaceous plutonic-volcanic rocks in the northern Erguna Block and discuss their origin within a regional tectonic framework. Late Mesozoic magmatism in the Erguna Block can be divided into two major periods: Late Jurassic (162–150 Ma) and Early Cretaceous (140–125 Ma). Late Jurassic quartz monzonite and dacite show adakite characteristics such as high Al₂O₃, high Sr, and steeply fractionated REE patterns. Contemporary granitoids and rhyolites are also characterized by strong enrichment of light rare earth elements (LREE) and significant depletion in heavy rare earth elements (HREE), but with more pronounced negative Eu anomalies. Early Cretaceous trachytes and monzoporphyries exhibit moderate LREE enrichment and relatively flat HREE distributions. Coeval granites and rhyolites have transitional signatures between A-type and fractionated I-type felsic rocks. Both Late Jurassic and Early Cretaceous rocks have distinctive negative Nb, Ta, and Ti anomalies, and positive zircon ε_Hf(t) values, suggesting that these magmas were derived from partial melting of Meso-Neoproterozoic accreted lower crust, although melting occurred at a variety of crustal levels. The transition from adakite to non-adakite magmatism reflects continued crustal thinning from Late Jurassic to Early Cretaceous. Our data, together with recently reported isotopic data for plutonic and volcanic rocks, as well as geochemical data, in NE China, suggest that Late Jurassic–Early Cretaceous magmatism in the Erguna Block was possibly induced by post-collisional extension after closure of the Mongol-Okhotsk Ocean.     

Recognition of early Carboniferous alkaline granite in the southern Altai orogen: post-orogenic processes constrained by U–Pb zircon ages, Nd isotopes, and geochemical data

The Altai orogen forms the southern part of the Central Asian Orogenic Belt (CAOB), the world’s largest accretionary orogen. However, its tectonic evolution, particularly during the late Paleozoic, is still not well understood. U–Pb zircon analyses for the Bulgen alkaline granite yield crystallization ages of 358?±?4?Ma (SHRIMP) and 354?±?4?Ma (LA-ICP-MS). These ages are significantly younger than published emplacement ages for subduction/collision-related syn-orogenic granitoids (460–375?Ma) in this region. The Bulgen granite has high SiO₂, total alkalis, rare earth elements, HFSE (Th, Zr, Hf, Nb, and Ce), and low Ba, Sr with pronounced negative anomalies in Eu, Ba, Sr, P, and Ti, showing a clear A-type geochemical signature. The granite records high εNd(t) values of +6.3 to +6.4 and young model ages (T _DM) of ca. 600?Ma. The Bulgen alkaline granite is largely undeformed as opposed to the early-middle Paleozoic counterparts, which form elongated deformed bodies parallel to the prevailing tectonic fabric (NW direction). Available data suggest that magmatism in the southern Altai region evolved from early-middle Paleozoic I-type tholeiitic and calc-alkaline granitoids to late Paleozoic A-type alkaline granitoids. The high εNd(t) values of the Bulgen alkaline granite indicate a homogeneous juvenile mantle source, whereas the early-middle Paleozoic granitoids are characterized by lower and more variable εNd(t) values (?2.6 to +4.2). These differences provide an important insight into the late Paleozoic orogenic processes of the Chinese Altai and indicate a significant change of the tectonic regime from a syn-orogenic regional compression setting to a post-orogenic extensional one. Major tectonic movements in this region ceased after the early Carboniferous.     

北黄海盆地花岗斑岩锆石U-Pb年代学、地球化学及其地质意义

北黄海盆地X1和X2钻井岩心揭示上侏罗统中有侵入的花岗质岩石,镜下鉴定其为花岗斑岩。对花岗斑岩进行了主量、微量和稀土元素测试分析,样品的Si O2含量介于70.22%~71.88%之间,K2O/Na2O比值介于0.95~1.68之间,A/CNK比值介于0.75~1.12之间,有高钾钙碱性、弱碱质-偏铝质性质。微量元素组成富集Rb、Th、U等元素,相对亏损Nb、Eu、Sr等元素。稀土总量较高(∑REE=50.38×10-6~162.27×10-6),轻稀土(LREE)相对富集(LREE/HREE=6.86~25.43,(La/Yb)N=10.06~57.76),具有明显的Eu负异常(?Eu=0.65~0.83)。样品的Th含量高,与Rb呈正相关性,综合主量元素特征(A/CNK1.1),判别其为I型花岗岩。LA-ICP-MS锆石U-Pb测年结果表明X1井花岗斑岩年龄为110±1 Ma,X2井花岗斑岩年龄108±1 Ma、107±1 Ma,形成于早白垩世晚期。结合区域构造背景及岩石地球化学特征认为,北黄海盆地花岗斑岩形成于板块碰撞后的伸展构造背景。     

东昆仑东段阿斯哈矿床石英闪长岩LA-ICP-MS锆石U-Pb定年及岩石地球化学特征

阿斯哈石英闪长岩体位于东昆仑中央隆起带,侵入于古元宇金水口岩群中。岩体内产有阿斯哈大型金矿床,石英闪长岩与该区金矿形成具有密切的时空关系。采用锆石LA-ICP-MS、XRF和ICP-MS对石英闪长岩进行了定年以及地球化学测定。研究表明：该区石英闪长岩属钙碱性准铝质岩石,具有I型花岗岩的特征;其成岩年龄为（238.4±1.4） Ma;岩体稀土配分曲线几近一致,显示为同源岩浆演化特点,均表现出轻稀土相对富集的右倾特征,Eu具有弱的负铕异常;岩体明显富集大离子亲石元素,亏损高场强元素;具有明显的“TNT”负异常,显示出安第斯型岩浆弧火成岩构造属性;岩石Rb/Sr和Nb/Ta值介于地壳和地幔之间,并广泛发育暗色微粒包体,表明岩浆的壳幔混合成因。综上所述认为：阿斯哈金矿床石英闪长岩具有I型花岗岩特征,形成于印支期,具有壳幔混合的特征。     

福建沿海晚中生代花岗质岩石成因及其地质意义

福建白云山、鼓山和石牛山均位于福建沿海地带,该区域花岗岩类分布广泛。LA-ICP-MS锆石U-Pb定年结果显示,白云山、鼓山（魁歧）和石牛山地区花岗岩年龄分别为99.3Ma±1.8Ma、99.4Ma±2.3Ma和94.7Ma±1.4Ma,属晚白垩世早期的产物。花岗岩均具有富硅、富碱、贫钙镁、高分异指数等特点,属弱过铝到准铝质岩石。稀土元素具中-强Eu负异常,总体呈现轻稀土元素富集的右倾“V型”模式。微量元素Rb、U、Th、La等强烈富集,相对亏损Ba、Sr、P、Ti等元素。岩相学和地球化学特征分析表明,研究区花岗岩属典型的A型花岗岩,其中魁歧花岗岩为碱性A型花岗岩,其余地区为铝质A型花岗岩。研究表明,研究区A型花岗岩具有相似的源区组成;岩浆来源于地壳物质的部分熔融,并可能有部分地幔物质参与;碱性A型花岗岩较铝质A型花岗岩可能有更多的地幔物质加入。结合地球化学、野外地质、区域背景及年龄资料综合判定,中国东南沿海2类A型花岗岩为古太平洋板块俯冲体系中弧后伸展环境下的产物。     

Petrogenesis and tectonic implications of early Palaeozoic igneous rocks of the western South Qilian Belt,central China

Early Palaeozoic granitoids in the South Qilian Belt, central China, record details of the tectonic evolution and crustal growth of the Qilian orogenic belt. Five representative granitoids from the western South Qilian Belt were sampled for zircon LA-ICPMS U–Pb dating, Lu–Hf isotopes, and whole-rock geochemical analyses. Zircon U–Pb dating of two porphyritic granodiorites and a porphyritic monzogranite yielded ages of 442.7 ± 3.5, 441.8 ± 4.3, and 435.4 ± 3.5 Ma, respectively. These granitoids exhibit a geochemical affinity to I-type granite, are metaluminous with a low aluminium saturation index (A/CNK = 0.75–1.15), have moderate Al₂O₃ and low MgO contents, high La/Yb and low Sr/Y ratios, and are depleted in Nb, Ta, P, and Ti, which suggests a subduction zone magmatic arc affinity, with mixing between a primary mantle-derived magma with lesser continental crustal material. The syenogranite and monzogranite from the South Qilian Belt, which yield U–Pb zircon ages of 440.4 ± 9.0 and 442.3 ± 1.2 Ma, respectively, have pronounced S-type geochemical affinities, are peraluminous with A/CNK values of 1.07–1.16, have relatively high SiO₂, Al₂O₃, K₂O, and Rb contents, low Y and Yb, low Sr/Y and La/Yb ratios, positive Th, U, and light Rare Earth Element (REE) anomalies, and depletions in Nb, Ta, Sr, and Ti. Their geochemical signature suggests derivation from partial melting of continental crust in a syn-collisional setting. The Hf isotopic data of zircons from the granitoids show a significant input of Paleoproterozoic crust in the crustal formation of the western South Qilian Belt in Palaeozoic. Compare the ε_Hf(t) value of S-type granite with that of I-type granite, the former may have a comparatively homogeneous source. Together with regional evidence, it is proposed that a collisional event occurred between the South Qilian Belt and the Central Qilian Belt at ca. 442–435 Ma.     

长白山新生代火山岩之下新太古代基底年代学及地球化学特征

对长白山第四系玄武岩覆盖区零星出露的花岗质岩石和片麻岩进行LA-ICPMS锆石U-Pb年龄测定及地球化学分析,结果显示花岗质岩石的年龄为2 509~2 558 Ma;斜长角闪片麻岩的年龄为2 475~2 553 Ma。地球化学特征上,这些岩石均属奥长花岗岩-英云闪长岩-石英闪长岩系列(TTG),稀土元素配分模式图呈右倾型,轻重稀土元素分馏明显(LREE/HREE=3.85~34.48),白云母二长花岗岩具有铕的负异常(δEu=0.41~0.54),富集Rb、K、Th等元素,亏损Nb、Sr、P、Ti等元素;黑云斜长角闪石片麻岩具有铕负异常(δEu=0.67~0.76),富集Rb、K、La、Nd等元素,亏损Th、Nb、Sr、P、Yb等元素;花岗质片麻岩和黑云斜长片麻岩具有铕的弱负-正异常(δEu=0.87~3.3),富集Rb、K、Sr等元素,亏损Nb、Th、P等元素。年代学和地球化学特征与白山地块和和龙地块中的同类岩石基本一致,表明白山地块与和龙地块在晚太古代是同一个陆块(龙岗陆块),二者目前的分布格局是后期北东向左行断裂构造改造的结果。