西北天山京希-伊尔曼德金矿区狮子山次火山岩的年代学、地球化学特征及其地质、成矿意义

京希-伊尔曼德金矿位于西北天山吐拉苏盆地中,矿区出露晚古生代火山-沉积岩和狮子山次火山岩;狮子山次火山岩主要为安山玢岩、英安玢岩,侵位于火山-沉积岩底部的凝灰质砂岩、凝灰岩、流纹岩以及安山岩组合中。锆石SHRIMP U-Pb年代学研究表明,狮子山次火山岩的形成年龄为370.5±2.1Ma,略晚于围岩火山岩。狮子山次火山岩MgO、TiO₂、K₂O含量低,为低钾拉斑系列,稀土元素总量低（5.1×10^-6~8.8×10^-6）,轻稀土弱富集（（La/Yb）_N=2.7~3.8）,弱Eu正异常和Ce负异常,相对富集大离子亲石元素和Zr、Hf,亏损Nd,地球化学特征与围岩安山岩明显不同。具有亏损的Sr-Nd同位素特征,（⁸⁷Sr/⁸⁶Sr）_i=0.703185~0.703810,ε_Nd（t）=4.03~4.54。狮子山次火山岩形成于火山弧环境,是火山弧中少量拉斑系列岩石的代表,其岩浆源区为俯冲带流体交代的亏损地幔,地幔石榴石二辉橄榄岩经~5%部分熔融形成原始玄武质岩浆,玄武质岩浆经~20%的矿物分离结晶形成狮子山次火山岩,其形成环境以及演化过程非常有利于岩浆演化形成热液型金矿床,可能与京希-伊尔曼德金矿具有密切的成因联系。     

新疆西天山尼勒克二叠纪火山岩的地球化学特征及构造意义

尼勒克二叠纪火山岩位于伊犁盆地北缘阿吾拉勒山西段,该地区发育一套完整的陆相二叠纪地层。本文对该区二叠纪中下统哈米斯特组和乌郎组火山岩进行了系统的岩相学、岩石地球化学和Sr-Nd同位素研究。尼勒克火山岩岩石类型多样,有玄武岩、安山岩、粗面岩、流纹岩等,地球化学特征复杂。上火山岩哈米斯特组火山岩具有典型的钾玄岩特征,高K₂O(2.81%~3.91%)、Sr(>1000×10^-6)、稀土(ΣREE>200×10^-6)和(La/Yb)_N比值(9.7~11.7),低Nb/La比值(大多<0.2)。下火山岩乌郞组可分为二组,一组具最低SiO₂,最高MgO,较低Sr(<500×10^-6)、稀土(50×10^-6<ΣREE<80×10^-6)和(La/Yb)_N比值(1.6~2.2),相对较高的Nb/La比值(>0.35),类似富集型洋中脊(E-MORB)特征,暗示其岩浆是浅部源区高程度部分熔融的产物;另一组火山岩有着相对较大的变化,总体特征介于哈米斯特组与第一组火山岩两者之间。尼勒克火山岩有高度亏损的Sr-Nd同位素组成,类似MORB,表明它们源自长期亏损的地幔源区。然而,火山岩高度亏损的Nb-Ta、分异且富集大离子亲石元素的特征暗示,地幔源区受到近期俯冲带流体的交代作用,并受部分熔融程度及结晶分异作用的控制,是不同批次岩浆作用在不同演化阶段的产物。尼勒克大规模玄武质火山岩的形成可能和塔里木二叠纪地幔柱活动有关。     

攀西地区大板山岩体的年代学、元素地球化学及其对铜镍硫化物矿床成因的约束

大板山镁铁-超镁铁质杂岩体位于攀西地区西北部,受金河-菁河断裂带控制,主要岩石类型有辉长岩、苏长辉长岩和二辉橄榄岩。本次研究集中于苏长辉长岩和二辉橄榄岩,其中,二辉橄榄岩具有明显的堆晶结构,橄榄石Fo值最高可达81.4。二辉橄榄岩SiO₂含量为42.93%~44.18%,苏长辉长岩SiO₂含量为44.89%~52.76%,稀土总量(∑REE)相对较低(23.2×10^-6~61.7×10^-6),并均呈现出近平行的、相对平缓的右倾稀土元素配分模式,说明其为同源岩浆演化的关系。此外,大部分样品相对富集大离子亲石元素(LILE;如Rb、Sr、Ba等),适度亏损高场强元素(HFSE;如Nb、Ta、Ti等)。结合其较低的SiO₂含量和微量元素比值(如Th/Ta和La/Nb等),表明岩浆未遭受大量的地壳混染。岩相学和岩石地球化学特征均显示了非常明显的分离结晶作用。根据(Tb/Yb)_PM-(Yb/Sm)_PM图解,大板山岩体的原始岩浆主要来源于岩石圈地幔轻度富集不相容元素的尖晶石相二辉橄榄岩。二辉橄榄岩样品中橄榄石Fo-NiO图解中多数点落在硫化物未熔离的范围,且样品全岩Cu/Zr比值为7.04~103,而苏长辉长岩中Cu/Zr比值为0.88~5.56,反映了二辉橄榄岩-苏长辉长岩可能经历了由S不饱和到过饱和的过程。推测硫化物的熔离可能是岩浆在上地壳岩浆房中发生了以橄榄石和辉石为主的分离结晶作用,造成硫化物达到过饱和。锆石LA-ICP-MS测年表明,岩体年龄为259.69±0.61Ma,与峨眉山大火成岩省其它镁铁-超镁铁质岩体的形成时间基本一致。     

大兴安岭诺敏河石榴石橄榄岩捕虏体的发现及其地质意义

在重力梯度带北端的大兴安岭诺敏河第四纪火山岩中发现石榴石相和尖晶石相地幔橄榄岩捕虏体,其矿物组成分别为Ol_40~55Opx_20~35Cpx_0~10Grt_5~25和Ol_45~65Opx_30~40 Cpx_0~15Sp_0~10。两种地幔相橄榄岩均以方辉橄榄岩为主,说明研究区上地幔具有难熔的特点。其高Mg^#橄榄石Fo_91~92和高Cr^#_31~47尖晶石特征与南区哈河的地幔橄榄岩特征一致。在橄榄石含量与Fo图解上,敏河橄榄岩包体落在太古代和元古代地幔区域,揭示大兴安岭地区岩石圈地幔可能保留了较多古老的残余地幔。根据石榴石橄榄岩的平衡温压条件(1114~1168℃和2.14~2.33GPa),推测来源深度为70~75km。这些数据暗示研究区具有较高的地温梯度,与中国东部新生代火山岩区的地温梯度相似。     

准噶尔盆地陆东—五彩湾地区石炭系火山岩地球化学特征及其构造背景

准噶尔盆地陆东—五彩湾地区石炭系火山岩位于上石炭统巴塔玛依内山组地层中,主要为玄武岩、玄武质安山岩和安山岩,基本属于钙碱性系列。火山岩的Mg^#介于38~57之间,全碱含量较高K₂O＋Na₂O为4.75%~6.16％）,TiO₂的含量（0.96%~2.04％）和Na₂O/K₂O比值（均大于2）较高,轻稀土元素（LREE）相对重稀土元素（HREE）富集（(La/Yb)_N=2.4~4.7）,同时显示有轻微的重稀土分馏（(Gd/Yb)_N=1.5~1.8）,无明显的Ce异常,大部分样品具有轻微的Eu负异常（δEu＝0.89~1.05）,大离子亲石元素（LILE）相对高场强元素（HFSE）富集,Nb、Ta相对于LREE和LILE明显亏损,La/Nb比值为2.0~2.8,Th/La比值（≈0.1）较低,Zr/Y比值（3.95~7.03）较高。火山岩(⁸⁷Sr/⁸⁶Sr) _i＝0.70278~0.70365,ε_Nd(t)＝＋5.69 ~ ＋8.24,t_DM为0.47~0.67Ga。这些特征连同相关判别图解一起表明,这套火山岩不是形成于典型的板内或岛弧环境,而是形成于后碰撞期伸展背景下,是软流圈物质上涌发生部分熔融、产生的岩浆在上升和侵位的过程中受到了晚石炭世之前弧组分混染的产物。其所携带的弧岩浆特征继承自混染的碰撞前的弧组分。     

新疆库鲁克塔格地区兴地Ⅱ号镁铁-超镁铁质岩体的地球化学特征与岩石成因

兴地Ⅱ号镁铁-超镁铁质岩体位于塔里木盆地东北缘的库鲁克塔格地区,形态为不规则的漏斗状岩盆,出露面积约10km²。岩石类型主要有方辉橄榄岩、二辉橄榄岩、(含长)单辉橄榄岩、橄榄辉石岩、方辉辉石岩、二辉辉石岩、单辉辉石岩、橄榄辉长苏长岩、辉长苏长岩、橄榄辉长岩、辉长岩等,岩石类型属拉斑玄武岩系列。岩体的稀土元素含量低(∑REE=10.73×10^-6~77.44×10^-6),富集轻稀土元素(La/Yb)_N=4.06~7.73和大离子亲石元素(Cs、Rb、Sr、Ba),亏损高场强元素尤其是Nb、Ta、Ti、P等,δEu为0.90~2.46多数岩石显示出正铕异常。岩相学及地球化学特征表明,岩浆运移过程中主要发生了橄榄石、斜方辉石、单斜辉石的分离结晶作用以及斜长石的聚集/堆晶。原生岩浆为富镁拉斑玄武岩,岩浆源区为富集型岩石圈地幔,岩浆上升侵位过程中局部遭受了陆壳的同化混染。兴地Ⅱ号岩体与金川岩体具有很多的相似之处,而且兴地Ⅱ号岩体已见有铜镍矿化。因此,兴地Ⅱ号岩体具有很好的找矿前景。     

扬子陆块西缘江浪穹窿超基性岩的成因:锆石U-Pb定年、岩石地球化学及Sr-Nd同位素

江浪穹窿位于扬子陆块西缘,本文作者在穹窿南部新发现一套侵入于二叠系及志留系的超基性岩,岩石主要由蛇纹石(约60%)、橄榄石(约30%)和少量磁铁矿(约5%)、角闪石(约5%)组成。为探讨超基性岩的成因,本文进行了LA-ICP-MS锆石U-Pb定年、岩石地球化学及Sr-Nd同位素研究。定年结果表明,超基性岩中发育大量2427~430 Ma的捕获锆石,最年轻一组岩浆锆石²⁰⁶Pb/²³⁸U加权平均年龄为222.3±4.4 Ma(MSWD=1.9,n=6)。主微量元素分析显示岩石：(1)具有低的SiO₂含量(46.76%~39.07%)、高的Mg#值(82.3~74.0)与Cr、Co、Ni丰度;(2)稀土元素含量(ΣREE平均31.8 μg/g)与(La/Yb)_N值(5.26~1.38)偏低,稀土配分型式较为平坦,具有较弱的Ce负异常(Ce/Ce^*=0.80~0.67);(3)富集大离子亲石元素Rb、Ba和U,亏损高场强元素Zr和Hf;(4)(Th/Yb)_PM值(29.8~1.56)、(Th/Ta)_PM值(0.22~0.03)、(La/Nb)_PM值(1.91~0.39)及La/Sm值(5.88~1.11)较低。Sr-Nd同位素分析显示,超基性岩具有较低的(⁸⁷Sr/⁸⁶Sr)_i值(0.706872~0.702598)和高的ε_Nd(t)值(8.02~5.64),成分接近于亏损地幔和岛弧玄武岩,计算表明地壳物质的混染程度低于5%。结合前人研究成果,本文认为超基性岩结晶年龄为222.3 Ma,可能形成于古特提斯洋闭合阶段的岛弧背景;原始岩浆来自高度部分熔融的地幔源区,上升侵位过程中可能经历了铬铁矿与橄榄石的分离结晶作用。此外,捕获锆石的年龄谱反映江浪穹窿很可能存在太古宙—古元古代变质基底,并且具有Rodinia超大陆会聚—裂解以及泛非事件的地质年龄记录。     

中甸岛弧红山地区两期中酸性侵入岩的年代学、地球化学特征及其成因

青藏高原东部中甸岛弧红山地区发育有印支期和燕山晚期两期中酸性岩浆侵入活动,主要集中在～216Ma和～76Ma两个时期。印支期中酸性岩浆的侵入活动形成于甘孜-理塘洋西向俯冲背景下,与矽卡岩型铜多金属成矿作用密切相关。形成于印支期的红山石英闪长玢岩具有埃达克质岩的部分地球化学特征,如高Sr(平均为938×10^-6)、低Y(平均为18.6×10^-6)、Yb(平均为1.7×10^-6)含量,轻重稀土分异明显((La/Yb)_N平均为20.1),同时也有着较高的Mg^#(平均为51)、Cr(平均为103×10^-6)、Ni(平均为22×10^-6)含量,指示印支期红山中酸性岩与普朗-雪鸡坪成矿岩体有着相似的地球化学特征,二者可能有着相似的物质源区和成岩模式。而形成于燕山晚期的红山花岗斑岩具有低Sr含量 (平均为149×10^-6)和更低的Y(平均为10.8×10^-6)、Yb(平均为0.9×10^-6)含量,轻重稀土强烈分异((La/Yb)_N平均为56.0),明显区别于义敦岛弧弧后区的高贡-措莫隆A型花岗岩,前者很可能是红山中下地壳部分熔融的产物。结合中甸岛弧发育于燕山晚期的斑岩型矿床,我们认为该地区发育于燕山晚期的中酸性岩浆作用以及与之相联系的斑岩型矿床形成于造山后伸展环境下。     

昌宁—孟连缝合带乌木龙—铜厂街洋岛型火山岩地球化学特征及其大地构造意义

详细的地球化学解析表明,乌木龙—铜厂街地区出露的蛇绿混杂岩主要包括方辉橄榄岩、纯橄榄岩和碱性玄武岩。其中,方辉橄榄岩和纯橄榄岩具有极低的CaO含量(<0.1%)、稀土总量(<5×10-6)和(La/Yb)N(0.96～1.14)值,(Ce/Yb)N为1.04～1.37,为轻稀土弱亏损型。本区碱性玄武岩具有高TiO2(2.57%～3.33%)、高K2O(2.29%～5.52%)的显著特征,(La/Yb)N为15.42～19.81,(Ce/Yb)N为12.48～14.76,为轻稀土强烈富集型;岩石Ti/V、Th/Ta、Th/Yb、Ti/Yb、Ta/Yb与来自亏损地幔的MORB以及与俯冲有关的岛弧火山岩明显不同,而主要显示为OIB型火山岩的微量元素地球化学特征,乃是典型的大洋板块内部岩浆作用的产物。该区洋岛型火山岩的厘定,表明昌宁—孟连古洋盆在石炭—二叠纪期间曾经历过一个由初始洋盆到成熟洋盆的完整发育演化过程。     

海拉尔盆地基底晚古生代adakite的发现及其地质意义

海拉尔盆地的前中生代基底隶属中亚造山带东段的兴蒙造山带。 在盆地基底地层中发现了具有adakite成分特征的粗面安山岩、英安岩和闪长玢岩。 这些火成岩与晚古生代沉积地层交互或伴生, 共同构成晚中生代裂陷盆地的基底。 地球化学研究表明, 这些火成岩基本上属于高钾钙碱性和准铝质岩石系列, 具有高SiO₂和Al₂O₃含量, 高Sr、Sr/Y和La/Yb值, 富集轻稀土(LREE), 亏损重稀土(HREE)、Y和高场强元素(HFSE),Eu表现弱的负异常或轻微的正异常, 相容元素Mg、Cr和Ni含量低, 这些特征与增厚下地壳部分熔融成因的adakite非常相似, 而明显不同于典型的由俯冲洋壳熔融形成的adakite。 样品的(⁸⁷Sr/⁸⁶Sr)_i值基本一致,为0.7041, (¹⁴³Nd/¹⁴⁴Nd)_i值为0.51243~0.51247, ε_Nd (t)为正值(+3.7~+4.5), 显示其岩浆源区可能源于弱亏损地幔, 或亏损地幔受到地壳物质混染。 本文认为海拉尔地区晚古生代adakite型岩浆很可能是由当时新底侵的玄武质下地壳在角闪岩相向榴辉岩相过度或榴辉岩相条件下部分熔融形成。 这些adakite岩石的出现反映了兴蒙造山带晚古生代受到了古亚洲洋的俯冲消减引起的强烈的地幔玄武质岩浆底侵作用, 并由此导致地壳垂向上显著的增生加厚过程。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).