铜镍矿床地球化学模式的应用——在贵州西部寻找隐伏铜镍矿床（含矿岩体）的探讨

根据已建立的铜镍矿床地球化学模式,通过对区域化探地球化学数据(Cu、N i、Co、Cr、Ag、B、Ba、As等元素)处理、分析、综合研究,认为在贵州威宁黑石镇—哲觉镇地区有可能找到隐伏铜镍矿床(含矿岩体)。     

遵义牛蹄塘组黑色岩系中多元素富集层的主要矿化特征

在对大量数据进行系统分析的基础上，将贵州遵义下寒武牛蹄塘组黑色岩系中多元素富集层矿化元素按富集系数分为三组。超富集元素：富集系数大于1000，包括Mo、As、Se、Re等；强富集元素：富集系数介于100～1000，包括Ni、U、Au、Ag、Pt、Pd、Tl等；弱富集元素：富集系数近于5～100，包括V、Co、Cu、Pb、Zn、Y、Cd等。结合上述元素的地球化学性质和矿化岩石类型，指出贵州牛蹄塘组多元素富集层综合了岩浆作用、热水沉积和机械沉积作用的特点，是深部岩浆活动强烈喷发期的产物，提出了可能的成矿模式：早期岩浆(火山)活动伴随热水沉积，形成磷块岩(和硅质岩)；中期岩浆活动减弱，表现为剥蚀沉积；晚期火山爆发，除大量射气元素的富集，还带出深部的成矿物质，然后通过水流机械富集成矿。     

我国东部平原土壤微量元素共生组合特征及含量预测

对我国东部平原土壤微量元素共生组合特征及含量预测的研究表明，第四周期过渡元素之间、亲铜元素之间具有较好的相关关系；采用Logistic生长曲线处理的结果表明，在我国华北平原及其周围地区可对土壤的微量元素含量作出较为准确的预测，而在长江及其以南地区，只能得出大致的含量估计。     

红透山式块状硫化物铜锌矿床地球化学特征及找矿意义

产于辽宁省清原地区太古宙花岗-绿岩地体中的红透山式块状硫化物铜锌矿床，具有独特的地球化学特征。以往应用微量元素、稀土元素、同位素、岩石化学等地球化学特征，在原岩恢复、时空演化、矿床成因等基础地质研究中发挥了重要作用。通过该类矿床地层(矿体)中微量元素、卤族元素、汞元素、硫同位素及容矿岩石的岩石化学等地球化学特征的研究，提出了其对清原地区寻找红透山式块状硫化物铜锌矿床的地质找矿意义。     

基于成分数据分析和多重分形滤波技术识别青海红垭豁地区地球化学异常

红垭豁地区位于青藏高原东北缘，秦祁昆晚加里东造山系中祁连构造带内，区内岩浆岩分布广泛，成矿条件优越。为有效提取矿致地球化学异常，本文采用主成分分析(PCA)和多重分形模型(S-A)方法对研究区沟系641件土壤样品异常进行了提取及ilr(对数比)变换，并结合密度曲线及箱线图，对比三类数据(原始、对数、ilr变换)元素的多元统计含量特征，运用S-A提取研究区地球化学异常及背景。结果显示，ilr变换后数据消除了数据闭合效应，元素含量更接近正态分布。主成分分析得到2类不同的元素组合，PC1为Cu、Fe、Mn、Ni、Pb、Zn元素组合，即中高温热液成矿元素组合形式，代表与侵入体和断裂有关的Cu-Pb-Zn多金属矿化，反映了铜多金属矿成矿过程的叠加；PC2为Au、As、Sb元素组合，代表与金锑矿化有关的低温热液活动。PC1分解图显示，PC1低背景、高异常主要分布在安山岩地层中，且周围附近有中酸性侵入岩及构造破碎带，为铜多金属矿提供物质来源，经异常查证，发现铜矿体1条。研究认为，红垭豁地区具有良好的找矿潜力，S-A所圈定的综合异常可为下一步的地质找矿工作提供依据。     

亲铜(亲铁)元素含量比值在地球科学中的初步应用实例

亲铜(亲铁)元素在行星增生演化、核幔分异、地幔岩浆过程、壳幔相互作用以及金属矿床成因等领域具有举足轻重的作用。本文从亲铜元素的地球化学性质出发,介绍了"高维度思维"的亲铜元素含量比值及其在地球科学领域的初步应用:①获得同一份样品中不同亲铜元素含量可在一定程度上降低样品的不均一性(块金效应)对含量比值的影响;②Cu/Ag值可以约束不同高温岩浆过程中硫化物固液状态和亲铜元素地球化学性质,进而认识地幔、洋壳和大陆地壳间的联系;③具有不同分配系数的亲铜元素含量的比值可以鉴别岩浆硫化物饱和史,比如通过亲铜元素的分异约束火星陨石母岩浆的硫化物不饱和演化历史;④依据In-Cd-Zn在硅酸盐地球的含量以及它们的相对亲铜亲铁性质,地球主体增生物质已经消失,不能由陨石代表。     

西秦岭铜矿区域地球化学研究

对西秦岭地区4种主要成因类型铜矿的区域地球化学研究证明,在2个铜矿床或矿(化)点上很少显示铜或其它元素的浓集区.通过对甘肃南部碧口群分布地区主要铜矿产出的地球化学环境的分析认为,西秦岭地区各类型铜矿指示元素反映的是相应铜矿类型的区域地质建造,最佳指示元素则反映的是含矿地质建造.碧口群分布区的已知具规模的铜矿床及新探明的伐子坝中型铜矿均位于本区火山喷发沉积型铜矿的最佳指示元素所指示的有利部位.     

山西省阳高县堡子湾金矿床矿物标型特征

根据成因矿物学及找矿矿物学观点，系统研究堡子湾金矿床黄铁矿、金矿物、方铅矿、黄铜矿和闪锌矿等金属矿物，石英、碳酸盐、绢(白)云母和金红石等非金属矿物的产状、形态及化学成分标型，结果表明：①矿床中矿物组合复杂，硫化物种类多，有少量硫盐矿物出现；②矿物中微量元素成分复杂，富含As，Sb，Bi，Se，Te等Au活化、迁移有利的矿化搬运剂，Cu，Ph，Zn，Au，Ag等成矿元素和Cr，Ni，V等深源元素；元素矿物组合及其特征比值指示金矿化与深源(下地壳或上地慢)浅成岩浆热液活动(斑岩系统)有关，燕山期石英二长斑岩(角砾岩)是成矿的主导因素；③矿石中大量出现铁白云石、富铁闪锌矿，粒状、富Ti金红石的大量分布，反映矿床剥蚀深度较大，目前可能已揭露至中深部中温带，位于斑岩系统的中下部，深部金矿化不利；④矿石含丰富的铜矿物，其他硫化物矿物中含铜量大，指示深部可能存在斑岩型Cu(Au)矿化。     

蒙甘新相邻(北山)地区金铜矿床时空分布特征及成矿作用

文章首次对蒙甘新相邻(北山)地区各类金、铜和铜—镍矿床(点)地质特征、成因类型和空间分布特点进行了系统总结，论证了金、铜和铜—镍成矿作用与古生代岩浆活动的关系，对区域地壳演化过程中金、铜和铜—镍成矿的动力学机制进行了深入讨论。研究结果表明，该区的金矿床(点)大体可划分为变质岩型、火山岩型、斑岩型和深成侵入岩型；铜矿床(点)有斑岩型、夕卡岩型和铜—镍硫化物型。金和铜矿床(点)大都沿古板块汇聚带分布，与海西期火成岩具密切的时空分布关系，它们是古板块对接碰撞期和碰撞期后大规模构造—岩浆活动的产物。     

铜陵地区微量元素铊与金在成矿中的相关性初步探讨

古铜陵地区是长江中下游成矿中重要的多金属成矿区,有着独特的多位一体、"层".带"结合、多矿种、多种成因类型复合的成矿地质环境,产生了丰富的接触交代与层控式夕卡岩-热液充填交代的块状硫化物型的铜、金、银、硫等内生矿产,成为国内外地学研究的热点地区.本文从铊元素的地球化学研究探寻其作为金(铜)矿床的探途元素的可能,从本区一些主要矿床中过铊与金(铜)相关性的研究,得出铊与金(铜)密切正相关的结论,并进行了微量元素铊在找矿方面应用的一些初步探读者论坛,指出下一步找矿方向及预测靶区.     

Lead isotopic systematics for native copperchalcocite mineralization in basaltic lavas of the Emeishan large igneous province, SW China： Implications for the source of copper

The Emeishan continental flood basalt, which is widespread in Yunnan, Guizhou and Sichuan provinces of Southwest China, is the volcanic product of a Permian mantle plume, and native copper-chalcocite mineralization associated with the basalt is very common in the border area of Yunnan and Guizhou provinces. The mineralization occurred in the tuff intercalation and terrestrial sedimentary rock intercalation which were formed during the main period of basalt eruption. The orebodies are controlled by the stratigraphic position and faults. Metal ore minerals in the ores are mainly native copper, chalcocite and tenorite, with small amounts of chalcopyrite, bomite, pyrite and malachite, and sometimes with large amounts of bitumen, carbon and plant debris. Several decades of ore deposits are distributed in the neighboring areas of the two provinces, while most of them are small-scale deposits or only ore occurrences. By comparing the lead isotopic composition of the ores with that of the wall-rocks, cover and basement rocks of various periods, the source of copper in this type of ore deposits was studied in this paper. The results showed that: (1) The Pb isotopic composition of the ores from ten deposits is absolutely different from that of sili-ceous-argillaceus rocks of the Upper Permian Xuanwei Formation, limestones of the Lower Permian Series and Carboniferous, Cambrian sandstone-shale and recta-sedimentary rock and dolomite from the upper part of the Meso-Proterozoic Kunyang Group, This indicates that ore lead was derived neither from the cover rock nor from the basement rocks; (2) Although the Neo-Proterozoic Siman dolomite and silicalite, and dolomite in the lower part of the Kunyang Group are similar in Pb isotopic composition to the ores, lead and copper contents in these rocks are very low and they have not made great contributions to copper mineralization; (3) The ores have the same Pb iso-topic composition as the basalt, the latter being enriched in copper. These facts indicate that lead and copper were derived from the basalt. According to the regional geological data and the geological-geochemical characteristics of the ore deposits, it is suggested that ore-forming materials were leached out from the basalt. The thickness and buried depth of the basalt and regional tectonic dynamics can affect the formation of large-scale copper deposits. Therefore, exploration for this type of ore deposits should be conducted in the areas from western Yunnan to western Sichuan, where there are developed basalts of great thickness, with extensive tectonic movement and magmatic activity.     

浅析贵州二叠系锰矿与峨眉山玄武岩之关系

贵州遵义-水城地区中二叠纪茅口组第二段顶部产出的原生碳酸锰和氧化锰矿床,为贵州二叠系锰矿主要矿床。贵州中西部有大量的峨眉山玄武岩分布。本文就贵州二叠系锰矿与峨眉山玄武岩之关系进行探讨。     

上扬子西部茅口组灰岩顶部古喀斯特地貌的厘定及地质意义

上扬子西部滇东、黔西茅口组之上多为峨眉山玄武岩所覆盖，长期以来人们一直认为两者不存在沉积间断和地层剥蚀。作者通过野外实地考察和室内综合研究首次系统地厘定上扬子西部茅口组顶部的古喀斯特地貌，其形态多种多样，包括起伏不平的古剥蚀面、溶蚀洼地、溶斗、峰林、溶丘、洞穴以及洞穴充填物和古剥蚀面上红壤土。古喀斯特地貌在一个地区的地质发展中具有重要的意义，它代表了一次地壳上升运动。本区古喀斯特的系统研究不仅丰富了中国古喀斯特研究的内容，而且对确定云南地区东吴运动的存在和峨眉山地幔柱的活动提供了重要佐证。     

滇-黔边境鲁甸沿河铜矿床的发现与峨眉山大火成岩省找矿新思路

滇-黔边境鲁甸沿河铜矿床矿化受二叠纪玄武岩最上部古火山口相角砾凝灰岩-气孔状熔岩和上覆宣威组碳泥质层控制。矿石矿物主要为自然铜、氧化铜与辉铜矿。自然铜呈板片状、网脉状、浸染状产出。矿化与阳起石化、沥青化、硅化和沸石化密切相关。在峨眉山大火成岩省寻找沿河式铜矿应关注以下重要问题：①地球化学急变带所确定的岩石圈不连续界面控制了峨眉山玄武岩裂隙式喷发；②古火山口相从苦橄质到安山质高分异岩浆喷发；③火山口环境联系下的贫硫、贫酸根同生热液活动；④富有机质地层中有机-无机相互作用所产生的强还原性环境；⑤脆韧性断裂带的发育导致矿体的进一步富化。     

贵州及邻区二叠系锰矿地质特征及成矿作用探讨

本文在系统收集和分析了近年来贵州锰矿资源评价工作及以往锰矿工作资料的基础上,获得了对贵州及邻区二叠系锰矿更深入系统的认识。主要成果为：认为该区中二叠世茅口期含锰岩系可大致对比,可沿用遵义锰矿产出地区所使用的名称——中二叠统茅口组白泥塘层（P2m^b）;水城纳雍锰矿与宣威格学锰矿特征及成矿机制十分相似,均为第四纪氧化富集成矿,矿床类型属于风化矿床类的锰帽型锰矿床亚类,矿质来源于原始沉积的含锰岩系——白泥塘层,而白泥塘层的锰质来源于中二叠世茅口期峨眉山玄武岩喷发;将贵州及邻区二叠系各类型锰矿床的特征及含锰岩系、物质来源、成矿作用等方面作了有机联系和系统分析,并建立了统一的成矿模式。     

黔西南下三叠统飞仙关组沉积物源分析对峨眉山大火成岩省火山剥蚀序列的重建约束

峨眉山大火成岩省在形成后遭受了强烈的风化剥蚀，与右江盆地构成了独特的源- 汇沉积体系，相关的碎屑沉积记录是重建峨眉山大火成岩省晚期火山序列、揭示大火成岩省岩浆演化的关键。本文对黔西南地区右江盆地北缘下三叠统下部飞仙关组开展了详细的沉积物源研究。飞仙关组泥岩由长石、石英和黏矿物等组成，具有低SiO2、高TiO2含量和低Al2O3/TiO2值的特征，具Eu的弱负异常，微弱的Nb、Ta负异常。基于Al2O3/TiO2和La/Sm物源图解分析，研究样品的主要物源由峨眉山大火成岩省的高- Ti玄武岩和少量酸性火山岩构成，这与右江盆地晚二叠世的碎屑沉积物源组成一致。碎屑锆石具有～260 Ma 的年龄峰值，对应锆石具有较低的Th/Nb和较高的Nb/Hf值，均支持峨眉山大火成岩省作为主要的沉积物源区，而同时存在的>400 Ma的碎屑锆石则对应于峨眉山玄武质岩浆上升时所捕获的华南地壳物质。与上二叠统的碎屑锆石U- Pb年龄组成和锆石化学组成对比分析表明，峨眉山大火成岩省在晚二叠世到早三叠世早期剥蚀的火山岩构成了一定的火山序列，反映了该大火成岩省晚期从强烈地壳混染到分异结晶为主的岩浆演化过程。     

峨眉山玄武岩浆喷发对贵州西部区域成矿贡献研究

早、晚二叠世之间大规模峨眉山玄武岩喷发是峨眉地幔热柱基性岩浆活动的高峰期.峨眉山玄武岩在贵州西部地区广泛分布,它不仅以矿源层形式参与钼、铜、铅、锌、金、锑、汞、铊等以地下水热液成矿作用为主的层控矿床的形成,而且它自身形成火山气液型矿床--玄武岩铜矿及伴生热液型铂、钯等矿化点;再者它是外生矿床--高砷煤、高氟煤、高硫煤、高汞煤形成的主要原因.     

Geological significance of nickeliferous minerals in the Fule Pb–Zn deposit,Yunnan Province,China

The Fule Pb–Zn deposit is located in the Sichuan–Yunnan–Guizhou Province, and it is an important and giant low temperature metallogenic domain in China. In our research area, the Pb–Zn deposits are mainly hosted in the Permian Yangxin Formation and are composed of dolostone and limestone. The distance between the ore bodies and the Permian Emeishan basalt ranged from 50 to 160 m. In this study, the nickel rich minerals, including vaesite, polydymite and millerite, were reported for the first time in the Fule deposit. These minerals occurred as xenomorphic mineral aggregate and were sporadically distributed in the sphalerite–galena–calcite vein, which is the main ore type in the deposit. Our study indicated that the paragenetic sequence of minerals in the Fule deposit is the following order: polydymite?→?vaesite?→?millerite?→?sphalerite?→?galena?→?tetrahedrite (tennantite). The geological occurrence characteristics of those nickeliferous minerals suggested that the Permian Emeishan basalt is a possible barrier layer of Pb–Zn ore-forming fluid, and it is an important source for the Ni and part of the Cu in the deposit. The Sichuan–Yunnan–Guizhou Pb–Zn mineralization province is a world-class production base of Pb and Zn, in which the Permian Emeishan basalt and Pb–Zn deposits have uniformly spatial distribution, but the relationship of mineralization between them is still under debate. This report provides new evidence for understanding the relationship between Pb–Zn mineralization and Permian Emeishan basalt in the Sichuan–Yunnan–Guizhou Pb–Zn mineralization province.     

Study on the geological conditions of metallogenesis of the Shazi large-scale anatase deposit in Qinglong County,Guizhou Province

The Shazi large-scale anatase deposit in Qinglong County, Guizhou Province, has been discovered recently and now is under exploration. Investigations show that the orebodies mostly occur at the top of the karst unconformity of the Middle Permian Maokou Formation strata and at the bottom of the Emeishan basalt. And the following three prerequisites should be satisfied for the formation of the deposit： 1） there must be the material source of anatase; 2） there must be weekly alkaline media and low-tempeature and low-pressure conditions; 3） there was no high-temperature and high-pressure environment subsequently for the transformation of anatase into rutile. In the Emeishan basalt of western Guizhou, the element Ti mostly entered the silicon-oxygen tetrahedra of picrite in heterovalent isomorphism （Ti4＋＋Al3＋→Mg2＋＋Si4＋）. When volcanic ejecta resultant from strong eruption of the Emeishan basalt magma fell into water, picrite was usually dissociated to chlorite. Thus, the element Ti4＋ in the picrite could be released from the silicon-oxygen tetrahedraa of picrite into water, and conbined with oxygen in the water to form TiO2. This paper has proved that this deposit, enriched in anatase, discovered recently at Shazi, Qinglong Country, Guizhou Province, is a residual-deluvial-type deposit. Its genesis can be explained as follows. Volcanic clastics formed at the early stage of strong eruption of the Emeishan basalt magma were chemically deposited to form anatase in the low-temperature, low-pressure and weekly alkaline waters in the karst depressions at the top of the Maokou Formation （limestone） strata. The anatase was then dissociated owing to weathering and leaching during the Quaternary and the anatase was further enriched to form the residual-deluvial-type anatase ore deposit.     

峨眉山大火成岩省与玄武岩铜矿--以贵州二叠纪玄武岩分布区为例

贵州晚二叠世玄武岩是峨眉山大火成岩省的组成部分，并位于其东区。全属高钛玄武岩。它是地幔柱边部或消亡期局部熔融产物。产物我省玄武岩中的铜矿床（点），与北美大陆同类铜矿有相似之处，可统称为玄武岩铜矿，属于“与陆相镁铁质喷发岩有关的铜矿床成矿系列”。