黄铁矿的一般特征与含金性的关系探讨

通过全面考察研究黄铁矿的一般矿物学特征与含金性的关系得知，第二和第三世代的黄铁矿是金矿化主期的形成物，与黄铁矿共生的矿物组合可作为金矿化的找矿标志和评价准则。黄铁矿的形态粒度与其含金性之间存在着显著的关系，即｛２１０｝晶形和｛１００｝＋｛２１０｝晶形的黄铁矿越多，自形程度越差，晶粒越细、越破碎，含金性就越好；反之亦然。成分研究分析表明，本区黄铁矿富Ｓ贫Ｆｅ，多Ａｓ多Ｃｏ，Ｃｏ／Ｎｉ平均为２．５３，Ｓ／Ｓｅ平均为１０８０４，显示内生热液矿床特征。Ｒ聚类分析和逐步回归分析表明，Ａｎ与Ｓ、Ｆｅ、Ｎｉ、Ａｓ关系密切。     

阿坝盆地区域地球化学特征及其地质意义

１：２０万区域水系沉积物地球化学是量结果显示,队坝盆地４０种元素簇群特征明显,按其相关性可划分为三大组合,明显富集Ｓｉ、Ｚｒ、Ｃａ、Ｎａ、Ｓｒ、Ｌａ,贫化Ｆｅ、Ｃｒ、Ｔｉ、Ｋ、Ａｌ。元素组合及分布均表现为风化残积的表生地球化学特点,表明盆地区现今仍以沉积为主,侵蚀作用居次要地位。阿坝盆地是一个发育在断裂 下降盘并逐渐向南西迁移的不对称箕状断陷盆地。     

铁硫化物球粒

铁硫化物的合成,通常是通过固－气反应来实现,本文利用电弧放电的方法,使黄铁矿（ＦｅＳ２）还原成磁黄铁矿（Ｆｅ１－ｘＳ）、陨硫铁（ＦｅＳ）和金属铁（Ｆｅ）,利用反光显微镜（ＲＬＭ）,Ｘ射线衍射（ＸＲＤ）,扫描电镜（ＳＥＭ）,透射电镜（ＴＥＭ）和能谱（ＥＤＳ）综合研究合成物的特征及各物相的相互关系。初步研究了合成物的电学和磁学性能。讨论在电弧作用的还原环境里,ＦｅＳ２向ＦｅＳ、Ｆｅ１－ｘ和Ｆｅ转变的特     

吉林省和龙市和安河金矿地质特征及找矿标志

本文对和安河金矿地质特征及找矿标志进行了总结.矿体呈脉状、细脉状赋存于燕山期花岗闪长岩中,主要受北北西向断裂构造控制,矿石类型以含金蚀变岩型为主,其次为含金石英脉型.矿石结构以半自形晶—他形晶粒状结构为主;构造主要为浸染状构造.矿床属于中高温热液蚀变矿床,硅化、绿泥石化、黄铁矿化是蚀变矿物找矿标志,土壤测量Au元素异常是地球化学找矿标志.     

庐枞盆地西湾铅锌矿床黄铁矿微量元素组成特征及成矿启示

黄铁矿作为铅锌矿床中最常见的金属硫化物之一,是铅锌矿床形成过程中的贯通性矿物,其矿物学与地球化学特征可探究成矿作用过程,进而探讨矿床成因。庐枞盆地是长江中下游多金属成矿带的重要组成部分,近年来在其北缘新发现了可达大型规模的西湾铅锌矿床。虽然前人对西湾铅锌矿床已开展了相关的研究,但对与成矿关系密切的黄铁矿化学组成及其成因等方面的研究还较为薄弱。本研究首次利用偏反光显微镜与激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)对该矿床多类黄铁矿开展研究,揭示黄铁矿微量元素组成特征和替换机制,进一步探讨矿床成因。结果显示,根据晶体形态及矿物组合特征将黄铁矿分为成矿前与成矿期两期。成矿前黄铁矿主要呈半自形-它形粒状结构,粒径为10～50μm,可见多个细小颗粒组成粒状集合体,其特征元素主要为Cu、Ag、As、Pb、Sb;而成矿期黄铁矿主要呈自形-半自形粒状结构,粒径大于200μm,通常和方铅矿、闪锌矿组合,呈脉状的形式产出于灰岩裂隙中,其特征元素主要为Mn、Co、Ni、Zn、Cs、Cd、In、Sn。黄铁矿中微量元素替代机制主要为单元素和多元素耦合替代,其中单元素替代机制主要有Co²⁺     

内蒙古中部区地台区和地槽区元素地球化学分布特征

本文利用历史地球化学的观点，研究了内蒙中部区地台和地槽区各时代常量元素（Ｓｉ、Ｋ、Ｎａ、Ａｌ、Ｆｅ、Ｃａ、Ｍｇ）、微量元素（Ｃｕ、Ｐｂ、Ｚｎ、Ａｕ、Ａｇ、Ａｓ、Ｓｂ、Ｈｇ等）的分布特征，以及稀土元素（Ｌａ、Ｃｅ、Ｎｄ、Ｓｍ、Ｇｄ、Ｅｕ、Ｔｂ、Ｙｂ、Ｌｕ）总量变化、元素的配分和稀土元素的组成模式，总结了元素随地质年代由老到新的演化规律，指出了主要成矿元素相对富集的层位，得出内蒙中部区相对富集轻稀土、贫中稀土和重稀土的结论。     

凤太泥盆纪拉分盆地中硅质铁白云岩—硅质岩特征及成岩成矿方式

从岩石学、矿物学、地球化学等叫结秦岭凤太地区泥盆纪硅质白云岩－硅质岩的地质地球化学特征。硅质岩类中,ＳｉＯ２〉８０％,（ＦｅＯ＋Ｆｅ２Ｏ３＋ＭｇＯ）〈１０％;硅质铁白云岩类中,ＳｉＯ２为３０％～５０％,（ＦｅＯ＋ＦｅＯ３＋ＭｇＯ）大于２０％,提出该类热水沉积岩热水同生沉积作用、热水温合同生沉积作用,热水同生沉积交代作用,热水爆炸－液压致裂作用及热水充填－交代作用形成。     

皖南金家山金矿地质地球化学特征及找矿方法

金家山金矿位于江南隆起带北缘,赋存于新元古代浅变质浊积岩基底岩层中,其成矿结构面为张性或扭张性断层,成矿地质体为角砾岩。矿石工业类型为角砾岩型金矿,矿石矿物主要为毒砂、黄铁矿,少量黄铜矿、闪锌矿、方铅矿、褐铁矿、自然金,矿石结构主要为半自形晶粒状结构、他形粒状结构,矿石构造以浸染状构造为主。通过地球化学工作有效圈出矿致异常,研究区Au元素属显著富集、强烈变异、极强叠加型元素,说明该区地质体遭受的后期各种构造作用叠加对金矿成矿有利,初步认为地球化学配合地质测量和探矿工程可快速找金。     

广西弄拉白云岩环境元素的岩溶地球化学迁移

广西弄拉是典型的岩溶峰丛山区,主要的岩石是泥盆系东岗岭组泥硅质白云岩,不但富含Ｃａ、Ｍｇ碳酸盐成分,而且Ａｌ、Ｆｅ、Ｓｉ、Ｐ、Ｋ等常量元素和Ｍｎ、Ｚｎ、Ｃｕ、Ｃｏ等微量元素的背景值也较高。在岩溶地球化学过程中,岩石的碳酸盐成分迅速溶解并以很高的浓度正向迁移,岩溶泉水的暂时硬度一般为１３～１５德国度,郁闭森林下的最高值可达１８．９德国度;并伴随岩石的溶解,难溶的Ｆｅ、Ｓｉ、Ａｌ、Ｐ、Ｍｎ元素在岩溶水中也有一定的含量。岩溶泉水在地表流动中,ＣＯ２逸出,元素发生随碳酸钙沉淀的反向迁移。白云岩的岩石－土壤的元素迁移不同于灰岩地区,其土壤剖面Ｂ层以下,主要岩石组分和微量元素含量具有随深度而增加的一般规律性,反映了原地残积和逐步淋溶风化的特征。弄拉环境元素的岩溶地球化学迁移与岩石的地球化学背景密切相关。      

层间氧带砂岩型铀矿床的铁物相特征及其地球化学意义——以伊犁盆地511铀矿床和吐哈盆地十红滩铀矿床为例

层间氧化带砂岩型铀矿床在空间上与层间氧化带各亚型的分布具有严格的对应关系。铁元素的物相特征是所处地球化学环境变化的敏感标志，FeFe2O3/TFe,Fe(FeCO3 FeS2)/TFe,FeFe2O3/Fe(FeCO3 FeS2)等比值是反映地球环境变化的重要指标，应用铁物相特征及其以上比值，可以简捷地对层间氧化带进行亚带的划分，这对指导铀矿勘查具有重要理论和实践意义，过渡带中菱铁矿（FeCO3)和黄铁矿（FeS2)等对地球化学环境敏感的矿物的富集，指示了有利于铀成矿的中性－弱酸性，还原的地球化学环境。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.     

PALEONTOLOGY

正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)     

GEOCHEMICAL EXPLORATION

正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)     

MICROPALAEONTOLOGY

正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)     

PETROLOGY

正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,     

ENVIRONMENTAL GEOLOGY

正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an     

PROSPECTING EXPLORATION

正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of