New carbonatite complex in the western Baikal area,southern Siberian craton: Mineralogy,age, geochemistry,and petrogenesis

A dike–vein complex of potassic type of alkalinity recently discovered in the Baikal ledge, western Baikal area, southern Siberian craton, includes calcite and dolomite–ankerite carbonatites, silicate-bearing carbonatite, phlogopite metapicrite, and phoscorite. The most reliable ⁴⁰Ar–³⁹Ar dating of the rocks on magnesioriebeckite from alkaline metasomatite at contact with carbonatite yields a statistically significant plateau age of 1017.4 ± 3.2 Ma. The carbonatite is characterized by elevated SiO₂ concentrations and is rich in K₂O (K₂O/Na₂O ratio is 21 on average for the calcite carbonatite and 2.5 for the dolomite–ankerite carbonatite), TiO₂, P₂O₅ (up to 9 wt %), REE (up to 3300 ppm), Nb (up to 400 ppm), Zr (up to 800 ppm), Fe, Cr, V, Ni, and Co at relatively low Sr concentrations. Both the metapicrite and the carbonatite are hundreds of times or even more enriched in Ta, Nb, K, and LREE relative to the mantle and are tens of times richer in Rb, Ba, Zr, Hf, and Ti. The high (Gd/Yb)_CN ratios of the metapicrite (4.5–11) and carbonatite (4.5–17) testify that their source contained residual garnet, and the high K₂O/Na₂O ratios of the metapicrite (9–15) and carbonatite suggest that the source also contained phlogopite. The Nd isotopic ratios of the carbonatite suggest that the mantle source of the carbonatite was mildly depleted and similar to an average OIB source. The carbonatites of various mineral composition are believed to be formed via the crystallization differentiation of ferrocarbonatite melt, which segregated from ultramafic alkaline melt.     

Nature and timing of the Solonker suture of the Central Asian Orogenic Belt: insights from geochronology and geochemistry of basic intrusions in the Xilin Gol Complex,Inner Mongolia,China

The Solonker suture zone of the Central Asian Orogenic Belt (CAOB) records the final closure of the Paleo-Asian Ocean. The nature and timing of final collision along the Solonker suture has long been controversial, partly because of an incomplete record of isotopic ages and differing interpretations of the geological environments of key tectonic units. The Xilin Gol Complex, consisting of strongly deformed gneisses, schists and amphibolites, is such a key tectonic unit within the CAOB. Lenticular or quasi-lamellar amphibolites are dispersed throughout the complex, intercalated with biotite–plagioclase gneiss. Both rock types experienced amphibolite-facies metamorphism. The protolith of the amphibolite is a basic rock that intruded into the biotite–plagioclase gneiss at 319 ± 4 Ma based on LA-ICPMS zircon U–Pb dating. The basic intrusion was sourced from a modified magma that experienced crystal fractionation and was admixed with slab-derived fluids. The slab-derived fluids, which formed during Early Paleozoic oceanic subduction along the north-dipping Sonidzuoqi–Xilinhot subduction zone, mixed with the magma source and produced subduction-related geochemical signatures superimposed on volcanic arc chemistry. After Early Paleozoic oceanic subduction and arc-continent collision, a transient stage of extension occurred between 313 and 280 Ma in the Sonidzuoqi–Xilinhot area. Deformation and recrystallization during the switch from compression to extension and reheating by the later magmatic intrusions reset the isotope systems of minerals in the Xilin Gol Complex, recorded by a 312.2 ± 1.5 Ma biotite ⁴⁰Ar/³⁹Ar age from biotite–plagioclase gneiss, a 309 ± 12 Ma zircon intercept age and a 307.5 ± 3.5 Ma hornblende ⁴⁰Ar/³⁹Ar age from amphibolites in the complex. There was an arc/forearc-related marine basin at the southern margin of the Xilin Gol Complex during the Permian. The closure of the oceanic basin led to Late Paleozoic–Middle Triassic north-dipping subduction beneath the Xilin Gol Complex and induced the amphibolite-facies metamorphism of the complex. The final suturing of the Solonker zone occurred from 269 to 231 Ma. This latest amphibolite-facies metamorphism with pressures of 0.31–0.39 GPa and temperatures of 620–660 °C was recorded at 263.4 ± 1.4 Ma to the Xilin Gol Complex, as indicated by the hornblende ⁴⁰Ar/³⁹Ar age from the amphibolites, as well as several zircon ages of 260 ± 3–231 ± 3 Ma. The Xilin Gol Complex documented the progressive accretion of a single, long-lived subduction system at the southern margin of the south Mongolian microcontinent from the Early Paleozoic (~452 Ma) to Middle Triassic (~231 Ma). The CAOB shows protracted collision prior to final suturing.     

东构造结那木拉断裂带上新世以来强烈活动的年代学证据

为揭示东喜马拉雅构造结那木拉断裂带上新世以来强烈活动特征,对采集自那木拉断裂带的三件基岩样品进行黑云母40Ar/39Ar、磷灰石裂变径迹两种热年代学方法测年;并利用"Pecube"软件对测得年龄数据及断裂带两侧已发表年龄数据进行定量模拟计算。测试结果显示黑云母40Ar/39Ar年龄范围为4.44±0.71 Ma~3.45±0.24 Ma,磷灰石裂变径迹年龄范围为3.7±0.4 Ma~1.8±0.2 Ma。年龄数据及其模拟计算结果表明,约3 Ma以前那木拉断裂带南侧地壳隆升最快,隆升速率约2.5 km/Ma,断裂带以正断层运动特征为主;约3 Ma以来那木拉断裂带北侧地壳隆升最快,约为1.3 km/Ma,断裂带以逆断层运动特征为主。那木拉断裂带运动特征变化可能与约8 Ma以来东喜马拉雅构造结快速地壳隆升剥露区域由南向北逐渐迁移有关。      

Integrated U–Pb and Sm–Nd geochronology for a REE-rich carbonatite dyke at the giant Bayan Obo REE deposit,Northern China

The Bayan Obo deposit in North China contains the largest rare-earth element (REE) resources in the world, but its forming time remains controversial. Nearly one hundred carbonatite dykes occur around the Bayan Obo deposit, including dolomite, calcite and calcite–dolomite carbonatite varieties. Zircons from a REE-rich carbonatite dyke and wallrock quartz conglomerate at Bayan Obo have been analyzed for U–Pb to determine the age of the dyke. Zircon from the carbonatite dyke, analyzed by conventional isotope dilution thermal ionization mass spectrometry (ID-TIMS), yielded an upper intercept age of 1417 ± 19 Ma. This age is confirmed by SHRIMP U–Pb analysis of zircon from the same carbonatite dyke, which gave a ²⁰⁷Pb/²⁰⁶Pb weighted mean age of 1418 ± 29 Ma. In situ Nd isotope measurements of monazite collected from the carbonatite dyke gave an isochron age of 1275 ± 87 Ma. These results demonstrate that the dyke intruded ~ 1400 Ma. In view of predecessor's results, it is clarified that the REE mineralization at Bayan Obo occurred at ca. 1400 Ma, consistent with the timing of carbonatite dyke intrusion in the region. The youngest detrital zircons from the quartz conglomerate yielded a ²⁰⁷Pb/²⁰⁶Pb weighted mean age of 1941 ± 7 Ma using LA ICP-MS U–Pb method. Detrital zircons in the carbonatite dyke also gave a mean apparent age of 1932 ± 3 Ma using ID-TIMS U–Pb method and 1914 ± 14 Ma using SHRIMP U–Pb method. These ages constrain the beginning active time of the Zha'ertai–Bayan Obo rift in the northern margin of the North China Craton after ~ 1900 Ma.     

Timing of the Yuchiling giant porphyry Mo system, and implications for ore genesis

The Yuchiling Mo deposit is a recently discovered giant porphyry system in the East Qinling Mo belt, China. Its apparent causative intrusion, i.e., the Yuchiling granite porphyry, is the youngest intrusion (phase 4) of the Heyu multiphase granite batholith, which was emplaced between 143 and 135 Ma. New robust constraints on the formation of the Yuchiling porphyry Mo system are provided by combined zircon U–Pb, biotite ⁴⁰Ar/³⁹Ar, and molybdenite Re–Os dating. Zircon grains from the Mo-mineralized granite porphyry yield weighted ²⁰⁶Pb/²³⁸U age of 134.0?±?1.4 Ma (n?=?19, 2σ error, MSWD?=?0.30). Magmatic biotite from the same sample yield a ⁴⁰Ar/³⁹Ar plateau age of 135.1?±?1.4 Ma (2σ error), and an inverse isochron age of 135.6?±?2.0 Ma (n?=?7, 2σ error, MSWD?=?10.8), which are effectively coincident with the zircon U–Pb age within analytical error. Three pulses of mineralization can be deduced from the molybdenite Re–Os ages, namely: ～141, ～137, and ～134 Ma, which agree well with the zircon U–Pb ages of granitic phases 1, 2, and the Yuchiling porphyry (phase 4), respectively. These well-constrained temporal correlations indicate that Mo mineralization was caused by pulses of granitic magmatism, and that the ore-forming magmatic-hydrothermal activity responsible for the Yuchiling porphyry Mo system lasted about 8 Ma. The Yuchiling Mo deposit represents a unique style of porphyry Mo system formed in a post-collision setting, and associated with F-rich, high-K calc-alkaline intrusions, which differ from convergent margin-associated porphyry Mo deposits.     

Age and tectonomagmatic setting of the Eocene Çöpler–Kabataş magmatic complex and porphyry-epithermal Au deposit, East Central Anatolia, Turkey

The Çöpler epithermal Au deposit and related subeconomic porphyry Cu–Au deposit is hosted by the middle Eocene Çöpler–Kabata? magmatic complex in central eastern Anatolia. The intrusive rocks of the complex were emplaced into Late Paleozoic–Mesozoic metamorphosed sedimentary basement rocks near the northeastern margin of the Tauride-Anatolide Block. Igneous biotite from two samples of the magmatic complex yielded ⁴⁰Ar/³⁹Ar plateau ages of 43.75?±?0.26 Ma and 44.19?±?0.23, whereas igneous hornblende from a third sample yielded a plateau age of 44.13?±?0.38. These ages closely overlap with ⁴⁰Ar/³⁹Ar ages of hydrothermal sericite (44.44?±?0.28 Ma) and biotite (43.84?±?0.26 Ma), and Re–Os ages from two molybdenite samples (44.6?±?0.2 and 43.9?±?0.2 Ma) suggesting a short-lived (<1 my) magmatic and hydrothermal history at Çöpler. No suitable minerals were found that could be used to date the epithermal system, but it is inferred to be close in age to the precursor porphyry system. The Çöpler–Kabata? intrusive rocks show I-type calc-alkaline affinities. Their normalized trace element patterns show enrichments in large ion lithophile and light rare earth elements and relative depletions in middle and heavy rare earth elements, resembling magmas generated in convergent margins. However, given its distance from the coeval Eocene Maden–Helete volcanic arc, the complex is interpreted to be formed in a back-arc setting, in response to Paleocene slab roll-back and upper-plate extension. The tectonomagmatic environment of porphyry-epithermal mineralization at Çöpler is comparable to some other isolated back-arc porphyry systems such as Bajo de la Alumbrera (Argentina) or Bingham Canyon (USA).     

From emplacement to unroofing: thermal history of the Jiazishan gabbro, Sulu UHP terrane, China

On the eastern extremity of the Jiaodong peninsula, China, shoshonitic magmas have been injected into the supracrustal rocks of the Sulu ultra-high pressure (UHP) terrane during the crustal exhumation phase. These granitoids (collectively termed the Shidao igneous complex or Jiazishan alkaline complex) show geochemical and isotopic signatures of an enriched subcontinental lithospheric mantle and intruded soon after the subducted Yangtze crust had reached peak metamorphic pressure conditions (240–220 Ma). We have applied various geochronometers to an alkali-gabbro sample from the Jiazishan pluton and the results allow reconstruction of the Triassic-to-present thermal history. Initial rapid cooling of the gabbro at crustal depths is indicated by the close agreement between the Sm-Nd mineral isochron age (228?±?36 Ma) and the Rb-Sr biotite age (207?±?1) Ma. This interpretation is confirmed by previously published U-Pb zircon ages (225–209 Ma), and ⁴⁰Ar/³⁹Ar amphibole and K-feldspar ages (～214 Ma) from the Jiazishan syenites. A titanite fission-track age of 166?±?8 Ma (closure temperature range 285–240°C) records widespread Jurassic magmatism in the Jiaodong peninsula, indicating that the gabbro reached upper crustal levels before it was reheated by nearby Jurassic plutons. A subsequent cooling and reheating event is indicated by an apatite fission-track age of 106?±?6 Ma which coincides with the emplacement of the adjacent Weideshan pluton (108?±?2 Ma) and postdates a period of regional lithospheric thinning beneath eastern China. A period of slow cooling (or thermal stability) from late Cretaceous to early Tertiary, documented by an apatite (U-Th)/He age of 39?±?5 Ma, was followed by a final stage of more enhanced cooling since the late Eocene. Results of this work imply that the eastern Sulu terrane has experienced a complex cooling and reheating history. Our data are consistent with a model of initial rapid cooling (sudden exhumation) of the UHP terrane, driven by the release of buoyancy forces, followed by two progressively slower cooling intervals (both after renewed crustal reheating) during the Jurassic and Cretaceous.     

Age of Cu(-Fe)-Au mineralization and thermal evolution of the Punta del Cobre district, Chile

The Punta del Cobre belt is located 15?km south of Copiapó, northern Chile. It comprises several Cu(-Fe)-Au deposits in the Punta del Cobre and Ladrillos districts, east of the Copiapó river, and the Ojancos Nuevo district, with the new Candelaria mine, and Las Pintadas district, west of the river. The mineralization in the Punta del Cobre belt is characterized by a simple hypogene mineral assemblage of chalcopyrite, pyrite, magnetite, and hematite. Average ore grades are 1.1 to 2% Cu, 0.2 to 0.6?g/t Au, and 2 to 8?g/t Ag. Massive magnetite occurs as veins and irregularly shaped bodies. The ore is spatially associated with alkali metasomatism and in particular with potassic alteration. The Cu(-Fe)-Au deposits are hosted mainly in volcanic rocks of the Punta del Cobre Formation (pre-upper Valanginian) that underlie Neocomian limestones of the Chañarcillo Group. This region experienced backarc basin formation in the Neocomian, uplift and granitoid intrusions in the middle Cretaceous, and eastward migration of the magmatic front of about 30?km between middle Cretaceous and Paleocene. To determine the timing of ore deposition and to reconstruct parts of the thermal history of the Punta del Cobre district, in the eastern part of the belt, we have obtained ⁴⁰Ar/³⁹Ar incremental-heating and Rb-Sr analyses of mineral and whole-rock samples. An ⁴⁰Ar/³⁹Ar incremental-heating experiment on hydrothermal biotite, formed synchronous with the Cu(-Fe)-Au mineralization, yielded an inverse isochron age of 114.9?±?1.0 Ma (all errors reported at ±2σ), consistent with a Rb-Sr isochron of 116.8?±?2.7 Ma calculated from 7 whole-rock samples. These data are interpreted to represent the age of potassic alteration that accompanies mineralization. Ore formation temperatures of 400?°C to 500?°C were previously estimated based on paragenetic relationships. Shearing at the Candelaria deposit occurred after ore deposition and before the main stage of batholith emplacement. Published K-Ar ages for the middle Cretaceous batholith near the Punta del Cobre belt range from 119 to 97?Ma. Our data suggest that the mineralization is related to the earlier stages of batholith emplacement. The biotite age spectrum indicates that the Punta del Cobre district was not affected by temperatures above ～300?°C–350?°C, the closure temperature for argon in biotite, during the contact metamorphic overprint produced by later emplaced batholithic intrusions. Whole-rock ⁴⁰Ar/³⁹Ar ages are considerably younger; incremental-heating experiments yielded an inverse isochron age of 90.7?±?1.2?Ma and weighted mean plateau ages of 89.8?±?0.6?Ma and 89.5?±?0.6?Ma. These samples are dominantly K-feldspar, for which we assume an argon closure temperature of ～150?°C, thus they give the age of cooling below ～150?°C–200?°C.     

Rb-Sr and Sm-Nd Geochronology of the Eppawala Metamorphic Rocks and Carbonatite,Wanni Complex,Sri Lanka

Petrological studies on the surrounding metamorphic rocks of the Eppawala carbonatite body, Wanni complex, Sri Lanka, revealed that these rocks had been metamorphosed under amphibolite to granulite facies conditions. Garnet-sillimanite-biotite gneiss shows lower range of metamorphic temperature (730–770°C) than the migmatite gneiss (750–780°C) and the pressure varies from 6.6–7.8 kbar to 5.6–6.4 kbar respectively. The metamorphic age of the garnet-sillimanite-biotite gneiss and migmatite gneiss dated 607±23 Ma and 626±16 Ma, respectively for mineral — whole rock isochron in Sm-Nd system. These ages are compatible with the ages of regional high-grade metamorphism occurred 610–550 Ma in the three crustal units in Sri Lanka.Rb-Sr system for biotite, apatite and whole-rock fractions suggests 493±5 Ma for the Eppawala carbonatite body. This age indicates the cooling age of the biotite. The presence of non-crystalline carbonatite matrix and large hexagonal apatite crystals suggests a slow cooling history. Further, low closure temperature of biotite in Rb-Sr system suggests that the intrusion age of carbonatite body should be more than 493 Ma, but non-metamorphosed nature provides evidence that the intrusion age of the carbonatite body should be less than the period of regional metamorphism 610–550 Ma. Therefore, Eppawala carbonatite body has a strong possibility to be a late to post magmatic intrusion. The other late to post magmatic intrusions in the Wanni complex and Highland complex are dated between 580–550 Ma. Therefore, the most probable intrusion age of the Eppawala carbonatite body is suggested to be around 550 Ma.     

Porphyry Cu-Mo-(Au) mineralization: the age and relationship with igneous rock complexes of the Borgulikan ore field (upper-Amur region)

The Borgulikan ore field is localized in the west of the Umlekan-Ogodzha volcanoplutonic belt made up of various igneous (upper-Amur granite-granodiorite (140–134 Ma), Burunda monzodiorite-granodiorite (130–127 Ma), and Taldan andesite (127–123 Ma)) and superposed (Early Cretaceous Gal’ka trachybasalt-rhyolite (119–115 Ma) and Late Cretaceous trachybasalt-trachyandesite (97–94 Ma)) complexes. ⁴⁰Ar/³⁹Ar dating of porphyry intrusions breaking through the Taldan volcanic complex and associated with Cu-Mo-(Au) mineralization yielded the following ages: early (dark) “pre-ore” quartz monzodiorite porphyrites — 125.8±0.7 Ma (groundmass) and 125.2±1.8 Ma (biotite phenocrysts); late (cream) “syn-ore” quartz monzodiorite porphyrites — 122.6±0.7 Ma (biotite phenocrysts). In age and many geochemical features the quartz monzodiorite porphyrites are close to the Taldan complex volcanics. Both of these rocks seem to belong to the same volcanoplutonic association.     

The Late Triassic Central Patagonian Batholith: Magma hybridization, 40Ar/39Ar ages and thermobarometry

The Late Triassic Central Patagonian Batholith is a key element in paleogeographic models of West Gondwana just before to the break-up of the supercontinent. The preexisting classification of units of this batholith was mainly based on isotopic and geochemical data. Here we report the results of field mapping and petrography, backed up by three new ⁴⁰Ar/³⁹Ar biotite ages, which reveal previously unnoticed relationships of the rocks in the batholith. Based on the new information we present a reorganization of units where the batholith is primarily formed by the Gastre and the Lipetrén superunits. The Gastre Superunit is the oldest magmatic suite and is composed of I-type granites which display evidence of felsic and mafic magma interaction. It is formed by 4 second-order units: 1) equigranular hornblende–biotite granodiorites, 2) porphyritic biotite–hornblende monzogranites, 3) equigranular biotitic monzogranites and 4) hornblende quartz-diorites. Emplacement depth of the Gastre Superunit is bracketed between 6 and 11 km (1.8–3 kbar), and the maximum recorded temperatures of emplacement are comprised between 660 and 800 °C. The recalculated Rb/Sr age is 222 ± 3 Ma and the porphyritic biotite–hornblende monzogranites yielded a ⁴⁰Ar/³⁹Ar age in biotite of 213 ± 5 Ma. On the other hand, the Lipetrén Superunit is made up by fine-grained biotitic monzo- and syenogranites that postdate magma hybridization processes and intrude all the other units. The recalculated Rb/Sr age for this suite is identical to a ⁴⁰Ar/³⁹Ar age in biotite extracted from one of its monzogranites (206.4 ± 5.3 and 206 ± 4 Ma, respectively). This and the observed textural features suggest very fast cooling related to a subvolcanic emplacement. An independent unit, the “Horqueta Granodiorite”, which has previously been considered as the record of a Jurassic intrusive stage in the Central Patagonian Batholith, gave a ⁴⁰Ar/³⁹Ar age in biotite of 214 ± 2 Ma. This and the reexamination of available isotopic data allow propose that this granodiorite unit is part of the Late Paleozoic intrusives in the region. The Late Triassic Central Patagonian Batholith is overlain by 190–185 Ma volcano-sedimentary rocks, suggesting that it was exposed sometime between the latest Triassic and earliest Jurassic times, roughly coeval with a major accretionary episode in the southwestern margin of Gondwana.     

40Ar/39Ar Ages of the Da Lien Granite Related to the Nui Phao W Mineralization in Northern Vietnam

⁴⁰Ar/³⁹Ar dating was conducted on the Da Lien granite related to greisen‐skarn type polymetallic (W‐CaF₂‐Cu‐Bi‐Au) mineralization in Nui Phao, northern part of Vietnam in the South China Plate. Biotite and muscovite separates from the biotite‐muscovite granite and greisenized granite indicate four plateau ages: 82.2 ± 0.4 Ma, 82.8 ± 0.3 Ma, 81.5 ± 0.3 Ma and 82.5 ± 0.4 Ma. The plateau ages were not significantly influenced by excess ⁴⁰Ar in dated minerals or by loss of radiogenic ⁴⁰Ar due to hydrothermal activities. The results indicate that solidification of granite related to the polymetallic mineralization occurred in the Late Cretaceous between 82.8 Ma and 81.5 Ma.     

40Ar/39Ar ages of detrital white mica from Upper Austroalpine units in the Eastern Alps, Austria: Evidence for Cadomian and contrasting Variscan sources

Five detrital white mica concentrates from very low-grade, metaclastic sequences within pre-Variscan basement and post-Variscan cover units of the Upper Austroalpine Nappe Complex (Eastern Alps) have been dated with ⁴⁰Ar/³⁹Ar incremental heating techniques to constrain the age of tectonothermal events in their respective source areas. Two samples from early Palaeozoic sandstone exposed within the same Alpine nappe record slightly discordant age spectra. The maximum age recorded in one is 562.2±0.7?Ma, whereas the other yielded a ⁴⁰Ar/³⁹Ar plateau age of 607.3±0.3?Ma. These results indicate a source area affected by Cadomian tectonothermal activity. Three detrital muscovite concentrates from post-Variscan, Late Carboniferous and Permian cover sequences exposed within three different Alpine nappes yielded ⁴⁰Ar/³⁹Ar plateau ages of 359.6?±?1.1?Ma, 310.5±1.2?Ma, and 303.3±0.2?Ma. The contrasting detrital white mica ages are interpreted to reflect different source areas. Detrital muscovite from a post-Variscan Carboniferous molasse-type sequence and from a Permian Verrucano-type sequence record ages which indicate “late” Variscan (e.g. 330–300?Ma) metamorphic sources. By contrast, detrital white mica from another Permian Verrucano-type sequence suggests a source area affected by “early” Variscan (e.g. 400–360?Ma) metamorphism. These results help clarify palinspastic relationships and tectonic correlations between pre-Late Carboniferous metamorphic basement sequences and Carboniferous to Permian cover sequences.     

LOW TEMPERATURE DATING OF HIGH MOUNTAIN ROCKS:(U-Th)/He AGES FROM HIGHER HIMALAYAN SAMPLES, EASTERN NEPAL

LOW TEMPERATURE DATING OF HIGH MOUNTAIN ROCKS:(U-Th)/He AGES FROM HIGHER HIMALAYAN SAMPLES, EASTERN NEPAL1　HouseMA ,WernickeBP ,FarleyKA .DatingtopographyoftheSierraNevada ,California ,usingapatite (U Th) /Heages[J].Nature,1998,396 (5 ) :6 6～ 6 9. 2　HubbardMS ,Harrison .4 0 Ar/ 3 9ArageconstraintsondeformationandmetamorphismintheMainCentralThrustzoneandTibetanSlab ,EasternNepalHimalaya[J].Tectonics,1989,8(4) :86 5～ 880 . 3　HubbardMS …     

40Ar/39Ar record of late Pan–African exhumation of a granulite facies terrain, central Dronning Maud Land, East Antarctica

⁴⁰Ar/³⁹Ar geochronological data on hornblende, biotite and K-feldspar provide constraints on the cooling path experienced by a high-grade metamorphic complex from the Mühlig–Hofmannfjella and Filchnerfjella (6–8°E), central Dronning Maud Land, Antarctica, during the late Neoproterozoic-early Palaeozoic Pan–African orogeny. Hornblende ages yield c. 481 Ma, biotite ages range from c. 466 Ma to c. 435 Ma, whereas K-feldspar ages of the gneisses are c. 437 Ma. The ⁴⁰Ar/³⁹Ar data suggest initial cooling at a rate of ~10 °C/Myr between 481 and 465 Ma, followed by a lower cooling rate of ~6 °C/Myr during the subsequent c. 30 million years. The K-feldspar ⁴⁰Ar/³⁹Ar ages place a lower time limit on the duration of the exhumation, by the time of thermal relaxation to a stable continental geotherm. The ⁴⁰Ar/³⁹Ar data reflecting cooling indicate tectonic exhumation related to orogenic collapse during a later phase of the Pan–African orogeny.     

蓟县剖面杨庄组和雾迷山组形成年龄的研究

对蓟县剖面杨庄组和雾迷山组白云岩中条带状燧石采用⁴⁰Ar/³⁹Ar阶段加热技术和Cl-Ar相关性,消除了样品中次生流体包体及过剩Ar的干扰,从而获得燧石⁴⁰Ar/³⁹Ar等时年龄。结果表明高于庄组-杨庄组、杨庄组-雾迷组和雾迷山-洪水庄组的界限年龄分别是1380、1310和1207Ma.     

Genetic and ore-forming ages of the Fe–P–(Ti) oxide deposits associated with mafic–ultramafic–carbonatite complexes in the Kuluketage block,NW China

Abstract

During the past 50 years, many geological and ore-deposit investigations have led to the discovery of the Fe–P–(Ti)-oxide deposits associated with mafic–ultramafic–carbonatite complexes in the Kuluketage block, northeastern Tarim Craton. In this paper, we discuss the genetic and ore-forming ages, tectonic setting, and the genesis of these deposits (Kawuliuke, Qieganbulake and Duosike). LA-ICP-MS zircon U–Pb dating yielded a weighted mean ²⁰⁶Pb/²³⁸U ages of 811?±?5?Ma, 811?±?4?Ma, and 840?±?5?Ma for Kawuliuke ore-bearing pyroxenite, Qieganbulake gabbro and Duosike ore-bearing pyroxenite, respectively. The CL images of the Kawuliuke apatite grains show core–rim structure, suggesting multi-phase crystallisation, whereas the apatite grains from Qieganbulake and Dusike deposits do not show any core–rim texture, suggesting a single-stage crystallisation. LA-ICP-MS apatite ²⁰⁷Pb-corrected U–Pb dating provided weighted mean ²⁰⁶Pb/²³⁸U ages of 814?±?21?Ma and 771?±?8?Ma for the Kawuliuke ores, and 810?±?7?Ma and 841?±?7?Ma for Qieganbulake and Duosike ores, respectively. The core–rim texture in apatite by CL imaging as well as two different ore-forming ages in the core and rim of the apatite indicate two metallogenic events for the Kawuliuke deposit. The first metallogenic period was magmatic in origin, and the second period was hydrothermal in origin. The initial ore-forming age of the Kawuliuke Fe–P–Ti mineralisation was ca 814?Ma and the second one was ca 771?Ma. On the other hand, the ore-forming ages of the Qieganbulake and Duosike deposits were ca 810?Ma and ca 841?Ma, respectively. Qieganbulake and Duosike deposits were of magmatic origin. Combined with previous geochronological data and the research on the tectonic background, we infer that the Kawuliuke, Qieganbulake and Duosike Fe–P–(Ti)-oxide deposits were formed in a subduction-related tectonic setting and were the product of subduction-related magmatism.     

Timing and duration of hydrothermal activity at the Los Bronces porphyry cluster: an update

New geochronological data from the Los Bronces cluster of the Río Blanco-Los Bronces mega-porphyry Cu-Mo district establish a wide range of magmatism, hydrothermal alteration, and mineralization ages, both in terms of areal extent and time. The northern El Plomo and southernmost Los Piches exploration areas contain the oldest barren porphyritic intrusions with U-Pb ages of 10.8?±?0.1 Ma and 13.4?±?0.1 Ma, respectively. A hypabyssal barren intrusion adjacent northwesterly to the main pit area yields a slightly younger age of 10.2?±?0.3 Ma (San Manuel sector, U-Pb), whereas in the Los Bronces (LB) open-pit area, the present day mineral extraction zone, porphyries range from 8.49 to 6.02 Ma (U-Pb). Hydrothermal biotite and sericite ages are up to 0.5 Ma younger but consistent with the cooling of the corresponding intrusion events of each area. Two quartz-molybdenite B-type veins from the LB open pit have Re-Os molybdenite ages of 5.65?±?0.03 Ma and 5.35?±?0.03 Ma consistent with published data for the contiguous Río Blanco cluster. The San Manuel exploration area within the Los Bronces cluster, located about 1.5–2 km southeast of the open-pit extraction zone, shows both the oldest hydrothermal biotite (7.70?±?0.07 Ma; ⁴⁰Ar/³⁹Ar) and breccia cement molybdenite ages (8.36?±?0.06 Ma; Re-Os) registered in the entire Río Blanco-Los Bronces district. These are also older than those reported from the El Teniente porphyry Cu(-Mo) deposit, suggesting that mineralization in the late Miocene to early Pliocene porphyry belt of Central Chile commenced 2 Ma before the previously accepted age of 6.3 Ma.     

The performance of the Noblesse multi-collector noble gas mass spectrometer for <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronology

Noblesse multi-collector noble gas mass spectrometer is specially designed for multi-collection of Ar isotopes with different beam sizes, especially for small ion beams, precisely, and hence is perfectly suitable for ⁴⁰Ar/³⁹Ar geochronology. We have analyzed widely used sanidine, muscovite, and biotite standards with recommended ages of ~ 1.2–133 Ma, with the aim to assess the reliability of Noblesse for ⁴⁰Ar/³⁹Ar dating. An ESI MIR10 30W CO₂ laser was used for total fusion or incremental heating samples. Extracted gases were routinely purified by four SAES NP10 getters (one at ~ 400 °C and others at room temperature). A GP50 getter and a metal cold finger cooled by liquid N (? 196 °C) were also attached for additional purification if necessary. The Ar isotopes were then measured by Noblesse using Faraday or multiplier according to the signal intensities. Over a period of 1.5 months 337 air calibrations produced a weighted mean ⁴⁰Ar/³⁶Ar of 296.50 ± 0.08 (2σ, MSWD = 4.77). Fish Canyon sanidine is used to calculate J-values, which show good linear relationship with position in irradiation. The age of four mineral standards (Alder Creek sanidine, Brione muscovite, Yabachi sanidine, and Fangshan biotite) are within error of the accepted ages. Five Alder Creek sanidine aliquots yielded an age range of 1.174–1.181 ± 0.013 Ma (2σ) which broadly overlaps the established age of the standard and the uncertainty approaches those of the foremost Ar/Ar laboratories in the world. The weighted mean ages of four Brione muscovite aliquots (18.75 ± 0.16 Ma, 2σ), five Yabachi sanidine aliquots (29.50 ± 0.19 Ma, 2σ), and three Fangshan biotite aliquots (133.0 ± 0.76 Ma, 2σ) are consistent with the recommended values of these standards, and the uncertainties are typical of modern Ar/Ar laboratories world-wide.     

Thermal Evolution of the Tanlu Fault Zone on the Eastern Margin of the Dabie Mountains and Its Tectonic Implications

Five samples of muscovite from mylonites of the earlier Tanlu ductile shear zone on the eastern margin of the Dabie Mountains yield 40Ar/39Ar ages ranging from 178 Ma to 196 Ma. Three of them have reliable plateau ages of 188.7±0.7 Ma, 189.7±0.6 Ma and 192.5±0.7 Ma respectively, which indicates a syn-orogenic, sinistral strike-slip thermal event. This displacement movement derived from the continent-continent collision of the North and South China blocks took place in the Early Jurassic and after uplifting of high-pressure to ultrahigh-pressure slabs to the mid-crust. It is suggested that during the collision the Tanlu fault zone was an intracontinental transform fault caused by differential subduction speeds. The 40Ar/39Ar ages of mylonite whole-rock and muscovite from the later Tanlu ductile shear zone suggest another sinistral strike-slip cooling event at 128 Ma. During this strike-slip faulting, large-scale intrusion and doming uplift occurred in the eastern part of the Dabie orogenic belt. Data o