东天山圪塔山口铜镍矿区镁铁-超镁铁质岩体橄榄石与尖晶石矿物学特征

新近发现的圪塔山口含铜镍矿化镁铁-超镁铁质岩体位于新疆东天山黄山-镜儿泉铜镍矿带东端,共有4个镁铁-超镁铁质岩体,其中Ⅰ、Ⅱ、Ⅲ号岩体均见铜镍硫化物矿化,研究表明其形成时代(282Ma)及岩浆来源与东天山地区其它铜镍矿化镁铁-超镁铁质岩体一致。本文对主要造岩矿物橄榄石及副矿物尖晶石进行了显微镜下观察及电子探针分析,结果表明橄榄石Fo值介于83.1~86.6之间,平均85.2,为贵橄榄石,其Ni含量变化于1273×10-6~2719×10-6,平均1918×10-6;尖晶石根据铝含量的不同可以分为高铝和低铝两种。圪塔山口岩浆为地幔源区发生15.8%~18.8%的部分熔融,并有过剩橄榄石加入的玄武质岩浆经结晶分异作用形成的派生岩浆。对橄榄石分离结晶和硫化物熔离的计算模拟表明橄榄石结晶前,岩浆已经达到S饱和,结晶过程始终伴随硫化物的熔离作用,虽然早期结晶的橄榄石与硫化物熔体间发生了Fe-Ni交换,但仍有很好的铜镍成矿潜力。     

塔里木板块东北部坡一镁铁质-超镁铁质层状侵入体岩石成因

坡一侵入体位于塔里木板块东北部坡北岩体内,是该岩体第三阶段岩浆活动形成的十几个小侵入体中的一个,锆石U-Pb年龄为278±2Ma。该侵入体属于以超镁铁质岩石为主的层状岩系,堆晶结构与韵律性堆晶层理非常发育。岩浆分异充分,形成了从纯橄岩到石英闪长岩的多种岩石类型。在超镁铁质岩石中,所有的橄榄石和大部分斜方辉石是堆晶相,少量斜方辉石是填隙相,大部分单斜辉石、褐色普通角闪石和黑云母是填隙相。在镁铁质岩石中,橄榄石和斜方辉石全部是堆晶相,单斜辉石与斜长石既可以是堆晶相,也可以是填隙相;褐色普通角闪石、黑云母和石英均为填隙相。超镁铁质岩石属拉斑玄武岩系列,镁铁质岩石属钙碱性系列。侵入体中大量存在的捕掳体、微量元素地球化学、Nd-Sr同位素组成的EMⅡ型演化趋势,充分证明了同化混染作用伴随岩浆演化过程而逐渐增强,并不断促进了岩浆的分异,而且导致了岩石化学系列的转化。PGE和亲硫元素地球化学以及硫同位素组成证明,硫主要来自于岩浆,硫化物形成于岩浆阶段,岩浆未经历过早期硫化物熔离作用,硫化物熔离起始于橄榄岩相结晶的晚期阶段,并伴随着此后的岩浆演化过程而继续熔离。硫化物熔离是岩浆自身演化和同化混染共同作用的结果。橄榄石Fo分子含量和全岩FeO含量显示,原生岩浆是苦橄质岩浆;源区物质应该是石榴石辉石岩;岩浆生成于地幔柱轴部。在塔里木板块东北部还存在分别来自于软流圈和亏损型大陆岩石圈地幔的二叠纪岩浆岩,它们都应该是塔里木大火成岩省的组成部分。     

新疆东天山土墩基性-超基性杂岩体橄榄石成分特征及其成因意义

橄榄石通常是玄武质岩浆最早结晶出的矿物之一,其化学成分可以很好地反演母岩浆成分、岩浆结晶分异、硫化物熔离等成岩及成矿信息。本文以土墩镁铁质-超镁铁质杂岩体为研究对象,采用电子探针对岩体中的橄榄石矿物颗粒进行化学成分测试。利用橄榄石的Fo值和其中Ni含量,计算得到土墩杂岩体母岩浆中Mg O含量约为12.95%,是一种富镁的玄武质岩浆。同时,定量模拟结果表明,土墩杂岩体母岩浆中硫化物熔离几乎与橄榄石结晶作用同时进行,早阶段由橄榄石结晶(分离结晶程度约2%)而导致硫化物的熔离程度为0.2%。随后,橄榄石分离结晶程度在6%~7%时,硫化物熔体的熔离程度仅为0.01%。这些表明土墩杂岩体发生过一定程度的硫化物熔离,但成矿前景不是很好。此外,部分数据显示出Ni-Fo的负相关性,表明少许富铁橄榄石和晶间硫化物熔浆发生了Fe-Ni物质交换反应,这对橄榄石的成分有重要影响。     

塔里木东北缘坡十Ni矿化侵入体中橄榄石和铬尖晶石对成岩成矿及源区特征的约束

坡十Ni矿化超镁铁侵入体的矿化岩相主要为第二侵入期次的（斜长）单辉橄榄岩、（斜长）二辉橄榄岩、 纯橄岩等岩相。坡十超镁铁岩的橄榄石成分变化范围较大, 橄榄石的Fo值在76.8～89.6之间, Ni含量为767×10^-6～4 580×10^-6。铬尖晶石的Mg^#值和Cr^#值变化范围分别为19.4～41.9和49.8～64.8, 原生铬尖晶石中Cr₂O₃和Al₂O₃表现为负相关, 蚀变改造的铬尖晶石则表现为正相关。橄榄石成分剖面显示坡十母岩浆处于一个动态的岩浆系统中, 成分稳定的新鲜岩浆的补给、 持续向上的动力及浅部橄榄石快速分离结晶,造成了不同深度橄榄石成分的不同变化。坡十侵入体母岩浆估算结果为MgO=14.49％, FeO=10.01％,模拟结果显示橄榄石中Ni含量的变化主要受橄榄石结晶分异和硫化物不混溶作用共同控制,其中橄榄石与硫化物熔体发生明显的Fe-Ni交换反应。坡十母岩浆中橄榄石分离结晶造成的硫饱和,是坡十硫化物熔离的重要因素。橄榄石高Fo值、母岩浆高MgO、超镁铁岩中斜长石发育、矿物高结晶温度和铬尖晶石成分的弧岩浆特征显示,塔里木东北缘坡十侵入体是俯冲交代的岩石圈地幔部分熔融形成的母岩浆的产物,表现出低压高温的演化特征,其中源区熔融机制可能与塔里木二叠纪地幔柱提供的热源或该区大规模拆沉作用造成的软流圈上涌有关。     

新疆北山红石山含铜镍镁铁-超镁铁质岩体PGE和Re-Os同位素地球化学特征及成矿意义

对新疆北山地区红石山镁铁-超镁铁质岩体中含铜镍的硫化物矿石和岩石进行了铂族元素和Re-Os同位素地球化学特征研究,结果表明,矿石及岩石的铂族元素(PGE)总量较低,变化于0.54×10-9~15.84×10-9之间。较低的Pd/Ir比值表明岩石主要受岩浆作用控制,后期热液作用影响不明显。较高的Cu/Pd和Ti/Pd比值表明岩浆在演化过程中发生了硫化物的熔离。岩体的母岩浆为有早期结晶橄榄石加入的高镁的玄武质岩浆。γOs(t)的变化较大,变化于-282~+282之间,表明有较多的地壳物质混入。地壳物质混染和橄榄石等矿物的分离结晶可能是引起岩浆中的S达到饱和进而熔离的重要因素。红石山岩体是经历了结晶分异和硫化物熔离后橄榄石的堆积体与残余岩浆演化的混合体。     

新疆坡北镁铁-超镁铁杂岩体中橄榄石成分特征及其成因意义

橄榄石的矿物化学成分可以很好的反映母岩浆成分、岩浆分异结晶及硫化物熔离作用等信息.坡北镁铁-超镁铁杂岩体中橄榄石电子探针成分分析表明:橄榄石均为贵橄榄石,其化学成分与寄主岩石类型密切相关,其中橄榄辉长岩中橄榄石的Fo值在74～81之间,橄长岩或橄榄单斜辉石岩中橄榄石Fo=75～82.7,异剥橄榄岩或橄榄岩中橄榄石Fo值为83.6～86.3,暗示橄榄岩结晶早于橄榄辉长岩.橄榄石Ni含量变化范围为(174～2281)×10-6.利用最高Fo含量的橄榄石成分计算得到坡北岩体母岩浆MgO=14.38％,为高镁玄武岩浆.橄榄石分离结晶和硫化物熔离模拟显示:坡北岩体主要发生了～25％的橄榄石分离结晶,在橄榄石结晶程度为2％～4％的过程中,发生过硫化物熔离作用,但熔离程度较低(～0.2％).总体来看,该区成矿远景不佳.     

内蒙古乌拉特中旗克布镁铁质-超镁铁质岩体年代学、矿物学和岩石地球化学

内蒙古乌拉特中旗地处华北陆块北缘西段,大地构造分区属于狼山-白云鄂博陆缘裂谷。区域上,镁铁质-超镁铁质岩呈东西向带状分布,断续出露长约300km,宽约30km。该镁铁质-超镁铁质岩带内铜镍矿床(点)较为发育,克布为该带内一个中-小型铜镍硫化物矿床。克布镁铁质-超镁铁岩体出露面积约45km2,主要由辉长岩相和橄榄岩相组成,辉长岩相为岩体的主要岩相,橄榄岩相为主要的赋矿岩石,两个相带相伴产出,呈渐变过渡关系。本文采用LA-ICP-MS锆石U-Pb法测年,获得克布斜长方辉橄榄岩年龄为258.1±1.8Ma(MSWD=2.3),属于晚二叠世。岩石主、微量及稀土元素分析结果表明,岩石样品属铁质镁铁质-超镁铁质岩,具有拉斑玄武岩系列演化趋势,并相对富集大离子亲石元素(Rb、Sr、Ba),亏损高场强元素(Nb、Ta、Zr、Hf、Ti),以及具有轻稀土富集[(La/Yb)N=2.47~11.29]的右倾型稀土配分模式。以橄榄石-熔体平衡原理估算克布镁铁质-超镁铁质岩体母岩浆的MgO含量为10.1%,FeO为12.1%,应为高镁的拉斑玄武质岩浆。综合分析认为,克布镁铁质-超镁铁质岩体应形成于后碰撞伸展阶段,岩浆源区由被消减板片交代的地幔楔物质和软流圈物质组成。橄榄石和辉石等富镁铁矿物的分离结晶和富硅地壳物质的混染可能对硫化物熔离富集成矿起到了关键性作用。     

新疆东天山镁铁-超镁铁岩体中橄榄石成分特征及其成因意义:以黄山东和图拉尔根为例

新疆东天山发育有十多个与铜镍硫化物成矿有关的镁铁-超镁铁杂岩体,对选取于黄山东和图拉尔根岩体岩体内不同岩性中的新鲜橄榄石进行了矿物化学成分测试。黄山东岩体角闪辉长岩相的橄榄角闪辉长岩中橄榄石Fo为67～73,超镁铁岩相的角闪(斜长)橄榄岩、角闪二辉橄榄岩和斜长单辉橄榄岩中橄榄石Fo为81～84,Ni含量为308～1762μg/g;图拉尔根岩体中橄榄石Fo为82～85,Ni含量变化范围为857～1818μg/g。利用最高Fo含量的橄榄石成分计算得到黄山东岩体母岩浆MgO为10.3%,图拉尔根岩体母岩浆MgO为11.47%。橄榄石分离结晶和硫化物熔离模拟结果显示,黄山东岩体发生了19%的橄榄石分离结晶,由橄榄石分离结晶导致硫化物熔离的程度约为0.3%,晶间硫化物熔浆的物质交换作用对黄山东橄榄石的成分有重要影响;图拉尔根岩体发生了9%左右的橄榄石结晶,由橄榄石结晶导致出熔的硫化物熔体大约为0.5%。     

四川攀西地区层状侵入体中堆晶岩成因的矿物学约束

火成岩中可以包含多种晶体群这一发现具有重要意义,使得成因矿物学重新成为揭示岩浆系统演化的基本指导思想。但是,这种重要性在许多文献中都没有得到反映,其典型实例就是镁铁质层状侵入体中堆晶岩的成因。争论在于堆晶矿物是循环晶还是母岩浆的液相线相。因此,本文致力于探讨四川攀西地区镁铁质层状侵入体中堆晶岩的形成过程,重申成因矿物学的重要意义。显微镜观察表明,堆晶单斜辉石富含Fe-Ti氧化物出溶叶片(含叶片辉石),表明其形成环境明显不同于与斜长石呈共结关系的单斜辉石(无叶片辉石);无叶片辉石和斜长石中的橄榄石包裹体呈浑圆状,表明了橄榄石与结晶环境间的热力学不平衡。橄榄石与熔体间Fe-Mg分配关系分析表明,根据母岩浆成分推测的橄榄石Fo值远低于岩体中观测橄榄石化学成分变化范围(Fo₆₁-Fo₈₁)的高限,表明至少部分橄榄石不是寄主侵入体的液相线相。橄榄石的Mg^#值(100×Mg/(Mg+Fe))与微量元素(特别是Ni)的相关关系表明存在多种橄榄石晶体群,它们形成于不同的热力学环境中。晶体沉降过程分析表明,寄主岩浆析出的晶体几乎不可能发生快速重力沉降来形成堆晶岩。所有这些证据都表明,形成堆晶岩的矿物主要来自岩浆系统深部不同的岩浆房中,是被岩浆携带输运到终端岩浆房的循环晶。     

新疆北山二叠纪镁铁-超镁铁质岩成因、成矿作用和找矿信息

为认识新疆北山二叠纪镁铁-超镁铁质岩石成岩成矿作用,基于地质调查获得的新资料,对这套岩石存在争议或认识模糊的年代学、岩浆起源与性质、动力学背景、硫化物熔离机制等进行了重新梳理.区内幔源岩浆除了早二叠世大规模侵入,中二叠世还有一期小规模侵入（261~266 Ma）.母岩浆起源于受俯冲流体交代改造的亏损地幔在相对浅的深度发生高程度部分熔融,其具高温、高镁、含水、氧化特征.这些岩石并非地幔柱成因,亦非产于岛弧环境,而是造山后伸展背景下板片断裂引起的软流圈地幔上涌形成镁铁质侵入岩.坡北亚带和红石山亚带具有类似的岩石矿物组合和地球化学特征,但是矿化方式有明显差异.不同类型矿化是硫化物多期次熔离的产物,来自邻近VMS型铜矿床的外源硫混染触发硫化物在橄榄石结晶分异之前熔离,高品位脉状矿化是硫化物矿浆晚期贯入苏长岩的产物.超镁铁质岩相橄榄石中较低的Ni含量,岩体低Ti、高Mg、高m/s和m/f比值、母岩浆MgO含量大于11.5%、部分熔融程度不低于10%、固结指数SI大于50,均是有利的找矿指标,红十井深大断裂一带可能具有找矿潜力.      

Origin of ultra-nickeliferous olivine in the Kevitsa Ni–Cu–PGE-mineralized intrusion, northern Finland

The 2,058 ± 4 Ma mafic–ultramafic Kevitsa intrusion is located in the Central Lapland greenstone belt, northern Finland. It is hosted by a Paleoproterozoic volcano–sedimentary sequence that contains komatiitic volcanic rocks and sulfide- and graphite-rich black schists. Economic Ni–Cu–(PGE) sulfide mineralization occurs in the middle part of the ultramafic lower unit of the intrusion. Two main types of ore are distinguished, “normal” and “Ni–PGE” ores. The normal ore is characterized by ~2 to 6 vol% disseminated sulfides and average Ni and Cu grades of 0.3 and 0.42 wt %, respectively (Ni/Cu < 1). The Ni–PGE ore has broadly similar sulfide contents, but a higher Ni grade and lower Cu grade. As a result, the Ni/Cu ratio reaches 15, much higher than in the normal ore. The Ni–PGE ores occur as irregular, discontinuous, lense-like bodies in the ultramafic rocks. Notably, the olivines in the Ni–PGE ore contain extremely high Ni contents of up to 14,000 ppm, which is significantly higher than the Ni content of olivine in other mafic–ultramafic igneous rocks globally (up to ~5,000 ppm) and in harmony with the associated Ni-rich sulfide assemblage containing pentlandite, millerite and pyrite. Microprobe mapping of olivine from the Ni–PGE ore suggests relatively low and homogeneous S contents and homogeneous distribution of Ni, Mg, Fe, which is inconsistent with the presence of sulfide inclusions in the olivine grains, or diffusion of Ni from interstitial sulfides into the olivine grains. We therefore conclude that Ni substitutes for Mg in the olivine lattice. The clinopyroxenes from the Ni–PGE ore also have unusually high Ni concentrations reaching 1,500 ppm and show a positive correlation with the nickel content of the associated olivine. The Ni_cpx/Ni_olivine is ~0.1 to 0.2 corresponding to high T partitioning of Ni between clinopyroxene and olivine. K _D of 20 can account for the partitioning of nickel between olivine and the sulfide phase, consistent with magmatic equilibration. These data suggest that the olivine, clinopyroxene, and sulfides all crystallized from a basaltic magma with an unexceptionally high Ni content ranging from 300 to 1,100 ppm. The Ni–PGE ores are spatially associated with ultramafic xenoliths. Olivine in these ultramafic xenoliths have relatively high Fo contents (up to 90 mol %) and high Ni contents (up to 5,200 ppm) suggesting that the xenoliths formed from a komatiitic parental magma. It is proposed that assimilation by the Kevitsa magma of massive or semi-massive sulfides associated with komatiitic rocks elevated the Ni content of the magma and resulted in the formation of Ni–PGE ores and related extremely Ni-rich olivines.     

甘肃黑山铜镍硫化物含矿岩体的地质特征及橄榄石成因探讨

黑山铜镍硫化物含矿岩体位于中亚造山带南缘北山褶皱带东部,对该岩体的研究有助于正确理解造山带型铜镍硫化物的成矿作用。详细的野外基础地质特征表明黑山矿区仅出露单一的新元古代青白口系地层,无寒武纪地层出露。黑山含矿岩体由早期的方辉橄榄岩、二辉橄榄岩和橄榄辉长苏长岩,以及稍晚期的辉长岩脉组成。黑山岩体位于黑山背斜南翼,其初始产状应为一水平或近水平的岩床状岩体,因后期褶皱作用,岩体发生了倾斜形成现今的产状。黑山岩体中橄榄石Fo值为80.5~87.0,其Ni含量为1070×10^-6~3461×10^-6。借助"MELTS"软件,我们进一步厘定了黑山母岩浆为高镁玄武岩浆 (12.81% MgO, 10.84% FeO, 430×10^-6 Ni)。研究表明,黑山橄榄石的主要控制因素为:1)母岩浆的成分;2)后续新鲜岩浆的补充混合作用;3)硫化物熔离作用;4)晶间硅酸盐熔浆作用;5)橄榄石与硫化物之间发生的Fe-Ni交换。模拟计算表明,硫化物熔离与橄榄石结晶几乎同时发生,橄榄石与硫化物的最小质量比约为20:1。1号矿体及矿化体的橄榄石比4号矿体更富Mg和Ni,并且还呈现非常好的负相关关系,表明这些橄榄石与硫化物发生了不同程度的Fe-Ni交换,而与其发生Fe-Ni交换的硫化物更富Ni以及共生的岩浆更为原始。这很可能是因为黑山岩体形成于开放的岩浆通道系统,早期融离的硫化物与后续的新鲜的硫不饱和岩浆发生反应,使得该类硫化物含量减少但硫化物中的金属元素含量增高从而形成1号矿体及矿化体。     

Origin of anomalously Ni-rich parental magmas and genesis of the Huangshannan Ni–Cu sulfide deposit,Central Asian Orogenic Belt,Northwestern China

The Huangshannan Ni–Cu sulfide deposit at the southern margin of the Central Asian Orogenic Belt (CAOB) is an important recent discovery in the Eastern Tianshan Region, Northwestern China. The Huangshannan Intrusion is composed of mafic and ultramafic rocks, and its websterite and lherzolite sequences host the sulfide orebodies. Olivine is the dominant mineral in the Huangshannan Intrusion, occurring as olivine inclusions hosted by pyroxene oikocrysts, as olivine crystals in magmatic sulfides, and as poikilitic crystals in the lherzolite. Small olivine inclusions always coexist with large poikilitic olivine crystals in the same sample, resulting in a heterogeneous texture on the scale of the oikocrysts. The Ni abundance ranges from 1540 to 3772 ppm in poikilitic olivine grains, from 2114 to 3740 ppm in olivine grains hosted by sulfide minerals, and from 2043 to 4023 ppm in olivine inclusions hosted by pyroxene oikocrysts. For the three types of olivine, the ranges in forsterite (Fo) content are 78.97–84.92 mol.%, 81.57–84.79 mol.%, and 80.33–84.68 mol.%, respectively. The Ni content of olivine in the lherzolite is anomalously high relative to the range found in most within plate olivine-bearing mafic-ultramafic rocks. The composition of olivine is controlled mainly by that of the parental magma, fractional crystallization and reactions with interstitial silicate and sulfide melts. Both fractional crystallization and reaction with interstitial silicate may cause a decrease in the Ni content of olivine. The possibility that Ni–Fe exchange causes the anomalously high Ni contents in olivine can be excluded because the olivine grains contained in sulfide have similar or lower Ni content than the olivine grains hosted in the silicate rock. Most of the olivine grains are unzoned, and they have anomalously high Ni contents throughout the crystal. Assuming a partition coefficient of Ni between olivine and silicate magma to be 7, the measured Ni content of olivine in the lherzolite (1540–4023 ppm with a mean of 2907 ppm) indicates that the parental magma contains 220–575 ppm (average of 415 ppm) Ni. This value is higher than that found in basaltic magmas that crystallized olivine with similar Fo contents compared to the Huangshannan Intrusion. As mentioned above, the symmetric and reproducible variations in both Fo and Ni contents from core to margin in most of the olivine grains cannot be explained by fractional crystallization and reactions with interstitial silicate or sulfide melts but may reflect the equilibration of the olivine with new fluxes of magma as the chamber was replenished. The anomalously Ni-rich composition of the parental magmas of the Huangshannan Intrusion, relative to those of many other mineralized olivine-bearing mafic-ultramafic intrusions, may be produced by upgrading and scavenging of metals from a previously formed sulfide melts by a moderately Ni-rich magma. The mass-balance calculations of PGE data indicate that the parental magma that formed lherzolite contains 0.04 ppb Os, 0.02 ppb Ir and 0.4 ppb Pd, whereas the parental magma that formed websterite has 0.02 ppb Os, 0.009 ppb Ir and 0.75 ppb Pd. Rayleigh modeling using PGE tenors indicates that the massive sulfides may be produced by monosulfide solid solution (MSS)-sulfide liquid fractionation from the magma that formed the websterite. Rayleigh modeling of Fo and Ni contents of olivine shows that the parental magma that formed the lherzolite has experienced previous sulfide segregation and olivine crystallization.     

金川Ⅰ号岩体橄榄石Ni-MgO相互关系及其地质意义

金川超镁铁质岩体赋存着仅次于加拿大Sudbury和俄罗斯Noril'sk-Talnakh的世界第三大在采铜镍硫化物矿床,岩体以一系列的NE向断层为界分成四个小岩体,由西至东依次为:Ⅲ、Ⅰ、Ⅱ、Ⅳ岩体.Ⅰ号岩体主要由二辉橄榄岩、含辉橄榄岩和橄榄二辉岩构成,橄榄石在各岩相中均为保存较好的主要造岩矿物.本文研究得到金川Ⅰ号岩体上部二辉橄榄岩和含辉橄榄岩中橄榄石的镁橄榄石F_o值介于83.9～85.7,而其Ni含量为1396×10~(-6)～2043×10~(-6),大多低于从S不饱和玄武岩浆中结晶出来的橄榄石的Ni含量.模拟计算结果表明橄榄石较低的Ni含量是因为橄榄石结晶的同时,发生了强烈的硫化物熔离;橄榄石的Fo-Ni关系还因与晶间硅酸盐熔浆的物质交换而发生改变.模拟计算还证明大约有30%的晶间硅酸盐岩浆与橄榄石发生Fe-Mg物质交换反应,导致早结晶橄榄石的Fo值减少了1～1.5.同时,橄榄石较小的Fo值变化表明,在橄榄石结晶和硫化物熔离过程中,不断有新的岩浆贯入和补充.     

扬子地块北缘周庵超镁铁质岩体矿物学特征及其对铜镍矿化的启示

扬子地块北缘~635 Ma周庵超镁铁质岩体是一个新发现的含铜镍硫化物矿化的隐伏岩体,主要由二辉橄榄岩组成。文章通过研究周庵岩体中橄榄石、铬铁矿和辉石的矿物成分变化探讨了岩浆演化过程和含矿岩体成因。根据岩石的矿物组合和蚀变程度,岩体从上到下分为3个部分:上部绿泥石-蛇纹石化二辉橄榄岩相带、中部二辉橄榄岩相带和下部绿泥石-角闪石化二辉橄榄岩相带。根据岩体中部带橄榄石和铬铁矿的成分,计算得到母岩浆的Mg^#值为0.63,MgO/FeO摩尔比值为1.72,w(Al₂O₃)为10.2%~11.7%,w(Ni)为476×10^-6,说明其为高镁玄武质岩浆;岩体中部带原生铬铁矿和粒间相铬铁矿核部的Cr₂O₃和Al₂O₃呈正相关关系,说明铬铁矿与粒间硅酸盐熔体发生了平衡交换,铬铁矿的高w(TiO₂) 和Cr^#值与拉张环境中层状岩体的铬铁矿特征一致;根据辉石温压计得到岩体中部单斜辉石和斜方辉石的共结温度为1 017~1 077℃,压力为(3.6~4.5)×10⁸ Pa,暗示形成岩体的浅部岩浆房深度约为12 km。岩体上部和中部带的橄榄石Fo值大部分集中在80 mol%~85 mol%,w(Ni)介于2 255×10^-6~4 455×10^-6,说明这些橄榄石是从没有经过强烈分离结晶和硫化物熔离的岩浆中结晶出来的。岩体下部带橄榄石的Fo值(67 mol%~68 mol%)和w(Ni) (1 500×10^-6~2 000×10^-6)都低于岩体上部和中部带的橄榄石相应值,说明岩体下部带的橄榄石可能形成于演化程度较高、并经历了硫化物熔离的岩浆。因此,笔者认为周庵岩体是由相对原始的和演化了的高镁玄武质岩浆两期侵位形成的。     

亲铜元素的地球化学行为研究进展及其在岩浆硫化物矿床中的应用

亲铜元素在岩浆演化和硫化物熔离过程中的行为是解释岩浆硫化物矿床形成过程的一个窗口,通过实验研究来探讨亲铜元素的地球化学行为,并用于岩浆硫化物矿床的定量化研究是此类矿床今后的一个发展方向。本文总结了硫和亲铜元素在岩浆演化过程中的行为规律,并阐明了在岩浆硫化物矿床中的应用,在如下五个方面分别做了讨论：① 通过实验对玄武质岩浆中S溶解度的研究,总结出引起硫化物饱和的4个控制因素: 岩浆混合、温度迅速降低、壳源混染、快速的结晶分异作用;② 通过Ni在橄榄石和硅酸盐熔浆中的分配,定量模拟了岩浆演化过程中,橄榄石中的Ni含量随着橄榄石成分（Fo）变化的规律;③ 总结了Ni—Cu—PGE—Au在液态硫化物和硅酸盐岩浆中的分配系数,总结了控制分配系数的因素,并探讨了“R因素”对亲铜元素富集的控制机理;④ 橄榄石被硫化物包围时,与硫化物发生交换反应,通过交换反应系数（KD）可以定量估算硫化物熔浆中Ni的含量;⑤ 通过实验得出的亲铜元素在单硫化物固溶体（MSS）和液态硫化物之间的分配,总结了岩浆铜镍硫化物矿床中的分带现象。最后探讨了岩浆硫化物矿床存在的问题和发展方向。     

Late Paleozoic mafic–ultramafic intrusions in southern Central Asian Orogenic Belt (NW China): Insight into magmatic Ni–Cu sulfide mineralization in orogenic setting

The mafic–ultramafic intrusions hosting magmatic Ni–Cu sulfide ore deposits, usually present within the Precambrian cratons and on their margin, have been extensively studied, whereas those occurring within the Phanerozoic orogenic belts have received little attention. The southern margin of the Central Asian Orogenic Belt is a region of late Paleozoic mafic–ultramafic intrusions emplaced during post-orogenic stage. In order to recognize the mineralization features, this study compares barren or weakly mineralized mafic–ultramafic intrusions in the Beishan with those hosting Ni–Cu sulfide ore deposit in the Altay and Eastern Tianshan in petrology, mineralogy and geochemistry aspects. Several mineralization features can be recognized with respects to petrology, mineralogy and geochemistry from comprehensive comparisons. Among the mineralization indicators, we highlight strong alteration accompanying sulfide emplacement, post-erosion exposure of magma conduit, abundant primary hydrous minerals and potential transportation mechanism of ore-forming elements. Other indicators are the presence of orthopyroxene and pyroxenite for potential sulfide formation through crystal fractionation, restricted Fo and Ni ranges in olivines for sulfide segregation, and some other special geochemical characteristics related to crustal contamination. The variation in mineralization could be ascribed to different degrees of partial melting, crustal assimilation and subduction-related modification of a mantle source. We suggest that the Ni–Cu sulfide mineralization of mafic–ultramafic intrusions within orogenic belts is remarkably different from that of cratonic and continental marginal settings in respects of petrogenesis and mineralizing mechanism. Magmatic conduit-type Ni–Cu sulfide ore deposit is a target for future prospecting and exploration for mafic–ultramafic intrusions in the orogenic belts.     

金川超大型Ni-Cu-(PGE)矿床橄榄石微量元素特征及地质意义

我国金川超大型铜镍硫化物矿床是世界上第三大在采岩浆硫化物矿床,Ni开采量仅次于俄罗斯Noril'sk-Talnakh和加拿大Sudbury矿床,其成因研究备受关注。利用激光—等离子体质谱(LA-ICP-MS)原位分析了金川岩体中橄榄石微量元素含量,并探讨了影响元素含量变化的因素,进而阐述成岩及成矿过程。分析结果显示橄榄石中元素Ni,Cr与Fo呈负相关,Mn/Fe与Fo呈正相关,而Mn/Zn,Zn/Fe与Fo无相关性。在原始地幔橄榄石多元素标准化图中,金川Ⅰ号和Ⅱ号岩体橄榄石具相同的配分模式,均显示Cr,V,Ni,Co和Ti的亏损,富集不相容元素Zr,Y,Ti,Sc和Ca的特征。元素变化特征暗示Ⅰ号和Ⅱ号岩体具相同的母岩浆成分;与铬尖晶石的共结使橄榄石亏损Cr,V和Ti元素,而熔离的硫化物及其与橄榄石的相互反应共同影响着橄榄石中Ni和Co元素的含量。Ⅱ号岩体橄榄石较Ⅰ号岩体具较低的Cr和V含量,暗示Ⅱ号岩体母岩浆较Ⅰ号岩体经历了更高程度的演化。橄榄石高的Mn/Zn值(>13)和低的Zn/Fe值(<11)指示金川岩体岩浆可能起源于橄榄岩地幔的部分熔融,而非辉石岩地幔源区。     

Trace Elements in Olivines from the Giant Jinchuan Ni-Cu-(PGE) Deposit,NW China,and Its Geological Implication

The giant Jinchuan magmatic sulfide deposit in China is the third largest mining deposits in the world. Although many research have been done, there still exist some debates in the genesis of deposit. This study using the LA-IC-MS to obtain the trace elements concentrations of the olivine in order to discuss the mechanism of influence the element variability and illustrate the process of magmatism and ore-forming. The analytical results show that Ni, Co correlate negatively with Fo in the olivine, Mn/Fe is positively correlate with Fo, while Mn/Zn and Zn/Fe show no obvious correlation with Fo. The primitive mantle olivine-normalized trace element patterns of the Jinchuan olivine show that Jinchuan Ⅰ, Ⅱ intrusions have the same trace elements characteristics, which display negative Cr, V, Ni, Co and Ti anomalies and enrichment of Zr, Y, Ti, Sc and Ca. The multi-element patterns of the Jinchuan olivine imply same parental magma in the intrusion Ⅰ and Ⅱ. The spinel which cocrystallization with the olivine make it display negative Cr, V and Ti anomalies. The contents of Ni and Co in olivine are influenced by the process of sulfide segregation and the reaction between sulfide and olivine. The lower content of Cr and V in olivine of the intrusion Ⅱ compared with the intrusion Ⅰ imply that the parental magma of the intrusion Ⅱ was more evolved. Higher Mn/Zn (>13) ratios and lower Zn/Fe (<11) ratios indicate that the magma of Jinchuan intrusion likely originate from partial melting of peridotite mantle possibly, instead of pyroxene mantle sources.