碳酸盐岩溶解-沉淀热力学模型及其在塔北地区的应用

 碳酸盐岩作为一种化学岩类其物性受成岩作用的影响十分明显,溶解作用是否发育直接关系到碳酸盐岩储层质量的好坏。碳酸盐矿物在埋藏环境中的溶解度与地层水的化学成分、环境的温度、pH等有着密切的关系。利用地层水化学资料,根据化学热力学的理论,通过方解石及白云石与地层水作用的平衡反应,计算吉布斯自由能变化ΔG,以此来判断方解石及白云石的溶解趋势,并建立了封闭系统中这两种矿物与水作用的热力学模型。根据这个理论模型,对塔北地区159口井奥陶系及6口井的寒武系地层水进行了ΔG的计算,结果显示,塔北地区碳酸盐岩与地层水反应的ΔG基本为负值,表明该地区总体处于碳酸盐岩溶解的环境,寒武系白云岩反应的自由能小于奥陶系灰岩,即在这种深埋条件下白云岩比灰岩更易溶解,这一点在实际岩芯资料上及前人的实验模拟中均有显示。塔北于奇地区自由能的计算结果也为负值,说明该地区强烈的充填作用并非发生在现今条件下,于奇地区现今的埋藏环境是有利于碳酸盐矿物溶解的,这一结论也在该地区奥陶系及寒武系岩芯上得到了验证。
      

巴丹吉林地区的寒武和奥陶纪地层

巴丹吉林地区位于我国北边,与蒙古人民共和国相毗邻,它包括弱水河以东、巴丹吉林沙漠及其以北的地区(图1)。由于地域偏僻,该区地质研究程度颇低,只进行过一百万分之一的区域地质测量,从未有过关于寒武、奥陶系的报导。1977—1978年,由宁夏地质局综合研究队和西安地质矿产研究所部分地层古生物工作者组成的地层小组,对沙漠以北的古生代地层进行了调查,首次在该区发现了富含动物化石的寒武系和奥陶系,现将其报导如下。     

论三峡东部地区奥陶系划分对比中的问题

三峡东部地区——宜昌分乡、黄花场,秭归新滩龙马溪一带奥陶系是我国乃至世界范围内研究奥陶系的重要地区。自1924年李四光教授首先在这里分层,创立宜昌石灰岩和艾家山系以来,经过半个多世纪,特别是解放后的大量工作(表1),使地层划分日臻完善,动物群特征更加清楚。1978年,我所奥陶系小组在前人工作基础上对三峡东部地区奥陶系作了进一步研究。事实说明三峡东部地区奥陶系作为我国奥陶系层型剖面还有不少问题有待进一步深入研究。这些问题的     

中国西藏南部珠穆朗玛峰地区构造特征

中华人民共和国成立以来,在中国共产党的领导下,曾几次派遣科学考察队到西藏地区进行考察。在无产阶级文化大革命期间,中国科学院组织了一支科学考察队,于1966-1968年在东起亚东西到吉隆我国喜马拉雅地区大约50,000平方公里的范围内进行了考察。在地质方面,根据地层发育、变质程度和构造变形的不同考察地区可以分成南、北两条东西向构造带。南带的地层层序非常完全,而北带则只有石炭-二迭纪和中生代地层出露。在南带发现了奥陶纪、志留纪和泥盆纪化石,对中生代和新生代沉积地层进行了较详细的划分,从而初步建立了珠穆朗玛峰(以下简称珠峰)地区比较完整的地层系统。     

从钻井测温曲线看地下水流方向及油气储藏条件——以川东南地区丁山1井为例

实测丁山1井测温曲线显示:温度向井底持续升高,井口温度25℃左右,井底温度107.5℃。温度曲线在1 000～3 000 m深度范围内出现"上凸"的扰动现象。现今平均地温梯度纵向上分段明显:三叠系及二叠系地层平均地温梯度为23.94℃/km;志留系和奥陶系地层平均地温梯度较大,为37.27℃/km;寒武系地层平均地温梯度较低,为16.65℃/100m。根据地温梯度分段性特征与地层热导率、地层岩性的相关性分析认为地下流体垂向上升运动造成了温度曲线扰动。进而推断出下奥陶统—中寒武统的地层具有较高的孔隙度和渗透率,而中奥陶统—志留系的地层则具有良好的封堵性,而这种上盖下储的地层组合,对油气成藏较为有利,反映了川东南地区下组合良好的油气储藏条件。     

华北地台中部曲阳奥陶系碳酸盐岩石学及沉积相特征

华北奥陶系的研究,从刘季辰等(1919)在徐州贾汪进行地质调查,及孙云铸等(1922)在唐山建立标准剖面起,至今约有60年。以往的研究,主要限于地层和古生物方面,岩石学的研究,只是近来才逐渐开展起来。     

滇西海相侏罗系

前言我国的海相侏罗系有两种类型。一种是特提斯(Tethys)型,属于这一类型的有西藏、青海南部、新疆、滇西等地区的海相侏罗系,这些地层的岩性和动物群性质或多或少都能与欧洲、印度西部、东非甚至东印度群岛的侏罗系相对比。另一种是环太平洋型,属于这一类型的包括湖南、广东、东北等地区的海相侏罗系。除东北拉丹哈达岭有侏罗纪的海相沉积外,其余地区仅含有海相里阿斯统的中下部。关于在中国以及中南半岛地区特提斯型与环太平洋型两种里阿斯时期海相地层的关系,至今仍然不清楚。滇西是我国海相中生代地层发育比较好的地区之一,过去虽然经过洛齐(L.vonLoczy,1893年)和布朗(Brown,Coggin J.,1916年)等人的调查,但对中生代地层,尤其是侏罗系缺乏详细研究。     

广西来宾、合山地区二叠系地层中的遗迹化石及其环境意义

1982、1983年,笔者在广西来宾、合山地区进行考察时,在该区地层中先后发现了比较丰富的遗迹化石。这些发现,无疑会丰富我国遗迹化石方面的实际资料,并对判明该区的沉积环境和古地理概貌,起着突出的作用。     

苏北地区上前寒武系古地磁研究及我国南北方上前寒武系的对比

苏北地区上前寒武系发育一套厚约五千米以上以海相为主的未变质地层。由于其岩性和生物组合的特殊性及其所处地理和构造位置的重要性,被视为解决我国南北方上前寒武系衔接和对比的关键地区之一。近年来,本区上前寒武系在生物地层、岩石地层、同位素地质等方面已经取得了一些重要成果,但对它们在我国上前寒武系所处的位置仍持有不同意见。至今,尚未见到有关的古地磁文章发表。     

西藏申扎地区奥陶系岩石地层划分之见解

西藏申扎地区奥陶系地层组的建立不是根据岩性特征,而是根据地层中的化石组合和多重地层划分的原则。笔者认为,申扎组应被废弃,德悟卡下组底界应作修订,并对该地区奥陶系岩石地层单位进行了简要的时代讨论和对比。     

某区磁铁矿床中钠质交代作用的特征及其找矿意义

河北省某区接触交代型磁铁矿床与燕山期角闪闪长岩-闪长岩和闪长岩-二长岩两个岩石系列的中性侵入岩有成因联系。磁铁矿体主要赋存在这些侵入岩与中奥陶统碳酸盐岩的接触带中。与铁矿床的形成有密切联系的蚀变现象主要是钠长石化和矽卡岩化。本文仅就钠质交代作用予以较详尽论述,对矽卡岩化等顺便提到,不作赘述。     

Mineralogical and geochemical studies of boron-rich bauxite ore deposits in the Songqi region,SW Henan,China

The Songqi region, SW Henan, is an important bauxite province in China. The bauxite ore deposits occur unconformably on the top of Middle Ordovician argillaceous carbonates. The bauxite ores from the Songqi region are characterized by unusually high boron contents. In this paper, we report the mineralogical and chemical compositions of selected bauxite ores from the region. These new data, together with existing geochemical data of soils in the region, are used to evaluate the origin of boron enrichment in the bauxite ores. The compositional characteristics of tourmaline in the bauxite ores suggests that this mineral was likely derived from a meta-sedimentary protolith. Mass balance calculation reveals that tourmaline only accounts for a small portion of boron in the bauxite ores; the majority of boron in the ores must occur in other forms, possibly by ion absorption on the surfaces of diaspore and clay minerals. In the Songqi region, the Precambrian meta-sedimentary rocks are known to contain abundant tourmalines whereas the Cambrian–Ordovician argillaceous carbonates and the Upper Proterozoic shales are all enriched in boron in free ion state. We suggest that these rocks provided tourmaline and boron ion to the bauxite deposits in the region. Most known bauxite deposits in the Songqi region occur at the margins of boron-rich soil domains, suggesting that boron in soils is a potential exploration indicator for unknown bauxite deposits in this region.     

Metallogeny and tectonic development of the tasman fold belt system in tasmania

In western Tasmania, Precambrian sedimentary sequences form the basement for narrow trough accumulations of Eocambrian and younger sequences. The main trough, the meridional Dundas Trough, is flanked to the west by the Rocky Cape region of Precambrian rocks within which major, apparently stratiform, exhalative magnetite-pyrite deposits are intercalated with metabasaltic volcanics and ultramafic bodies.The Eocambrian-Cambrian troughs apparently developed during extension of Precambrian continental crust. Early shallow-water deposition includes thick dolomite units in some troughs. Deepening of the troughs was accompanied by turbidite sedimentation, with minor limestone, and submarine basaltic volcanism with associated minor disseminated native copper. Ultramafic and related igneous rocks were tectonically emplaced in some troughs during a mild compressional phase. They contain only minor platinoids, copper-nickel sulphides and asbestos, but are source rocks for Tertiary secondary deposits of platinoids, chromite and lateritic nickel.In the Dundas Trough, Eocambrian-Early Cambrian rocks are separated by an inferred erosional surface from structurally conformable overlying Middle to Late Cambrian fossiliferous turbidite sequences. The structural conformity continues through overlying Ordovician to Early Devonian terrestrial and shallow-marine stable shelf deposits.A considerable pile of probable Middle Cambrian felsic volcanics accumulated between the sedimentary deposits of the Dundas Trough and the Tyennan region of Precambrian rocks to the east. A lava-dominated belt within the volcanics hosts major volcanogenic massive sulphide deposits, including those of the exhalative type, which in the south are enriched in copper, gold and silver, whereas in the north they are rich in zine, lead, copper, gold and silver. Cambrian movements along faults near the margin of the Tyennan region resulted in erosion of the mineralized volcanics, locally exposing sub-volcanic granitoids. Above the local unconformities occur unmineralized volcaniclastic sequences that pass conformably into Ordovician to Early Devonian shelf deposits. Ordovician limestone locally hosts stratabound disseminated and veined base metal sulphide deposits.Pre-Middle Devonian rocks of western Tasmania differ, for most part, from those in the northeast where deeper marine turbidite quartz-wacke sequences were deposited during the Ordovician and Early Devonian.The Eocambrian to Early Devonian rocks of Tasmania were extensively deformed in the mid-Devonian. The Precambrian regions of western Tasmania behaved as relatively competent blocks controlling early fold patterns. In northeastern Tasmania, folding is of similar age but resulted from movements inconsistent with those affecting rocks of equivalent age in western Tasmania.The final metallogenic event is associated with high-level granitoid masses emplaced throughout Tasmania during the Middle to Late Devonian. In northeastern Tasmania, extensive I-type granodiorite and S-type granite, with alkali-feldspar granites, are associated with mainly endogranitic stanniferous grelsens and wolframite ± cassiterite vein deposits. In contrast, scheelite-bearing skarns and cassiterite stannite pyrrhotite carbonate replacement deposits are dominant in western Tasmania, associated mainly with S-type granites. Several argentiferous lead-zinc vein deposits occur in haloes around tin-tungsten deposits. A number of gold deposits are apparently associated with I-type granodiorite, but some have uncertain genesis.The contrasting regions of western and northeastern Tasmania have probably been brought together by lateral movement along an inferred fracture. Flat-lying, Late Carboniferous and younger deposits rest on the older rocks, and the only known post-Devonian primary mineralization is gold associated with Creta ceous syenite.     

苏、浙、皖地区沉积-大地构造演化

中国南部近东西延伸的扬子板块形成于距今800Ma 前。自震旦纪开始,在其东缘苏、浙、皖地区形成了两个呈北东东向展布的并在其东端相联的裂陷槽。其沉积厚度达万米。沉积演化晚期形成了复理石与磨拉石。复理石堆积于晚奥陶世,此时裂陷槽为两个向东开口的海湾,碎屑物来自盆地南北两侧的扬子古陆。磨拉石堆积的时代从晚奥陶世末到中泥盆世,碎屑物     

皖南祁门-歙县地区元古界变质岩地层原始构造环境和形变

1975年和1976年,作者和安徽省地质局332队宿立先、黄清涛同志先后观测了皖南的铺岭组和井潭组剖面,并将部分资料作过初步介绍。1977年作者又到现场观测和收集了牛屋组、板桥组、漳前组的有关资料。本文就是根据已收集的初步资料整理而成。研究地区元古界变质杂岩包括休宁组以前的地层。安徽省区域地质调查队将它分为漳前、板桥、木坑(环沙)、牛屋、邓家和井潭(铺岭)六个组分别归于震旦系和前震旦系(表1)。     

Palynological evidence for a latest Carboniferous-Early Permian glaciation in Northern Ethiopia

Palynomorphs extracted from glacigenic sediments in Northern Ethiopia are latest Carboniferous-Early Permian in age. These sediments were hitherto thought to be either of Upper Ordovician or of Late Carboniferous-Early Permian age. The predominantly glaciolacustrine and glaciofluviatile sediments were deposited in glacial troughs and valleys that were eroded into Precambrian basement rocks and into Early Palaeozoic deposits, possibly equivalents of Upper Ordovician sediments in Eritrea. In the latest Carboniferous-Early Permian, glaciated uplands to the north of Ethiopia must have existed in Eritrea and/or in southern or central Saudi Arabia.     

论古代海洋碳酸盐沉积环境基本模式

我国碳酸盐地层分布广泛,厚度巨大,类型复杂,从而为我国碳酸盐研究提供广阔前景。解放以后,我国首先在四川盆地的二、三叠系碳酸盐岩中获得高产气田,推动了碳酸盐岩的研究。     

江苏宁镇山脉仑山灰岩的新认识

“仑山灰岩”标准地点在江苏南部句容县的仑山。1933年,俞建章在研究“仑山灰岩”中的头足类动物群时,曾指出:“仑山灰岩”的时代应属于早、中奥陶世。1935年,李捷等在系统研究宁镇山脉地质时,对“仑山灰岩”重新进行划分,把上部含鞘角石(Vaginoceras)动物群的灰岩归入中奥陶统,称汤山灰岩。     

湖北当阳白垩纪风成石英砂

风成沉积是干旱或半干旱气候下的一种典型产物,包括石漠戈壁滩,沙漠和风成黄土。世界上研究得较详细的古代沙漠沉积的地质时代是侏罗纪、二叠-三叠纪、泥盆纪、下寒武世和前寒武纪,尤其是二叠纪最佳。在我国,已经报道的古风成沉积时代不老于白垩纪。1963年张步春和王景钵首次报道在广东河源红色盆地地层中,发现了风成斜层理和风棱石。后来,笔者在湖南沅麻红色盆地的白垩系中也发现有风成砂。