新疆铁木尔特铅锌铜矿床锆石U-Pb和黑云母40Ar/39Ar年代学及其矿床成因意义

新疆铁木尔特铅锌铜矿床位于阿尔泰造山带南缘克兰盆地内,矿体呈脉状产于康布铁堡组火山岩地层中.为准确厘定其成岩成矿时代,作者分别对矿区赋矿火山岩和含矿石英脉中的云母进行了年龄测定,获得2件火山岩样品的锆石LA-ICP-MS U-Pb年龄分别为396±5Ma和405±5Ma,2件黑云母样品的40 Ar/39 Ar坪年龄分别为240±2Ma和235±2Ma,相应的39Ar/36Ar-40Ar/36Ar等时线年龄分别为238±3Ma和233±3Ma,与坪年龄在误差范围内一致.据此,认为矿区内康布铁堡组火山岩形成于396～405 Ma,成矿作用发生于235～240Ma;成岩年龄早于成矿年龄约165Ma.因此,铁木尔特铅锌铜矿为典型的后生矿床,而不可能是同生VMS型矿床.考虑到成矿年龄稍晚于区域大规模变质作用(约250Ma),推测成矿作用与阿尔泰造山带碰撞造山作用有关.结合矿床地质特征和流体包裹体特征,认为铁木尔特铅锌铜矿为典型的陆陆碰撞体制下形成的造山型矿床.     

论广东凡口铅锌矿床成矿作用及双源卤水成矿模式讨论

广东凡口铅锌矿床是我国研究程度较高的铅锌矿床之一,目前公认其为典型层控矿床,多数研究者认为其与密西西比型矿床相似,少数研究者则认为属典型的喷气——沉积型矿床。根据近几年我们对湘南粤北铅锌矿的研究,凡口铅锌矿床成矿作用复杂,既不同于密西西比型铅锌矿床,也不是典型的喷气——沉积矿床,本文在分析其成矿作用的基础上提出双源卤水(深循环地下热卤水和浅源层间卤水)沉积——叠加改造成矿模式。     

西藏斯弄多铅锌矿床成矿岩体LA-ICP-MS锆石U-Pb年龄及地质意义

斯弄多铅锌矿床位于南冈底斯-念青唐古拉成矿带北缘铅锌银多金属矿带上,该矿床铅锌矿化与矿区花岗斑岩密切相关,为典型的热液脉型-矽卡岩型铅锌矿床。为厘定其成岩成矿时代,本文对矿区花岗斑岩进行了锆石LA-ICP-MS U-Pb年龄测定。结果得到2组年龄,一组年龄介于(75.1±1.8)～(77.7±1.8)Ma之间,加权平均年龄为(75.7±0.9)Ma(MSWD=0.27,n=11),可能反映岩浆在岩浆房演化过程中结晶的锆石年龄;另一组年龄为(67.5±1.4)～(69.4±1.4)Ma,加权平均年龄为(68.8±1.2)Ma(MSWD=0.31,n=6),代表花岗斑岩真实的结晶年龄,这一花岗斑岩的年龄(68.8±1.2)Ma明显早于冈底斯带内主碰撞期形成的矽卡岩型矿床。结合该成矿带其他矿床的成岩、成矿年龄,本文认为南冈底斯-念青唐古拉成矿带在印-亚大陆碰撞早期或新特提斯洋壳俯冲晚期,也伴有较强的铅锌多金属成矿作用。     

云南保山核桃坪铅锌矿成矿年龄及动力学背景分析

保山地块成矿作用主要形成了铁铜铅锌银汞锡稀有金属的热液矿床,核桃坪铅锌矿为保山地块中一个重要的典型矿床,矿床赋存在寒武系碳酸盐岩地层中,矿化类型包括矽卡岩型富铜矿体、矽卡岩型磁铁矿体和矽卡岩型-热液脉型铜铅锌多金属矿体,估计铅锌储量大于100万吨、潜在铜资源量大于100万吨。矿区有矽卡岩及大量辉绿岩脉出露,外围有多期花岗岩岩体、岩株产出。经人工分选出核桃坪铅锌矿矿石中的闪锌矿、黄铜矿、黄铁矿及与矿石矿物密切共生的纯净石英共10件单矿物样品,采用Rb-Sr同位素定年分析,获得等时线年龄116.1±3.9Ma、矿石硫化物锶同位素组成初值0.71185。同时,我们对保山地块内部出露的志本山花岗岩体和柯街岩体进行了锆石U-Pb年龄及Hf同位素组成分析。志本山花岗岩、柯街花岗岩均为高钾过铝质花岗岩,锆石U-Pb年龄分析获得成岩年龄分别为126.7±1.6Ma和93±13Ma。同位素年龄测定的结果揭示成矿作用与地块内燕山晚期岩浆活动时期一致,并与中特提斯班公湖-怒江洋的闭合时代大致相当。志本山、柯街花岗岩锆石的εHf(i)值变化范围分别为-3～-8和-0.7～-4,亏损地幔模式年龄值分别在1.5Ga和1.3Ga左右,指示岩浆来源于中元古代地壳物质的深熔作用,与俯冲作用无关。花岗岩的地球化学组成表明其与变质杂砂岩熔出的熔体相当,分析认为岩浆源区为中、下地壳变质杂砂岩,岩浆活动形成于碰撞造山带后造山的拉张构造背景,地壳缩短加厚基础上的剪切拉张导致地壳发生深熔作用。地壳深熔成因的过铝质花岗岩、岩石圈伸展有关的辉绿岩、矽卡岩型-岩浆热液型矿床构成了保山地块早白垩世成矿作用中相关联的地质体组合、是中特提斯怒江洋闭合过程中碰撞造山作用的响应,核桃坪铅锌矿为三江特提斯复合造山成矿系统中一种重要的成矿作用类型。     

陆相红层型铜铅锌矿床与红层盆地热卤水成矿作用

新疆乌恰县乌拉根超大型铅锌矿是中国发现的首个产于陆相红层盆地中的红层型铅锌矿床,对其成矿作用及成因有多种不同认识,但都将其归入现有的一些矿床类型,如喷流沉积型、砂岩型等,却均不能反映其独特的成矿环境与成矿作用。为此,在广泛收集和研究全国陆相红层盆地及其矿产的地质资料基础上,通过区域地质构造背景、含矿建造、矿床特征、控矿因素、成矿物质来源、成矿流体等方面对比分析,认为乌拉根铅锌矿与中国大量产于陆相盆地内红色建造中的红层铜矿,在矿床特征、控矿条件、矿床成因等方面具有高度的一致性,均为陆相红层盆地热卤水作用的结果,是同一类型的矿床。红层型矿床是地洼区的特有矿产,是地球地质演化到地洼阶段才出现的新的矿床类型,陆相红层盆地热卤水作用是一个完全独立的成矿系统,因此将其作为一个单独的矿床类型——红层型矿床是合理的,既具有重要理论意义,也具有重要的实践意义,为铅锌矿找矿开辟了新的方向和领域。     

西藏亚贵拉含钼岩体锆石LA-ICP-MS年龄和地质意义

冈底斯带东段的念青唐古拉地区除了发育许多大中型铅锌矿床外,还发育大型钼矿床,前者被认为是始新世成矿作用的产物,后者则被认为是古新世斑岩型钼矿床。在该区规模最大的亚贵拉铅锌矿床评价过程中,不仅发现铅锌矿化与石英斑岩体关系密切,而且在岩体内发现了规模较大的辉钼矿脉。应用LA-ICP-MS对石英斑岩锆石微区U-Pb年龄和微量元素进行了测定,90%的测点Th/U比值较高,阴极发光图像显示锆石内部发育明显的环带构造,具岩浆成因特点。2件石英斑岩样品的锆石206Pb/238U加权平均年龄分别为(65.8±1.3)Ma(MSWD=3.0)、(68.6±1.7)Ma(MSWD=1.8),表明岩体形成于晚白垩世。在野外实地调研的基础上,结合石英斑岩体微量元素含量以及前人对钼矿体的辉钼矿Re-Os年龄测定,认为辉钼矿化、铅锌矿化均与石英斑岩岩浆热液密切相关,但亚贵拉钼矿化与沙让斑岩钼矿化有别。念青唐古拉地区在晚白垩世可能发生铅锌成矿作用以及钼成矿作用。     

东天山硫磺山铜多金属矿床成岩成矿作用同位素地质年代学

前人根据矿体的产出受碳酸盐岩层位控制和Pb同位素模式年龄资料,多认为硫磺山铜多金属矿床为层控型铜铅锌多金属矿床,其形成时代为奥陶纪.基于矿区石英斑岩体见矿化和矿化蚀变,矿体与围岩呈渐变关系等特点,笔者主张该矿床属斑岩型铜铅锌多金属矿床.年代学研究表明,含矿石英脉Rb-Sr等时线年龄(346±30 Ma)与石英斑岩的锆石U-Pb年龄(340～360 Ma)在测定误差范围内一致,表明成岩与成矿作用均发生在早石炭世-晚泥盆世,成矿作用无论从空间上和时间上都与石英斑岩有关.     

新疆阿尔泰南缘大东沟铅锌矿区火山岩LA-ICP-MS锆石U-Pb定年及地质意义

大东沟铅锌矿位于新疆阿尔泰南缘的克兰盆地,赋存于康布铁堡组上亚组火山-沉积岩系,矿体直接围岩为变质钙质砂岩及不纯的大理岩,矿体呈层状、似层状、透镜状分布,与地层产状一致。利用LA-ICP-MS锆石U-Pb测年法,获得矿区2件康布铁堡组上亚组变质流纹岩加权平均年龄分别为(388.9±3.2)Ma(MSWD=3.3)和(400.7±1.6)Ma(MSWD=1.3)。结合前人的年龄数据,将克兰盆地康布铁堡组的时代厘定为晚志留世末期至早泥盆世(413~389 Ma)。大东沟铅锌矿为火山岩容矿的喷流沉积型矿床(VMS),2件变质流纹岩年龄限定大东沟铅锌矿的成矿作用发生在早泥盆世(401~389 Ma)。     

三江特提斯兰坪盆地构造-流体-成矿系统

西南三江中段兰坪地区经历了复杂的碰撞造山过程,导致成矿时间长、强度大、作用多样,复合叠加成矿突出;碰撞造山时空演化格架和成矿作用已有深入探索,而叠加成矿作用及其对碰撞造山过程的响应,构造控矿样式,及金属富集机理尚需研究。本文以碰撞造山过程与成矿系统研究为基础,选取金顶和金满等矿床为重点解剖对象,以盆地卤水和热液铅锌铜银成矿作用为主线,利用锆石LA-ICP-MS U-Pb和流体包裹体测试分析手段,解析兰坪盆地构造-流体-成矿系统。利用锆石U-Pb同位素定年获得兰坪盆地西侧片麻质花岗岩和二长花岗岩的上交点年龄和加权平均年龄为1067±20Ma和206±1Ma,分别代表了基底岩石前寒武时期变质事件的年龄,以及昌宁-孟连古特提斯洋后碰撞造山事件的年龄。在此基础上,构建了兰坪盆地的前寒武盆地基底形成、中二叠世-中三叠世前陆盆地、晚三叠世裂谷盆地、侏罗纪-白垩纪坳陷盆地、古新世-早渐新世前陆盆地和晚渐新世-中新世走滑拉分盆地等复杂的转化过程。三江特提斯兰坪盆地发育3个与碰撞造山盆地有关的Pb-ZnCu-Ag-Au-Sb-Hg成矿系统:(1)中低温热液脉型Cu-Ag多金属成矿系统,以金满-连城铜钼矿床为代表。成矿铜和铅锌矿化两期叠加,集中于早始新世(56~46Ma)和渐新世-中新世(32~21Ma)。成矿流体盐度变化于0.88%~20.51%NaC leqv之间,成矿温度较低,通常在210~270℃,显示以低温高盐度的盆地卤水为主的特征,可能受到来自富CO2的变质流体影响;(2)浅成低温热液Sb-Au-Hg-As多金属成矿系统,以笔架山锑矿床为代表。成矿时间集中于中-晚始新世。成矿流体盐度6.0%NaC leqv,成矿温度较低,通常在145~200℃,显示以大气降水为主的特征;(3)密西西比河谷型Pb-Zn多金属成矿系统,以金顶超大型铅锌矿床为代表。成矿时间集中于32~21Ma之间。成矿流体盐度变化于1.6%~18%NaC leqv之间,成矿温度较低,通常在80~190℃,显示以低温高盐度的盆地卤水为主的特征,可能有大气降水的贡献。文章最后解析了兰坪盆地构造-流体-成矿过程。研究对兰坪地区盆地卤水–岩浆热液型铅锌铜银成矿系统认识,为大陆碰撞过程及叠加成矿作用进一步研究提供理论支撑。     

安徽池州许桥—乌古墩铅锌矿石榴子石和锆石U-Pb定年

石榴子石U-Pb定年在限定金属矿床形成时代上具有一定的优越性,而且近年来得到不少成功地应用。作为长江中下游的重要组成部分,池州地区燕山期岩浆活动强烈,伴随有成矿作用。然而,由于矿体赋存于沉积围岩中,区内的铅锌矿化时代目前还很模糊。本次对许桥—乌谷墩铅锌矿中多条岩脉及石榴子石进行多种矿物原位U-Pb定年。乌谷墩矿区内见有两种岩性的岩脉,其一为闪长玢岩,与铜、钼矿化关系密切,锆石U-Pb定年结果为146～141 Ma;另一为细粒花岗岩,与钼矿化关系密切,锆石U-Pb定年结果为113.4±2 Ma。矽卡岩中石榴子石U-Pb定年结果为148～143 Ma,形成时代与闪长玢岩脉一致。根据现有数据,池州地区存在3个阶段的成岩成矿作用：第一阶段（150～135 Ma）,主要形成中酸性侵入岩和与之相关的铜、金、钼、铅、锌等矿床;第二阶段（134～124 Ma）,形成钾长花岗岩和相关的铅锌钼矿化;第三阶段（115～110 Ma）,岩浆活动接近尾声,主要发育花岗岩脉,并伴随弱的钼矿化。结合区域成矿规律,池州地区的成矿作用不完全与长江中下游地区相同,且池州区内的多期Mo （W）矿化可能与中-新元古代增生地壳多阶段活化有关。     

Zircon U/Pb and Pb/Pb geochronology of the Rastenberg granodiorite,South Bohemian Massif,Austria

Summary A combined zircon typology, zircon Pb-Pb evaporation, and conventional U-Pb study of the late- to post-tectonic Rastenberg granodiorite yields the following results: Typological investigations show two distinguishable zircon populations. Type l: subtype S24 ofPupin, colourless to slightly pink, clear to turbid, often with cores, few to abundant inclusions, long prismatic; type 2: subtype S4 ofPupin, colourless to reddish or slightly pink, clear to slightly turbid, no visible cores, abundant inclusions, tabular habit, short prismatic.At least 4 different zircon-forming events can be distinguished: Inherited cores with ages around 623±22Ma and single ages > 1206Ma from type 1 zircons imply the reworking of rocks derived from Cadomian and Proterozoic to Archean crust. Ages around 353±9Ma from type 1 zircons are interpreted as timing a first magma formation or the onset of a long-lasting magma-generating event during the Variscan plutonism in the South Bohemian pluton. The actual intrusion of the granodioritic magma into the middle crust took place around 338±2Ma (type 2 and rims of type 1 zircons).Only type 1 zircons are found as inclusions in large K-feldspar phenocrysts providing evidence that these phenocrysts have grown before the 338Ma event and may be as old as 353 Ma.[]

---

Zirkon U/Pb und Pb/Pb Geochronologie des Rastenberger Granodiorits, südliche Böhmische Masse, Österreich

Zusammenfassung Zirkon-typologische Untersuchungen, Einzelzirkon Pb-Pb-Evaporations- und konventionelle U-Pb-Altersbestimmungen an Gesteinen des spät- bis postkinematischen Rastenberger Granodiorits geben folgende Resultate: Typologisch lassen sich zwei Zirkonpopulationen unterscheiden: Typ 1: S24 Subtyp vonPupin, farblos bis leicht rosa, klar bis getrübt, häufig mit Kernen, wenige bis viele Einschlüsse, lang prismatisch; Typ 2: S4 Subtyp vonPupin, farblos bis rötlich oder leicht rosa, klar bis leicht getrübt, keine sichtbaren Kerne, viele Einschlüsse, flachtafeliger Habitus, kurzprismatisch.Mindestens 4 unterschiedliche Altersgruppen lassen sich unterscheiden: Ererbte Kerne von Typ 1 Zirkonen mit Altern um 623±22Ma und einzelnen Altern > 1206Ma sprechen für die Aufarbeitung von Gesteinen, die von cadomischen und proterozoischen bis archaischen Gesteinen im Krustenbereich des Südböhmischen Plutons abstammen könnten. Alter um 353±9Ma von Typ 1 Zirkonen werden einer ersten magmatischen Phase oder dem Beginn der Krustenaufschmelzung im Zuge der Bildung der variszischen Plutonite zugeordnet. Die eigentliche Intrusion des Granodiorits um 338±2Ma wird mit Typ 2 und mit Randpartien von Typ 1 Zirkonen erfaßt.In den großen K-Feldspat-Phänokristallen finden sich nur Zirkone vom Typ 1. Dies deutet darauf hin, daß die Phänokristalle vor dem 338Ma Ereignis gebildet wurden, eventuell also bis 353Ma alt sein können.

---

---

With 6 Figures     

Pb同位素标准物的研制

质谱Pb同位素标准物质严格按照国家一级标准物质技术规范要求进行研究，其均匀性好，定值准确可靠。它包括SPb1、SPb2、SPb3、SPb4等4个标准，其覆盖面较NBS981、NBS982、NBS983更大。它可用于同位素地质年代学、同位素地质、环境、食品、医疗卫生等领域。     

城镇周边土壤中含铅矿物的环境意义

通过对长江下游南京至苏州一带铅污染土壤中含铅矿物的鉴定识别和来源分析,确定土壤中铅的来源,既有附近含铅矿床开采过程中带出的含铅矿物,也有人为叠加的成分。作为相对稳定的含铅矿物,方铅矿、白铅矿和人工含铅颗粒含量越高,土壤中有效态铅所占比例就越低。对Pb异常土壤中含Pb矿物的研究,可以解释土壤与农作物籽实中铅含量间的复杂关系,同时也可以为生态地球化学评价标准和预测预警方案的制定提供参考。     

Tracing diffuse anthropogenic Pb sources in rural soils by means of Pb isotope analysis

Knowledge of the cause and source of Pb pollution is important to abate environmental Pb pollution by taking source-related actions. Lead isotope analysis is a potentially powerful tool to identify anthropogenic Pb and its sources in the environment. Spatial information on the variation of anthropogenic Pb content and anthropogenic Pb sources in rural topsoils is remarkably limited. This study presents results of a survey of approximately 350 topsoil samples from rural locations covering the entire Netherlands, for which the bulk geochemical and Pb isotope compositions were determined. The specific aim of this study is to determine the anthropogenic Pb sources in the topsoils from rural areas in The Netherlands. The spatial distribution of anthropogenic Pb in soils in The Netherlands will be explained in terms of land use and pollution sources.Nearly all studied topsoils display Pb contents that exceed the amount expected based on the soil lithology. The range in Pb isotope ratios of the additional Pb fraction in rural Dutch topsoils is established at 1.056–1.199, 2.336–2.486 and 0.452–0.490 for ²⁰⁶Pb/²⁰⁷Pb, ²⁰⁷Pb/²⁰⁸Pb and ²⁰⁶Pb/²⁰⁸Pb, respectively. Five land use types are distinguished (forest, open nature, moor, arable land and grassland) with distinct isotopic compositions for added Pb. Additional Pb in soils of natural areas (forest, open nature and moor) has on average lower ²⁰⁶Pb/²⁰⁷Pb, ²⁰⁸Pb/²⁰⁷Pb and ²⁰⁶Pb/²⁰⁸Pb ratios than the agricultural soils (arable land and grassland). Additional Pb in both natural area soils and agricultural soils is interpreted to be of anthropogenic origin: most likely a mixture of coal/galena, incinerator ashes and gasoline Pb. The dominant sources of additional Pb in the topsoil of open nature areas are most likely incinerator ash and gasoline Pb. In contrast, the on average higher ²⁰⁶Pb/²⁰⁷Pb, ²⁰⁸Pb/²⁰⁷Pb and ²⁰⁶Pb/²⁰⁸Pb ratios of additional Pb in agricultural soils are most likely caused by the presence of animal manure and N–P fertilizers.Several areas are observed with notably high additional Pb contents (26–211 mg/kg on an organic matter-free basis) in the topsoil. The largest area is the Randstad area, which has the highest population and traffic density, and hosts a considerable fraction of the Dutch chemical industry. Two other areas with high additional Pb contents in the topsoil are located near the Dutch borders and are most likely influenced by German and Belgian chemical industries. The topsoils in the coastal dunes and southern, central and northern forests are characterized by relatively low additional Pb contents (<10 mg/kg on an organic matter-free basis). The population, traffic and chemical industry density is low in these areas and no fertilizers are applied.     

Pb diffusion in rutile

Diffusion of Pb was measured in natural and synthetic rutile under dry, 1 atmosphere conditions, using mixtures of Pb titanate or Pb sulfide and TiO₂ as the sources of diffusant. Pb depth profiles were then measured with Rutherford Backscattering Spectrometry (RBS). Over the temperature range 700–1100 °C, the following Arrhenius relation was obtained for the synthetic rutile: D=3.9 × 10⁻¹⁰exp(−250 ± 12 kJ mol⁻¹/RT) m²s⁻¹. Results for diffusion in natural and synthetic rutile were quite similar, despite significant differences in trace element compositions. Mean closure temperatures calculated from the diffusion parameters are around 600 °C for rutile grains of ∼100 μm size. This is about 100 °C higher than rutile closure temperature determinations from past field-based studies, suggesting that rutile is more resistant to Pb loss through volume diffusion than previously thought. Received: 28 June 1999 / Accepted: 29 December 1999     

Determination of the extent of anthropogenic Pb migration through fractured sandstone using Pb isotope tracing

The extent of vertical migration of anthropogenic Pb beneath a medieval smelting site in Derbyshire, U.K. has been estimated using the determination of total Pb concentrations and ²⁰⁶Pb/²⁰⁷Pb isotope ratio from samples taken down 6 m of drill core. Preliminary studies of total Pb concentrations established that the surface slag derived from the smelting contained up to 16% Pb and that the normal background levels in uncontaminated sandstone were 10±2 ppm. Sample analyses beneath the site revealed elevated Pb concentrations in fracture infill clays (270 ppm Pb) and sandstone (76–83 ppm Pb). Both are well above the background Pb concentration.Lead isotope analysis of the slag wastes, the underlying contaminated sandstone and fracture infill has shown that all 3 contain very similar isotope ratios for ²⁰⁶Pb/²⁰⁷Pb (1.1802–1.1820). However, matched control sandstone samples show that the background ²⁰⁶Pb/²⁰⁷Pb isotope ratio (1.1670 ± 0.003) is distinctly different. This would indicate that both the sandstone and fracture infill underlying the historical smelting site contain a substantial proportion of Pb that has been derived from the overlying contamination.The application of total Pb concentrations along the core and isotope analysis suggest that anthropogenically derived Pb from the smelting site (that was operated between 665 and 445 a BP) has migrated to a depth of 4.50 m. Assuming a uniform migration rate and a mean time of migration of 555 a, then the mean migration rate is estimated to be 8 ± 2 mm/a.The proportion of natural versus anthropogenic Pb in the samples has been estimated from small variations in the ²⁰⁶Pb/²⁰⁷Pb isotope ratio. If the slag is considered to contain 100% anthropogenic Pb and the uncontaminated sandstone considered to contain 100% natural Pb, the linear interpolation can be applied between the 2 end members of the isotope ratio. The use of this approach to the ²⁰⁶Pb/²⁰⁷Pb ratio measurements has shown that 88% of the Pb in the contaminated sandstone (i.e. 69 ppm from a mean total Pb concentration of 78.5 ppm) has been derived from the anthropogenic Pb at the surface. For the fracture infill sample taken at a depth of 4.50 m, and with a total Pb concentration of 270 ppm, the % of Pb that has been derived from the slag wastes is approximately 98% (equivalent to 265 ppm Pb). The remaining Pb in both these samples (9.4 and 5 ppm, respectively) is deduced to have originated from the natural background concentration of Pb in the sandstone.The closeness of these estimates to the measured background concentration, suggests that a simple two-source model of Pb contamination is valid for this site.     

A Correction Approach to the Common Pb Contribution to ^207Pb／^206Pb Ratios Obtained by the Zircon Evaporation Technique

An approach is recommended for the correction of common Pb contribution to ^207Pb/^206Pb ages obtained by the zircon evaporation technique.A comparison with that by Cocherie et al.(1992)shows that two approaches yield similar results in the ^207Pb*/^206Pb* ratios.But when using the new approach,only two errors of the measured ^204Pb/^206Pb and ^207Pb/^207Pb ratios are introduced to the calculated ^207Pb^*/^206Pb^* ratios.     

用双稀释法测定地质样品中的铅同位素组成

随着超净化实验室条件的完善以及多接收同位素质谱技术的成熟，铅同位素双稀释法倍受关注。用双稀释法测定铅同位素比值的方法原理，以及^204Pb—^207Pb双稀释剂的配制和标定方法。通过对标准物质NBS981和地质样品的分析测定，表明用双稀释法测定铅同位素比值，可以有效校正由质谱分析造成的同位素分馏效应，从而提高分析结果的精度和准确度。     

238U-206Pb, 235U-207Pb,systematics on Pyrenean basement

U-Pb ages for zircons of pyreneean gneisses and associated granites are comparable to whole rock Rb-Sr ages of 580, 320 m.y. and recent. Inherited radiogenic Pb in the granites limits the dating accuracy but points out an important contribution of crustal material in their formation.     

Eastern Laurentia in Rodinia: constraints from whole-rock Pb and U/Pb geochronology

Whole-rock Pb isotopic signatures and U/Pb geochronology refute a Rodinian correlation of northeastern Laurentia and proto-Andean Amazonia. According to this previously proposed model, the Labrador–Scotland–Greenland Promontory (LSGP) of northeastern Laurentia collided with the proto-Andean margin of Amazonia, at the Arica Embayment, during the Grenville/Sunsás Orogeny (ca. 1.0 Ga). Links between the two margins were based upon the correlation of the LSGP with Arequipa-Antofalla Basement (AAB), a Proterozoic block along the proto-Andean margin of Amazonia adjacent to the Arica Embayment. Specifically, similarities in 1.8–1.0 Ga basement rocks in both regions suggested that the AAB was originally a piece of the LSGP. Furthermore, similarities in unique, post-collisional, but pre-rift, glacial sedimentary sequences also supported a link between the AAB and LSGP.Tests of these apparent similarities fail to support correlation of the AAB and the LSGP and, thus, eliminate a direct link between northeastern Laurentia and southwestern Amazonia in Rodinia. However, Pb isotopic compositions and U/Pb geochronology provide the basis for two new correlations, namely, (1) the ca. 1.3–1.0 Ga basement in the central and southern Appalachians may be an allochthonous block that was transferred to Laurentia from Amazonia at ca. 1.0 Ga, and (2) an allochthonous AAB may be a piece of the Kalahari Craton that was transferred to Amazonia at ca. 1.0 Ga. Based on these new correlations and a previously proposed Grenvillian connection between southern Laurentia (Llano) and Kalahari, we propose that Amazonia may have collided with a contiguous southeastern Laurentia/Kalahari margin at ca. 1.0 Ga.