蛇纹石化过程中铁活动性的高温高压实验研究

蛇纹石化过程中铁的活动性影响铁氧化物的形成和体系的氧逸度。然而,关于橄榄岩蛇纹石化过程中各矿物(橄榄石、斜方辉石和单斜辉石)蚀变过程中铁的活动性仍没有详细的研究。本文报道了80~200℃、饱和蒸气压下,不同的初始流体、水岩比条件下,橄榄岩蛇纹石化过程中铁的活动性。结果表明,蛇纹石化流体的铁含量较低(0.0~0.7mmol/kg),没有形成铁氧化物或铁氢氧化物,铁主要富集在蛇纹石和未反应的初始矿物中(例如,橄榄石和辉石)。由橄榄石蚀变形成的蛇纹石和由斜方辉石蚀变生成的蛇纹石化学组成相差较大,前者富铁而贫铝,后者贫铁而富铝。但当初始流体为碱性的0.5mol/L Na Cl(aq)时,两种不同来源的蛇纹石组成相差不大。尤为重要的是,单斜辉石蚀变生成的蛇纹石铁含量较高,8.1%~10.2%Fe O,远高于单斜辉石的铁含量(2.6%Fe O)。以上表明,低温蛇纹石化过程中,铁不能够大规模、长距离的运移,但在微米尺度上是活动的。     

内蒙古苏尼特左旗乌兰敖包基性-超基性岩的成因及其对含矿性的指示

乌兰敖包基性-超基性岩位于阿拉善北缘兴蒙造山带,由方辉橄榄岩、辉绿岩、辉长岩组成。地球化学分析表明:蛇纹石化橄榄岩为地幔橄榄岩,辉绿岩和辉长岩为拉斑玄武岩系列岩石,均具有与N-MORB相似的微量元素特征,但区别于N-MORB,3种岩石共同组成了蛇绿混杂岩。矿物学分析表明蛇纹石化橄榄岩中橄榄石为地幔橄榄岩中镁橄榄石(Fo=91.10~91.81),铬铁矿为铬尖晶石,具有高的Cr~#和Mg~#值分别为61.04~64.44、50.40~56.37)。单斜辉石出现在方辉橄榄岩、辉长岩及辉绿岩中,而斜方辉石只出现在方辉橄榄岩中,其中方辉橄榄岩中单斜辉石为顽透辉石,辉长岩中为普通辉石,而辉长岩中为次透辉石、贫钙普通辉石、普通辉石,斜方辉石均为斜顽辉石。辉长岩U-Pb年龄为344.5±1.5 Ma,表明该蛇绿混杂岩形成于早石炭世。地球化学及矿物学特征表明乌兰敖包蛇绿岩形成于俯冲早期的弧前环境中,属于SSZ型蛇绿岩。蛇绿混杂岩成因提供铬铁矿形成的有利条件,因此应围绕铬铁矿进行找矿工作。     

河北阳原新生代玄武岩中橄榄岩捕虏体的含水量研究

为约束华北克拉通岩石圈的流变机制,使用傅立叶变换显微红外光谱仪（FTIR）测量了阳原玄武岩中尖晶石橄榄岩捕虏体的矿物含水量。FTIR光谱结果表明阳原橄榄岩捕虏体的橄榄石、斜方辉石和单斜辉石都有特征的OH吸收峰。橄榄石含有微量的水（4×10-6~9×10-6 H2O）,斜方辉石含水量为（105~201）×10-6,单斜辉石含水量为（260~440）×10-6,计算得出的全岩含水量为（49~75）×10-6。值得注意的是,富流体交代以及后期蚀变作用使得含角闪石的方辉橄榄岩样品中单斜辉石的含水量显著增加。阳原橄榄岩中单斜辉石与斜方辉石的含水量存在明显的正相关关系,水在单斜辉石和斜方辉石中的分配系数D cpx/opxOH =2.4±0.9,与全球橄榄岩样品的平均值基本一致（D cpx/opx OH = 2.2±0.1）。与汉诺坝的橄榄岩捕虏体相比,阳原捕虏体中橄榄石和辉石的结构水含量都明显较高,这可能与阳原橄榄岩经历的上地幔交代作用有关。统计表明全球克拉通玄武岩携带的尖晶石橄榄岩捕虏体中橄榄石的含水量普遍较低（0~10×10-6）,而斜方辉石和单斜辉石的含水量则存在明显的不均一性。金伯利岩携带的石榴石橄榄岩中橄榄石、斜方辉石和单斜辉石的含水量都明显高于玄武岩携带的尖晶石橄榄岩中相应矿物的含水量,这可能与金伯利岩来源深、富流体、上升快的性质相关。     

云南哀牢山蛇绿岩的矿物学研究

云南哀牢山蛇绿岩由变橄榄岩、堆晶杂岩、火山熔岩和硅质岩等四个单元组成,其主要矿物有橄榄石,斜方辉石、单斜辉石、尖晶石、斜长石、角闪石、石榴子石等,这些矿物均已不同程度地遭到蚀变、橄榄石、斜方辉石的化学成分显示蛇绿岩中的二辉橄榄岩为原始地幔岩;是石的化学特征表明蛇绿岩中的橄榄岩为深海橄榄岩;单斜辉石的成分反映二辉橄榄岩经历过熔融作用,堆晶杂央才基性熔岩具有火山弧和洋底玄武岩的特征。     

西准噶尔白碱滩二辉橄榄岩中两种辉石的出溶结构及其地质意义

克拉玛依白碱滩尖晶石二辉橄榄岩主要由橄榄石、单斜辉石、斜方辉石和尖晶石组成,橄榄石和斜方辉石均发生程度不等的蛇纹石化。单斜辉石一般很新鲜。单斜辉石和斜方辉石均发育出溶结构,出溶条纹或者平直或者发生舒缓的弯曲变形(即便是在发生弯曲的情况下也是完全平行的)。透辉石-普通辉石出溶体一般呈针状(直径一般为1μm,长度>150μm),顽火辉石出溶条纹直径一般为1～3μm(长度>300μm)。斜方辉石主晶属于顽火辉石-易变辉石,单斜辉石主晶为透辉石(成分很均一)。地质温度压力估算表明,白碱滩二辉橄榄岩中辉石出溶结构发生的温度为700℃～1000℃、压力为2.0～2.7GPa,它们代表辉石出溶结构形成的最低PT条件。白碱滩二辉橄榄岩至少经历了三个演化阶段:原始辉石与尖晶石和橄榄石平衡共生(阶段Ⅰ,>94km);随着地幔上隆,原始辉石结构不稳定,分解并形成出溶结构(阶段Ⅱ,700℃～1000℃),斜方辉石开始分解的深度为94km,单斜辉石开始分解的深度为78km;之后,蛇绿岩经历的侵位事件导致辉石发生塑性变形(阶段Ⅲ)。蛇绿岩侵位之前,地幔岩曾发生了>50km的隆升,而且,在隆升过程中地幔岩没有发生明显部分熔融(地幔岩因此没有经历明显的岩浆抽提过程)。     

甘肃金川Ⅱ号岩体辉石化学特征及其地质意义

金川Ⅱ号岩体主要由二辉橄榄岩和硫化物橄榄岩构成,单斜辉石和斜方辉石为岩相中主要造岩矿物,单斜辉石含量一般高于斜方辉石.矿物间的结构关系表明主要造岩矿物的结晶顺序为:橄榄石-斜方辉石-单斜辉石-斜长石.单斜辉石的TiO2,Al2O3,Cr2O3和Na2O质量分数依次为:0.29%～1.26%、3.17%～3.59%、0.86%～1.14%、0.29%～0.57%,斜方辉石的TiO2,Al2O3,Cr2O3和Na2O质量分数普遍低于单斜辉石,依次为:0.16%～0.40%、1.85%～2.38%、0.48%～0.68%、0.03%～0.10%.元素间的相关关系显示辉石的类质同像置换方式为:M1Fe2 2 Si=M1Ti 2IV Al,M1Fe2 Si=M1Fe3 IVAl,Fe3 和Ti进入矿物晶格置换Fe2 来平衡Al置换Si产生的正电价差.两种辉石较低的TiO2,Al2O3和Na2O质量分数显示出母岩浆为拉斑玄武岩浆的特征.二辉石温度计和单辉石温度计算表明斜方辉石的结晶温度下限和单斜辉石结晶温度上限大致在1146℃～1166℃之间,单斜辉石的结晶一直持续到1032℃或者更低.金川Ⅱ号岩体单斜辉石演化明显表现出向透辉石端员偏离,暗示岩浆在结晶分异过程中,可能与富钙质围岩发生了同化混染作用.     

斜方辉石筛状反应边的成因机制及其对岩石圈地幔性质转变的意义

本文利用电子背散射衍射(EBSD)技术对河北张家口大麻坪汉诺坝玄武岩橄榄岩捕虏体中斜方辉石与玄武岩反应结构的显微构造进行了详细研究。研究结果表明: ① 其反应边具有复杂的多层筛状结构特征,包括玄武岩层、富橄榄石层以及橄榄石和单斜辉石交生层;② 由外至内,橄榄石的Mg值逐渐升高,而单斜辉石的Mg值变化不大;③ 反应边结构中的单斜辉石与斜方辉石残斑之间存在很好的结晶学拓扑关系,即(100)_opx//(100)_cpx、(010)_opx//(010)_cpx、(001)_opx//(001)_cpx;④ 橄榄石的结晶学取向无序且与斜方辉石和单斜辉石均无关。这个反应过程可以用贫硅熔体先与斜方辉石反应形成单斜辉石,并导致熔体富硅,从而橄榄石从反应熔体中结晶出来合理地解释。相对富硅熔体与橄榄岩的反应,贫硅熔体与橄榄岩的反应过程由于筛状反应边的存在可能更容易进行,筛状结构反应边可以为熔体在橄榄岩中沿颗粒边界运移提供通道,并使橄榄岩主要组成矿物发生细粒化和岩石结构变得松散,可以有效保证熔体上升过程中对橄榄岩的持续侵蚀和破坏,从而可能导致岩石圈地幔性质的迅速转变。     

哀牢山南段蛇绿岩变质橄榄岩的矿物化学及其成因意义

哀牢山南段蛇绿岩中变质橄榄石单元,由方辉橄榄石和二辉橄榄岩组成,前者已强烈蚀变,后者的矿物组成有橄榄石,斜方辉石,单斜辉石及少量尖晶石等,对这些矿物进行了较详细的化学成分分析,橄榄石,斜方辉石的化学分显示,二辉橄榄石为较弱亏损的地幔岩,橄榄石,尖晶石的矿物化学反应,变质橄榄石的原始岩石具有深海橄榄石的特征,单斜辉石,尖晶石的化学特征显示,二辉橄榄石经历过程熔融作用,因此,二辉橄榄石为部分熔融较弱亏     

大兴安岭地幔橄榄岩中熔体的多样性及其成因

本文报道了大兴安岭第四纪火山岩中的地幔橄榄岩中橄榄石、单斜辉石和斜方辉石颗粒内部熔体产状(囊体、包裹体和反应边)和成分(低硅熔体和高硅熔体)的多样性,初步讨论了不同熔体的成因。低硅熔体囊体是在地幔深部玄武岩浆与橄榄岩中单斜辉石发生交代反应的产物,斜方辉石反应边的高硅熔体是橄榄岩被捕获上升过程中玄武岩浆与斜方辉石反应的产物,高硅熔体包裹体是地幔中存在的交代熔体。     

西准噶尔蛇绿混杂岩中的白云石大理岩和石榴角闪岩：早古生代残余洋壳深俯冲的证据

本文在描述达拉布特和克拉玛依蛇绿岩中四个典型剖面(达拉布特、萨尔托海、白碱滩和百口泉)的基础上,通过研究变白云石大理岩和石榴角闪岩的形成和演化过程,展示西准噶尔蛇绿混杂岩的复杂性。白碱滩白云石大理岩是尖晶石二辉橄榄岩变质反应的产物。变质反应导致单斜辉石转变为白云石+石英+磁铁矿,橄榄石和斜方辉石先转变为蛇纹石+磁铁矿,蛇纹石再转变为白云石+石英+磁铁矿。透辉石+CO₂=白云石+石英+磁铁矿以及蛇纹石+CaCO₃=白云石+石英 +磁铁矿+H₂O这两个变质反应基本同时发生,他们以及石英—柯石英相变关系所限定的P-T空间(660~670℃,26.5~27.5 kbar)代表白云石大理岩的形成温度和压力。白云石大理岩与尖晶石二辉橄榄岩在一个不大的区域共存,说明循环到地球深部的尖晶石二辉橄榄岩(即：白云石大理岩的原岩)折返到地壳浅部后又与蛇绿岩中未俯冲的尖晶石二辉橄榄岩混杂在一起。因此,克拉玛依蛇绿混杂岩代表古俯冲带的位置。变辉长岩和尖晶石二辉橄榄岩中的单斜辉石均发育出溶结构(出溶尖晶石和斜方辉石)。这些出溶结构是蛇绿岩快速上升就位时由于温度和压力突然降低辉石发生分解反应的产物。因此,西准噶尔蛇绿混杂岩中的岩石组合记录着蛇绿岩形成时期、以及之后部分岩块通过俯冲带循环到地幔深处(最大深度~70km)并折返到地壳浅部的全过程。西准噶尔蛇绿混杂岩带是一个多时期、多阶段和多成因岩石的混杂体。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.     

PALEONTOLOGY

正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)     

GEOCHEMICAL EXPLORATION

正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)     

MICROPALAEONTOLOGY

正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)     

PETROLOGY

正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,     

ENVIRONMENTAL GEOLOGY

正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an     

PROSPECTING EXPLORATION

正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of