Zircon U-Pb Ages of the Granodioritic Porphyry in the Laba Molybdenum Deposit,Yunnan, SW China and Its Geological Implication

The Geza island-arc is a well-known mineralization concentration area,part of the Sanjiang Domain at the east margin of the Tibetan Plateau.In recent years,several Late Yanshanian granitic intrusions and associated deposits have been found in this region,the largest one of which in the Shangri–La region is the Laba molybdenum deposit.Previous studies suggested that the timing of the Laba mineralization is 85 ± 2 Ma.However,the ages of the granodioritic porphyry remain unknown.In this study,LA-ICP-MS U-Pb dating of zircons from three samples of the molybdenite-bearing granodioritic porphyry has been conducted with resulting dates of 85.00 ± 0.23 Ma(MSWD = 0.58),85.28 ± 0.28 Ma(MSWD = 1.12),and 84.83 ± 0.26 Ma(MSWD = 0.79),respectively,indicating that these granodioritic porphyries formed in the Late Yanshanian around ~85 Ma.Combined with the geological features of the mineralization,the Laba deposit is spatially,temporally,and probably genetically associated with the granodioritic porphyries.In addition,the ages of the Laba deposits are consistent with the other Late Yanshanian intrusions and mineralization,suggesting that the mineralization was probably generated under an intra-plate extensional environment during the Late Cretaceous.     

粤北大宝山矿区船肚岩体和大宝山花岗斑岩锆石LA-ICP-MS U-Pb年龄及多阶段成矿分析

粤北大宝山矿床矿区出露船肚和大宝山矿化岩体。本文分析了两个岩体矿物组成特征和锆石LA-ICP-MS U-Pb年龄。船肚岩体为似斑状结构,块状构造,主要由似斑状花岗岩、似斑状二长花岗岩及似斑状花岗闪长岩等组成,和云英岩型及矽卡岩型Mo-W矿化紧密共生。大宝山岩体为斑状结构,块状构造,主要由碱长花岗斑岩、普通花岗斑岩、二长花岗斑岩及花岗闪长斑岩组成,矿物组成和船肚岩体的基本相同,和细脉浸染状Mo-W矿化紧密共生。船肚似斑状二长花岗岩和大宝山二长花岗斑岩锆石LA-ICP-MS U-Pb年龄分别为162.1±1.6 Ma,MSWD=2.72和165.8±2.0 Ma,MSWD=1.38。据船肚和大宝山岩体矿物组成基本相同、岩石结构不同及两者锆石Th/U比值不同和U-Pb年龄存在约4 Ma左右时差,提出大宝山矿区在燕山期发生了两阶段岩浆成矿事件,第一阶段岩浆成矿事件发生在166 Ma左右,形成大宝山斑岩型矿床,第二阶段岩浆成矿的形成时间约为162 Ma左右,形成船肚似斑状二长花岗岩及与岩体紧密共生的矽卡岩型和云英岩型矿化;大宝山斑岩体和船肚似斑状岩体是同一岩浆房两次脉动侵入形成的。     

拉萨地块北部~90Ma斑岩型矿床年代学及成矿地质背景

近年来青藏高原多个大型—超大型斑岩Cu-Mo-Au矿床的发现已引起人们广泛的关注,现有研究显示这些含矿斑岩和斑岩型矿床的形成年龄主要集中在120～110Ma、～90Ma、54～45Ma和18～12Ma4个阶段,其中90Ma左右的斑岩型矿床的成矿地质背景仍存在很大争议。本文报道拉萨地块北部尼玛县拔拉扎斑岩型矿床含矿斑岩的LA-ICPMS锆石U-Pb定年以及辉钼矿Re-Os定年结果,并分析了该期的成矿地质背景。两件花岗闪长斑岩锆石206Pb/238U加权平均年龄分别为92.1±1.2Ma、93.8±1.2Ma,代表了岩浆的结晶时代;而辉钼矿Re-Os模式年龄为88.2～89.6Ma,代表了拔拉扎矿床的成矿年龄。依据区域地质资料,本文认为拉萨地块北部～90Ma岩浆活动和成矿作用既不可能是雅鲁藏布江结合带所代表的新特提斯洋平板俯冲或洋脊俯冲的产物,也不可能是班公湖-怒江洋盆南向俯冲消减直接的产物,而很可能是班公湖-怒江洋盆俯冲消减闭合之后碰撞过程的产物。因此本文认为拉萨地块中北部地区～90Ma的岩浆作用及其成矿作用是形成于碰撞的构造背景。     

云南哈播斑岩型铜（ 钼 金）矿床地质与成矿背景研究

哈播斑岩铜(-钼-金)矿床位于哀牢山-红河新生代成矿带南端西侧,是近年来新发现的一个斑岩型矿床.矿区内出露的哈播侵入体具有多期侵入的特征,花岗岩依次侵入的序列为坪山花岗岩、三道班花岗岩、阿树花岗岩、哈播南山花岗岩(37.3 Ma),随后有4期斑岩侵入到哈播南山花岗岩中,依次为黑云母钾长石斑岩、石英钾长石斑岩、石英二长斑岩和晚期黑云母钾长石斑岩岩脉.采用LA-ICP-MS锆石U-Pb年龄法测定黑云母钾长石斑岩和石英二长斑岩的加权平均年龄分别为36.20±0.20 Ma和36.19±0.22 Ma,哈播南山花岗岩和4期斑岩具有相似的岩石地球化学特征,都有富钾、高氧化态和类似岛弧花岗岩的岩石地球化学特征,可能具有相同的来源.辉钼矿Re-Os年龄显示,哈播矿床的成矿年龄为35.47±0.16 Ma.相似的成岩-成矿年龄暗示哈播矿床成岩和成矿作用是一个连续的岩浆-热液过程,与玉龙斑岩铜矿相似.基于哈播矿床的岩石学、地球化学特点,结合前人关于青藏高原东部斑岩铜矿的研究成果,我们认为哈播斑岩矿床可能为藏东富碱斑岩带向东南的延伸,与玉龙斑岩铜矿带具有相似的成因,为哀牢山-红河新生代成矿带的重要组成部分,是晚碰撞构造转换背景下的重要产物.     

哈萨克斯坦阿克斗卡特大型斑岩铜矿床成矿时代与剥露历史研究

哈萨克斯坦阿克斗卡特大型斑岩型铜矿床产在中亚成矿域巴尔喀什成矿带阿克斗卡矿田。本文根据花岗岩类岩石的锆石U-Pb、40Ar/39Ar和裂变径迹(FT)热年代学研究,结合前人研究成果,给出了阿克斗卡斑岩铜矿床从深成岩浆活动、成矿作用、区域冷却到剥露作用的全过程。阿克斗卡矿床及附近花岗岩类锆石SHRIMPU-Pb定年结果,给出科尔达尔岩体早期英云闪长岩的结晶年龄为335.7±1.3Ma;主成矿期的含矿二长花岗斑岩结晶年龄为327.5±1.9Ma,反映了阿克斗卡矿床斑岩型铜成矿作用的年龄。花岗岩类角闪石、黑云母、钾长石40Ar/39Ar热年代学分别给出矿物冷却年龄为310.6Ma、271.5Ma和274.9Ma,进一步限定了深成斑岩型铜成矿作用的时代和区域冷却的历史。磷灰石FT测年数据揭示,受区域构造作用的影响,阿克斗卡铜矿田在晚白垩世(91～68.0Ma)发生地块的差异隆升和剥露作用。     

福建紫金山矿田晚中生代英安玢岩形成时代及其成矿意义

福建紫金山Cu-Mo-Au-Ag多金属矿田是一个完整的斑岩-浅成低温热液矿床成矿体系。英安玢岩主要分布在紫金山Au-Cu矿床内火山机构及其附近,与高品位Au-Cu矿体空间上联系密切,是矿田内火山-侵入岩浆过程的一个重要环节。采自矿区的两个英安玢岩样品LA-ICP-MS锆石U-Pb定年结果分别为(105.0±0.7)Ma(MSWD=0.83)和(105.0±2.2)Ma(MSWD=1.70),其形成时代与区内Mo-Cu矿化的萝卜岭和四方岩体形成时代相近。三个岩体形成时代及地球化学特征的相似性表明它们应为同源岩浆演化的产物,它们均具有较高的锆石Ce4+/Ce3+值,即岩浆体系具有较高的氧逸度,与区内斑岩成矿体系巨量金属堆积的地质事实相一致。英安玢岩的精确定年表明,紫金山Cu-Au矿与萝卜岭Mo-Cu矿及四方岩体有关的Mo矿床为同一斑岩成矿体系的产物。     

Zircon U–Pb,Molybdenite Re–Os and K‐feldspar 40Ar/39Ar Dating of the Bolong Porphyry Cu–Au Deposit,Tibet, China

The Bolong porphyry Cu–Au deposit is a newly discovered deposit in the central Tibetan Plateau, and is ranked as the second largest copper deposit discovered to date in the Bangong‐Nujiang metallogenic belt in China. Three granodiorite porphyry phases occur within the Bolong porphyry Cu–Au deposit. Phyllic alteration is widespread on the surface of the deposit, and potassic alteration occurs at depth, associated with granodiorite porphyries. The copper and gold mineralization is clearly related to the potassic and phyllic alteration. Multiple chronometers were applied to constrain the timing of magmatic–hydrothermal activity at the Bolong deposit. Zircon U–Pb geochronology reveals that the granodiorite porphyry phases were emplaced at ca. 120 Ma. Re–Os data of four molybdenite samples from quartz–molybednite veinlets yielded an isochron age of 119.4 ± 1.3 Ma. The plateau age of hydrothermal K‐feldspar from the potassic alteration zone, analyzed by ⁴⁰Ar/³⁹Ar dating, is 118.3 ± 0.6 Ma, with a similar reverse isochron age of 118.5 ± 0.7 Ma. Therefore, the magmatic–hydrothermal activity occurred at ca. 120–118 Ma, which is similar in age to the neighboring Duobuza porphyry copper deposit. The period of 120–118 Ma is therefore important for the development of porphyry Cu–Au mineralization in the central Tibetan Plateau, and these porphyry deposits were formed during the final stages of the northward subduction of the Neo‐Tethys Ocean.     

Ages and petrogenesis of the late Triassic andesitic rocks at the Luerma porphyry Cu deposit,western Gangdese,and implications for regional metallogeny

The Tibetan Plateau is one of the most significant Cu poly-metallic mineralization regions in the world and preserves important information related to subductional and collisional porphyry Cu mineralization. This study investigates a new occurrence of Cu mineralization-related andesitic porphyries in the western domain of the Gangdese magmatic belt and assesses its petrologic, zircon U-Pb geochronology, whole-rock chemistry, and Sr-Nd-Hf-Pb isotope data. Zircon U-Pb dating of three ore-related porphyries yields crystallization ages of 212–211 Ma. These ages are consistent with previous molybdenite Re-Os dating, indicating a late Triassic magmatic and Cu mineralization event in the western Gangdese magmatic belt. Nb, Ta, and Ti depletion, Th and LREE enrichment, and high La/Yb and Th/Yb ratios in addition to high U/Yb ratios from zircons suggest that the magma was generated in an active continental arc setting. The porphyries have radiogenic isotopic compositions with (⁸⁷Sr/⁸⁶Sr)_i 0.70431–0.70473, ε_Nd(t) +1.1 to +3.8, (²⁰⁷Pb^/204Pb)_i 15.601–15.622, and (²⁰⁸Pb/²⁰⁴Pb)_i 38.450–38.693, as well as high positive zircon ε_Hf(t) values from +6.2 to +10.6 (mean value 8.3), corresponding to model ages (T_DM) ranging from 509 Ma to 819 Ma (mean 646 Ma). This suggests that the andesitic magmatism was dominantly sourced from depleted mantle materials that were modified by subducted oceanic sediment-derived melts during the subduction of the Neo-Tethys Ocean. The mineralization-related porphyries contain amphibole and epidote, as well as high whole-rock Fe₂O₃/FeO and zircon Ce⁴⁺/Ce³⁺ ratios, suggesting hydrous and highly oxidized parent magmas. Considering the existing Cu mineralization and highly oxidized magma of the well-preserved Triassic andesitic igneous rocks in the western Gangdese belt, the subduction-related continental arc magma system is favorable for subduction-related porphyry Cu deposits. The existence of Luerma porphyry mineralization demonstrates that there are at least five generations of porphyry Cu-(Mo-Au) mineralization in the Gangdese magmatic belt, which advances the timeframe of porphyry mineralization to the late Triassic.     

Geochronological Constraints on the Haftcheshmeh Porphyry Cu-Mo-Au Ore Deposit, Central Qaradagh Batholith, Arasbaran Metallogenic Belt, Northwest Iran

The Haftcheshmeh porphyry Cu-Mo-Au deposit in the Arasbaran metallogenic belt(AMB) of NW Iran contains more than 185 Mt of ore, with a grade ranging from 0.3% to 0.4%. It is hosted within a porphyritic diorite to granodiorite intruded into an older gabbro-diorite intrusion. 40 Ar/39 Ar analyses of primary magmatic hornblende from the granodiorite porphyry and gabbro-diorite show plateau ages of 26.41 ± 0.59 Ma, with an inverse isochron age of 25.9 ± 1.0 Ma and a plateau age of 27.47 ± 0.17 Ma, with an inverse isochron age of 27.48 ± 0.35 Ma for these two rock types, respectively. Comparing these new age data with those from the nearby Sungun(20.69 ± 0.35 Ma) and Kighal porphyry deposits defines a northwest-southeast Cu-Mo-Au mineralization zone extending for 20 km over the time span of ~27 to 20 Ma. Geochemically, Haftcheshmeh rocks are calc-alkaline with high potassium affinities with tectonic setting in relation to volcanic arc setting. Large ion lithophile elements(LILE) such as Th, U and K show enrichment on a primitive mantle normalized diagram(specially Pb), and are depleted in high field strength elements(HFSE) such as Ti and Nb, pointing to a mantle magma source contamination with crustal materials by subducted oceanic crust.     

The Chalukou deposit in the North Great Xing’an Range of China: A protracted porphyry Mo ore-forming system in a long-lived magmatic evolution cycle

The Chalukou deposit is located in the North Great Xing’an Range of the Xing’an-Mongolia Orogen bordering and to the northeast of the North China Craton. The deposit is a high-F-type porphyry Mo deposit hosted by the Chalukou composite igneous body containing small intrusive bodies genetically related to Mo mineralization. The composite igneous body includes pre-mineralization dolerite, monzogranite and syenogranite, syn-mineralization rhyolitic porphyry, granitic porphyry and fine-grained monzogranite, and post-mineralization rhyolitic porphyry, quartz porphyry, dioritic porphyry and andesitic porphyry. Detailed laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb zircon dating of the igneous components of the composite igneous body was carried out to determine the temporal framework for magmatism in the Chalukou region. The new LA-ICP-MS U-Pb ages constraint documented here, together with the published ages, indicate that there was a protracted porphyry Mo ore-forming event of approximately 7 million years between ca. 152 when the ore related rhyolitic porphyry was emplaced and ca.145 Ma when molybdenite ceased being deposited. The dating reveals that the mineralization is a part of relatively long-lived magmatic cycle involving the emplacement of small doleritic stocks at ca. 165 Ma that progressively evolved into extensive granitic intrusions at ca. 164 Ma, and then diminished with the emplacement of mineralization-related porphyries to ca. 152 Ma. The emplacement of barren Early Cretaceous magmatism, represented by volcanic units in the ca. 136 Ma Guanghua Formation and porphyries, followed the mineralized magmatism.The syn-mineralization porphyry units associated with Mo contain zircons assaying ∼15 times higher in U and Th than the pre-mineralization magmatic phases. This indicates that there was a significant enrichment of Mo, U and Th in the magma, and directly associated with ore fluid exsolution. The return to their normal levels in the three elements in the post-mineralization magmatic phases indicates that they were exhausted from the magma chamber in the later phases. A genetic model is proposed for the enormous introduction of ore metals and enrichment at the Chalukou deposit. The protracted and multiphase igneous activity during the long-lived magmatism reflects a multistage enrichment of metal, and may play a crucial role in the formation of a volatile-enriched, fertile and large-volume magma chamber beneath the Chalukou deposit. Such a chamber is envisaged to be required for the formation of porphyry Mo deposits in general.     

金沙江-哀牢山断裂带几个富碱斑岩体的锆石U-Pb定年及地质意义

运用LA-ICP-MS锆石U-Pb同位素定年方法测定了金沙江-哀牢山断裂带内4个富碱斑岩的年龄.结果表明:剑川地区角闪正长斑岩形成时间为(37.6±2.2)Ma,姚安地区黑云母二长斑岩具有2组锆石U-Pb年龄数据,较年轻的一组为(36.86±0.63)Ma,较老的一组为(40.41±0.24)Ma,姚安黑云母角闪正长斑...     

Geochemistry and petrogenesis of Triassic mineralized porphyries in the Geza of the Sanjiang orogenic belt,southwestern China

The Geza Andean-type arc is located in the southwestern Sanjiang tectonic belt (i.e. Jinsha, Lancang, and Nujiang River) of SW China, which is a product of the subduction of the Garzê–Litang oceanic crust beneath Zhongdian landmasses in the Late Triassic (235–204 Ma). The Geza Andean-type arc is an important belt of Cu-rich polymetallic mineralization that was recently discovered in China. Prolonged regional tectono-magmatic activity and several episodes of rich mineralization throughout the tectonic evolution of the Andean-type arc produced the super-large Pulang porphyry Cu deposits, the large Xuejiping porphyry Cu deposits, and the large Hongshan skarn-porphyry Cu polymetallic deposits. Here we report new LA-ICP-MS zircon U–Pb age of Songnuo and Qiansui intrusive rocks, and whole-rock major and trace element compositions of the Late Triassic mineralized porphyries from Geza in this region. Zircon U–Pb dating of the Qiansui quartz diorite porphyrite revealed a crystallization age of 220.3 ± 0.66 Ma, for the Songnuo quartz monzonite porphyry, a crystallization age of 204.7 ± 0.72 Ma. The Geza Andean-type arc granitic belt can be divided into three porphyry subzones based on the stage of Andean-type arc orogenic development and the distribution, composition, and geochemical characteristics of the intrusive rocks. Lithogeochemical characteristics show that the porphyry and Andean-type arc granite are of the same rock series (high-K calc-alkaline) and genetic type (I-type granite). The trace element geochemistry of these rocks is similar to that of Andean-type arc granite, which is enriched in Ba, Rb, La, Hf, chalcophile elements (Cu, Pb), and siderophile elements (Mo, Ni), and depleted in Nb, Ta, P, and Ti. In the Geza Andean-type arc, similarities in the major element, REE, and trace element compositions between porphyry and local acidic volcanic rocks suggest that they have the same or similar magmatic source rocks. The petrological characteristics of granite in the Geza Andean-type arc are similar to those of adakitic rocks, and the formation of porphyry and porphyry-related deposits resulted from magmatic hydrothermal fluids that originated in the upper mantle and lower crust. The porphyry Cu mineralization was probably produced from the accumulation and migration of ore-forming hydrothermal fluids and the resultant alteration of host rocks.     

阿尔泰山南缘中—酸性斑岩的地球化学特征及其岩石成因探讨

阿尔泰山南缘中—酸性斑岩侵入于中泥盆统北塔山组火山岩地层中,斑岩体规模较小,主要岩石类型为闪长斑岩、石英闪长斑岩、花岗闪长斑岩、石英二长斑岩等。对哈腊苏、卡拉先格尔、喀腊萨依、托斯巴斯陶和乔夏哈拉等5个与铜矿有关矿区的斑岩研究表明,其地球化学特征既有相似性,又有不同的特点,其中SiO2含量为534%~662%,A/CNK为098~127(大多数小于1),稀土元素表现为轻稀土相对富集、不具Eu异常的特点。微量元素表现为明显的Nb和Ta的负异常。但是Harker图解以及稀土元素配分曲线表明,不同地区的斑岩不存在演化关系。斑岩的Sr和Nd同位素组成基本上与与其共生的玄武岩相同,因此根据实验岩石学以及稀土模拟结果推测,它们可能是岛弧阶段底侵的基性岩石部分熔融形成的,源区相当于下地壳无水的角闪岩相,但含有少量的石榴子石,其中石榴子石和角闪石比例的差别可能是导致不同地区斑岩地球化学特征差别的主要原因。     

新疆青河玉勒肯哈腊苏铜矿区酸性岩锆石U-Pb法定年及其地质意义

新疆青河县哈腊苏地处南蒙古铜矿带的西延部分,是铜矿勘查与研究的重点和热点地区.文章以近年发现的玉勒肯哈腊苏铜矿床为主要研究对象,对矿区内铜矿化的斑状花岗岩和石英二长斑岩进行了锆石U-Pb法精确定年.研究表明,这2个主要矿化岩体先后形成于中泥盆世和早二叠世,两期岩浆活动形成了重要的斑岩型铜矿化.玉勒肯哈腊苏地区主期斑岩型矿化发生在中泥盆世,早二叠世有斑岩型矿化复合,中晚三叠纪有明显的构造-岩浆-热液引起的矿化-蚀变叠加,复合叠加铜矿化过程有确切的年代学纪录.该研究为认识铜矿成因和明确勘查方向提供了新的事实依据.     

青海省纳日贡玛斑岩钼铜矿床成矿花岗斑岩锆石LA-ICP-MSU-Pb定年及地质意义

对青海省纳日贡玛斑岩钼铜矿床开展了锆石LA-ICP-MS U-Pb同位素定年研究,结果表明,纳日贡玛矿区2个黑云母花岗斑岩样品的锆石206Pb/238U同位素加权平均年龄分别为(43.4±0.4)Ma和(42.9±0.3)Ma,锆石形态、结晶振荡环带结构及元素含量均显示出岩浆成因特点;因此,锆石U-Pb年龄可代表斑岩的岩浆结晶年龄,纳日贡玛含矿斑岩岩浆的侵位年代可精确地限定于新生代喜马拉雅期,相当于中始新世。1件辉钼矿样品Re-Os同位素模式年龄为(40.8±0.4)Ma,结合前人的辉钼矿测试结果,认为在纳日贡玛岩浆活动约2.6 Ma后,岩浆热液成矿流体开始产生成矿作用。三江走滑断裂构造系统控制斑岩矿床的分布,青海三江北段斑岩钼铜矿具有很大的找矿潜力。     

西藏玉龙铜矿带包买矿床含矿斑岩锆石U-Pb年代学

包买斑岩型铜钼矿床是西藏玉龙铜矿带北段重要组成部分,具有典型的斑岩型矿化、蚀变特征.最新勘查进展揭示其铜、钼资源量均已达中型矿床规模,但理论研究工作仍十分薄弱.以矿区基本地质特征为基础,运用LA-ICP-MS锆石U-Pb年代学方法,精确获得包买矿区与成矿有关的黑云母花岗岩和黑云母二长花岗岩侵位时代分别为:41.3±0.2 Ma和40.8±0.2 Ma,与玉龙、扎那尕等矿床一致,是始新世印度大陆与欧亚大陆碰撞造山过程的产物.综合区域已有年代学证据,玉龙铜矿带与成矿有关的斑岩体主要集中侵位于37~42 Ma,可能不存在明显的早（51 Ma）、中（41 Ma）、晚（33 Ma）三期,且从北西向南东,成岩成矿时代也没有明显降低变新的趋势.      

Geochronology of magmatism and mineralization of the Daheishan giant porphyry molybdenum deposit,Jilin Province,Northeast China: constraints on ore genesis and implications for geodynamic setting

Daheishan giant porphyry Mo deposit is located in the Lesser Xing’an–Zhangguangcai Ranges, Jilin Province, NE China. Mineralization is closely related to the Daheishan intrusive complex, which can be divided into Changganglin biotite granodiorite, Qiancuoluo biotite granodiorite, and Qiancuoluo granodioritic porphyry. Four stages of mineralization are distinguished, based on the cross-cutting relationships of mineralized veins. LA-ICPMS zircon U-Pb analysis yields ²⁰⁶Pb/²³⁸U ages of 177.9 ± 2.3 Ma for the Changganglin biotite granodiorite, 169.9 ± 2.3 Ma for the Qiancuoluo biotite granodiorite, and 166.6 ± 4.0 Ma for the Qiancuoluo granodioritic porphyry. Hydrothermal fluids responsible for mineralization evolved from different magmas. Six molybdenite samples yield Re-Os model ages of ~167 Ma. Muscovite from the last mineralization stage gives a ⁴⁰Ar/³⁹Ar plateau age of 163.6 ± 0.9 Ma. Geochronology data indicate that the entire magmatic system lasted for about 10 million years, and the total duration of hydrothermal activity was less than 4 million years. The ε_Hf(t) values of zircons obtained from the Changganglin biotite granodiorite, Qiancuoluo biotite granodiorite, and Qiancuoluo granodioritic porphyry range from 4.5 to 9.1, 5.7 to 10.9, and 4.4 to 7.1, respectively, indicating that they were mainly derived from the depleted mantle, although contaminated by crustal materials to a greater or lesser extent. The formation of the Daheishan porphyry Mo deposit was temporally and spatially related to the amalgamation of Jiamusi Massif and Songliao terrane in the Palaeo-Pacific Ocean regime. Regional Hf isotopic compositions of zircon suggest an episode of crustal growth in the Phanerozoic in the Lesser Xing’an–Zhangguangcai Ranges. Regional Mo mineralization ages suggest a peak of porphyry Mo mineralization in the Jurassic in the Lesser Xing’an-Zhangguangcai Ranges.     

巴基斯坦贾盖火山岩浆岩带斑岩型铜-金矿床地质特征、成矿作用及找矿潜力

贾盖火山岩浆岩带是巴基斯坦境内西部第二大岩浆弧,属于特提斯成矿域的重要组成部分之一。晚渐新世—中新世,随着新特提斯洋的闭合,阿拉伯板块、印度板块与欧亚板块不断碰撞。在持续的挤压条件下,巴基斯坦西部发育了一系列逆冲褶皱系统,并且先后经历了中—晚始新世(43~37 Ma)、早中新世(24~22 Ma和18~16 Ma)、中中新世(13~10 Ma)和晚中新世—早上新世(6~4 Ma)4次大规模的岩浆作用,形成了贾盖火山岩浆岩带,赋存有48个斑岩型铜金矿床(点)、远景区。根据区域地质及矿化情况,可将贾盖火山岩浆岩带内的斑岩型铜-金矿床分为东、西两部分。前者主要分布在贾盖侵入体的边缘或与围岩接触带中,矿体产于晚白垩世辛贾拉尼群碎屑岩和始新世贾盖侵入体中;后者则分布在索尔科侵入体的岩株中,矿体产于古新世和更年轻的碎屑岩和火山岩中。矿体主要与磁铁矿系列的石英闪长斑岩和花岗闪长斑岩相关,具有钙碱性系列的特征,围岩热液蚀变分带明显,自岩体中心向外依次为钾硅酸化(钾化)、泥化、石英绢云母化、青磐岩化。境内外斑岩铜矿产出特征显示,索尔科侵入岩可能符合"小岩体成大矿"的现实情况,贾盖侵入岩的大型复合岩基中也可能存在斑岩铜矿床,具有很好的找矿潜力。最新勘查资料显示,贾盖火山岩浆岩带已发现的48个矿床(点)、远景区可能都具有很好的找矿前景和巨大的资源潜力,如萨因达克、雷克迪克、塔拉鲁格、科·伊·达利尔等矿床(点)、远景区,以及Western War Chah斑岩体,尤其是贾盖火山岩浆岩带西部和Koh Dalil(Rackodiq)矿点。     

云南马厂箐斑岩型铜—钼—金矿床40Ar 39Ar年龄及地质意义

马厂箐矿集区铜、钼、金矿化之间的关系对于认识该矿床的成矿作用过程及地质勘查具有重要意义。利用40Ar-39Ar同位素定年方法对乱硐山矿段夕卡岩型铜钼金矿化和人头箐矿段蚀变岩型金矿石中热液白云母进行同位素定年,得到夕卡岩化矿石中白云母样品(B119)40Ar-39Ar坪年龄为35.25±0.36Ma,等时线年龄为35.0±1.8Ma,反等时线年龄为34.8±1.9Ma。蚀变岩型金矿化矿石中白云母样品(B118)40Ar-39Ar坪年龄为35.35±0.32Ma,等时线年龄为34.44±0.99Ma,反等时线年龄为34.4±1.2Ma。这与正长斑岩(35.6±0.3Ma)、花岗斑岩(35.0±0.2Ma)、斑岩型铜钼矿化成矿年龄(35.8±1.6Ma)和(33.9±1.1Ma)较为一致,显示马厂箐铜钼金矿床与正长(斑)岩+二长(斑)岩+花岗斑岩+斑状花岗岩岩性组合有关,铜钼金成矿属于同一个构造—岩浆—成矿系统的产物。     

中亚巴尔喀什成矿带钼-钨矿床的地质热年代学

巴尔喀什成矿带是世界著名的中亚成矿域斑岩型铜钼成矿带, 产出许多斑岩型铜钼矿床和一些石英脉-云英岩型钨钼矿床.对巴尔喀什成矿带西部的东科翁腊德、阿克沙套、扎涅特3个典型的石英脉-云英岩型钼钨矿床的成矿时代和剥露过程进行了地质热年代学研究.锆石SHRIMP U-Pb定年给出东科翁腊德、阿克沙套、扎涅特与成矿作用有关的花岗岩类岩浆作用的时代分别为293.6±2.7 Ma、306±1 Ma和304±4 Ma, 属海西晚期构造-岩浆活动的产物.花岗岩类40Ar/39Ar测年结果给出了与成矿有关岩体的冷却年龄, 其等时线年龄分别为292±3 Ma(阿克沙套黑云母)、288.8±3.6 Ma(阿克沙套钾长石)和278±5 Ma(东科翁腊德钾长石).磷灰石裂变径迹测年给出东科翁腊德、阿克沙套、扎涅特的年龄分别为92.1±5.7 Ma、92.2±5.0 Ma和80.3±4.9 Ma, 说明这3个矿床的剥露作用主要发生在晚白垩世.花岗岩类岩石U-Pb、40Ar/39Ar和裂变径迹热年代学研究, 揭示了巴尔喀什成矿带Mo-W矿床从深成岩浆侵入活动、成矿作用、区域冷却到剥露作用的全过程.