Study on the element geochemical charactersitics of the Shazi large-sized anatase ore deposit in Qinglong,Guizhou Province

The Shazi anatase ore deposit in Qinglong, Guizhou Province, is a large-sized anatase deposit that has been recently explored. The characteristics of major oxides in the ore are similar to those of modem laterite weath- ering crust and laterite in the laterite-type gold deposits in the western part of Guizhou Province. Studies on the REE characteristics of basalts and anatase ores in the study region showed that both of them do have extremely strong affinities. There are two groups of trace elements in the ores, i.e., Au-Ag-As-Sb-Hg-Tl association and Sc-TiO2-Cu-Fe-Mn association, reflecting that the formation of anatase ore is related to the formation of siliceous claystone at the early stage of eruption of the Emeishan basaltic magma. The siliceous claystones are the major country rocks for the formation of laterite-type gold ores and anatase ores. In the region anatase ores are rich in Sc and the basalts enriched in Fe, Mn, Ti and Sc are the material source of metallogenesis.     

贵州盘县地区峨眉山玄武岩铜矿的成矿地质条件

以峨眉山玄武岩底部与中二叠统茅口组灰岩接触界面上赋存的黄见坑-哈树富铜矿带为例，论述了这一新类型玄武岩铜矿的成矿地质条件及峨眉山玄武岩浆喷-溢对Cu(Au、Pb、zn、Pt、Pd、Sb、F等)元素的富集和后期热液改造成矿作用，以扩大找矿思路。     

Stratigraphic records of the dynamic uplift of the Emeishan large igneous province

Abstract

Fluid dynamical and numerical modelling predicts a large-scale regional domal uplift prior to basalt eruptions in large igneous provinces, which can be readily measured when a plume head rises below a shallow marine sedimentary basin. Research on the sedimentology, biostratigraphy, and isotopic chronology of the Emeishan large igneous province demonstrates that the sedimentary environment in the Maokou stage is not uniform carbonate platform facies, but rather sedimentary facies with a north–south linear alignment and west–east different distribution controlled by the syn-depositional normal faulting of the Changhai and Xiaojiang faults, which are the result of underwater dynamic uplift induced by deep mantle activity. The dynamic uplift started in the Maokou stage. Thus, thinning of the Maokou limestone was the product of the difference in the initial depositional thickness caused by the underwater uplift and post-depositional surface uplift and erosion, but post-depositional uplift was much less than kilometre scale. Sedimentary facies differentiation and tectonic–sedimentary evolution in the Maokou stage provide a constraint for the time of the initial eruption and eruption environment before and during the Emeishan basalt eruption. Small-scale magmatic activity might have already begun in the middle of the Maokou stage, whereas submarine and terrestrial sedimentary environments coexisted before and during Emeishan basalt eruption.     

贵州大方地区粘土岩成因探讨

大方庆阳煤矿区龙潭煤系和茅口灰岩界限粘土岩分析结果表明:该层粘土岩为黄铁矿质高岭石粘土岩,对其化学成分中Na2O、K2O、MgO、CaO和Pb的研究认为,该层粘土岩是在安静低能、酸性介质还原环境下,为受峨眉山玄武岩影响的火山事件沉积粘土岩。     

晴隆锑矿床中萤石的稀土元素特征及其指示意义

本文系统地研究了黔西南晴隆锑矿床中萤石的稀土元素地球化学,表明不同颜色、不同矿物组合的萤石的稀土元素含量变化较大,但具有固定的REE分配模式,以明显的负Ce异常、富MREE、分配曲线相对平缓为特征;这种配分模式主要是受其晶体化学因素的控制,而与溶液中REE络合物的稳定性关系不大。萤石的稀土元素组成与其矿物共生组合关系不大,但与其颜色关系较密切。萤石的Ce、Eu异常主要是受氧逸度的控制,流体源区的氧逸度较高,矿物沉淀场所的氧逸度相对较低,从而导致该矿中萤石呈明显的负Ce异常,或正或负的Eu异常。晴隆锑矿床形成于开放体系条件下,水/岩反应很可能是导致萤石发生沉淀的主要机制。萤石中的Ca部分来自茅口组灰岩,部分来自大厂层玄武岩;而矿化剂F可能主要来自外部。     

Geochemical studies on Dachang antimony ore deposit in Qinglong, Guizhou Province

The Dachang antimony deposit in Qinglong,Guizhou Province,is strictly controlled by the “Dachang Layer” which is a complex altered rock occurring at unconformity between the Permian Emeishan basalt and the Maokou limestone.Based on the studies of the hanging-and foot-wall rocks,the trace elements and REE contents of the rocks and ores and heavy placer minerals in the basalt,this paper is focused on the relations between these data and the “Dachang Layer”and its hanging- and oot-wall rocks.The author pointed out that the “Dachang Layer” and basalt are the source-beds of antimony;ilmenite and magnetite are the major mineral carriers of antimony.In the processes of halmyrosis and burial metamorphism of the “Dachang Layer” an basalt,antimony was mobilized along with the mobilization of iron and was preliminarily concentrated in the“ Dachang Layer”.     

贵州峨眉山玄武岩喷发期的岩相古地理研究

贵州峨眉山玄武岩喷发，从动态的角度可以分为茅口期晚期和龙潭期（吴家坪期），龙潭期又可分为三个喷发旋回，对应于四个不同的岩相古地理环境，体现了东吴运动在造成贵州地区地壳抬升、下沉和接受最大海侵之后，又上升、拉张、沉陷带发生地裂（又称峨眉地裂）以及地幔物质喷溢等地质活动，具间歇性和多旋回性的特点。本文从研究海陆变迁入手，揭示峨眉山玄武岩喷发与沉积作用的内在联系，进而探讨其与金、锑等矿产的成因联系，提出该期各相区与成矿区的形成模式。通过对贵州峨眉山玄武岩不同喷发期岩相古地理的研究可以看到，茅口期晚期和龙潭期早期海域的沉积韵律和相带展布格局与玄武岩喷发的间歇性和多旋回性特征完全一致。玄武岩的喷发为成矿提供了物质基础，玄武岩喷发的间歇期又为沉积矿产的富集提供机遇。这种岩浆期后气液以富硅和二氧化碳为特征的玄武岩，本身富含铁、锰、铜、铅、锌、锑、砷、汞、金、银、氟、磷以及一些稀散和放射性元素等成矿组分。在喷发过程中，气液成分有一定变化，各阶段和离岩浆的远近距离不同以及喷发性质和环境差异，形成了火山气液矿床、火山沉积矿床和沉积矿床的不同成矿带。     

浅析贵州二叠系锰矿与峨眉山玄武岩之关系

贵州遵义-水城地区中二叠纪茅口组第二段顶部产出的原生碳酸锰和氧化锰矿床,为贵州二叠系锰矿主要矿床。贵州中西部有大量的峨眉山玄武岩分布。本文就贵州二叠系锰矿与峨眉山玄武岩之关系进行探讨。     

峨眉山玄武岩浆喷发对贵州西部区域成矿贡献研究

早、晚二叠世之间大规模峨眉山玄武岩喷发是峨眉地幔热柱基性岩浆活动的高峰期.峨眉山玄武岩在贵州西部地区广泛分布,它不仅以矿源层形式参与钼、铜、铅、锌、金、锑、汞、铊等以地下水热液成矿作用为主的层控矿床的形成,而且它自身形成火山气液型矿床--玄武岩铜矿及伴生热液型铂、钯等矿化点;再者它是外生矿床--高砷煤、高氟煤、高硫煤、高汞煤形成的主要原因.     

滇东北乌蒙山地区峨眉地幔柱活动与火山-沉积盆地的响应关系

为加深滇东北乌蒙山地区峨眉地幔柱演化的认识,对该区的峨眉山玄武岩及下伏的栖霞组—茅口组开展了详细地质调查工作,并对峨眉山玄武岩进行了岩石学、同位素年代学研究,结果显示:峨眉地幔柱活动导致的地壳抬升形成了研究区栖霞组—茅口组西薄东厚、峨眉山玄武岩西厚东薄的地质特征,地壳开始隆升的时限为(273.1±3.1)Ma,地壳抬升...     

贵州省威宁县炉山铜矿床地质特征研究

炉山铜矿床产于宣威组(P₃x)底部的深灰、灰黑色粉砂质泥岩及峨眉山玄武岩第三段(βp³)顶部的火山角砾赤铁矿层内,是近年来贵州省发现的含铜矿层的新层位,矿石类型也是一种新的矿石类型。含矿岩系自上而下,存在钛(Ti)-铜(Cu)-铁(Fe)等元素分带,以上特征符合玄武岩型风化淋滤型铜矿的特征。通过对炉山铜矿床地质特征的研究,系统总结出该类矿床的地质特征,为该区相同类型的铜矿勘查工作提供一定的思路。     

贵州西部铂钯地质化学异常特征及找矿前景分析

贵州西部Pt、Pd异常是川滇黔铂钯地球化学巨省的一部分,在威宁东部和水城南部地区存在2个异常强度规模大、结构模式理想的铂钯地球化学省。贵州西部发育NW向的断陷裂谷构造,分布有数个古火山口,构成了玄武岩浆喷溢活动通道,提供了Pt、Pd、Cu等多金属成矿物质来源和成矿条件,可望找到一定规模的铂钯矿床。本区可能存在一种新的铂钯矿床类型：受裂谷环境古火山口相峨眉山玄武岩顶部假整合面控制的同生火山热液叠加改造型铂钯铜矿床;此外还有可能存在构造热液型铂钯矿、红土型砂铂矿等类型。要取得在该区发现铂钯矿床的突破性进展,需要持续大量有效的勘查投入。     

贵州老万场红土型金矿地球化学特征及其成因

对贵州西南部晴隆老万场红土型金矿与相关岩石（矿石）和喀斯特红土等进行了常量元素、微量元素和稀土元素地球化学比较研究,阐明了矿床的各类元素的地球化学特征,追溯了矿术的物质来源。研究表明,本类红土型金矿的物质来源是高硅质（石英）、富铁质（黄铁矿等）的富金矿（岩）石;具有Ａｕ－Ａｓ－Ｓｂ－Ｈｇ－Ｔｌ－Ｗ－Ａｇ－Ｂａ的微量元素组合特征,与卡林型金矿十分相似,是原始卡林型金矿风化演化的产物。常量元素和稀土元     

贵州晴隆锑矿田微量元素地球化学特征及其对成矿流体的指示意义

硅化凝灰岩是贵州晴隆锑矿田普遍发育的成矿作用产物。对比分析未蚀变凝灰岩、硅化凝灰岩、峨眉山玄武岩、萤石和辉锑矿稀土元素配分特征,以及某些高场强元素特征参数,探讨成矿流体物理化学特征。大厂层下段（P2d1）强硅化凝灰岩、中段（P2d2）近矿硅化凝灰岩及上段（P2d3）未蚀变凝灰岩Sb元素丰度显示,与峨眉山玄武岩喷发有关的凝灰岩可能是潜在的晴隆锑矿矿源层,后期热液带来部分矿质来源,热液改造作用是成矿物质富集的关键。凝灰岩蚀变前后稀土元素演化特征研究表明,成矿流体稀土元素含量很低、以富F为特征且具有还原性。Y／Ho、Zr／Hf和Nb／Ta比值表明晴隆锑矿成矿流体具多源特征。辉锑矿稀土元素配分特征与国内其他辉锑矿有显著区别,其具有近似的w型四分组效应是继承海水或地层水稀土元素特征的表现。     

上扬子西部茅口组灰岩顶部古喀斯特地貌的厘定及地质意义

上扬子西部滇东、黔西茅口组之上多为峨眉山玄武岩所覆盖，长期以来人们一直认为两者不存在沉积间断和地层剥蚀。作者通过野外实地考察和室内综合研究首次系统地厘定上扬子西部茅口组顶部的古喀斯特地貌，其形态多种多样，包括起伏不平的古剥蚀面、溶蚀洼地、溶斗、峰林、溶丘、洞穴以及洞穴充填物和古剥蚀面上红壤土。古喀斯特地貌在一个地区的地质发展中具有重要的意义，它代表了一次地壳上升运动。本区古喀斯特的系统研究不仅丰富了中国古喀斯特研究的内容，而且对确定云南地区东吴运动的存在和峨眉山地幔柱的活动提供了重要佐证。     

地幔柱成矿系统:以峨眉山地幔柱为例

地幔柱沟通了地核、地幔、地壳各个圈层之间的物质与能量交换,提供了板内构造岩浆活动及成矿作用的一种重要的动力学机制。峨眉山地幔柱是晚古生代全球最显著的地幔柱活动之一,形成了多种有重大资源经济价值的矿床类型。以峨眉山地幔柱为例,对几种典型矿床类型的产出特征及成因进行了系统分析,阐述了地幔柱成矿系统中各种成矿作用与地幔柱构造岩浆活动的关系及成矿机理。(1)通过对部分典型岩浆硫化物矿床的地质地球化学特征和矿化特征分析,揭示了峨眉山大火成岩省不同矿化特征的岩浆硫化物矿床形成于统一的地幔柱岩浆活动体系,并与峨眉山玄武岩为同源演化关系,岩浆演化过程及硫化物熔离富集过程存在的差异造成了矿化类型的变异。(2)对攀西地区4个超大型钒钛磁铁矿矿床进行了详尽的地质地球化学分析,论述了成矿岩浆的性质、与峨眉山玄武岩的关系及成岩演化过程和成矿模式,表明成矿母岩浆来自于地幔柱,但经历了较大程度的地壳混染作用,提出岩浆的多次补给混合及结晶锋面上发生的双扩散造成的液态分层导致了韵律条带矿石的形成。(3)阐述了滇黔相邻地区玄武岩型自然铜和黑铜矿铜矿化现象,指出玄武岩岩浆气液阶段的自变质作用和玄武岩构造变质热液蚀变改造作用两种方式造成铜矿化富集,岩浆气液阶段的自变质作     

Signatures of the source for the Emeishan flood basalts in the Ertan area： Pb isotope evidence

The Emeishan flood basalts can be divided into high-Ti (HT) basalt (Ti/Y>500) and low-Ti (LT) basalt (Ti/Y<500). Sr, Nd isotopic characteristics of the lavas indicate that the LT- and the HT-type magmas originated from distinct mantle sources and parental magmas. The LT-type magma was derived from a shallower lithospheric mantle, whereas the HT-type magma was derived from a deeper mantle source that may be possibly a mantle plume. However, few studies on the Emeishan flood basalts involved their Pb isotopes, especially the Ertan basalts. In this paper, the authors investigated basalt samples from the Ertan area in terms of Pb isotopes, in order to constrain the source of the Emeishan flood basalts. The ratios of 206Pb/204Pb (18.31–18.41), 207Pb/204Pb (15.55–15.56) and 208Pb/204Pb (38.81–38.94) are significantly higher than those of the depleted mantle, just lying between EM I and EM II. This indicates that the Emeishan HT basalts (in the Ertan area) are the result of mixing of EMI end-member and EMII end-member.     

扬子西缘丹巴水子乡辉石岩年代学和岩石成因研究SCIEI北大核心CSCD

扬子克拉通西缘在~260Ma发生短期内大规模峨眉山玄武岩溢流喷发。攀西地区发育的镁铁-超镁铁质岩被广泛认为是峨眉山大火成岩省的产物,但在北端松潘-甘孜岩区一直缺乏该类岩石的报道。本文首次报道扬子西缘丹巴水子乡单斜辉石岩的准确年龄,其锆石LA-ICP-MS U-Pb加权平均年龄为260.7±3.3Ma,表明其为峨眉山大火成岩省北端松潘-甘孜岩区镁铁-超镁铁质岩的组成部分。通过与攀枝花钒钛磁铁矿含矿岩体边缘相带苦橄岩和上部相带浅色辉长岩进行锆石微量元素对比显示,水子乡单斜辉石岩具有相近的高氧逸度,其ΔQFM为0~3,Ce_(N)/Ce_(N)平均为~30,该性质可能同样源自扬子西缘洋壳板片俯冲交代形成的较高氧逸度地幔源区。尽管如此,水子乡辉石岩体并未因高氧逸度而有明显的含钛磁铁矿饱和结晶,可能由其较低结晶分异程度造成。相比之下,攀枝花岩体经历了更高程度的含钛磁铁矿和斜长石分离结晶作用,伴随大规模的钒钛磁铁矿成矿。     

Interaction of magma with sedimentary wall rock and magnetite ore genesis in the Panzhihua mafic intrusion,SW China

In southwestern China, several large magmatic Fe–Ti–V oxide ore deposits are hosted by gabbroic intrusions associated with the Emeishan flood basalts. The Panzhihua gabbroic intrusion, a little deformed sill that contains a large titanomagnetite deposit at its base, concordantly intrudes late-Proterozoic dolostones. Mineralogical and chemical studies of the contact aureole in the footwall dolostones demonstrate that the metamorphism was largely isochemical but released large quantities of CO₂ as the rocks were converted to marble and skarns during intrusion of the gabbroic magma. Petrological modelling of the crystallization of the intrusion, using H₂O-poor Emeishan basalt as parent magma, shows that under normal conditions, Fe–Ti oxides crystallize at a late stage, after the crystallization of abundant olivine, clinopyroxene and plagioclase. In order for titanomagnetite to separate efficiently to form the ore deposit, this mineral must have crystallized earlier and close to the liquidus. We propose that CO₂-rich fluids released during decarbonatization of sedimentary floor rocks passed up through the magma. Redox equilibria calculations show that when magma with the composition of Emeishan basalt is fluxed by a CO₂-rich gas phase, its equilibrium oxygen fugacity (fO₂) increases from the fayalite–magnetite–quartz buffer (FMQ) to FMQ + 1.5. From experimental constraints on magnetite saturation in basaltic magma under controlled fO₂, such an oxidizing event would allow magnetite to crystallize near to the liquidus, leading to the formation of the deposit.     

A new interpretation of the sedimentary environment before and during eruption of the Emeishan LIP,Southwest China

The environment where the Permian Emeishan large igneous province (LIP) of Southwest China erupted remains controversial, especially regarding whether it was terrestrial, involving a 1 km scale domal uplift, or submarine. Slightly younger Daqiao conglomerate and Binchuan pillow lavas suggest that the Emeishan LIP erupted in a submarine environment. We show that at Binchuan, sandstone and rhyolite lie beneath the pillow lavas. In the Daqiao cross-section, there is an eastwards-verging syncline that reverses the succession of basalt and conglomerate. The conglomerate is not a basal conglomerate, and it does not contain any magmatic hydrovolcanic deposits. The basalt underlying the conglomerate is not the first of the LIP eruptions; that first eruption is found ~420 m below, on top of the Permian Maokou limestone. All together, these observations show that the deposits, including the conglomerate and pillow lava, do not represent the environment at the very start of the LIP volcanic eruptions, but represent conditions that existed before and possibly during the Emeishan LIP eruptions. Based on field investigations, the petrology of the rocks, and structural features, we conclude that submarine sedimentation and subaerial basalt eruptions coexisted in time and space in the region during or prior to the Emeishan LIP basalt eruptions.