喀斯特石漠化地区土壤Fe组成及其发生学意义

土壤中氧化铁的组成反映了土壤的成土过程和环境条件。通过对西南喀斯特石漠化地区不同石漠化阶段山地自然土壤和农田土壤Fe组成的分析,研究了土壤全铁、游离氧化铁和非晶形氧化铁的分布规律,探讨了喀斯特地区石漠化土壤的发育过程和Fe的指示作用。研究表明:①喀斯特地区土壤表层全铁含量在38.9～53.9g/kg之间,游离氧化铁含量在18.0～26.7g/kg之间,铁游离度在44.1%～73.4%之间,铁活度在7.2%～11.4%之间。②随着石漠化程度的加剧,土壤游离氧化铁和铁游离度呈增加的趋势,而铁活度呈降低的趋势。③在土体分布上,自然土壤剖面随深度的增加,土壤铁游离度和铁活度呈明显降低的趋势,而农田土壤铁游离度呈增加的趋势。④喀斯特地区的土壤是石灰岩溶蚀风化的产物,人为活动干扰下的自然土壤石漠化过程是在水力作用下的表土侵蚀过程,而农田土壤受水分垂直运动的影响,是土壤丢失的过程。     

济阳坳陷前第三系顶部风化壳结构发育特征及对油气成藏的影响

基于地质综合研究,系统分析了济阳坳陷前第三系顶部风化壳结构地质特征,深入剖析了其形成主控因素,总结了风化壳结构发育模式,探讨了风化壳结构对油气成藏的影响。研究认为,济阳坳陷前第三系顶部风化壳中,风化粘土层厚度薄,分布地区局限,物性差;半风化岩石全区发育,岩石类型多样,除部分半风化碳酸盐岩、火成岩、变质岩等顶部存在一层致密“硬壳”外,物性多得到改善。风化壳结构形成受控于原岩岩性、间断时间、古气候、古地形、上覆层沉积环境等5大因素;多种因素共同作用,决定了风化壳结构空间发育;风化粘土层、半风化岩石顶部“硬壳”对油气起遮挡、封盖作用,顶部无“硬壳”的半风化岩石则可大大提高前第三系岩层的储集性能和不同层系之间的横向连通性。     

陕西柞山地区穆家庄铜矿床成矿流体来源的氦氩氢氧同位素示踪

最近,在秦岭柞山地区泥盆系中又发现了穆家庄铜矿,矿体明显受层间破碎带控制,矿石主要产在铁白云石-石英脉中,其后生成矿现象非常明显.文章利用的黄铁矿流体包裹体He-Ar同位素和氢氧同位素,来探讨这类矿床的成矿流体的来源.穆家庄铜矿床矿石矿物黄铁矿流体包裹体的3He/4He比值为0.322～0.889R/Ra,小于1.0R/Ra.3He/4He比值远远低于地幔流体的比值,与地壳流体的比值在相同的数量级上.穆家庄铜矿成矿流体的40Ar/36Ar比值为377～569,平均470,显然偏离大气氩的同位素组成.穆家庄铜矿成矿流体的40Ar/4He比值为0.09～0.23,平均值为0.164.很显然,该矿床的成矿流体的40Ar/4He比值接近地壳.根据以上分析,柞山地区的穆家庄铜矿床的成矿流体是壳源的.氢氧同位素分析表明穆家庄铜矿的氢氧同位素则落入原生岩浆水范围内,表明穆家庄铜矿的成矿流体为岩浆水.综合对比分析后认为,穆家庄铜矿的成矿流体是由壳源岩浆驱动并参与的岩浆流体提供的.     

高寒冻土区生物结皮对土壤理化属性的影响

生物结皮是高寒地区地被层的重要组分之一。其作为地表特殊的结构层,能够改变地表结构及土壤理化属性,从而影响冻土环境。迄今为止,关于青藏高原高寒生态系统中生物结皮对土壤理化属性的影响尚不清楚。以青藏高原高寒冻土区生物结皮为研究对象,初步研究了生物结皮的特征及其对土壤理化属性的影响。结果表明：生物结皮在高寒草甸退化过程中广泛发育,主要以藻结皮为主,其盖度可达37.3%~51.7%,结皮层平均厚度为12.6 mm。由于生物结皮的发育,高寒地区5~20 cm土层粉粒含量有所增加,但差异不显著,而结皮层土壤田间持水量相比于裸地表层（2 cm）增加了10%~40%,结皮层容重较裸地降低了30%;两种类型藻结皮均显著增加了结皮层及其下0~20 cm土层土壤有机质,而深色藻结皮增加了结皮层及其下0~20 cm土层土壤全氮含量,浅色藻结皮仅增加了结皮层土壤全氮含量,对其下0~20 cm土层土壤全氮含量没有显著影响;生物结皮对土壤pH没有显著影响;生物结皮是高寒生态系统植被退化过程中的关键环节。研究结果为揭示生物结皮在高寒生态系统中发挥重要生态功能提供依据。     

The impact of land use and land cover changes on soil moisture and hydraulic conductivity along the karst hillslopes of southwest China

The understanding of the temporal and spatial dynamics of soil moisture and hydraulic property is crucial to the study of several hydrological and ecological processes. Karst environments are extremely fragile because of thin soil and small soil water holding capacity. A marked intensification of agricultural land use and deforestation due to increase of population and thus expansion of agricultural areas has made the karst environment even more delicate. In this study, the soil moisture contents (SMC) and hydraulic conductivities (K) along four karst hillslopes were measured in situ by time domain reflectometry and the Guelph Permeameter, respectively, at test plots, each of which has a different vegetative cover, landform, land surface slope, soil property and content of rock fragment. The statistical results from the measurements show that land cover changes strongly affect the distribution of soil moisture and hydraulic properties. Compared with SMC in the bare soil areas, SMC values are 30.5, 20.1 and 10.2% greater in the forest, shrub and grass areas, respectively. Vegetation roots significantly increase permeability of low-layer silt soils. Measured K values were 0.8, 0.6 and 0.01 cm/min for the forest, agriculture and bare soil areas, respectively. When the forest was destroyed by fire or cut to become an agricultural area or bare soils, SMC would be reduced by 13.1 and 32.1%, respectively. If deforestation leads to strong rock desertification, SMC was reduced by 70%. Bedrock fractures significantly reduce the SMC in the overlying layer, but increase K values. SMC values of 30–45% would be reduced to 17–30% for the soil layer embedding rocks with and without fractures, respectively. K values could be increased from 1.0 to 8.5 cm/min. SMC are sensitive to terrain. A slope angle increase of 1° would reduce SMC about 0.82%. These changes resulting from land cover and land use alterations offer useful information to further investigate the response of ecosystem evolution to hydrodynamic processes.     

侵入岩脉风化壳对中林村残积土滑坡渗流场和稳定性的影响

岩脉侵入是一种普遍的地质现象,侵入岩脉及其风化壳对斜坡的渗流场和稳定性具有重要影响,但目前国内外在该方面的研究鲜见报道。我国东南沿海约50×104 km2的白垩系火山岩地层中广泛分布侵入岩脉及其风化壳,改变了该地区残积土斜坡的失稳机制。以浙江省文成县中林滑坡为对象,研究花岗岩脉风化壳对其渗流场和稳定性的影响。中林滑坡主要由凝灰岩及其残积土组成,后部有侵入的花岗岩脉及其残积土,利用室内土柱试验获取降雨作用下两种残积土渗透性质的差异,利用不同含水率下的直剪试验获取非饱和抗剪强度参数;利用Geo-studio软件中的Seep/W模块反演土柱降雨试验,获取两种土体的非饱和渗透参数;接着将上述参数应用于中林滑坡的渗流场模拟,获取降雨入渗下坡体的渗流场;将渗流场耦合到坡体稳定性计算中,获取了坡体的稳定性变化曲线及最危险滑面。结果表明,降雨通过侵入岩脉风化壳快速入渗,并顺着基覆面向凝灰岩残积土区侧向渗流,导致侵入区与原始斜坡的交界处以及基覆面附近的地下水位快速升高,孔隙水压力迅速增大,斜坡在该位置最易变形破坏,且失稳深度远大于普通的浅层残积土斜坡,可达6～10 m。该研究成果可为东南沿海地区有岩脉侵入的残积土斜坡的稳定性评价与防治设计提供理论依据。     

非饱和上海软土水力和力学特性耦合弹塑性模拟

目前大多数非饱和土的弹塑性本构模型用非饱和击实土的试验结果进行验证,但现场其他类型的土,如沉积土经常有在非饱和状态下外部环境变化的情况。现有的非饱和土弹塑性模型是否适用于沉积土一类的现场土是需要研究的课题。进行非饱和上海第③层土的吸力控制排水排气三轴剪切试验,使用文中提出的能统一考虑非饱和土水力性状和力学性状的弹塑性本构模型,预测上述三轴试验结果,并与试验数据进行比较。比较结果显示,建立的本构模型能够很好地预测非饱和上海软土的水力和力学性质,说明该模型不仅可以适用击实土的预测,还能够很好地适用于其他类型非饱和土的水力和力学性质的模拟。     

河套地区土壤基准值及背景值特征

通过对河套地区土壤背景值与基准值的确定与研究发现，河套地区主要是以富CaO、MgO及As、F等为主的地区，其他绝大多数元素的含量要低于全国以及世界水平。河套地区表层和深层土壤中样品含量也有一定的差别。此外长期的人类活动也对土壤中元素的含量变化产生比较明显的影响。通过对土壤基准值与土壤背景值的研究分析，为该地区农业、环境及地方病等方面的研究提供基础、全面的资料。     

Assessment of trace element contamination in soils around Chinnaeru River Basin, Nalgonda District, India

Concentrations of trace elements such as As, Ba, Co, Cr, Cu, Ni, Pb, Rb, Sr, V, Y, Zn and Zr were studied in soils to understand metal contamination due to agriculture and geogenic activities in Chinnaeru River Basin, Nalgonda District, India. This area is affected by the geogenic fluoride contamination. The contamination of the soils was assessed on the basis of geoaccumulation index, enrichment factor (EF), contamination factor and degree of contamination. Forty-four soil samples were collected from the agricultural field from the study area from top 10–50 cm layer of soil. Soil samples were analyzed for trace elements using X-ray fluorescence spectrometer. Data revealed that soils in the study area are significantly contaminated, showing high level of toxic elements than normal distribution. The ranges of concentration of Ba (370–1,710 mg/kg), Cr (8.7–543 mg/kg), Cu (7.7–96.6 mg/kg), Ni (5.4–168 mg/kg), Rb (29.6–223 mg/kg), Sr (134–438 mg/kg), Zr (141.2–8,232 mg/kg) and Zn (29–478 mg/kg). The concentration of other elements was similar to the levels in the earth’s crust or pointed to metal depletion in the soil (EF < 1). The high EFs for some trace elements obtained in soil samples show that there is a considerable heavy metal pollution, which could be due to excessive use of fertilizers and pesticides used for agricultural or may be due to natural geogenic processes in the area. Comparative study has been made with other soil-polluted heavy metal areas and its mobility in soil and groundwater has been discussed. A contamination site poses significant environmental hazards for terrestrial and aquatic ecosystems. They are important sources of pollution and may result in ecotoxicological effects on terrestrial, groundwater and aquatic ecosystems.     

多功能孔压静力触探在基坑工程降水设计中的应用分析

针对南京长江四桥漫滩沉积土,分别进行了室内试验和多功能地震波孔压静力触探（SCPTU）原位测试,从SCPTU应用于场地复杂地层 的精细划分、长江漫滩沉积黏性土透水性能的评价和预测渗透系数kh 3个方面进行了详细分析,试验结果表明：综合利用 多功能SCPTU测试qt、fs、u2 3个参数可以对具有高度分层性和不均匀性的长江漫滩沉积土进行精确分层,对不同性质土 层界面、同一土层内透水或不透水夹层进行精确探测;利用SCPTU钻进过程中的孔压消散试验功能,可以对复杂的混合土层的透水性能进行评价;基于SCPTU的渗透系数kh预测值均具有一定的离散性,一般比室内试验结果高1～2个数量级,Burns & Mayne方法预测值可以作为工程初设阶段的参考值;SCPTU的应用为基坑工程降水设计提供了一种简便、快捷的新型技术手段。     

基于数字图像技术的土冻胀试验系统研究

开展土冻胀过程的研究对于认识土冻胀机理具有重要的意义,以往学者多采用建立模型进行数值分析的方法,但是在试验中却不能对模型预测的冷生构造、冰分凝、水分迁移等实时过程进行验证。通过建立包括实时图像采集系统、图像预处理系统以及图像数字化系统为一体的基于数字图像技术的土冻胀试验系统,对青藏粉土的冻胀发展过程和冰分凝过程进行了研究分析。结果显示：试样冻胀后已冻区纵剖面的冷生构造可以分为微薄层状构造区、薄层状构造区以及最暖端厚层状构造区三个部分,其中薄层状构造区下部的冰透镜体的分凝作用是冻胀的主要贡献部分,最暖端厚层状构造区中冰透镜体的分凝作用导致了试样未冻区的固结,试样中冰透镜体的分凝过程与试样的冻胀过程和试后含水率的结果能够相互验证。建立的试验系统可以对土冻胀过程中包括冷生构造发育、冻胀变形、冰分凝等过程进行实时采集和定量分析,为冻胀模型的建立和验证提供了试验方法和技术支撑。     

荒漠地区土壤初始状况对水平入渗的影响

通过对沙坡头荒漠地区人工植被固沙区生物土壤结皮与固沙区外天然沙丘沙以及天然植被红砂、珍珠分布区砂粘土在不同初始含水率（θ_i）条件下土壤水平入渗过程的对比试验研究,探讨土壤质地以及θ i对水平入渗系数（λ_f）、剖面平均含水率（θ_m）状况的影响。生物土壤结皮对降水入渗量的截持作用大于沙丘沙,因而将显著地改变降水入渗过程中土壤水分的再分配格局,减少降水对深层土壤（沙丘沙）的有效补给。通过对土壤剖面平均含水率θ_m与距离湿润锋前缘0～5 cm、5～10 cm处体积含水率θ_fA、θ_fB比较,生物土壤结皮的θ_m、θ_fA和θ_fB分别约为沙丘沙的1．5倍。     

Performances of two instrumented laboratory models for the study of rainfall infiltration into unsaturated soils

Rainfall infiltration and suction variation in unsaturated soils must be taken into consideration in the analysis of most slope stability problems, particularly in the tropical regions where the annual precipitation is high. The process of rainfall infiltration into unsaturated soils is an extremely complex problem attributed to the non-linearity of the hydraulic property functions of the unsaturated soils. This paper describes in detail two instrumented laboratory models, i.e. one-dimensional soil column, and two-dimensional slope model used to provide experimental evidences for the transient suction variations in the unsaturated soils under certain rainfall conditions. The performances of the laboratory models were tested on four typical types of residual soils, i.e. sand-gravel, silty gravel, sandy silt, and silt (kaolin), and a two-layered soil system, i.e. sandy silt underlain by silty gravel. The results showed that the suction distributions for the single-layered homogeneous soils obtained from the simpler one-dimensional soil column were almost identical to that of two-dimensional slope model. However, the two-dimensional slope model should be employed for the two-layered soil system because of the dominant effect of the lateral flow mechanism. The capillary barrier effect was observed when a less permeable soil layer was underlain by a more permeable soil layer. The minimum suction value in soil is governed by the rainfall intensity, rainfall duration, and the saturated permeability of soil. The infiltration rate of the fine-grained soils that subjected to shrink and crack was independent of the soil permeability, but was significantly governed by the preferential flows developed in the soils.     

土结构性本构模型研究现状综述

土本构模型的建立是一个重要而又复杂的问题,到目前为止,国内外学者们已提出数以百计的土本构模型,诸多文献也对这些模型进行了评述和归纳。然而这些土本构模型多是在扰动土或砂土的基础上发展和建立起来的,它们难以描述由于土结构性引起的各种非线性行为,其计算结果与实际情况相差甚远。天然土体一般都具有一定的结构性,所以有必要建立考虑土结构性影响的土本构模型。针对这个现实,目前有些学者已基于各种理论和方法,提出了一些可以考虑土结构性影响的土本构模型,并得了较好的应用。但在目前的文献中还很少有对土的结构性本构模型研究进行归纳,基于此,本文简要介绍了一下目前土的结构性本构模型研究现状,并提出了这些本构模型在应用中所存在的问题。     

用红外吸收光谱确定层状硅酸盐中羟基键的方向

层状硅酸盐样品用于红外二色性研究,当射线的电场矢量与振动的偶极矩方向成一角度时,这吸收与角度成比例,当某振动的偶极矩与电场矢量平行时,产生最大吸收,而这两矢量彼此垂直时将不产生吸收。在云母和有关晶体中可看到,在二八面体组成中,在改变电场矢量时倾斜OH团的OH振动强度保持不变,而与在三八面体组成中垂直于解理面方向的八面体OH团相比,当层状定向颗粒方向改变时显示强度大大增加,由此能获得层状硅酸盐OH键的方向,在晶体结构分析中能提供有价值的信息。     

土壤的冷生构造及其对阿拉斯加土地利用的意义

Cryogenic structure (patterns made by ice inclusions) in seasonally frozen and permafrost-af-fected soils result from ice formation during freezing. Analysis of cryogenic structures in soils is essential to our understanding of the cryogenic processes in soils and to formulating land use management interpretations. When soils freeze, the freezing front moves downward and attracts water moving upward resulting in mainly horizontal lenticular ice formation. Platy and lenticular soil structures form between ice lenses in upper active layer. The reticular soil structure usually forms above the permafrost table caused by freeze-back of the permafrost. The upward freeze-back resulted in platy soil structure and the volume changes following the annual freeze-thaw cycle resulted in vertical cracks. The combined result is an ice-net formation with mineral soils embedded in the ice net. The upper permafrost layer that used to be a part of the active layer has an ice content exceeding 50% due to repeated freeze-thaw cycles over time. The mineral soils appear in blocks embedded in an ice matrix. The permafrost layer that never experienced the freeze-thaw cycle often consists of alternate layers of thin ice lens and frozen soils with extreme hard consistence and has relatively lower ice content than the ice-rich layer of the upper permafrost. Ice contents and thaw settling potentials associated with each cryogenic structure should be considered in engineering and land use interpretations.     

土壤呼吸作用和全球碳循环

土壤呼吸作用是全球碳循环中一个主要的流通途径 ,导致土壤碳以CO2 形式流向大气圈。全球土壤中碳贮存量的增加有助于缓和人为CO2 的进一步释放 ,而土壤CO2 的流失则显著地加剧大气CO2 的升高和增强温室效应。文章简单评述了土壤呼吸作用、大气CO2 升高、全球温度升高三者之间的关系 ,并提出 :改进的管理实践能减少农业土壤中CO2 净流失 ,增加有机碳贮存。减缓土壤呼吸作用的一项简单措施是减少土壤耕作。土壤扰动最小的耕作实践称为免耕作。实践证明 ,当实施免耕作时 ,土壤有机质的流失明显降低。     

浙江富硒土壤资源调查与评价

浙江省农业地质环境调查发现,浙北、浙东、浙中地区富硒土壤呈大面积分布。不同类型土壤中,以石灰岩土硒含量最高,黄壤和红壤硒含量次之;不同类型成土母质中,以残坡积物硒含量相对较高;不同类型岩石中,以石英砂岩、硅质岩和中深变质岩硒含量较高,高于中国东部地壳丰度值。富硒土壤主要分布于富硒岩石和煤系地层区。硒多富集在土壤表层,由地表向深部含量迅速下降。根据土壤背景值和硒生态景观分级标准,建立了富硒土壤评价标准,划分硒含量等级区,圈定了浙江省富硒土壤分布。     

青藏粉质黏土单向冻结冷生构造发育及冻胀发展过程试验研究

通过对青藏饱和粉质黏土进行开放条件下的单向冻结试验,并结合土样冻结过程的图像数据,分析土样在单向冻结过程中冷生构造的发育和冻胀变形的发展规律,得到以下结论：试样冻结稳定所需时间为26 h左右,基本不受顶板温度变化的影响,但土样冻结后形成不同冷生构造带的位置及薄厚与土样顶板温度（顶底板温度梯度）密切相关,顶板温度越低,微薄层状和薄层状构造带的厚度越大,最暖端厚层冰透镜体以及未冻土部分整体状构造带的厚度越小。研究结果还表明,土样的冻胀变形经历了快速冻胀、稳定冻胀和线性冻胀3个阶段,其中线性冻胀阶段是冻胀发展最快的阶段,也是冰透镜体生长最快的阶段。研究成果揭示了土样单向冻结过程中冷生构造发育和冻胀发展的动态过程,为冻胀机制的认识以及冻胀模型的建立与验证提供了试验基础。     

Analysis of soil–pile–structure interaction in a two‐layer ground during earthquakes considering liquefaction

This study is conducted with a numerical method to investigate the seismic behaviour among certain soils, single piles, and a structure. A series of numerical simulations of the seismic behaviour of a single‐pile foundation constructed in a two‐layer ground is carried out. Various sandy soils, namely, dense sand, medium dense sand, reclaimed soil, and loose sand, are employed for the upper layer, while one type of clayey soil is used for the lower layer. The results reveal that when a structure is built in a non‐liquefiable ground, an amplification of the seismic waves is seen on the ground surface and in the upper structure, and large bending moments are generated at the pile heads. When a structure is built in a liquefiable ground, a de‐amplification of the seismic waves is seen on the ground surface and in the upper structure, and large bending moments are generated firstly at the pile heads and then in the lower segment at the boundary between the soil layers when liquefaction takes place. Copyright © 2007 John Wiley & Sons, Ltd.