The role of lithology,catchment size and the alluvial zone on the hydrogeochemistry of two intermittent Mediterranean streams

Hydrology and solute concentrations of two intermittent Mediterranean streams draining two nested catchments were compared. The two catchments were mainly underlain by granitic rocks and different types of sericitic schists. Only the lowland catchment had an alluvial zone and a well‐developed riparian forest. The rainfall–runoff relationship and the correlation between daily flow concentrations showed that hydrological behaviour was similar at both sites during most of the year. However, reverse fluxes were detected during the wetting and drying up periods only in the stream with an alluvial zone. The intermittence in stream flow also had effects on absolute solute concentrations, temporal solute dynamics and streamwater stoichiometry. Streamwater chemistry was not affected by drainage area, except for cations produced mainly by bedrock dissolution (i.e. calcium and magnesium) that increased with increasing catchment size. Differences in the relationship among cations and anions were detected between the two streams, which could be attributed to biogeochemical processes occurring in the alluvial zone. The multivariate model used in this study showed that stoichiometry was more useful than absolute concentrations when analyzing the influence of different lithologies on streamwater chemistry. Such differences were amplified in autumn, likely due to a low hydrological connectivity between the two nested catchments. Copyright © 2007 John Wiley & Sons, Ltd.     

The seasonal variation of streamwater chemistry in three forested Mediterranean catchments

Streamwater chemistry is described for three streams draining undisturbed, evergreen broad-leaved forested catchments on phyllites in NE Spain: two streams with no or negligible flow in summer are located in the Prades massif, and one perennial stream is in the wetter Montseny mountains. Weekly data for a study period of 2–4 years are provided to (1) describe the seasonal variations in streamwater chemistry, (2) analyse the relationship between stream discharge and solute concentrations using a two-component mixing model and (3) search for patterns of temporal variation in stream solute concentrations after discounting the effects of discharge. At Prades, concentrations of all analysed ions, except NO⁻₃, showed marked seasonal variations in stream water, whereas at Montseny only ions related to mineral weathering (HCO⁻₃, Na⁺, Ca²⁺ and Mg²⁺) showed strong seasonality. Ion concentrations were more closely dependent on instantaneous discharge at Montseny than at Prades. The residuals of the relationship between solute concentrations and discharge retained a strong seasonality at Prades, but not at Montseny. These differences are related to the major hydrochemical processes that determine the streamwater chemistry at each site. The same processes are probably operative in the three catchments, but are of varying relative importance. At Montseny, the mixing of waters of different chemical composition seems to be the major process controlling streamwater chemistry, although the soilwater end-member composition predicted by the mixing model applied did not match the measured soilwater chemistry. In the drier Prades catchments, the two major hydrochemical processes determining the seasonal variation of streamwater chemistry are (1) the restart of flow after the summer drought, which flushes out the solutes accumulated during the dry period, and (2) the seasonal changes in groundwater chemistry that result from the interplay of water residence time, temperature and CO₂ partial pressure. In Mediterranean catchments with relatively high precipitation, such as Montseny, the seasonal variation in the streamwater chemistry is largely determined by the same processes as at humid-temperate sites, whereas in drier Mediterranean catchments, such as Prades, the major hydrochemical processes are clearly distinct.     

Streamwater quality as affected by wild fires in natural and manmade vegetation in Malaysian Borneo

In 1998 a wild fire struck a paired catchment research area under long‐term monitoring of hydrological and nutrient budgets. Streamwater quality as concentrations of dissolved and suspended particulate matter was monitored during 1·5–2·5 years after the fire in streams from seven different catchments. As the catchments, due to earlier experimental treatments, had different vegetations, varying effects related to different fire intensities were observed. The highest, mean stormflow, suspended sediment concentrations resulted from intensive fire in secondary vegetation that had experienced severe soil disturbance in previous treatments (crawler tractor timber extraction 10 years earlier). Stormflow concentrations were typically still about 400 mg l^?1 in 1999 (10–21 months after the fire), which was about the maximum recorded concentration in streams during initial soil disturbance in 1988. Forest fire in natural forest resulted in less than half as high stormflow concentrations. For dissolved elements in streamwater there was a positive relation between fuel load (and fire intensity) and concentration and longevity of effects. Stream baseflow dissolved nutrient concentrations were high in the months following the fire. Mean baseflow K concentrations were 8–15 mg l^?1 in streams draining catchments with intensive fire in secondary vegetation with large amounts of fuel. After controlled fire for forest plantation establishment in 1988 corresponding concentrations were 3–5 mg l^?1, and after forest fire in natural forest in this study about 2 mg l^?1. This study shows differences in response from controlled fire for land management, forest fire in natural forests and wild fires in manmade vegetations. These differences relate to resistance and resilience to fire for the involved ecosystems. There is reason to believe that wild fires and repeated wild fires during or after droughts, in successions caused by human influence, may lead to larger losses of ecosystem nutrient capital from sites compared with forest fires in natural forests. As fire in the humid tropics becomes more common, in an increasingly spatially fragmented landscape, it will be important to be aware of these differences. Copyright © 2004 John Wiley & Sons, Ltd.     

Seasonal,hydrological, and land management factors controlling dissolved organic carbon concentrations in the loch fleet catchments,Southwest Scotland

Dissolved organic carbon (DOC) was measured at hourly or two-hourly intervals during more than 30 events in one forested and two moorland subcatchments of the Loch Fleet catchment in southwest Scotland. The dominantly peaty soils in the catchments resulted in small discharge-related DOC variations within individual events, with a maximum range of about 2 mg 1^?1. Seasonal variations were larger with an amplitude of 8-9 mg 1^?1 and maximum concentrations in the summer months. The forested stream had the highest mean DOC, twice as large as the comparable moorland stream in the preliming phase. Applications of lime to the catchments increased stream DOC concentrations, with the largest increases in the moorland catchments.     

A comparison of stream water temperature regimes from open and afforested moorland,Yorkshire Dales,northern England

Despite the known importance of water temperature for river ecosystems, the thermal regime of streams and rivers can be heavily modified by afforestation. Although the nature of the heat budget affecting streams in forested catchments shows high variability in space and time, most of the studies of stream temperature response to afforestation have lacked replication among streams. This study examined the impacts of coniferous forest plantations on stream water temperature at six sites (three forested and three open moorland) in the Yorkshire Dales, northern England. Our aim was to test the hypothesis that afforestation would alter the thermal regime of streams, leading to reduced year‐round thermal variability, and cooler summer/warmer winter water temperatures, relative to streams flowing across open moorland. Data collected from April 2007 to March 2009 showed similar thermal dynamics among all six streams over the study period, although variability in forested streams was markedly lower as expected. Mean and maximum daily water temperatures were significantly higher in open moorland streams for much of the year but while some forested streams were warmer than individual moorland streams during winter months (November to February), there was considerable overlap in water temperature between moorland and forest streams. Most stream temperature records showed evidence of low/no winter flow and freezing. These results contrast with many previous studies that have reported warmer temperatures in forested versus open moorland streams during winter, a finding that most likely reflects site‐specific hydrological, geomorphological and climatological influences on water temperature in addition to afforestation. This study demonstrates the need for replication of hydrological monitoring when examining the effects of basin‐scale management practices and provides further evidence for changes in stream thermal regime following afforestation, a practice that is likely to increase in future due to growing demands for increased forest cover in the UK uplands. Copyright © 2010 John Wiley & Sons, Ltd.     

Modelling long term stream acidification trends in upland wales at plynlimon

Historical reconstructions and predictions of streamwater acidification are presented for moorland and afforested catchments in the Welsh Uplands at Plynlimon. MAGIC (Model of Acidification of Groundwater In Catchments) is validated by application to an afforested catchment. MAGIC is used to illustrate that atmospheric deposition is primarily responsible for stream acidification but that conifer afforestation can enhance stream acidity. The historical trends determined by the model illustrate that long-term acidification has been present since the turn of the century and will continue unless either deposition levels are reduced significantly or liming is undertaken on a major scale.     

A comparison of stream bank erosion processes on forested and moorland streams in the Balquhidder Catchments,central Scotland

Stream bank erosion rates measured over a two-year period on a moorland and a forested stream in the Institute of Hydrology's Balquhidder Paired Catchments in central Scotland were compared. Bank erosion rates are generally higher on the mainstream of the moorland catchment and highest in wintger on both streams. Bank erosion is correlated with the incidence of frost: minimum temperatures measured on stream banks of the forested stream were an average of 3·7°C higher than on stream banks both outside the forest and on the moorland stream. This makes the incidence of frost on forested stream banks half as frequent. Volumes of material eroded from the mainstreams were combined with bulk density measurements and it is estimated that erosion of the mainstream banks is contributing 1·5 and 7·3 per cent of the sediment yield of the forested and moorland catchments, respectively. Analysis of the vertical distribution of erosion on the banks of both streams suggests an undercutting mechanism which is more pronounced in the moorland stream. The influence of trees on bank erosion and possible implications for the management of forest streams are discussed. © 1997 by John Wiley & Sons, Ltd.     

The role of wetland coverage within the near‐stream zone in predicting of seasonal stream export chemistry from forested headwater catchments

Stream chemistry is often used to infer catchment‐scale biogeochemical processes. However, biogeochemical cycling in the near‐stream zone or hydrologically connected areas may exert a stronger influence on stream chemistry compared with cycling processes occurring in more distal parts of the catchment, particularly in dry seasons and in dry years. In this study, we tested the hypotheses that near‐stream wetland proportion is a better predictor of seasonal (winter, spring, summer, and fall) stream chemistry compared with whole‐catchment averages and that these relationships are stronger in dryer periods with lower hydrologic connectivity. We evaluated relationships between catchment wetland proportion and 16‐year average seasonal flow‐weighted concentrations of both biogeochemically active nutrients, dissolved organic carbon (DOC), nitrate (NO₃‐N), total phosphorus (TP), as well as weathering products, calcium (Ca), magnesium (Mg), at ten headwater (<200 ha) forested catchments in south‐central Ontario, Canada. Wetland proportion across the entire catchment was the best predictor of DOC and TP in all seasons and years, whereas predictions of NO₃‐N concentrations improved when only the proportion of wetland within the near‐stream zone was considered. This was particularly the case during dry years and dry seasons such as summer. In contrast, Ca and Mg showed no relationship with catchment wetland proportion at any scale or in any season. In forested headwater catchments, variable hydrologic connectivity of source areas to streams alters the role of the near‐stream zone environment, particularly during dry periods. The results also suggest that extent of riparian zone control may vary under changing patterns of hydrological connectivity. Predictions of biogeochemically active nutrients, particularly NO₃‐N, can be improved by including near‐stream zone catchment morphology in landscape models.     

Characterizing and classifying urban watersheds with compositional and structural attributes

Current land-use classifications used to assess urbanization effects on stream water quality date back to the 1980s when limited information was available to characterize watershed attributes that mediate non-point source pollution. With high resolution remote sensing and widely used GIS tools, there has been a vast increase in the availability and precision of geospatial data of built environments. In this study, we leverage geospatial data to expand the characterization of developed landscapes and create a typology that allows us to better understand the impact of complex developed landscapes across the rural to urban gradient. We assess the ability of the developed landscape typology to reveal patterns in stream water chemistry previously undetected by traditional land-cover based classification. We examine the distribution of land-cover, infrastructure, topography and geology across 3876 National Hydrography Dataset Plus catchments in the Piedmont region of North Carolina, USA. From this dataset, we generate metrics to evaluate the abundance, density and position of landscape features relative to streams, catchment outlets and topographic wetness metrics. While impervious surfaces are a key distinguishing feature of the urban landscape, sanitary infrastructure, population density and geology are better predictors of baseflow stream water chemistry. Unsupervised clustering was used to generate a distinct developed landscape typology based on the expanded, high-resolution landscape feature information. Using stream chemistry data from 37 developed headwater catchments, we compared the baseflow water chemistry grouped by traditional land-cover based classes of urbanization (rural, low, medium and high density) to our composition and structure-based classification (a nine-class typology). The typology based on 22 metrics of developed landscape composition and structure explained over 50% of the variation in NO₃⁻-N, TDN, DOC, Cl⁻, and Br⁻ concentration, while the ISC-based classification only significantly explained 23% of the variation in TDN. These results demonstrate the importance of infrastructure, population and geology in defining developed landscapes and improving discrete classes for water management.     

Converting tropical rainforest to forest plantation in sabah,malaysia. Part II. Effects on nutrient dynamics and net losses in streamwater

Streamwater chemistry was monitored for five years in six streams in a paired catchment experiment in Mendolong, Sabah, Malaysia, comparing the effects of different ways to establish forest plantations with Acacia mangium. At the start of the monitoring in 1985 three catchments were covered with selectively logged rain forest (W4-W6) and three with secondary vegetation after forest fire (W1-W3). The treatments were: (1) clearing of secondary vegetation, burning and planting (W1 and W2); (2) clear-felling, crawler tractor extraction, burning and planting (W5); and (3) clear-felling, manual extraction, no burning and planting (W4). W3 and W6, with no treatment, were monitored as control catchments. Reference monitoring at all streams was for two years and was followed by treatments which lasted for nine months before the full establishment of a new vegetation cover. This paper covers monitoring for a further 2.5 years. The soil types of the catchments were Orthic Acrisol in W3, Gleyic Podsol in W6 and a mix of both soil types in the other catchments. The effect of treatments on streamwater chemistry was clear at both base- and stormflows. Concentrations of major plant nutrients (N, P and K.) became positively correlated to streamflow during treatments. The response of leaching from slash at clear-felling was fast and larger from the clear-felling residues (W4 and W5) than the cleared secondary vegetation (W1 and W2). The intense response to burning was more marked. The stormflow period mean nutrient concentrations were approximately 10-fold for N and K and 10-100 fold for P after burning compared with baseflow mean concentrations over the same period. Significant differences in baseflow concentrations in treated streams generally lasted one year for most elements, but elevated concentrations were still detectable after three years. The first large pulse of leaching was related to mineralization after tree-felling and particularly burning. The longer lasting elevated concentrations in baseflow were associated with the loss of weathering products. The amounts of nutrients lost, calculated by regression analysis as the effect of treatment compared with control, were found to be higher with the degree of vegetation killed and with increased soil disturbance. Consequently, normal forestry practices, with crawler tractor extraction and burning before planting, created the largest leaching losses. The total calculated effect of losses in total N, P and K were (i) W1 + W2 0.5, 1.8, 83.9; (ii) W4 0.8, 0.8, 105.6; and (iii) W5 1.3, 1.3, 189.4 kg ha^?1 for the period of 33 months during and after treatment. With normal forestry practice using crawler tractors and with burning before planting (W5), the treatment-induced loss of K was equivalent to 86% of the content of easily decomposed parts of the biomass (leaves, twigs, fine roots and ground vegetation) of the old forest, or larger than K removed by harvest. Exhaustion effects of lowered leaching after repeated burning (forest fire and pre-planting fire) was observed for several elements, indicating possible nutrient deficiencies.     

Hydrology and related changes after harvesting native forest catchments and establishing pinus radiata plantations. Part 3. Stream temperatures

Eight small steep south-west facing catchments (1-63-8-26 ha) have been monitored in Westland, New Zealand since 1974. Two catchments were retained in native mixed evergreen forest and the rest were subjected to various harvesting and land preparation techniques before being planted with Pinus radiata between 1977 and 1980. Stream temperatures were measured in all catchments for 11 years, including up to four years before harvesting. The streamwater temperature regime under the native forest cover has a seasonal cycle, with an annual mean of about 9°C and mean daily temperatures ranging between a winter minimum of about 5.8°C and a summer maximum of 12.S°C. After harvesting, the winter minimum stream temperatures in all trials were unchanged as topography exerts the major control over incoming solar radiation. The largest rises in mean summer stream temperatures, up to 5.5°C, were in the catchments that had been clearcut and burnt before planting. The maximum stream temperature recorded was 22.8°C in a clearcut catchment with no riparian reserve. Summer stream temperatures in this catchment were up to 11°C higher than in an adjacent control catchment. Summer stream temperature rises in catchments with riparian reserves were less than 1.5°C. Seven years after harvesting, stream temperatures were dropping towards pre-treatments levels in only two of the six treated catchments as revegetation of the riparian areas occurred and the plantations became established. As these small headwater streams discharge into streams with flows one or two orders of magnitude larger, the increases in summer stream temperatures will be rapidly dissipated. However, the cumulative impact of harvesting many small headwater catchments that discharge into a larger stream could have a noticeable effect on stream temperature if intact riparian reserves were not retained in both headwater and main streams.     

Concentration versus streamflow trends of major ions and tritium in headwater streams as indicators of changing water stores

Documenting the processes that control the variations in stream geochemistry at different streamflows is important for being able to use chemical tracers to understand catchment functioning. The concentrations of most solutes, including reactive cations (e.g., Na, Ca, K, and Mg) and anions that are primarily derived from precipitation (Cl and Br), in five headwater streams from southeast Australia vary little with streamflow and are close to being chemostatic. By contrast, NO₃ and SO₄ concentrations are higher at high streamflows. There is also a systematic increase of ³H activities from as low as 1.1 to as high as 2.6 TU with increasing streamflow. The changes in geochemistry cannot be explained solely by increased mineral dissolution at high streamflows or enhanced baseflow driven by hydraulic loading. They are best explained by an increased baseflow input augmented by water mobilized from shallower stores as the catchments wet up. The mean transit times of the water sustaining streamflow varies from 35 to 70 years at low streamflows to <7 years at high streamflows. The use of a range of geochemical tracers, including radioactive isotopes, allows the different possible causes of chemostatic behaviour to be assessed and improves our understanding of catchment functioning.     

Hydrological flow paths controlling stream chemistry in Japanese forested watersheds

Water sources and flow paths contributing to stream chemistry were evaluated in four Japanese forested watersheds with steep topography (slopes ≥30°). Stream chemistry during periods without rainfall and during events with less than 100 mm of precipitation was similar to seepage water chemistry, but markedly different from that of soil water which had higher concentrations of NO⁻₃ and Ca²⁺ and lower concentrations of Na⁺ and HCO⁻₃. Also, stream Cl⁻ concentrations in a Cl⁻‐treated watershed did not increase either during events with less than 100 mm of total rainfall or at baseflow conditions, even three years after the Cl⁻ treatment. These results suggest that groundwater within bedrock fissures of Paleozoic strata had a long residence time and was a major contributor to steam water under baseflow conditions and even during small precipitation events (≤100 mm). In contrast, for large precipitation events (≥100 mm), stream chemistry became more similar to soil water chemistry, especially within the steepest watershed. Also, for large precipitation events, stream Cl⁻ concentrations in the Cl⁻‐treated watershed increased markedly. These results suggest that soil water was a major contributor to stream waters only during these large events. Copyright © 1999 John Wiley & Sons, Ltd.     

Spatial and temporal variations in surface water nitrate concentrations in a mixed land use catchment under humid temperate climatic conditions

Streamwater nitrate (NO^―₃) concentrations along the main stream and at the outlet of several subcatchments within the 114\3 km² Zwalm watershed in Flanders, Belgium, have been monitored regularly since 1991. Land use within the Zwalm catchment is predominantly agricultural, with forested regions in the south and urban concentrations in the north‐east of the catchment. Streamwater NO^―₃ concentrations increased with increases in stream discharge rates, but in general, discharge rate explained only about 30% of the variation in NO^―₃ concentrations. The low R² values were attributed to the observed anticlockwise hysteresis in the NO^―₃ concentration – discharge relationship and to differences in NO^―₃ concentrations between both seasonal flow and various flow regimes, with winter flow explaining 51% of the variation in NO^―₃ concentrations, whereas summer flow explained only 28% of the variation. A hypothesis was formulated in which flow regime accounts for the seasonal variation in NO^―₃ export, postulating that the catchment seasonally alternates between two hydrological stages. The first stage occurs during wet winter periods, when the catchment drains as a single source area, whereas the second stage occurs during dry summer periods, when the groundwater store disconnects into separate subcatchments. This causes NO^―₃ concentration peaks to be more delayed during summer storm events compared with winter storm events. Regarding flow regimes, differences between high and low flow conditions and between increasing and stable/decreasing flow were not as pronounced a differences between seasons. In contrast to the estimation of NO^―₃ concentrations, discharge was a strong predictor (R²= 0\71) of the NO^―₃ flux within the tributaries of the Zwalm catchment. The NO^―₃ concentrations in the main stream increased with decreasing elevation, whereas the seasonal concentration patterns along the main channel were similar to those observed at the outlet. NO^―₃ concentrations varied considerably among catchments and showed a high variability over time, although in general, the variation in NO^―₃ concentration was higher between catchments than within catchments. The impact of land use is clearly reflected in the streamwater NO^―₃ concentrations, although NO^―₃ concentration patterns were also affected by topography and, to a lesser extent, by soil type. A gradual increase in NO^―₃ concentrations at the outlet of the Zwalm catchment could be observed throughout the 1991 – 1998 study period, providing evidence for the general trends of increase in Flanders, which are attributed to the intensification of agricultural activities. Copyright © 2000 John Wiley & Sons, Ltd.     

Dissolved organic carbon dynamics in two streams draining forested catchments at loch ard,Scotland

Dissolved organic carbon (DOC) was measured at four or eight hour intervals between mid-1989 and mid-1991 in two catchments in west central Scotland. The experimental catchment had been recently clear-felled and the control remained under forest. The amount of DOC varied during individual storm events following the stream hydro-graph. Maximum variations were found in the summer half-year and in the clear-felled catchment. There was also evidence of the exhaustion of DOC in the later events of a sequence. Differences between the catchments were related to catchment characteristics and to land-use change. The reduced magnitude of variation in DOC with discharge in the control stream was due to the influence of a wetland area through which the stream flowed. The mean DOC concentrations were similar in the two streams and annual exports were 15 g m^?2 from the control and 16g m^?2 from the felled catchment. The stream draining the clear-felled catchment had greater high flow DOC concentrations in the summer half-year, probably due to the effect of greater mean summer temperatures on DOC release and of the greater supply of organic debris in the stream channel.     

Environmental factors regulating stream nitrate concentrations at baseflow condition in a large region encompassing a climatic gradient

Though high rates of nitrate (NO₃⁻) leaching from forests are undesirable, the factors significantly regulating stream NO₃⁻ concentration is not clarified yet. In Japan, not only near metropolitan areas but also the Japan Sea-side area with heavy snowfall is well known for receiving more than 10 kg-N ha⁻¹ year⁻¹ of nitrogen (N) deposition. However, NO₃⁻ concentration in stream water is relatively low in the Japan Sea-side area compared with its concentration in other areas. We examined important environmental factors regulating stream NO₃⁻ concentrations at baseflow condition in a large region of Japan, the Kinki region (KIN) including a part of Japan Sea-side (JSK) using Random Forest regression. The amounts of N deposition and precipitation were common regulating factors for stream NO₃⁻ concentration at baseflow condition. Random forest showed the significant correlation between the factors related to ecosystem N retention and stream NO₃⁻ concentration at baseflow condition, and it suggests that large N deposited during the growing season was incorporated into the ecosystem in the entire KIN. Heavy rain and snow flush N and wash out N accumulated in the surface soil, causing small N accumulation in forests. Also, large precipitation dilute NO₃⁻ concentration in baseflows. These things lowered stream NO₃⁻ concentration at baseflow condition. Especially in JSK, most of N deposed with the heavy snow flushed out during the snowmelt period. We provided the first statistical confirmation using Random Forest regression that N accumulation and cycling in forest ecosystems were related to NO₃⁻ leaching from forests into streams.     

Effects of instream processes,discharge, and land cover on nitrogen export from southern Appalachian Mountain catchments

Catchments with minimal disturbance usually have low dissolved inorganic nitrogen (DIN) export, but disturbances and anthropogenic inputs result in elevated DIN concentration and export and eutrophication of downstream ecosystems. We studied streams in the southern Appalachian Mountains, USA, an area dominated by hardwood deciduous forest but with areas of valley agriculture and increasing residential development. We collected weekly grab samples and storm samples from nine small catchments and three river sites. Most discharge occurred at baseflow, with baseflow indices ranging from 69% to 95%. We identified three seasonal patterns of baseflow DIN concentration. Streams in mostly forested catchments had low DIN with bimodal peaks, and summer peaks were greater than winter peaks. Streams with more agriculture and development also had bimodal peaks; however, winter peaks were the highest. In streams draining catchments with more residential development, DIN concentration had a single peak, greatest in winter and lowest in summer. Three methods for estimating DIN export produced consistent results. Annual DIN export ranged from less than 200 g ha^?1 year^?1 for the less disturbed catchments to over 2,000 g ha^?1 year^?1 in the catchments with the least forest area. Land cover was a strong predictor of DIN concentration but less significant for predicting DIN export. The two forested reference catchments appeared supply limited, the most residential catchment appeared transport limited, and export for the other catchments was significantly related to discharge. In all streams, baseflow DIN export exceeded stormflow export. Morphological and climatological variation among watersheds created complexities unexplainable by land cover. Nevertheless, regression models developed using land cover data from the small catchments reasonably predicted concentration and export for receiving rivers. Our results illustrate the complexity of mechanisms involved in DIN export in a region with a mosaic of climate, geology, topography, soils, vegetation, and past and present land use.     

A three‐component end‐member analysis of streamwater hydrochemistry in a small Japanese forested headwater catchment

Intensive water sampling in conjunction with hydrological observations was conducted during three different rainstorms in order to understand the effects of rainfall events on the temporal variation of streamwater chemistry in a small headwater forest catchment. Concentrations of Na⁺ and SO₄^2? decreased as the discharge rate increased. Hydrograph separation of the components was made using the three‐component model based on the end‐members mixing analysis (EMMA). The three end‐members were:

• 1 the groundwater in the saturated zone that prescribes the chemistry of the baseflow;
• 2 the throughfall that dilutes the streamwater;
• 3 the groundwater in the transient saturated zone prescribed, which was dependent on the groundwater level.

When the groundwater level was lower, only the two components, groundwater in the saturated zone and throughfall, affected the streamwater chemistry. When the groundwater level rose and the saturated zone spread, the groundwater in the transient saturated zone became the third component. When the groundwater in the transient saturated zone contributed to the discharge, this component became the dominant source and the streamwater chemistry was affected by the groundwater chemistry in the transient saturated zone. When this component was discharged as the saturation overland flow, the streamwater chemistry was greatly affected by this component. Copyright © 2001 John Wiley & Sons, Ltd.     

Effect of bedrock flow on catchment rainfall‐runoff characteristics and the water balance in forested catchments in Tanzawa Mountains,Japan

In this paper, we examined the role of bedrock groundwater discharge and recharge on the water balance and runoff characteristics in forested headwater catchments. Using rigorous observations of catchment precipitation, discharge and streamwater chemistry, we quantified net bedrock flow rates and contributions to streamwater runoff and the water balance in three forested catchments (second‐order to third‐order catchments) underlain by uniform bedrock in Japan. We found that annual rainfall in 2010 was 3130 mm. In the same period, annual discharge in the three catchments varied from 1800 to 3900 mm/year. Annual net bedrock flow rates estimated by the chloride mass balance method at each catchment ranged from ?1600 to 700 mm/year. The net bedrock flow rates were substantially different in the second‐order and third‐order catchments. During baseflow, discharge from the three catchments was significantly different; conversely, peak flows during large storm events and direct runoff ratios were not significantly different. These results suggest that differences in baseflow discharge rates, which are affected by bedrock flow and intercatchment groundwater transfer, result in the differences in water balance among the catchments. This study also suggests that in these second‐order to third‐order catchments, the drainage area during baseflow varies because of differences between the bedrock drainage area and surface drainage area, but that the effective drainage area during storm flow approaches the surface drainage area. Copyright © 2012 John Wiley & Sons, Ltd.     

Spatial variation of wetlands and flux of dissolved organic carbon in boreal headwater streams

In order to investigate the relation between water chemistry and functional landscape elements, spatial data sets of characteristics for 68 small (0·2–1·5 km²) boreal forest catchments in western central Sweden were analysed in a geographical information system (GIS). The geographic data used were extracted from official topographic maps. Water sampled four times at different flow situations was analysed chemically. This paper focuses on one phenomenon that has an important influence on headwater quality in boreal, coniferous forest streams: generation and export of dissolved organic carbon (DOC). It is known that wetland cover (bogs and fens) in the catchment is a major source of DOC. In this study, a comparison was made between a large number of headwater catchments with varying spatial locations and areas of wetlands. How this variation, together with a number of other spatial variables, influences the DOC flux in the streamwater was analysed by statistical methods. There were significant, but not strong, correlations between the total percentages of wetland area and DOC flux measured at a medium flow situation, but not at high flow. Neither were there any significant correlations between the percentage of wetland area connected to streams, nor the percentage of wetland area within a zone 50 m from the stream and the DOC flux. There were, however, correlations between catchment mean slope and the DOC flux in all but one flow situations. This study showed that, considering geographical data retrieved from official sources, the topography of a catchment better explains the variation in DOC flux than the percentage and locations of distinct wetland areas. This emphasizes the need for high‐resolution elevation models accurate enough to reveal the sources of DOC found in headwater streams. Copyright © 2007 John Wiley & Sons, Ltd.