古马岭金矿床地质、地球物理、地球化学特征

本文总结了古马岭金矿地质、地球物理、地球化学特征,确定了金矿体和金矿化蚀变带的找矿标志。     

火试金法测定铜精矿中金含量结果的不确定度评定

对火试金法测定铜精矿中金含量的结果进行不确定度评定。分析了铜精矿样品称量、铜精矿样品的不均匀性和配料处理,以及金粒称量等因素对金含量测量结果不确定度的影响,并得出火试金法测量铜精矿中金含量的扩展不确定度。     

活性炭吸附-碘量法测定金矿石中金的不确定度评定

根据测量不确定度的评定方法,对活性炭吸附-碘量法测定金矿石中的金进行不确定度评定。实验样品从低温升至650℃灼烧2 h除硫,用50%(体积分数)的王水溶解1 h,经活性炭动态吸附抽滤,将载金炭灰化复溶,用硫代硫酸钠标准溶液滴定,该方法简便、快速、实用性强。测量结果的不确定度由滴定样品消耗的硫代硫酸钠标准工作溶液体积、硫代硫酸钠对金的滴定度、称量质量、重复测定等不确定度分量组成。对各个不确定度分量进行分析并量化,合成得到测量结果的标准不确定度,换算成扩展不确定度。通过评定不确定度主要是由硫代硫酸钠对金的滴定度引入。     

我国金矿样加工制备及其设备的选择

简述金矿样加工制样的原理、规范以及合格的加工设备。对金矿样细磨设备选型从技术、标准化管理和法律、法规的角度进行了分析。确定了细碎金矿样的设备 ,为棒磨和盘磨保证了金矿样制备的合理性     

氢醌滴定法测定金矿石中金的不确定度评定

以氢醌滴定法测定金矿石中贵金属金的实例进行不确定度评定。测量结果的不确定度由配制金标准母液、金标准工作液、氢醌滴定液浓度、称样质量、滴定样品所用氢醌溶液体积等所引入的不确定度分量组成。在对各个不确定度分量进行量化的基础上，通过合成得到测量结果的标准不确定度，再乘以95％置信概率下的扩展因子2，得到测量结果的扩展不确定度。     

x我国金矿样加工制备及其设备的选择

简述金矿样加工制样的原理、规范以及合格的加工设备.对金矿样细磨设备选型从技术、标准化管理和法律、法规的角度进行了分析.确定了细碎金矿样的设备,为棒磨和盘磨保证了金矿样制备的合理性.     

堆浸提金原理与试验研究

本文介绍了堆浸提金原理和在实验室进行金矿石堆浸可行性研究的方法.以我国辽宁猫岭金矿、四川茶铺子金矿和福建紫金山金矿为研究对象,研究了矿石粒度、氰化钠溶液浓度、浸出时间等因素对金浸出率的影响,从而确定堆浸提金最佳工艺条件.通过对上述三类矿石性质及堆浸性能的比较,认为矿石的物质组成和金的嵌布特性对金的浸出率影响较大.     

基于Sufer软件的安徽巢湖马家凹地区土壤化探测量的数据处理方法

通过各项地质工作,完成面积约7.47 km2的土壤化探测量,采集样品1 353个,根据统计分析结果,确定了区内Au元素与Cu、Pb、Zn及Ag的关系较之Co、Ni密切,反映了区内金的成矿与老地层有一定的成因联系。通过异常等级的确定,圈定金化探异常9个。并利用地球化学块体方法对区内金的资源潜力进行了评估。初步认为区内金在构造、地层有利地段是最佳的最找矿地段。     

地电化学（泡塑）样品中金与锑的预处理

通过模拟实验获得附载金、锑的泡塑样品，并对其进行了硫脲解脱法、灰化法、硝酸加氧化剂消解法的比较实验，确定采用硫脲解脱法是地电化学(泡塑)样品金、锑的最佳解脱方法，通过正交实验及其结果分析确定了最佳实验条件。利用硫脲解脱一原子吸收光谱法对某隐伏金锑矿床82件地电化学(泡塑)样品进行了测试，分析结果显示出有明显的金、锑异常，指示了重要的勘探靶区。     

石墨炉原子吸收法测定土壤中痕量金检出限的不确定度分析

根据石墨炉原子吸收光谱法对土壤中痕量金进行测定,选取金系列标准浓度测量质量—吸光度工作曲线,连续测定多次空白溶液的吸光度值,计算检出限。通过对其检出限的不确定度的分析,确定了检出限不确定度的因素,计算出其扩展不确定度。能比较直观地了解选择的测试条件、建立的分析方法是否达到现行的相关标准及其灵敏度的要求。     

甘肃省文县阳山金矿床地质及同位素特征

阳山金矿床位于陕甘川交界地带,在大地构造位置上属西秦岭南亚带.矿床产于中泥盆统三河口组浅变质岩地层中,受文县弧形构造控制.矿体在平面上呈舒缓波状,在剖面上为脉状、似层状,矿石中金属矿物主要有黄铁矿、毒砂和辉锑矿,金主要以微细粒金赋存于黄铁矿、毒砂和黏土矿物中.矿床的钾-氩、氩-氩、氢、氧、硫、碳同位素研究表明,阳山金矿形成于侏罗纪早期(195Ma),与区域上三叠纪末期-侏罗纪早期的岩浆-构造活动关系密切,其不同于典型的卡林型金矿以及类卡林型金矿,其成矿流体及成矿物质均与岩浆热液活动有关.     

Geological and geochemical characteristics and formation mechanisms of the Zhaishang Carlin-like type gold deposit,western Qinling Mountains,China

Located in the western part of the Min–Li metallogenic belt within the western Qinling Mountains, the Zhaishang gold deposit is a giant Carlin-like disseminated gold deposit discovered recently. The ore deposit is present both in rocks of low grade metamorphic Middle Devonian and Lower Permian clastic formation, which is composed of quartz sandstone, siltstone, calcareous slate and argillaceous limestone. Gold mineralization is strictly controlled by a fault zone. Minerals in ores are quite complex and consist of sulfides, sulfosalt, oxides, sulfate, carbonate, tungstate, telluride, native metals, and polymetallic alloys. The diversity of mineral in the ores and the existence of microscopic visible native gold constitute the outstanding features of the gold deposit.We believe that the mineral source of the ore deposit has a close connection with the host rocks, because all samples show the light of the REE distribution patterns. The S, C, Pb, H and O isotopic compositions show that the ore-forming elements were mainly derived from the country rocks, the underlying rocks, and partially deep sources. Data obtained suggest that the ore-forming fluids were derived predominantly from an active meteoric groundwater system. Mineralization and related alteration have features of a low water/rock ratio. Ore-forming temperatures are estimated to have been in the range from 120 to 240 °C. The dissolution of ferruginous limestone in the host rocks and the sulfidation of the dissolved iron by H₂S introduced by ore fluids constituted not only the most important depositional mechanisms for the existence of microscopic visible gold grains but also favorable conditions for gold enrichment in the Zhaishang gold deposit.     

福建紫金山矿田金、银赋存状态及黄铁矿标型研究

福建紫金山铜金矿床、悦洋银多金属矿床和罗卜岭斑岩型矿床同属于与陆相火山岩相关的斑岩-浅成低温热液成矿系统。通过显微镜观察、电子探针成分分析、场发射扫描电子显微镜观测和矿石元素含量分析等综合研究方法,认为紫金山铜金矿床金的赋存状态除金矿石中自然金矿物外,金还赋存于铜矿石中硫砷铜矿、蓝辉铜矿、久辉铜矿和黄铁矿中,硫砷铜矿含金性最好,金含量最高达370 μg/g;悦洋银多金属矿床银的赋存状态包括独立银矿物、亚显微银矿物和类质同象银,银的载体矿物有方铅矿、黄铁矿、黄铜矿等;黄铁矿是紫金山铜金矿床和悦洋银多金属矿床中共同存在的矿物,黄铁矿成分标型特征表明两处矿床的形成均与热液有关,与前人的研究结果一致。     

http://www.sciencedirect.com/science/article/pii/S1674987113000790

The Heilangou gold deposit is located in the northern QixiaePenglai gold belt, which is one amongst the three large gold belts in the eastern Shandong Province （Jiaodong Peninsula）. The ore body has formed within the Guojialing granite. In this study, we report the mineral chemistry of pyrite, as well as the S, Pb, and HeO isotope data of the Heilangou gold deposit. The chemical composition of pyrite in the Heilangou gold deposit indicates that the associated gold deposit is a typical magmatic hydrothermal one. The geochemical signatures and crystal structure of pyrite show that the ore-forming materials have been derived from the crust. The S isotope data of the pyrites from Heilangou show an overall range from 5.5 to 7.8＆amp;and an average of 6.7＆amp;. The S isotope data in this deposit are similar to those from the deposits in the Jiaodong gold belt. The Pb and S isotope variations are small in the Heilangou gold deposit. The 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios are 17.4653e17.5958, 15.5105e15.5746 and 38.0749e38.4361, respec-tively. These data plot between the lower crust and the orogenic belt. The Pb isotope data in the Heilangou gold deposit are similar to those in the Linglong gold deposit. From the Qixia gold area （the Liukou and Majiayao gold deposits） to the MupingeRushan gold belt （Rushan gold deposit） to the ZhaoeYe gold belt （the Linglong, Sanshandao and Jiaojia gold deposits）, the 206Pb/204Pb ratios progressively increase. The DeO isotope data obtained from quartz separates suggest that the ore-forming fluid was similar to a mixture of magmatic and meteoric waters. These results suggest that the ore-forming elements were primarily from source fluids derived from the lower crust.     

辽宁白云金矿床稳定同位素地球化学特征及矿床成因

白云金矿床是辽东地区的一个大型金矿床,其成矿物质来源及矿床成因一直存在争议。本文系统地研究了白云金矿床的氢、氧、硫和碳同位素地球化学特征。研究结果显示:成矿流体中δ~(18)OV-SMOW值变化范围为13.5‰15.9‰,δD_(V-SMOW)为-107‰-83‰,表明成矿流体以岩浆水为主;矿石中黄铁矿的δ~(34)S_(V-CDT)为-8.3‰2.9‰,以富轻硫和贫重硫为特征,与辽河群围岩中黄铁矿的硫同位素组成(δ~(34)S_(V-CDT)为7.0‰18.7‰)有明显差异;矿石中方解石的碳同位素δ~(13)C_(V-PDB)为-2.2‰-0.4‰,类似于火成碳酸岩或地幔包体来源的碳同位素特征,也与辽河群大理岩的碳同位素组成明显不同。成矿元素特征对比也显示,成矿物质来源与辽河群没有必然联系。综合矿床地质特征和地球化学特征,认为白云金矿床是与深部岩浆流体活动有关的岩浆热液型金矿床。     

西秦岭凤太矿集区丝毛岭金矿床地质地球化学特征

西秦岭凤太矿集区丝毛岭金矿床位于八卦庙造山型金矿床西侧5km左右,是一个新探明的剪切带型金矿。其成矿作用过程可分为早期石英-绢云母-硫化物阶段、中期多金属-硫化物阶段和晚期碳酸盐阶段。对早、中期的石英流体包裹体测试结果表明,丝毛岭金矿床成矿流体以富CO2、中温、低盐度为特征,总体上属于中温低盐度CO2-H2O体系,流体包裹体类型的多样性是流体不混溶性的产物。从早阶段到主成矿阶段成矿流体的温度、压力和盐度均有降低,硫逸度增高,有利于金的沉淀富集。H、O、S、C同位素研究结果,以及与八卦庙金矿床的对比分析表明,二者的成矿流体具有相似性和同源性,都是以深部来源为主的多源流体。由于丝毛岭金矿床产出的层位高于八卦庙金矿床,其成矿环境相对开放。     

广西龙头山次火山-隐爆角砾岩型金矿床

龙头山金矿床与燕山晚期流纹斑岩、角砾熔岩等次火山岩相有关。据围岩和构造条件将矿体分为次火山隐爆角砾岩类、接触带－构造角砾岩类和围岩中断裂构造角砾岩等３种类型。主要金矿化与电气石化、硅化关系密切。通过矿石组成、Ａｕ及其伴生元素分布特征,以及Ｓ、Ｐｂ、Ｈ、Ｏ、Ｃ等稳定同位素、流体包裹体地球化学和成矿物理化学条件等综合研究结果,认为龙头山矿床是与次火山隐爆角砾岩有关的气成－高温热液型金矿床。     

Mineralogy and Geochemistry of Pyrite and Arsenopyrite from the Zaozigou Gold Deposit in West Qinling Orogenic Belt,Central China: Implications for Ore Genesis

The Zaozigou gold deposit lies in the West Qinling orogenic belt, Gansu Province, China. It is one of the largest gold deposits, and the orebodies are hosted in fine‐grained slates intercalated with limestone of the Middle‐Triassic Gulangdi Formation and varied dykes. The gold orebodies are strictly controlled by the NE‐, NW‐, and SN‐trending tensional and shearing faults with high dipping angle. The mineralogy and geochemistry of pyrite and arsenopyrite are measured by electron microprobe. Pyrite has up to 0.12 wt.% Au, and arsenopyrite contains up to 0.17 wt.% Au. The antithetic correlation between S and As indicates the substitution of As for S in pyrite, and arsenic occurs in anionic As^1? state in the pyrite structure under the reduced conditions. Pyrite has relatively high Co (~364–2248 ppm) but relatively low Ni (~109–497 ppm) contents, with Co/Ni ratios ranging from ~1.63 to 10.50, indicating that the deposit originated from a volcanogenic fluid and remobilized by hydrothermal fluid. Au in arsenopyrite occurs as cationic Au in solid solution, whereas Au in pyrite is in solid solution and metal nanoparticles (Au⁰). The texture characteristics and trace element geochemistry among cores, transition zones, and rims of pyrites demonstrate that there are at least four pulses of fluid participating in the generation of pyrite in the deposit. The calculated formation temperatures of the Zaozigou deposit vary from 148°C to 304°C, with an average temperature of 213°C based on Au contents in pyrite. The Pb isotopic compositions of pyrite samples suggest that the metallogenic materials of the Zaozigou deposit were derived from the mantle and upper crust. All the characteristics above lead us to draw the conclusion that the Zaozigou gold deposit is classified as an epithermal deposit.     

滇东南底圩金矿床矿物学与地球化学研究

位于右江盆地南部的滇东南底圩金矿床是近年来新发现的一处金矿床,为理清其成因,对不同类型矿石和赋矿围岩进行了主、微量元素及硫化物的硫同位素分析.结果表明,相较于赋矿围岩,矿石中明显富集Au、As、Sb、Hg、Tl、S、K、C元素,应为热液带入;而Si、Mg、Fe、Zr 和Th在矿石和围岩中变化不大,Fe主要来源于赋矿围岩...     

辽东半岛青城子矿田典型金矿成因：来自硫、氢、氧同位素的证据

青城子矿田是辽宁东部重要的金多金属矿田,成矿作用复杂.选择白云金矿和小佟家堡子金矿进行了硫同位素和氢氧同位素研究.结果显示矿田内小佟家堡子等金矿硫同位素含量为1.87‰~16‰,无明显的塔式分布;白云金矿的硫同位素含量为-10.3‰~+1.9‰.氢氧同位素测试结果显示白云金矿中石英δD含量为-108.3‰~-74‰,δ¹⁸O含量为8‰~15.9‰;而小佟家堡子等金矿的石英氢氧同位素分布则较为分散.综合分析认为,小佟家堡子金矿代表了早期金成矿,与变质作用有关;白云金矿代表了晚期金成矿作用;矿田内层状铅锌矿与小佟家堡子等金矿可能是同期成矿事件.