中亚造山带东部非典型辉绿结构辉绿岩的岩相学特征及鉴定

在中亚造山带东部构造带中发现角闪变质辉绿岩,岩相学特征表明具非典型辉绿结构,显示变余辉绿结构及变余嵌晶含长结构.主要矿物为斜长石及角闪石,次要矿物为单斜辉石和阳起石.全岩岩石化学分析结果：SiO₂含量为49.15%～52.96%、Na₂O+K₂O含量为2.71%～5.07%、CaO含量为7.07%～10.40%、Al₂O₃含量为14.77%～17.31%、TFe0含量为8.80%～12.27%、MgO含量为6.45%～9.57%;在火山岩TAS分类图落入玄武岩区,属于基性岩范围;说明研究区具有非典型辉绿结构的岩石命名为角闪变质辉绿岩的正确性.角闪变质辉绿岩经历了退变质作用：基性斜长石（拉长石）退变质为中性斜长石（中长石）,进一步退变质为钠长石或钠更长石;单斜辉石退变质为角闪石,角闪石退变质为阳起石.     

Reactions and textures in grossular–wollastonite–scapolite calc–silicate granulites from Maligawila, Sri Lanka: evidence for high-temperature isobaric cooling in the meta-sediments of the Highland Complex

Grossular–wollastonite–scapolite calc–silicate granulites from Maligawila in the Buttala klippe, which form part of the overthrusted rocks of the Highland Complex of Sri Lanka, preserve a number of spectacular coronas and replacement textures that could be effectively used to infer their P–T–fluid history. These textures include coronas of garnet, garnet–quartz, and garnet–quartz–calcite at the grain boundaries of wollastonite, scapolite, and calcite as well as calcite–plagioclase and calcite–quartz symplectites or finer grains after scapolite and wollastonite respectively. Other textures include a double rind of coronal scapolite and coronal garnet between matrix garnet and calcite. The reactions that produced these coronas and replacement textures, except those involving clinopyroxene, are modelled in the CaO–Al₂O₃–SiO₂–CO₂ system using the reduced activities. Calculated examples of T–X_CO2 and P–X_CO2 projections indicate that the peak metamorphic temperature of about 900–875 °C at a pressure of 9 kbar and the peak metamorphic fluid composition is constrained to be low in X_CO2 (0.1<X_CO2<0.30). Interpretation of the textural features on the basis of the partial grids revealed that the calc–silicate granulites underwent high-temperature isobaric cooling, from about 900–875 °C to a temperature below 675 °C, following the peak metamorphism. The late-stage cooling was accompanied by an influx of hydrous fluids. The calc–silicate granulites provide evidence for high-temperature isobaric cooling in the meta-sediments of the Highland Complex, earlier considered by some workers to be confined exclusively to the meta-igneous rocks. The coronal scapolite may have formed under open-system metasomatism.     

Torngat ultramafic lamprophyres and their relation to the North Atlantic Alkaline Province

Geological mapping and diamond exploration in northern Quebec and Labrador has revealed an undeformed ultramafic dyke swarm in the northern Torngat Mountains. The dyke rocks are dominated by an olivine-phlogopite mineralogy and contain varying amounts of primary carbonate. Their mineralogy, mineral compositional trends and the presence of typomorphic minerals (e.g. kimzeyitic garnet), indicate that these dykes comprise an ultramafic lamprophyre suite grading into carbonatite. Recognized rock varieties are aillikite, mela-aillikite and subordinate carbonatite. Carbonatite and aillikite have in common high carbonate content and a lack of clinopyroxene. In contrast, mela-aillikites are richer in mafic silicate minerals, in particular clinopyroxene and amphibole, and contain only small amounts of primary carbonate. The modal mineralogy and textures of the dyke varieties are gradational, indicating that they represent end-members in a compositional continuum.

The Torngat ultramafic lamprophyres are characterized by high but variable MgO (10–25 wt.%), CaO (5–20 wt.%), TiO₂ (3–10 wt.%) and K₂O (1–4 wt.%), but low SiO₂ (22–37 wt.%) and Al₂O₃ (2–6 wt.%). Higher SiO₂, Al₂O₃, Na₂O and lower CO₂ content distinguish the mela-aillikites from the aillikites. Whereas the bulk rock major and trace element concentrations of the aillikites and mela-aillikites overlap, there is no fractional crystallization relation between them. The major and trace element characteristics imply related parental magmas, with minor olivine and Cr-spinel fractionation accounting for intra-group variation.

The Torngat ultramafic lamprophyres have a Neoproterozoic age and are spatially and compositionally closely related with the Neoproterozoic ultramafic lamprophyres from central West Greenland. Ultramafic potassic-to-carbonatitic magmatism occurred in both eastern Laurentia and western Baltica during the Late Neoproterozoic. It can be inferred from the emplacement ages of the alkaline complexes and timing of Late Proterozoic processes in the North Atlantic region that this volatile-rich, deep-seated igneous activity was a distal effect of the breakup of Rodinia. This occurred during and/or after the rift-to-drift transition that led to the opening of the Iapetus Ocean.     

江南造山带西段桂北四堡地区830 Ma辉长岩锆石SIMS U-Pb年代学和岩石地球化学特征及其岩石成因研究

本次研究对象为江南造山带西段桂北四堡地区新元古代辉长岩,主要由斜长石和单斜辉石组成,含有少量的橄榄石和钛铁氧化物,表明在岩浆演化过程中发生了斜长石和单斜辉石以及少量橄榄石的分离结晶作用。辉长岩锆石SIMS U-Pb谐和年龄为(830±7)Ma,指示其侵位年龄约为830 Ma。全岩具有低SiO₂含量(48.46%~53.99%)、高MgO含量(9.27%~25.22%)、Mg^#值较高(62~79)的特征。辉长岩为钙碱性系列岩石,其稀土元素球粒陨石标准化和微量元素原始地幔标准化与典型的弧岩浆相似,具有相对富集轻稀土元素((La/Yb)_N=2.2~3.7,(La/Sm)_N=2.5~2.9)和大离子亲石元素,明显的高场强元素(Nb、Ta和Ti)亏损的特征,还具有较高的Th/Nb比值(0.7~0.8)和低Nb/La比值(0.4~0.6)。辉长岩具有负的ε_Nd(t)值(-6.3~-3.0)和正的ε_Hf(t)值(8.0~12.1),指示其源区为亏损地幔,但有富集组分加入。结合区域地质特征,推测辉长岩形成于活动大陆边缘俯冲构造背景,起源于受沉积物流体交代了的楔地幔。     

On the origin of multi‐layer coronas between olivine and plagioclase at the gabbro–granulite transition,Valle Fértil–La Huerta Ranges,San Juan Province,Argentina

Troctolitic gabbros from Valle Fértil and La Huerta Ranges, San Juan Province, NW‐Argentina exhibit multi‐layer corona textures between cumulus olivine and plagioclase. The corona mineral sequence, which varies in the total thickness from 0.5 to 1 mm, comprises either an anhydrous corona type I with olivine|orthopyroxene|clinopyroxene+spinel symplectite|plagioclase or a hydrous corona type II with olivine|orthopyroxene|amphibole|amphibole+spinel symplectite|plagioclase. The anhydrous corona type I formed by metamorphic replacement of primary olivine and plagioclase, in the absence of any fluid/melt phase at <840 °C. Diffusion controlled metamorphic solid‐state replacement is mainly governed by the chemical potential gradients at the interface of reactant olivine and plagioclase and orthopyroxene and plagioclase. Thus, the thermodynamic incompatibility of the reactant minerals at the gabbro–granulite transition and the phase equilibria of the coronitic assemblage during subsequent cooling were modelled using quantitative μMgO–μCaO phase diagrams. Mineral reaction textures of the anhydrous corona type I indicate an inward migration of orthopyroxene on the expense of olivine, while clinopyroxene+spinel symplectite grows outward to replace plagioclase. Mineral textures of the hydrous corona type II indicate the presence of an interstitial liquid trapped between cumulus olivine and plagioclase that reacts with olivine to produce a rim of peritectic orthopyroxene around olivine. Two amphibole types are distinguished: an inclusion free, brownish amphibole I is enriched in trace elements and REEs relative to green amphibole II. Amphibole I evolves from an intercumulus liquid between peritectic orthopyroxene and plagioclase. Discrete layers of green amphibole II occur as inclusion‐free rims and amphibole II+spinel symplectites. Mineral textures and geochemical patterns indicate a metamorphic origin for amphibole II, where orthopyroxene was replaced to form an inner inclusion‐free amphibole II layer, while clinopyroxene and plagioclase were replaced to form an outer amphibole+spinel symplectite layer, at <770 °C. Calculation of the possible net reactions by considering NCKFMASH components indicates that the layer bulk composition cannot be modelled as a ‘closed’ system although in all cases the gain and loss of elements within the multi‐layer coronas (except H₂O, Na₂O) is very small and the main uncertainties may arise from slight chemical zoning of the respective minerals. Local oxidizing conditions led to the formation of orthopyroxene+magnetite symplectite enveloping and/or replacing olivine. The sequence of corona reaction textures indicates a counter clockwise P–T path at the gabbro–granulite transition at 5–6.5 kbar and temperatures below 900 °C.     

Modification of the subcontinental mantle beneath East Serbia: Evidence from orthopyroxene-rich xenoliths

Orthopyroxene-rich olivine websterite xenoliths (OWB₂) in Palaeogene basanites in East Serbia are mostly composed of tabular low-Al₂O₃ orthopyroxene (> 70 vol.%, Mg# 85–87) containing tiny Cr spinel inclusions. Orthopyroxene shows a slightly U-shaped primitive mantle-normalized trace element pattern with strong peaks at U and Pb, similar to that of orthopyroxene from normal regional peridotitic mantle. In between the orthopyroxenes are interstitial spaces composed of partially altered olivine (Mg# 85–87), clinopyroxene, Ti-rich spinel, Mg-bearing calcite, K-feldspar, apatite, ilmenite and relicts of a hydrous mineral. Clinopyroxene appears as selvages around orthopyroxene and as coarser euhedral crystals. Trace element patterns of the clinopyroxene selvages resemble those of adjacent orthopyroxene, whereas the coarser ones have flatter and more LREE- and LILE-enriched patterns, similar to that of metasomatic clinopyroxene. The OWB₂ xenoliths are interpreted as having formed in two stages. During Stage I orthopyroxene crystallized, along with some spinel, olivine and probably hydrous phase(s). This original OWB₂ lithology was a hydrous olivine-bearing orthopyroxenite that crystallised from subduction-related SiO₂-saturated, boninite-like magmas. During Stage II the interstitial minerals formed due to infiltration of a low-SiO₂, high-CaO and CO₂-rich external melt, accompanied by decomposition of original H₂O-bearing minerals. The calculated composition of the infiltrating liquid corresponds to a mafic alkaline melt similar to the basanitic host but more enriched in CO₂, LREE and LILE. Metasomatism is interpreted in terms of small degree melts related to the Palaeogene mafic alkaline magmatism.     

Formation of Al-rich titanite (CaTiSiO4O–CaAlSiO4OH) reaction rims on ilmenite in metamorphic rocks as a function of fH2O and fO2

Reaction rims of titanite on ilmenite are described in samples from four terranes of amphibolite-facies metapelites and amphibolites namely the Tamil Nadu area, southern India; the Val Strona area of the Ivrea-Verbano Zone, northern Italy, the Bamble Sector, southern Norway, and the northwestern Austroalpine Ötztal Complex. The titanite rims, and hence the stability of titanite (CaTiSiO₄O) and Al–OH titanite, i.e. vuaganatite (hypothetical end-member CaAlSiO₄OH), are discussed in the light of fH₂O- and fO₂-buffered equilibria involving clinopyroxene, amphibole, biotite, ilmenite, magnetite, and quartz in the systems CaO–FeO/Fe₂O₃–TiO₂–SiO₂–H₂O–O₂ (CFTSH) and CaO–FeO/Fe₂O₃–Al₂O₃–SiO₂–H₂O–O₂ (CFASH) present in each of the examples. Textural evidence suggests that titanite reaction rims on ilmenite in rocks from Tamil Nadu, Val Strona, and the Bamble Sector originated most likely due to hydration reactions such as clinopyroxene + ilmenite + quartz + H₂O = amphibole + titanite and oxidation reactions such as amphibole + ilmenite + O₂ = titanite + magnetite + quartz + H₂O during amphibolite-facies metamorphism, or, as in the case of the Ötztal Complex, during a subsequent greenschist-facies overprint. Overstepping of these reactions requires fH₂O and fO₂ to be high for titanite formation, which is also in accordance with equilibria involving Al–OH titanite. This study shows that, in addition to P, T, bulk–rock composition and composition of the coexisting fluid, fO₂ and fH₂O also play an important role in the formation of Al-bearing titanite during amphibolite- and greenschist-facies metamorphism.     

电子探针波谱法在辉石种属鉴定中的应用

变质岩中辉石显微镜下以高正突起、辉石式解理和干涉色为主要鉴定特征.辉石族矿物有斜方辉石和单斜辉石2个亚族,其中斜方辉石亚族有7种辉石类型,单斜辉石亚族有12种辉石类型.为了验证岩石薄片鉴定结果的准确性,往往是利用X射线粉晶衍射技术进行比对分析.岩石中有几种辉石及辉石类型,X射线粉晶衍射方法则无法区分.本次研究是利用电子探针波谱技术对矿物主量元素进行分析,通过所测样品微区化学成分含量推测矿物名称.25件样品微区化学成分分析结果统计显示：MgO为8.36%~17.34%,FeO为27.57%~39.77%,SiO₂为47.94%~52.70%;次要成分含量：Cr₂O₃为0.01%~6.28%,Na₂O为0.00%~0.19%,Al₂O₃为0.43%~3.11%,CaO为0.38%~1.94%,MnO₂为0.09%~0.79%;总量为99.64%~100.00%.化学成分与紫苏辉石组分相当,可以确定所测样品为紫苏辉石.     

Petrology of the Hopen mangerite-charnockite intrusion, Lofoten, north Norway

The Hopen massif, intrusive age 1900 m.y., exposed area 15 km², in the Lofoten-Vesterålen granulite facies province has the mineral assemblages: (1) mesoperthite+plagioclase (An_7–20)+quartz+clinopyroxene (Di_20–25)+orthopyroxene En_15–25+opaques±minor amphibole±minor biotite; (2) mesoperthite+plagioclase (An <2)+quartz+clinopyroxene (Di <10)+olivine Fe lt;5)+opaques. By using mineral and whole rock analyses, the crystallization conditions were estimated to be 1000°C, 12 kb load pressure and an oxygen fugacity approximately corresponding to the WM buffer. Rocks with the assemblage of type (2) contain secondary orthoferrosilite (Fe_0.90–0.95Mn_0.04–0.07Mg_0.01Ca_0.01)₂Si₂O₆, generated by reactions involving fayalite, magnetite and quartz at 800°C, 10kb load pressure and at oxygen fugacities approaching QFM buffer conditions. Subsequent to a crustal thickening, the mangeritic rocks in Lofoten-Vesterålen were emplaced in a tensional environment comparable with modern continental rifts. A ‘gabbro pillow’ magma chamber at the crustal base is proposed as parental magma for the mangeritic rocks, of which the Hopen massif represents a late differentiation.     

西藏定结高压基性麻粒岩(退变榴辉岩)的变质P-T轨迹及构造意义

定结（Dinggye）位于藏南高喜马拉雅结晶岩系的中部,研究该区域麻粒岩的变质P-T轨迹对于理解青藏高原的碰撞和抬升过程至关重要.通过对该地区的高压基性麻粒岩（退变榴辉岩）的岩相学观察,确定了4期矿物组合:（1）峰期榴辉岩相矿物组合（M₁）由石榴子石（核部）+绿辉石（假象）+石英+金红石组成;（2）高压麻粒岩相矿物组合（M₂）主要由石榴子石（幔部）+单斜辉石+斜长石+钛铁矿+角闪石+黑云母组成;（3）中压麻粒岩相矿物组合（M₃）由石榴子石（边缘）+斜方辉石+斜长石+钛铁矿+黑云母组成;（4）角闪岩相矿物组合（M₄）主要由角闪石+斜长石组成.在NCFMASHTO体系下,用THERMOCALC软件对该高压基性麻粒岩进行了热力学模拟.结合传统温压计和平均温压计计算结果,求得M₂、M₃、M₄阶段的温压条件分别为786~826 ℃、0.78~0.96 GPa;798~850 ℃、0.71~0.75 GPa;610~666 ℃、0.51~0.60 GPa,这指示了一条以峰期后近等温降压（ITD）为特征的顺时针P-T轨迹.结合已有地质资料,表明定结高压基性麻粒岩（退变榴辉岩）是喜马拉雅碰撞造山的产物,峰期后经历了近等温降压的构造抬升过程.      

Petrogenesis of Corundum-Bearing Mafic Rock in the Horoman Peridotite Complex, Japan

A corundum-bearing Type II mafic rock, within the Horoman peridotite,Japan, was petrologically examined in detail to obtain the P–Tpaths of the mafic rock as well as of the host peridotite. Ofall the mafic rocks documented from the Horoman complex, onlythe corundum-bearing mafic rock has preserved, at least partly,its high-pressure mineralogy; all of the others have been completelyrecrystallized at low pressures. The Type II mafic rocks wereinitially formed at <1·0 GPa as cumulates of olivine,plagioclase and clinopyroxene. Corundum was then formed by metamorphismand/or partial melting of the Type II protolith at higher pressures(>1·5 GPa) than the initial condition of formation.Corundum reacted with clinopyroxene during exhumation of theHoroman peridotite down to the plagioclase stability field.The field and petrographical observations of the Type II maficrocks (± corundum) coupled with published isotopic datasuggest a complicated spiral-like P–T trajectory for theHoroman peridotite. The Type II protolith was formed at lowpressure within the peridotite at the time of initial formationof the Horoman peridotite as a residue from primitive mantleat     

胶东海阳所堆积辉长岩的变质反应结构、石榴石形成及P—T演化

海阳所堆积辉长岩由橄长岩、橄榄辉长岩和辉长岩组成。在橄长岩和橄榄辉长岩中发育有典型的变质反应结构：主要为橄榄石与斜长石之间形成由斜方辉石、尖晶石、角闪石和石榴石等矿物组成的多期次次变边，并有三个不同世代变质矿物，早期Cpx＋Opx＋Spl，中期Amp，晚期Grt；期次是钛铁矿与斜长石之间形成石榴石次变边，相对比较简单，只有一个世代变质矿物，为Grt＋Amp＋Rut或Grt＋Rut岩中石榴石是通过斜长石与角闪石或斜长石与钛铁矿之间的变质反应形成的，虽为峰值变质作用的产物，但变质反应的期次及类型不同导致了所形成石榴石的温度和压力有所不同。堆积辉长岩形成演化的温压计算表明，堆积辉长岩在经过近等压降温的岩浆作用之后的变质作用早期，仍为近等压降温，而晚期则表现为近等温升压。这一特殊的P－T演化可能反映了堆积辉长冷侵位与深俯冲特征。     

东昆仑中灶火地区超镁铁质辉石岩的成因

最近在青海东昆北中灶火地区发现超镁铁质岩的岩石学、地球化学以及成因矿物学等方面的研究成果.岩石主要由单斜辉石、斜方辉石和角闪石组成, 另有少量斜长石、石英、黑云母和铁质不透明矿物.角闪石和黑云母为后期退变质矿物.斜方辉石成因判别分析结果为岩浆成因, 故该超镁铁质岩为辉石岩而非麻粒岩.该辉石岩化学成分上表现为异常的高MgO、高CaO、低Al₂O₃特征, 微量元素表现为Rb、Th富集而Nb、Ti的亏损, 表明其来源于富集地幔.通过岩相学、稀土元素等特征与前人研究结果对比认为该辉石岩是俯冲洋壳部分熔融产生的富Si熔体与地幔橄榄岩发生交代反应产生辉石岩岩浆, 然后底侵到地壳中部冷却结晶形成的.野外地质特征显示辉石岩的侵位晚于发生糜棱岩化的围岩, 即晚于围岩的形成时代, 即早二叠世, 说明该辉石岩是在中二叠世古特提斯洋向北大规模俯冲及其所导致的弧后伸展的构造背景下形成的.      

Isotopic (O, Sr, Nd) and trace element geochemistry of the Laouni layered intrusions (Pan-African belt, Hoggar, Algeria): evidence for post-collisional continental tholeiitic magmas variably contaminated by continental crust

The three layered intrusions studied in the Laouni area have been emplaced within syn-kinematic Pan-African granites and older metamorphic rocks. They have crystallized at the end of the regional high-temperature metamorphism, but are free from metamorphic recrystallization, revealing a post-collisional character. The cumulate piles can be interpreted in terms of two magmatic liquid lines of descent: one is tholeiitic and marked by plagioclase–olivine–clinopyroxene cumulates (troctolites or olivine bearing gabbros), while the other is calc-alkaline and produced orthopyroxene–plagioclase rich cumulates (norites). One intrusion (WL (West Laouni)-troctolitic massif), shows a Lower Banded Zone where olivine-chromite orthocumulates are interlayered with orthopyroxene-rich and olivine–plagioclase–clinopyroxene cumulates, whereas the Upper Massive Zone consists mainly of troctolitic and gabbroic cumulates. The other two massifs are more homogeneous: the WL-noritic massif has a calc-alkaline differentiation trend whereas the EL (East Laouni)–troctolitic massif has a tholeiitic one. Separated pyroxene and plagioclase display similar incompatible trace element patterns, regardless of the cumulate type. Calculated liquids in equilibrium with the two pyroxenes for both noritic and troctolitic cumulates are characterized by negative Nb, Ta, Zr and Hf anomalies and light REE enrichment inherited from the parental magmas. Troctolitic cumulates have mantle-derived δ¹⁸O (+5 to +6‰), initial ⁸⁷Sr/⁸⁶Sr (Sr_i=0.7030 to 0.7054), _Nd (+5 to −1) values whereas noritic cumulates are variably enriched in δ¹⁸O (+7 to +9‰), show negative _Nd (−7 to −12) and slightly higher Sr_i (0.7040–0.7065). Based on field, isotopic ratios are interpreted as resulting from a depleted mantle source (Sr_i=0.7030; _Nd=+5.1; δ¹⁸O=+5.1‰) having experience short term incompatible element enrichment and variable crustal contamination. The mantle magma was slightly contaminated by an Archaean lower crust in troctolitic cumulates, more strongly and with an additional contamination by an Eburnian upper crust in noritic cumulates. Lower crust input is recorded mainly by Sr and Nd isotopes and upper crust input by O isotopes. This is probably due to the different water/rock ratios of these two crust types. Assimilation of low amounts (<10%) of quartz-bearing felsic rocks, coming from both lower and upper crust, can explain the rise of SiO₂ activity, the enrichment in ¹⁸O and ⁸⁷Sr and the lowering of _Nd in the noritic cumulates compared to troctolitic ones. The geodynamic model proposed to account for the Laouni tholeiitic magmatism involves a late Pan-African asthenospheric rise due to a rapid lithospheric thinning associated with functioning of shear zones, which allowed tholeiitic magmas to reach high crustal levels while experiencing decreasing degrees of crustal contamination with time.     

Coronas from the Thessaloniki gabbros (North Greece)

Coronas which have been developed between olivine and plagioclase in Precambrian gabbroic rocks from Thessaloniki, Greece, have been studied. These consist commonly of (olivine), clinopyroxene, amphibole (plagioclase) and rarely of (olivine) orthopyroxene, clinopyroxene amphibole (plagioclase) assemblages. The results of the electron-probe microanalysis of the above constituent minerals are presented. The formation of these coronas by regional or thermal metamorphism is unlikely, but an origin by a two-way diffusion of material across the olivine and plagioclase interface is proposed.     

辽宁本溪大台沟铁矿地球化学特征及其地质意义

通过主量元素和稀土元素相结合的方法,对大台沟铁矿成矿物质来源提出了有效制约.研究表明：大台沟铁矿化学成分主要由TFe₂O₃和SiO₂组成,并且具有较低的Al₂O₃和TiO₂含量,这一特征与鞍本地区及山西五台山和冀东迁安地区铁矿一致,表明大台沟铁矿为火山沉积变质铁矿.稀土元素呈现轻稀土亏损、重稀土富集的特征,具有明显的Eu正异常特征,这些特征表明成矿物质来源于火山热液和海水的混合液.     

The Asama igneous complex, central Japan: An ultramafic-mafic layered intrusion in the Mikabu greenstone belt, Sambagawa metamorphic terrain

The Asama igneous complex comprises layered mafic and ultramafic plutonic rocks exposed over about 500×6000 m in the Mikabu greenstone belt, Sambagawa metamorphic terrain of Mie Prefecture; its margins terminate by faults, and there is no trace of chilled rocks. The exposed layered sequence is about 460 m thick, and includes dunite, plagioclase wehrlite, olivine gabbro and two-pyroxene gabbro. The crystallization sequence of essential cumulus minerals is olivine, followed by plagioclase and clinopyroxene together, and finally the appearance of orthopyroxene. Olivine systematically varies in composition from Fo₈₉ to Fo₇₈ with stratigraphic height in the lower to middle portion of the layered sequence. The composition of clinopyroxene changes from Ca₄₉Mg₄₆Fe₅ to Ca₄₀Mg₄₇Fe₁₃ upward in the layered sequence; cumulus orthopyroxene, which occurs at the top of the exposed layered sequence, has a composition of Ca₂Mg₇₄Fe₂₄. Cumulus chromite occurs as disseminated grains in peridotitic rocks, and tends to increase its Fe³⁺/(Cr+Al+Fe³⁺) ratio with stratigraphic height. The most aluminous chromite [Cr/(Cr+Al) = 0.48] occurs in dunite that crystallized shortly before plagioclase began to separate as an essential phase. The Cr/(Cr+Al) ratio of the most aluminous chromite, coupled with the crystallization order of essential minerals, suggests that the Asama parental magma was moderately enriched in plagioclase and clinopyroxene components in the normative mineral diagram plagioclase-clinopyroxene-orthopyroxene. It was similar to a Hawaiian tholeiite and different from the Bushveld and Great “Dyke” parental magmas that were more enriched in orthopyroxene component; it also differed from mid-oceanic ridge basalts that are more depleted in the orthopyroxene component. The Asama clinopyroxene and chromite show characteristically high TiO₂ contents and are also similar to those in Hawaiian tholeiites. The Asama igneous complex probably resulted from the crystallization of a magma of a Hawaiian (oceanic-island) tholeiite composition and formed in an oceanic island regime.     

1.8 Ga Svecofennian post-collisional shoshonitic magmatism in the Fennoscandian shield

At least 14 small (1–11 km across) 1.8 Ga Svecofennian post-collisional bimodal intrusions occur in southern Finland and Russian Karelia in a 600-km-long belt from the Åland Islands to the NW Lake Ladoga region. The rocks range from ultramafic, calc-alkaline, apatite-rich potassium lamprophyres to peraluminous HiBaSr granites, and form a shoshonitic series with K₂O+Na₂O>5%, K₂O/Na₂O>0.5, Al₂O₃>9% over a wide spectrum of SiO₂ (32–78%). Although strongly enriched in all rocks, the LILE Ba and Sr and the LREE generally define a decreasing trend with increasing SiO₂. Depletion is noted for HFSE Ti, Nb and Ta. Available isotopic data show overlapping values for lamprophyres and granites within separate intrusions and a cogenetic origin is thus not precluded. Initial magmas (Mg#>65) in this shoshonitic association are considered to be generated in an enriched lithospheric mantle during post-collisional uplift some 30 Ma after the regional Svecofennian metamorphic peak. However, prior to the melting episode, the lithospheric mantle was affected by carbonatite metasomatism; more extensively in the east than in the west. The melts generated in the more carbonate-rich mantle are extremely enriched in P₂O₅4%, F12,000 ppm, LILE: Ba9000 ppm, Sr7000 ppm, LREE: La600 ppm and Ce1000 ppm. The parental magma underwent 55–60% fractionation of biotite+clinopyroxene+apatite+magnetite+sphene whereupon intermediate varieties were produced. After further fractionation, 60–80%, of K-feldspar+amphibole+plagioclase±(minor magnetite, sphene and apatite), leucosyenites and quartz-monzonites were formed. In the west, where the source was less affected by carbonatite metasomatism, calc-alkaline lamprophyres (vogesites, minettes and spessartites) and equivalent plutonic rocks (monzonites) were formed. Removal of about 50% of biotite, amphibole, plagioclase, magnetite, apatite and sphene produced peraluminous HiBaSr granites. The impact of crustal assimilation is considered to be low. At about 1.8 Ga, the post-collisional shoshonitic magmatism brought juvenile material, particularly enriched in alkalis, LILE, LREE and F, into the crust. Although areally restricted, the regional distribution of the post-collisional intrusions may indicate that larger volumes of 1.8 Ga juvenile material resides in unexposed parts of the crust.     

Geochemistry of the Uintjiesberg kimberlite, South Africa: petrogenesis of an off-craton, group I, kimberlite

The Uintjiesberg kimberlite diatreme occurs within the Proterozoic Namaqua–Natal Belt, South Africa, approximately 60 km to the southwest of the Kaapvaal craton boundary. It is a group I, calcite kimberlite that has an emplacement age of 100 Ma. Major and trace element data, in combination with petrography, are used to evaluate its petrogenesis and the nature of its source region. Macrocryst phases are predominantly olivine with lesser phlogopite, with very rare garnet and Cr-rich clinopyroxene. Geochemical variation amongst the macrocrystic samples (Mg# 0.85–0.87, SiO₂=27.0–29.3%, MgO=26.1–30.5%, CaO=10.9–13.5%) is shown to result from 10% to 40% entrainment and partial assimilation of peridotite xenoliths, whereas that shown by the aphanitic samples (Mg# 0.80–0.83, SiO₂=19.1–23.0%, MgO=17.9–23.9%, CaO=16.5–23.7%) is consistent with 7–25% crystal fractionation of olivine and minor phlogopite. Changing trajectories on chemical variation diagrams allow postulation of a primary magma composition with 25% SiO₂, 26% MgO, 2.3% Al₂O₃, 5%H₂O, 8.6% CO₂ and Mg#=0.85.

Forward melting models, assuming 0.5% melting, indicate derivation of the primary Uintjiesberg kimberlite magma from a source enriched in light rare earth elements (LREE) by 10× chondrite and heavy REE (HREE) by 0.8–2× chondrite, the latter being dependent on the proportion of residual garnet. Significant negative Rb, K, Sr, Hf and Ti anomalies present in the inferred primary magma composition are superimposed on otherwise generally smooth primitive mantle-normalized trace element patterns, and are inferred to be a characteristic of the primary magma composition. The further requirement for a source with chondritic or lower HREE abundances, residual olivine with high Fo content (Fo₉₄) suggests derivation from a mantle previously depleted in mafic melt but subsequently enriched in highly incompatible elements prior to kimberlite genesis. These requirements are interpreted in the context of melting of continental lithospheric mantle previously enriched by metasomatic fluids derived from a sublithospheric (plume?) source.     

Metamorphic evolution of oceanic gabbros: recrystallization from subsolidus to hydrothermal conditions in the MARK area (ODP Leg 153)

The 117.38 m of gabbroic core drilled during the Ocean Drilling Program (ODP) Leg 153 at Sites 921 to 924 in the Mid-Atlantic Ridge (MAR) between 23 °N and the Kane Fracture Zone, exhibits a remarkable primary compositional heterogeneity, such as magmatic layering, intrusive contacts and late magmatic veining, which express a succession of magmatic events. Textural indicators suggest that the cooling of the crystal mush occurred in a dynamic environment, with infiltration of progressively evolved liquids. Magmatic features include random shape fabric and magmatic lamination; the subsequent deformational overprint occurred in subsolidus conditions. The ductile deformation, generally concentrated in discrete domains of the gabbro, is associated with continuous re-equilibration of the metamorphic assemblages of (1) olivine + clinopyroxene + orthopyroxene + plagioclase + ilmenite + Ti-magnetite, (2) olivine + clinopyroxene + plagioclase + ilmenite + Ti-magnetite + red hornblende. At lower temperatures brittle deformation prevails and subsequent fractures control the development of metamorphic assemblages: (3) clinopyroxene + plagioclase + red brown hornblende + Ti-magnetite + magnetite (?) + ilmenite, (4) plagioclase + brown hornblende + Ti-magnetite + magnetite + hematite + titanite ± Ti-oxide, (5) plagioclase + green hornblende + magnetite + titanite, (6) plagioclase + actinolite + chlorite + titanite + magnetite, (7) albite + actinolite + chlorite + prehnite ± epidote ± titanite and (8) albite + prehnite + chlorite ± smectite. Assemblages 1 to 8 express increasing water/rock ratios and decreasing degrees of recrystallization.

During the ductile phase, red hornblende is stable and its abundance increases with deformation intensity, possibly as an effect of the introduction of hydrous fluids. During the brittle phase, water diffusion controls the development of the fracture-filling mineral assemblages and re-equilibration of the adjacent rock; temperatures decrease further, as demonstrated by mineral zoning and incompletely re-equilibrated assemblages. The lowest temperatures correspond to the development of hydrothermal assemblages.

Compared with oceanic gabbros from fast-spreading transform environments, high-temperature ductile phases (granulite and amphibolite) are well developed, whereas brittle phases are widespread, as microcracks, prevalent on fracturing associated with discrete veins.