Utilizing glacial geology in uranium exploration; Dismal Lakes, Northwest Territories, Canada

A field of uraniferous boulders was discovered in a drift-covered valley west of Dismal Lakes. Glacial geological information was combined with boulder location and trace element till geochemical data to model the dispersal of the boulders; and to predict their likely bedrock source. Uraniferous bedrock was eroded by the last, westward flowing glacial ice to cover the area. The debris was englacially transported and subsequently deposited during subglacial melt-out of ice block(s) stagnating below active ice. The distribution of the boulders forms acrude, westward-opening fan centred on the easternmost boulder and oriented with the last ice-flow direction. The largest uranium values from surface till samples (-2 μm fraction) occur 6.2 km east of the main boulder concentration or 1.5 km east of the first boulder occurrence. The likely bedrock source is 6.0 to 6.6 km east of the main boulder concentration.     

Overburden geochemistry related to W-Cu-Mo mineralization at Sisson Brook, New Brunswick, Canada: An example of short- and long-distance glacial dispersal

In 1982 and 1983 a surficial geology and overburden geochemistry survey was carried out on the Sisson Brook Mining Licence in York County, about 55 km northwest of Fredericton, New Brunswick, Canada.On the Sisson Brook Mining Licence three zones of W-Mo-Cu mineralization have been outlined; Zones I and II contain mainly wolframite with chalcopyrite and pyrrhotite, whereas Zone III has mainly scheelite and molybdenite.The glacial history of the area was studied during 1982 and 1983 to provide a framework for interpreting the geochemical results. Ice movement varied from 160° ± 10° towards the south during the Main Bantalor phase (maximum ≈ 13,500 y.B.P.) to 130° ± 10° toward the southeast during the Late Bantalor phase. Rapid changes in dominant pebble lithologies occur immediately upon crossing bedrock contacts. This suggests a very short distance of transport on the property. The glacier, butted against the Nashwaak Ridge, quickly sheared bedrock debris up into the body of the ice by compressive flow. Upon melting, some of this debris was deposited a short distance from source. Some debris appears to have been sheared up higher into the ice sheet, transported over the Nashwaak Ridge, and deposited approximately 8 km down-ice with no interconnecting dispersal train.In 1982, a geochemical orientation survey was carried out to determine which element(s) and sample medium could best and most economically be used in the search for W-Mo-Cu mineralization. Within the property area, both whole till <2000 μm (−10 mesh) samples and heavy mineral concentrates clearly defined the zones of mineralization (W, Mo, Cu) and associated geochemical dispersal trains (W, Mo, Cu, As, F). In later work, samples were not analyzed for As and F because this provided no additional information. The geochemical contrast between values in whole till samples derived from subcropping mineralization and those derived from barren bedrock is adequate to outline mineralization. Geochemical analysis of the whole till was used in later work because the sample preparation costs are considerably lower than those for heavy-mineral concentrates. Soils were not used because trace element patterns were diffuse, with the highest values occurring at variable distances down-ice from mineralization.In 1983, the objective was to better define glacial dispersal from the known mineralization and to explore for additional mineralization. Data from this program indicates a W dispersal train in whole till samples 300–400 m long. Tungsten values up to 1400 ppm and Mo values up to 260 ppm in whole till occur immediately down-ice from the main subcropping W-Mo mineralization. The element associations (i.e. W-Mo-Cu and W-Mo) in the till reflect the elemental composition of the source mineralization (i.e. Zones I and II and Zone III).Backhoe trenching is a useful and cost-effective technique to expose Quaternary sediments. Examination of the overburden sections provides an understanding of the glacial history which aids in tracing geochemical dispersal trains up-ice to bedrock source.     

Geological factors affecting the distribution of trace metals in glacial sediments of central Newfoundland

 In central Newfoundland (NTS 12A/10, 15, 16, 2H/1), As, Pb, and Zn concentrations in the clay-sized (<0.002 mm) and silt and clay-sized (<0.063 mm) fractions of till reflect compositional differences among and within rock terranes at scales of kilometers to tens of kilometers. In those fractions, till derived from volcanic bedrock of Victoria Lake Group (Tulks Hill) is notably enriched in As (50–>1000 ppm), exceeding levels commonly set for purposes of environmental protection. Near Pb-Zn mines at Buchans, geochemical variation with depth reflects the dispersal of detritus from mineralized bedrock, and differences in sediment type and provenance. There, surface sediments are rich in granitic debris derived from the Topsails igneous terrane 5 km north of Buchans and contain low concentrations of trace metals. These sediments are compositionally unrelated to either Buchans Group volcanic rock or an underlying, older till enriched in sulphide minerals and trace metals. Metal-rich till extending up to 10 km southwest of Buchans results from combined glacial and debris flow transport related to two distinct geological events. Trace metals are enriched (two- to fourfold) in the clay-sized fraction of till compared to the silt and clay-sized, and are associated with Al- and Mg-bearing minerals that preferentially concentrate in the clay fraction. The geochemistry of the silt and clay-sized fraction can approximate that of the <2-mm fraction. Background variations in till illustrate the important role of a geological framework to the interpretation of geochemical surveys and the origins of trace metals in the environment. Received: 31 October 1996 · Accepted: 27 May 1997     

The Las Cuevas deposit, Almaden district (Spain): An unusual case of deep-seated advanced argillic alteration related to mercury mineralization

The Hercynian mercury mineralization of Las Cuevas is hosted by a highly folded and sheared sequence of basalts, intrusive breccias, slates, psamitic rocks and quartzites. The mineral paragenesis is simple and consists of cinnabar, native mercury and pyrite. Hydrothermal alteration can be divided into `proximal' and `distal' with respect to the mineralized bodies. The proximal alteration (≤1.3 m wide) consists of quartz-pyrophyllite-kaolinite, quartz-pyrophyllite-(kaolinite)-(illite), and quartz-illite-(pyrophyllite)-(kaolinite). The distal alteration (∼100 m wide) consists of (quartz)-illite-chlorite-(pyrophyllite), or rectorite-(chlorite). These assemblages overprint an earlier, regional alteration consisting of quartz-chlorite-albite-carbonates (±ankerite, ±siderite, ±magnesite, ±calcite). The mercury deposit of Las Cuevas can be regarded as an unusual combination of mercury deposition and advanced argillic alteration within a relatively deep environment (≥1.8 km). Received: 3 February 1998 / Accepted: 8 June 1998     

Physical partitioning of mercury in till: an example from central British Columbia, Canada

The physical partitioning of Hg into different grain size fractions of till is predominantly controlled by the primary bedrock mineralogy, the distance of glacial transport, and the relative stability of cinnabar (HgS) in the soil weathering environment. At sites located short distances down-ice from bedrock cinnabar mineralization, the highest Hg concentrations in unoxidized till were measured in the sand- and granule-sized fractions reflecting the abundance of cinnabar in those size ranges. Similar partitioning was measured in oxidized till as cinnabar was found to be relatively resistant to postglacial weathering. Discrete clay-sized cinnabar grains obtained from the unoxidized till were viewed under the scanning electron microscope and suggest that the terminal grade of cinnabar is in the clay-sized range. In till collected from areas barren of cinnabar mineralization, the highest Hg levels were found in the clay-sized fraction which is attributed to the high adsorption of Hg by clay minerals.     

Distribution and type of sticky spots at the centre of a deglacial streamlined lobe in northeastern Manitoba,Canada

The distribution of basal drag zones (sticky spots) underneath palaeo‐ice streams or lobes is largely unknown. We investigated the centre of the large (300 km long and up to 400 km wide) deglacial Hayes Lobe in NE Manitoba, Canada, by focusing on surficial till and its composition to get insights into dispersal patterns and their potential relationships to areas of basal drag. Subglacial bed roughness is a good criterion to identify areas of basal drag, but till composition may provide important insights across smoother beds. The onset zone of the Hayes Lobe overlies Palaeozoic Carbonate Platform rocks, whereas the majority of the lobe overlies the low‐lying Canadian Shield. We show that, within a 3500‐km² central area of this lobe, calcareous detritus within the till has been transported over 100 km within subglacial environments of reduced ice‐bed coupling and fast ice flow. Six per cent of samples (n = 782), however, outline 0.2 to 4 km wide spots with a dominantly local composition. The glacial history and composition indicate that the till within these spots contains high inheritance from a pre‐Late Wisconsinan ice‐flow phase, which we suggest was protected beneath sticky spots (low erosion, high strength) during transport of substantial calcareous detritus to the area. Furthermore, our findings show that local till spots are present within streamlined landforms, as well as till blankets or veneers over bedrock. This diverse geomorphology indicates that the process of drumlinization within the deglacial Hayes Lobe does not appear to have been responsible for significant sediment transport or deposition across the study area. The overall record thus indicates potentially complex spatiotemporal shifts between calcareous till deposition, sticky conditions, erosion and drumlinization – which supports the subglacial bed mosaic model.     

Till mélange at Amsdorf, central Germany: sediment erosion, transport and deposition in a complex, soft-bedded subglacial system

Glacial mélange in the open-cast mine at Amsdorf, central Germany, consists of several square meters of large, sorted sediment blocks embedded in till. The blocks are composed of largely intact to slightly deformed glaciofluvial and glaciolacustrine sand, silt and clay, initially deposited in a proglacial lake (2–3 km up-ice) and subsequently overridden by a glacier. The blocks typically have cuboid to subrounded outlines, are randomly distributed in the till, and the contacts with the surrounding till are distinctly sharp. Underneath the mélange are varved clays which exhibit strong deformations occasionally intervening with entirely undisturbed areas. It is suggested that the blocks were entrained into debris-rich basal-ice by bulk freeze-on when the glacier sole was lowered onto the bottom of an overridden lake. After entrainment the blocks were transported englacially and re-deposited (with far-traveled till matrix) as a melt-out till from stagnant ice. The glacier moved mainly by sliding enhanced by low-permeability varved clays in the substratum. The glacier is believed to have been of a polythermal type. These results show that bulk freeze-on can lead to entrainment of soft sediment blocks at least 20 m² in size, and that these blocks can be englacially transported with little or no deformation for several kilometers and more. The occurrence of deformed and undeformed clays under the till mélange indicates a possible mosaic of coupled and decoupled ice, the latter caused by a thin, transient subglacial water film separating the bed from the glacier.     

Deglaciation chronology inferred from marine sediments in a proglacial lake basin, western Spitsbergen, Svalbard

Sub-bottom sediment profiles and sediment cores show that the lacustrine sediments in lake Linnevatnet are underlain by marine sediments and a basal till that mantles the bedrock. The till was probably deposited by the glacier that during the Late Weichselian glacial maximum removed all pre-existing sediments from the basin. The cores were collected in closed basins, where continuous deposition is expected. The marine sediment in the studied cores is up to 8 m thick and consists of bioturbated clay and silt. Radiocarbon dates on shells from the base of the marine sequence suggest that glacial retreat from the lake basin occurred around 12,500BP. This is more than a thousand years older than basal shell dates from raised marine sediments on the slopes above the lake. Typical ice proximal litbofacies were not identified in the cores. stratigraphic record indicates both a rapid glacial retreat and that no younger glacial re-advances occurred. During the Younger Dryas local glaciers on western Svalbard were smaller than during the Little Ice Age. This is in sharp contrast to western Europe, where Younger Dryas glaciers were much larger than those the Little Ice Age.     

End moraine construction by incremental till deposition below the Laurentide Ice Sheet: Southern Ontario,Canada

Eyles, N., Eyles, C., Menzies, J. & Boyce, J. 2010: End moraine construction by incremental till deposition below the Laurentide Ice Sheet: Southern Ontario, Canada. Boreas, 10.1111/j.1502‐3885.2010.00171.x. ISSN 0300‐9483. Just after 13 300 ¹⁴C a BP in central Canada, the retreating Ontario lobe of the Laurentide Ice Sheet briefly re‐advanced westwards through the Lake Ontario basin to build a large end moraine. The Trafalgar Moraine (27 km long, 4 km wide) is composed of a distinctly red‐coloured silt‐rich till (Wildfield Till, up to 16.5 m thick) formed by the reworking of proglacial lake deposits and soft shale bedrock. The moraine has a pronounced ramp‐like longitudinal form passing upglacier into fluted till resting on exposed shale. Analysis of water well stratigraphic data, drilled sediment cores, downhole gamma‐ray logs and exposures in deep test pits shows that within the moraine the Wildfield Till is built of superposed beds up to 7 m in thickness. These are inferred to result from the repeated incremental deposition of fine‐grained debris being moved towards the ice margin as a deforming bed such as identified at modern glaciers. A total till volume of 0.81 km³ was produced in a very brief time‐span along a transport path probably no greater than 10 km in length. Subglacial mixing of pre‐existing sediment and soft shale was clearly a very effective process for generating and moving large volumes of till to the ice margin. Similar till‐dominated end moraines occur widely around the margins of the Great Lake basins, where the markedly lobate margin of the retreating Laurentide Ice Sheet re‐advanced repeatedly into proglacial lakes and over fine‐grained sediment. This suggests the wider applicability of the till transport and incremental depositional model presented here.     

Heavy metal concentrations in shallow marine sediments affected by submarine tailings disposal and artisanal gold mining,Buyat-Ratototok district,North Sulawesi,Indonesia

Trace element concentrations in shallow marine sediments of the Buyat-Ratototok district of North Sulawesi, Indonesia, are affected by submarine disposal of industrial gold mine tailings and unregulated dumping of tailings and wastewater from small-scale gold mining using mercury amalgamation. Industrial mine tailings contained 590–690 ppm arsenic, 490–580 ppm antimony, and 0.8–5.8 ppm mercury. Tailings-affected sediment As and Sb concentrations were 20–30 times higher than in muddy sediments not contaminated with tailings, and 50–60 times higher than pre-mining average. Highest mercury concentrations were observed in sediments affected by small-scale mining using mercury amalgamation (5–29 ppm). Concentrations of most other trace elements were comparable in sediments affected by both types of mining and were slightly higher than regional averages for sediments collected before the onset of industrial mining. Elevated concentrations of both As and Sb in approximately equal proportions suggest tailings dispersal of at least 3.5 km. Mercury released from artisanal gold mining dispersed up to 4 km from river mouths. Slight increases in concentrations of non-mercury trace elements in areas affected by artisanal mining over pre-industrial mining concentrations were probably caused by increased rates of erosion. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

Carbonate dispersal trains, secondary till plumes, and ice streams in the west Foxe Sector, Laurentide Ice Sheet

Regional carbonate dispersal trains cross Melville Peninsula in the northeastern Canadian Arctic. These trains are 50-125 km across and 100-300 km long. The northern dispersal train crosses upland and lowland areas, while the Rae Isthmus train follows the lowlands. The distribution of carbonate in boulder, pebble and matrix till fractions indicates long-distance glacial transport of limestone, a low rate of dilution, and comminution from pebble to silt sizes. Dispersal patterns and geotechnical properties of the till suggest deforming bed and basal gliding mechanisms of ice flow associated with ice-streaming. Regional ice streams may have been 'normative' in carbonate terrain during the main Foxe (Wisconsin) Glaciation. Till plumes within regional dispersal trains, showing little dilution of carbonate down-ice from bedrock sources, are oriented towards lowlands. These features, sharp-edged and 300 mwide, mark zones of augmented flow. They are late-glacial features that formed after calving bays developed in Committee Bay. The dimensions of the dispersal trains, and ice-flow styles and mechanisms, are similar to those of modern Antarctic ice streams. The sharp edges of till plumes may delineate flow boundaries marked by lateral crevasse zones in the late-glacial ice sheet. Secondary streams-within-ice streams have not been reported previously in the literature.     

Regional reconstruction of subglacial hydrology and glaciodynamic behaviour along the southern margin of the Cordilleran Ice Sheet in British Columbia,Canada and northern Washington State,USA

Subglacial landsystems in and around Okanagan Valley, British Columbia, Canada are investigated in order to evaluate landscape development, subglacial hydrology and Cordilleran Ice Sheet dynamics along its southern margin. Major landscape elements include drumlin swarms and tunnel valleys. Drumlins are composed of bedrock, diamicton and glaciofluvial sediments; their form truncates the substrate. Tunnel valleys of various scales (km to 100s km length), incised into bedrock and sediment, exhibit convex longitudinal profiles, and truncate drumlin swarms. Okanagan Valley is the largest tunnel valley in the area and is eroded >300 m below sea level. Over 600 m of Late Wisconsin-age sediments, consisting of a fining-up sequence of cobble gravel, sand and silt fill Okanagan Valley. Landform–substrate relationships, landform associations, and sedimentary sequences are incompatible with prevailing explanations of landsystem development centred mainly on deforming beds. They are best explained by meltwater erosion and deposition during ice sheet underbursts.During the Late-Wisconsin glaciation, Okanagan Valley functioned as part of a subglacial lake spanning multiple connected valleys (few 100s km) of southern British Columbia. Subglacial lake development started either as glaciers advanced over a pre-existing sub-aerial lake (catch lake) or by incremental production and storage of basal meltwater. High geothermal heat flux, geothermal springs and/or subglacial volcanic eruptions contributed to ice melt, and may have triggered, along with priming from supraglacial lakes, subglacial lake drainage. During the underburst(s), sheetflows eroded drumlins in corridors and channelized flows eroded tunnel valleys. Progressive flow channelization focused flows toward major bedrock valleys. In Okanagan Valley, most of the pre-glacial and early-glacial sediment fill was removed. A fining-up sequence of boulder gravel and sand was deposited during waning stages of the underburst(s) and bedrock drumlins in Okanagan Valley were enhanced or wholly formed by this underburst(s).Subglacial lake development and drainage had an impact on ice sheet geometry and ice volumes. The prevailing conceptual model for growth and decay of the CIS suggests significantly thicker ice in valleys compared to plateaus. Subglacial lake development created a reversal of this ice sheet geometry where grounded ice on plateaus thickened while floating valley ice remained thinner (due to melting and enhanced sliding, with significant transfer of ice toward the ice sheet margin). Subglacial lake drainage may have hastened deglaciation by melting ice, lowering ice-surface elevations, and causing lid fracture. This paper highlights the importance of ice sheet hydrology: its control on ice flow dynamics, distribution and volume in continental ice masses.     

Environmental impact of mining waste disposal on a tropical lowland river system: a case study on the Ok Tedi Mine, Papua New Guinea

The 1000 km long Ok Tedi/Fly River system receives about 66 Mt/year of mining waste from the Ok Tedi copper-gold porphyry mine. Mine input has increased the suspended sediment load of the Middle Fly River about 5–10 times over the natural background. A significant yet unknown amount of copper-rich material deposits unevenly in the extensive tropical lowland floodplain. Recent alluvial sediments of the Fly River floodplain have copper contents of 620 mg/kg (±1σ: 430–900), whereas the regional background is 40 mg/kg (±σ: 25–60). This pattern is mirrored and enhanced by the gold dispersal pattern with a 7 ppb Au background versus a 140–275 ppb population in mine-derived material. Very high deposition rates (around 4 cm/y) of mine-derived sediment were determined in locations close to the creeks and channels which link the Fly River with the outer floodplain. A thin layer of 1–5 cm of copper-rich material (400–900 mg/kg Cu) was usually found on the bottom of drowned (tributary) valley lakes. Average dissolved copper content in waters of the inner floodplain is around 9 μg/l (±1σ: 5–14) as compared to unpolluted water from the outer floodplain with < 2 μg/l Cu. The present Fly River water, about 600 km downstream of the mine site, has concentrations of 17 ± 3 μg/l dissolved Cu. Received: 30 June 1996 / Accepted: 9 January 1997     

Contamination of two Oregon reservoirs by cinnabar mining and mercury amalgamation

 Two reservoirs in western Oregon contain mercury-contaminated sediment and fish as a result of historic mercury mining in the Cottage Grove Lake watershed and mercury amalgamation used in gold mining in the Dorena Lake watershed. On average, sediment in Cottage Grove Lake contains ten times as much mercury as sediment from Dorena Lake (2.720 versus 0.242 ppm). Mercury content in Cottage Grove Lake sediment shows a sharp initial decrease and leveling off with time that reflects the end of the major cinnabar mining phase; deposition of other heavy metals appears to be linked to the clay content of sediment. Mercury input to Dorena Lake has remained fairly constant with time, but small increases in mercury are associated with the deposits of large floods. Copper, lead, and zinc input to Dorena Lake exhibits a marked decrease and leveling off related to the end of commercial mining for these metals. Received: 12 October 1999 · Accepted: 22 March 2000     

The chemical and physical characteristics of heavy metals in humus and till in the vicinity of the base metal smelter at Flin Flon, Manitoba, Canada

 Trace element geochemistry of humus (<0.425 mm) and till (<0.002 mm) collected in the Flin Flon-Snow Lake area, northern Manitoba and Saskatchewan, provides a regional context for assessing smelter contamination in the environment. The area includes a Cu-Zn smelter known to discharge As, Cd, Cu, Fe, Hg, Pb, and Zn. In this study, sequential extraction analyses, scanning electron microscopy and x-ray diffraction analyses were used on a suite of samples to determine: (1) the chemical and physical characteristics of heavy metals in surficial sediments related to distance from the smelter, (2) criteria for assessing the relative contribution of these metals from natural and anthropogenic sources, and (3) the potential of these metals for remobilization in the environment. Humus geochemistry reflects the anthropogenic and natural component of heavy metal concentrations. Smelter-related elements show anomalously high values adjacent to the smelter, decreasing with distance until background values are reached at 70–104 km, depending on the element. In humus, Zn is associated primarily with labile phases; Hg with non-labile phases. Adjacent to the smelter, high proportions and concentrations of Zn and Hg in non-labile phases, indicative of smelter-derived particulates, are confirmed by SEM examination. The particles occur as spheres, irregular grains, and with organics. With increasing distance from the smelter, the geochemical response to bedrock composition is more obvious than the anthropogenic input. Till geochemistry reflects the natural variation imposed by bedrock composition. At highly contaminated sites (<3 km from the smelter), increased percentages of smelter-related elements in labile phases suggests heavy metals are leached from humus to the underlying sediment. Received: 5 November 1996 · Accepted: 31 March 1997     

Sedimentary rock-hosted gold mineralization at Zalaa Uul, Khentii Range, northeastern Mongolia

The recently discovered Zalaa Uul occurrence exhibits gold concentrations averaging about 1 ppm in silicified breccias as wide as 100 m. Most mineralization is hosted in brecciated siltstone, shale, and calcareous sandstone of the Permian Ulz Formation that exhibits multiple stages of silicification. Rock geochemistry indicates: (1) gold is strongly associated with arsenic and silver; (2) antimony, tellurium and thallium are locally anomalous but poorly correlated with gold; (3) mercury is spatially correlated with copper; and (4) Ag:Au ratios are low (≤3). A low-level Cu–(Hg + Sb, ±Au + As) anomaly occurs over an hypothesized feeder breccia. The feeder breccia occupies a major northwest-dipping reverse fault zone between dominantly greenschist-facies phyllite and schist of the Upper Proterozoic Toshint Formation and unmetamorphosed marine clastic rocks of the permian Ulz Formation. Ground magnetometer surveys identified a magnetic body, thought to represent part of an intrusive complex at depth, within the reverse fault zone, down-plunge from the ∼70° northwest-dipping feeder breccia. Altered rhyolite dikes crop out in the vicinity of the feeder breccia. The potentially economic gold grades are 2 to 3 km outboard of the feeder breccia and may represent the distal Au + As zone of an intrusion-related mineralizing system. Alteration, regional structural and geophysical setting, host rocks and trace element geochemistry, and finely disseminated nature of gold particles are similar to Carlin-type gold systems in the Great Basin of the western USA, but local geology, magnetically mapped intrusive bodies, and trace element zonation suggest affinity with some intrusion-related gold systems. Received: 28 February 1999 / Accepted: 3 March 2000     

Mercury-tainted overbank sediment from past gold mining in north Georgia, USA

 Gold was discovered in 1829 and mined until about 1940 in north Georgia, particularly within an area known as the Dahlonega mining district. The mining operations there, which involved mercury amalgamation in stamp mills and sluices, delivered significant quantities of mercury waste to streams. This paper focuses on the downstream dispersal and storage of mercury in streambank sediments of two watersheds near Dahlonega, Georgia. Mercury concentrations for individual samples of historical sediment range from 0.02 to 12.00 ppm, with average values in streambanks near the core of the mining district ranging from 0.2 to 0.6 ppm. Mercury levels rapidly decrease in the downstream direction to concentrations that are slightly above a background level of 0.04±0.02 ppm. Mercury concentrations also appear to decrease with increasing distance from streambanks. Similar levels of mercury contamination from former gold mines probably exist in many other parts of the gold-bearing rocks of the Piedmont of the eastern United States. The bioavailability and environmental hazard posed by the contaminated sediment is not certain. Received: 8 January 1996 · Accepted: 29 May 1996     

Gold mineralization in the Mazowe area, Harare-Bindura-Shamva greenstone belt, Zimbabwe: II. Genetic relationships deduced from mineralogical, fluid inclusion and stable isotope studies, and the Sm-Nd isotopic composition of scheelites

In the Mazowe area some 40 km NW of Harare in Zimbabwe, gold mineralization is hosted in a variety of lithologies of the Archean Harare-Bindura-Shamva greenstone belt, in structures related to the late Archean regional D2/3 event. Conspicuous mineralzogical differences exist between the mines; the mainly granodiorite-hosted workings at Mazowe mine are on pyrite-rich reefs, mines of the Bernheim group have metabasalt host rocks and are characterized by arsenopyrite-rich ores, and Stori's Golden Shaft and Alice mine, both in metabasalts, work sulfide-poor quartz veins. In contrast to the mineralogical diversity, near-identical fluid inventories were found at the different mines. Both H₂O-CO₂-CH₄ fluids of low salinity, and highly saline fluids are present and are regarded to indicate fluid mixing during the formation of the deposits. Notably, these fluid compositions in the Mazowe gold field markedly contrast to ore fluids “typical” of Archean mesothermal gold deposits on other cratons. Stable isotope compositions of quartz from the various deposits (δ¹⁸O=10.8 to 13.2‰ SMOW), calcite (δ¹⁸O=9.5 to 11.9‰ SMOW and δ¹³C=−3.2 to −8.0‰ PDB), inclusion water (δD=−28 to −40‰ SMOW) and sulfides (δ³⁴S=1.3 to 3.2‰ CDT) are uniform within the range typical for Archean lode gold deposits worldwide. The fluid and stable isotope compositions support the statement that the mineralization in the Mazowe gold field formed from relatively reduced fluids with a “metamorphic” signature during a single event of gold mineralization. Microthermometric data further indicate that the deposits formed in the PT range of 1.65–2.3 kbar and 250–380 °C. Ages obtained by using the Sm/Nd and Rb/Sr isotope systems on scheelites are 2604 ± 84 Ma for the mineralization at Stori's Golden Shaft mine, and 2.40 ± 0.20 Ga for Mazowe mine. The Archean age at Stori's is regarded as close to the true age of gold mineralization in the area, whereas the Proterozoic age at Mazowe mine probably reflects later resetting. Received: 30 September 1998 / Accepted: 17 August 1999     

Environmental mercury and arsenic sources in fossil hydrothermal systems, Northland, New Zealand

 Northland, New Zealand has been affected by natural hot water spring systems depositing elevated concentrations of mercury and arsenic over the past 5 million years. Due to the different erosion levels of these hot water systems, four principal types of mercury and arsenic occurrences are found: active hot springs; layered surface deposits (sinters) deposited by hot springs; highly fractured rock zones formed immediately beneath hot springs; and chemically altered and mineralized rock from the deeper roots of hot spring systems. Mercury occurs principally as cinnabar and as a minor impurity (<1 wt%) in phosphate minerals and iron sulfides, particularly marcasite. Mercury is irregularly distributed through limonitic cements formed during oxidation. Arsenic occurs as a minor impurity (<1 wt%) in phosphate minerals and iron sulfides, particularly marcasite. Arsenic is also variably dispersed through limonite, but not necessarily with mercury. Decomposition of marcasite constitutes the most significant source of mercury and arsenic pollution from the studied sites. Release of mercury and arsenic into the environment from marcasite, phosphates and limonite is enhanced by acidification of the sites (down to pH of 2), caused by oxidation of iron sulfides. Mercury and arsenic concentrations of up to 100 parts per billion should be expected in waters near the deposits; these concentrations are in excess of recommended drinking water levels. Received: 9 April 1999 · Accepted: 2 August 1999