Using isotopes to understand landscape-scale connectivity in a groundwater-dominated,lowland catchment under drought conditions

The Demnitzer Millcreek catchment (DMC), is a 66 km² long-term experimental catchment located 50 km SE of Berlin. Monitoring over the past 30 years has focused on hydrological and biogeochemical changes associated with de-intensification of farming and riparian restoration in the low-lying landscape dominated by rain-fed farming and forestry. However, the hydrological function of the catchment, which is closely linked to nutrient fluxes and highly sensitive to climatic variability, is still poorly understood. In the last 3 years, a prolonged drought period with below-average rainfall and above-average temperatures has resulted in marked hydrological change. This caused low soil moisture storage in the growing season, agricultural yield losses, reduced groundwater recharge, and intermittent streamflows in parts of an increasingly disconnected channel network. This paper focuses on a two-year long isotope study that sought to understand how different parts of the catchment affect ecohydrological partitioning, hydrological connectivity and streamflow generation during drought conditions. The work has shown the critical importance of groundwater storage in sustaining flows, basic in-stream ecosystem services and the dominant influence of vegetation on groundwater recharge. Recharge was much lower and occurred during a shorter window of time in winter under forests compared to grasslands. Conversely, groundwater recharge was locally enhanced by the restoration of riparian wetlands and storage-dependent water losses from the stream to the subsurface. The isotopic variability displayed complex emerging spatio-temporal patterns of stream connectivity and flow duration during droughts that may have implications for in-stream solute transport and future ecohydrological interactions between landscapes and riverscapes. Given climate projections for drier and warmer summers, reduced and increasingly intermittent streamflows are very likely not just in the study region, but in similar lowland areas across Europe. An integrated land and water management strategy will be essential to sustaining catchment ecosystem services in such catchment systems in future.     

Distinct export dynamics for dissolved and particulate phosphorus reveal independent transport mechanisms in an arable headwater catchment

This paper investigates particulate phosphorus (PP) and soluble reactive phosphorus (SRP) concentrations at the outlet of a small (5 km²) intensively farmed catchment to identify seasonal variability of sources and transport pathways for these two phosphorus forms. The shape and direction of discharge‐concentration hystereses during floods were related to the hydrological conditions in the catchment during four hydrological periods. Both during flood events and on an annual basis, contrasting export dynamics highlighted a strong decoupling between SRP and PP export. During most flood events, discharge‐concentration hystereses for PP were clockwise, indicating mobilization of a source located within or near the stream channel. Seasonal variability of PP export was linked to the availability of stream sediments and the export capacity of the stream. In contrast, hysteresis shapes for SRP were anticlockwise, which suggests that SRP was transferred to the stream via subsurface flow. Groundwater rise in wetland soils was likely the cause of this transfer, through the hydrological connectivity it created between the stream and P‐rich soil horizons. SRP concentrations were the highest when the relative contribution of deep groundwater from the upland domain was low compared with wetland groundwater. Hence, soils from non‐fertilized riparian wetlands seemed to be the main source of SRP in the catchment. This conceptual model of P transfer with distinct hydrological controls for PP and SRP was valid throughout the year, except during spring storm events, during which PP and SRP exports were synchronized as a consequence of overland flow and erosion on hillslopes. Copyright © 2015 John Wiley & Sons, Ltd.     

Conceptual modelling to assess how the interplay of hydrological connectivity,catchment storage and tracer dynamics controls nonstationary water age estimates

Although catchment storage is an intrinsic control on the rainfall–runoff response of streams, direct measurement remains a major challenge. Coupled models that integrate long‐term hydrometric and isotope tracer data are useful tools that can provide insights into the dynamics of catchment storage and the volumes of water involved. In this study, we use a tracer‐aided hydrological model to characterize catchment storage as a dynamic control on system function related to streamflow generation, which also allows direct estimation of the nonstationarity of water ages. We show that in a wet Scottish upland catchment dominated by runoff generation from riparian peats (histosols) with high water storage, nonstationarity in water age distributions is only clearly detectable during more extreme wet and dry periods. This is explained by the frequency and longevity of hydrological connectivity and the associated relative importance of flow paths contributing younger or older waters to the stream. Generally, these saturated riparian soils represent large mixing zones that buffer the time variance of water age and integrate catchment‐scale partial mixing processes. Although storage simulations depend on model performance, which is influenced by input variability and the degree of isotopic damping in the stream, a longer‐term storage analysis of this model indicates a system that is only sensitive to more extreme hydroclimatic variability. Copyright © 2014 John Wiley & Sons, Ltd.     

Quantifying groundwater discharge to a small perennial stream in southern Ontario, Canada

A study of the interaction between groundwater and surface water was undertaken within a small agricultural watershed in southern Ontario, Canada. Groundwater contributions to streamflow were measured along a section of stream during baseflow conditions and during rainfall events. Four techniques were used to estimate the contribution of groundwater to the stream along a 450 m reach (three during baseflow and one during stormflow conditions). Under baseflow conditions, streamflow measurements using the velocity–area technique indicated that the net groundwater flux to the stream during the summer months was 10 ml s⁻¹ m⁻¹. Hydrometric measurements (i.e. hydraulic gradient and hydraulic conductivity) taken using mini-piezometers installed in the sediments beneath the stream resulted in net groundwater flux estimates that were four to five times lower. Seepage meters failed to provide any measurements of water flux into or out of the stream. Therefore, based on these results, the velocity–area technique gives the best estimate of groundwater discharge. Hydrograph separations were conducted using isotopic ratios and electrical conductivity on two large rainfall events with different antecedent moisture conditions in the catchment. Both events showed that pre-event water (generally considered groundwater) dominated streamflow and tile drain flow with 64%–80% of the total discharge contributed by pre-event water. High water table conditions within the catchment resulted in greater stream discharge and a greater contribution of event water in the streamflow than that observed under low water table conditions for similar intensity storm events. The results also showed that differences in riparian zone width, vegetation and surface saturation conditions between the upper and lower catchment can influence the relative magnitude of streamflow response from the two catchment areas.     

Spatiotemporal variability in hydrochemistry of shallow groundwater in a small pre‐alpine catchment: The importance of landscape elements

Topography and landscape characteristics affect the storage and release of water and, thus, groundwater dynamics and chemistry. Quantification of catchment scale variability in groundwater chemistry and groundwater dynamics may therefore help to delineate different groundwater types and improve our understanding of which parts of the catchment contribute to streamflow. We sampled shallow groundwater from 34 to 47 wells and streamflow at seven locations in a 20‐ha steep mountainous catchment in the Swiss pre‐Alps, during nine baseflow snapshot campaigns. The spatial variability in electrical conductivity, stable water isotopic composition, and major and trace ion concentrations was large and for almost all parameters larger than the temporal variability. Concentrations of copper, zinc, and lead were highest at sites that were relatively dry, whereas concentrations of manganese and iron were highest at sites that had persistent shallow groundwater levels. The major cation and anion concentrations were only weakly correlated to individual topographic or hydrodynamic characteristics. However, we could distinguish four shallow groundwater types based on differences from the catchment average concentrations: riparian zone‐like groundwater, hillslopes and areas with small upslope contributing areas, deeper groundwater, and sites characterized by high magnesium and sulfate concentrations that likely reflect different bedrock material. Baseflow was not an equal mixture of the different groundwater types. For the majority of the campaigns, baseflow chemistry most strongly resembled riparian‐like groundwater for all but one subcatchment. However, the similarity to the hillslope‐type groundwater was larger shortly after snowmelt, reflecting differences in hydrologic connectivity. We expect that similar groundwater types can be found in other catchments with steep hillslopes and wet areas with shallow groundwater levels and recommend sampling of groundwater from all landscape elements to understand groundwater chemistry and groundwater contributions to streamflow.     

Modelling the interaction of climate,forest ecosystem,and hydrology to estimate catchment dissolved organic carbon export

The potential for increased loads of dissolved organic carbon (DOC) in streams and rivers is a concern for regulating the water quality in water supply watersheds. With increasing hydroclimatic variability related to global warming and shifts in forest ecosystem community and structure, understanding and predicting the magnitude and variability of watershed supply and transport of DOC over multiple time scales have become important research and management goals. In this study, we use a distributed process‐based ecohydrological model (Regional Hydro‐Ecological Simulation System [RHESSys]) to explore controls and predict streamflow DOC loads in Biscuit Brook. Biscuit Brook is a forested headwater catchment of the Neversink Reservoir, part of the New York City water supply system in the Catskill Mountains. Three different model structures of RHESSys were proposed to explore and evaluate hypotheses addressing how vegetation phenology and hydrologic connectivity between deep groundwater and riparian zones influence streamflow and DOC loads. Model results showed that incorporating dynamic phenology improved model agreement with measured streamflow in spring, summer, and fall and fall DOC concentration, compared with a static phenology. Additionally, the connectivity of deep groundwater flux through riparian zones with dynamic phenology improved streamflow and DOC flux in low flow conditions. Therefore, this study suggests the importance of inter‐annual vegetation phenology and the connectivity of deep groundwater drainage through riparian zones in the hydrology and stream DOC loading in this forested watershed and the ability of process‐based ecohydrological models to simulate these dynamics. The advantage of a process‐based modelling approach is specifically seen in the sensitivity to forest ecosystem dynamics and the interactions of hydroclimate variability with ecosystem processes controlling the supply and distribution of DOC. These models will be useful to evaluate different forest management approaches toward mitigating water quality concerns.     

Interactions and connectivity between runoff generation processes of different spatial scales

Monitoring runoff generation processes in the field is a prerequisite for developing conceptual hydrological models and theories. At the same time, our perception of hydrological processes strongly depends on the spatial and temporal scale of observation. Therefore, the aim of this study is to investigate interactions between runoff generation processes of different spatial scales (plot scale, hillslope scale, and headwater scale). Different runoff generation processes of three hillslopes with similar topography, geology and soil properties, but differences in vegetation cover (grassland, coniferous forest, and mixed forest) within a small v‐shaped headwater were measured: water table dynamics in wells with high spatial and temporal resolution, subsurface flow (SSF) of three 10 m wide trenches at the bottom of the hillslopes subdivided into two trench sections each, overland flow at the plot scale, and catchment runoff. Bachmair et al. ( 2012 ) found a high spatial variability of water table dynamics at the plot scale. In this study, we investigate the representativity of SSF observations at the plot scale versus the hillslope scale and vice versa, and the linkage between hillslope dynamics (SSF and overland flow) and streamflow. Distinct differences in total SSF within each 10 m wide trench confirm the high spatial variability of the water table dynamics. The representativity of plot scale observations for hillslope scale SSF strongly depends on whether or not wells capture spatially variable flowpaths. At the grassland hillslope, subsurface flowpaths are not captured by our relatively densely spaced wells (3 m), despite a similar trench flow response to the coniferous forest hillslope. Regarding the linkage between hillslope dynamics and catchment runoff, we found an intermediate to high correlation between streamflow and hillslope hydrological dynamics (trench flow and overland flow), which highlights the importance of hillslope processes in this small watershed. Although the total contribution of SSF to total event catchment runoff is rather small, the contribution during peak flow is moderate to substantial. Additionally, there is process synchronicity between spatially discontiguous measurement points across scales, potentially indicating subsurface flowpath connectivity. Our findings stress the need for (i) a combination of observations at different spatial scales, and (ii) a consideration of the high spatial variability of SSF at the plot and hillslope scale when designing monitoring networks and assessing hydrological connectivity. Copyright © 2013 John Wiley & Sons, Ltd.     

Seasonal changes in runoff generation in a small forested mountain catchment

This study aimed to investigate the seasonal variability of runoff generation processes, the sources of stream water, and the controls on the contribution of event water to streamflow for a small forested catchment in the Italian pre‐Alps. Hydrometric, isotopic, and electrical conductivity data collected between August 2012 and August 2013 revealed a marked seasonal variability in runoff responses. Noticeable differences in runoff coefficients and hydrological dynamics between summer and fall/spring rainfall events were related to antecedent moisture conditions and event size. Two‐component and three‐component hydrograph separation and end‐member mixing analysis showed an increase in event water contributions to streamflow with event size and average rainfall intensity. Event water fractions were larger during dry conditions in the summer, suggesting that stormflow generation in the summer consisted predominantly of direct channel precipitation and some saturated overland flow from the riparian zone. On the contrary, groundwater and hillslope soil water contributions dominated the streamflow response during wet conditions in fall. Seasonal differences were also noted between event water fractions computed based on isotopic and electrical conductivity data, likely because of the dilution effect during the wetter months. Copyright © 2014 John Wiley & Sons, Ltd.     

Influence of bedrock groundwater on streamflow characteristics in a volcanic catchment

Groundwater movements in volcanic mountains and their effects on streamflow discharge and representative elementary area (REA) have remained largely unclear. We surveyed the discharge and chemical composition of spring and stream water in two catchments: the Hontani river (NR) catchment (6.6 km²) and the Hosotani river (SR) catchment (4.0 km²) at the southern part of Daisen volcano, Japan. Daisen volcano is a young volcano (17 × 10³ years) at an early stage of erosion. Our study indicated that deep groundwater that moved through thick lava and pyroclastic flows and that could not be explained by shallow movements controlled by surface topography contributed dominantly to streamflow at larger catchment areas. At the NR catchment, the deep groundwater contribution clearly increased at a catchment boundary defined by an area of 3.0 km² and an elevation of 800 m. At the SR catchment, the contribution deep groundwater to the stream also increased suddenly at a boundary threshold of 2.0 and 700 m. Beyond these thresholds, the contributions of deep bedrock groundwater remained constant, indicating that the REA is between 2 and 3 km² at the observed area. These results indicate that the hydrological conditions of base flow were controlled mainly by the deep bedrock groundwater that moved through thick lava and pyroclastic flows in the undissected volcanic body of the upper part of the catchment. Our study demonstrates that deep and long groundwater movements via a deep bedrock layer including thick deposits of volcanic materials at the two catchments on Daisen volcano strongly determined streamflow discharge instead of the mixing of small‐scale hydrological conditions. Copyright © 2015 John Wiley & Sons, Ltd.     

Modelling storage‐driven connectivity between landscapes and riverscapes: towards a simple framework for long‐term ecohydrological assessment

The importance of conceptualizing the dynamics of storage‐driven saturation area connectivity in runoff generation has been central to the development of TOPMODEL and similar low parameterized rainfall–runoff models. In this contribution, we show how we developed a 40‐year hydrometric data base to simulate storage–discharge relationships in the Girnock catchment in the Scottish Highlands using a simple conceptual model. The catchment is a unique fisheries reference site where Atlantic salmon populations have been monitored since 1966. The modelling allowed us to track storage dynamics in hillslopes, the riparian zone and groundwater, and explicitly link non‐linear changes of streamflows to landscape storage and connectivity dynamics. This provides a fundamental basis for understanding how the landscape and riverscape are hydrologically connected and how this regulates in‐stream hydraulic conditions that directly influence salmonids. We use the model to simulate storage and discharge dynamics over the 40‐year period of fisheries records. The modelled storage‐driven connectivity provides an ecohydological context for understanding the dynamics in stream flow generation which determine habitat hydraulics for different life stages of salmon population. This new, long‐term modelling now sets this variability in the riverscape in a more fundamental context of the inter‐relationships between storage in the landscape and stream flow generation. This provides a simple, robust framework for future ecohydrological modelling at this site, which is an alternative to more increasingly popular but highly parameterized and uncertain commercial ecohydrological models. It also provides a wider, novel context that is a prerequisite for any model‐based scenario assessment of likely impacts resulting from climate or land use change. Copyright © 2016 The Authors Hydrological Processes Published by John Wiley & Sons Ltd. Copyright © 2016 The Authors Hydrological Processes Published by John Wiley & Sons Ltd.     

Effect of streamflow stochasticity on bedform-driven hyporheic exchange

The interactions between the stream and the geomorphologic units that compose the stream channel result in an exchange of water, heat, and chemicals that is an important component of the flows of energy and nutrients in the river ecosystem. This exchange is characterized by complex spatial and temporal dynamics that depend on the characteristics of the stream flow and morphology. At present, many studies have addressed the development of spatial patterns of hyporheic exchange that are induced by many geomorphological factors at different scales. However, much less is known about the temporal evolution of the surface–subsurface exchange in response to the dynamics of the stream discharge. In order to investigate this problem, the present work analyzes the influence of streamflow variability on the hyporheic exchange induced by fluvial bedforms. A stochastic approach is employed to generate streamflow series whose statistical properties are representative of streams with different hydrological regimes. The resulting exchange fluxes and travel times are then computed, and the relationships between the streamflow regime and the dynamics of the exchange flux and travel times are investigated. The results show that the mean stream discharge can be used to estimate the average features of the temporal dynamics of hyporheic exchange. Moreover, exchange fluxes and residence times distributions exhibit significant fluctuations, which are tightly related to the coefficient of variation of the streamflow hydrograph.     

Response characteristics of DOC flushing in an alpine catchment

The spatial distribution of source areas and associated residence times of water in the catchment are significant factors controlling the annual cycles of dissolved organic carbon (DOC) concentration in Deer Creek (Summit County, Colorado). During spring snowmelt (April–August 1992), stream DOC concentrations increased with the rising limb of the hydrograph, peaked before maximum discharge, then declined rapidly as melting continued. We investigated catchment sources of DOC to streamflow, measuring DOC in tension lysimeters, groundwater wells, snow and streamflow. Lysimeter data indicate that near-surface soil horizons are a primary contributor of DOC to streamflow during spring snowmelt. Concentrations of DOC in the lysimeters decrease rapidly during the melt period, supporting the hypothesis that hydrological flushing of catchment soils is the primary mechanism affecting the temporal variation of DOC in Deer Creek. Time constants of DOC flushing, characterizing the exponential decay of DOC concentration in the upper soil horizon, ranged from 10 to 30 days for the 10 lysimeter sites. Differences in the rate of flushing are influenced by topographical position, with near-stream riparian soils flushed more quickly than soils located further upslope. Variation in the amount of distribution of accumulated snow, and asynchronous melting of the snowpack across the landscape, staggered the onset of the spring flush throughout the catchment, prolonging the period of increased concentrations of DOC in the stream. Streamflow integrates the catchment-scale flushing responses, yielding a time constant associated with the recession of DOC in the stream channel (84 days) that is significantly longer than the time constants observed for particular locations in the upper soil. © 1997 John Wiley & Sons, Ltd.     

Flow dynamics at the continental scale: Streamflow correlation and hydrological similarity

Streamflow variability in space and time critically affects anthropic water uses and ecosystem services. Unfortunately, spatiotemporal patterns of flow regimes are often unknown, as discharge measurements are usually recorded at a limited number of hydrometric stations unevenly distributed along river networks. Advances in understanding the physical processes that control the spatial patterns of river flows are therefore necessary to predict water availability at ungauged locations or to extrapolate pointwise streamflow observations. This work explores the use of the spatial correlation of river flows as a metric to quantify the similarity between hydrological responses of two catchments. Following a stochastic framework, 340,000 cross‐correlations between pairs of daily streamflows time series are predicted at a seasonal timescale across the contiguous United States using 413 catchments of the MOPEX dataset. Model predictions of streamflow correlation obtained in absence of run‐off information are successfully used to identify catchment outlets sharing similar discharge dynamics and flow regimes across a broad range of geomorphoclimatic conditions, without relying on calibration. The selection of reference streamgauges based on predicted streamflow correlation generally outperforms the selection based on spatial proximity, especially as the density of available gauged sections decreases. Interestingly, correlated outlets share a broad spectrum of hydrological signatures (mean discharge, flow variability, and recession properties), suggesting that catchments forced by analogous frequency and intensity of effective rainfall events might exhibit common geomorphoecological traits leading to similar hydrological responses. The proposed framework provides a physical basis to assist the regionalization of flow dynamics and to interpret the spatial variability of flow regimes along stream networks.     

Regime-dependent streamflow sensitivities to Pacific climate modes cross the Georgia–Puget transboundary ecoregion

The Georgia Basin–Puget Sound Lowland region of British Columbia (Canada) and Washington State (USA) presents a crucial test in environmental management due to its combination of abundant salmonid habitat, rapid population growth and urbanization, and multiple national jurisdictions. It is also hydrologically complex and heterogeneous, containing at least three streamflow regimes: pluvial (rainfall-driven winter freshet), nival (melt-driven summer freshet), and hybrid (both winter and summer freshets), reflecting differing elevation ranges within various watersheds. We performed bootstrapped composite analyses of river discharge, air temperature, and precipitation data to assess El Niño–Southern Oscillation (ENSO) and Pacific Decadal Oscillation (PDO) impacts upon annual hydrometeorological cycles across the study area. Canadian and American data were employed from a total of 21 hydrometric and four meteorological stations. The surface meteorological anomalies showed strong regional coherence. In contrast, the seasonal impacts of coherent modes of Pacific circulation variability were found to be fundamentally different between streamflow regimes. Thus, ENSO and PDO effects can vary from one stream to the next within this region, albeit in a systematic way. Furthermore, watershed glacial cover appeared to complicate such relationships locally; and an additional annual streamflow regime was identified that exhibits climatically driven non-linear phase transitions. The spatial heterogeneity of seasonal flow responses to climatic variability may have substantial implications to catchment-specific management and planning of water resources and hydroelectric power generation, and it may also have ecological consequences due to the matching or phase-locking of lotic and riparian biological activity and life cycles to the seasonal cycle. The results add to a growing body of literature suggesting that assessments of the streamflow impacts of ocean–atmosphere circulation modes must accommodate local hydrological characteristics and dynamics. Copyright © 2007 John Wiley & Sons, Ltd. The copyright in Paul H. Whitfield's contribution belongs to the Crown in right of Canada and such copyright material is reproduced with the permission of Environment Canada.     

Understanding hydrological processes in glacierized catchments: Evidence and implications of highly variable isotopic and electrical conductivity data

The spatial and temporal characterization of geochemical tracers over Alpine glacierized catchments is particularly difficult, but fundamental to quantify groundwater, glacier melt, and rain water contribution to stream runoff. In this study, we analysed the spatial and temporal variability of δ²H and electrical conductivity (EC) in various water sources during three ablation seasons in an 8.4‐km² glacierized catchment in the Italian Alps, in relation to snow cover and hydro‐meteorological conditions. Variations in the daily streamflow range due to melt‐induced runoff events were controlled by maximum daily air temperature and snow covered area in the catchment. Maximum daily streamflow decreased with increasing snow cover, and a threshold relation was found between maximum daily temperature and daily streamflow range. During melt‐induced runoff events, stream water EC decreased due to the contribution of glacier melt water to stream runoff. In this catchment, EC could be used to distinguish the contribution of subglacial flow (identified as an end member, enriched in EC) from glacier melt water to stream runoff, whereas spring water in the study area could not be considered as an end member. The isotopic composition of snow, glacier ice, and melt water was not significantly correlated with the sampling point elevation, and the spatial variability was more likely affected by postdepositional processes. The high spatial and temporal variability in the tracer signature of the end members (subglacial flow, rain water, glacier melt water, and residual winter snow), together with small daily variability in stream water δ²H dynamics, are problematic for the quantification of the contribution of the identified end members to stream runoff, and call for further research, possibly integrated with other natural or artificial tracers.     

Landscape influence on small‐scale water temperature variations in a moorland catchment

We monitored temperatures in stream water, groundwater and riparian wetland surface water over 18 months in a 3.2‐km² moorland catchment in the Scottish Highlands. The stream occupies a glaciated valley, aligned east–west. It has three main headwater tributaries with a large north facing catchment, a south facing catchment and the smallest east facing headwater. The lower catchment sampling locations begin after the convalescence of all three headwaters. Much of the stream network is fringed by riparian peatlands. Stream temperatures are mainly regulated by energy exchanges at the air–water interface. However, they are also influenced by inflows from the saturated riparian zone, where surface water source areas are strongly connected with the stream network. Consequently, the spatial distribution of stream temperatures exhibits limited variability. Nevertheless, there are significant summer differences between the headwaters, despite their close proximity to each other. This is consistent with aspect (and incident radiation), given the south and east facing headwaters having higher temperatures. The largest, north‐facing sub‐catchment shows lower summer diurnal temperature variability, suggesting that lower radiation inputs dampen temperature extremes. Whilst stream water temperature regimes in the lower catchment exhibit little change along a 1‐km reach, they are similar to those in the largest headwater; probably reflecting size and comparable catchment aspect and hydrological flow paths. Our results suggest that different parts of the channel network and its connected wetlands have contrasting sensitivity to higher summer temperatures. This may be important in land management strategies designed to mitigate the impacts of projected climatic warming. Copyright © 2015 John Wiley & Sons, Ltd.     

The dynamics of natural pipe hydrological behaviour in blanket peat

Natural soil pipes are found in peatlands, but little is known about their hydrological role. This paper presents the most complete set of pipe discharge data to date from a deep blanket peatland in Northern England. In a 17.4‐ha catchment, we identified 24 perennially flowing and 60 ephemerally flowing pipe outlets. Eight pipe outlets along with the catchment outlet were continuously gauged over an 18‐month period. The pipes in the catchment were estimated to produce around 13.7% of annual streamflow, with individual pipes often producing large peak flows (maximum peak of 3.8 l s^?1). Almost all pipes, whether ephemerally or perennially flowing, shallow or deep (outlets > 1 m below the peat surface), showed increased discharge within a mean of 3 h after rainfall commencement and were dominated by stormflow, indicating good connectivity between the peatland surface and the pipes. However, almost all pipes had a longer period between the hydrograph peak and the return to base flow compared with the stream (mean of 23.9 h for pipes, 19.7 h for stream). As a result, the proportion of streamflow produced by the pipes at any given time increased at low flows and formed the most important component of stream discharge for the lowest 10% of flows. Thus, a small number of perennially flowing pipes became more important to the stream system under low‐flow conditions and probably received water via matrix flow during periods between storms. Given the importance of pipes to streamflow in blanket peatlands, further research is required into their wider role in influencing stream water chemistry, water temperature and fluvial carbon fluxes, as well as their role in altering local hydrochemical cycling within the peat mass itself. Enhanced piping within peatlands caused by environmental change may lead to changes in the streamflow regime with larger low flows and more prolonged drainage of the peat. Copyright © 2012 John Wiley & Sons, Ltd.     

Seasonal and storm flow dynamics of dissolved organic carbon in a Mediterranean mountain catchment (Vallcebre,eastern Pyrenees)

To improve understanding of DOC dynamics in seasonal Mediterranean environments, rainfall, soil water, groundwater and stream water samples were taken during a 27-month period in the Can Vila catchment (northeast Spain). Using these data, we characterized DOC dynamics in the different hydrological compartments and analysed the factors affecting them. We also analysed DOC dynamics during storm events and the factors that control DOC delivery to the stream. The results show some seasonality in rainwater and soil water DOC concentrations, while no clear seasonality was observed in stream water and groundwater, where DOC dynamics were strongly related to discharge and water table variations. For storm events with several discharge peaks, the slope of the discharge–DOC concentration relationship was higher for the first peak. The rather similar dynamics of stream water DOC concentration in all floods contrast with the observed diversity of hydrological processes. This raises the question of the origin of the observed rapid DOC increase.

EDITOR M.C. Acreman

ASSOCIATE EDITOR K. Heal     

A hydropedological approach to simulate streamflow and soil water contents with SWAT+

Reflecting internal catchment hydrological processes in hydrological models is important for accurate predictions of the impact of climate and land-use change on water resources. Characterizing these processes is however difficult and expensive due to their dynamic nature and spatio-temporal variability. Hydropedology is a relatively new discipline focusing on the synergistic integration of hydrology, soil physics and pedology. Hydropedological interpretations of soils and soil distribution can be used to characterize key hydrological processes, especially in areas with no or limited hydrometric measurements. Here we applied a hydropedological approach to reflect flowpaths through detailed routing in SWAT+ for a 157 ha catchment (Weatherley) in South Africa. We compared the hydropedological approach and a standard (no routing) approach against measured streamflow (two weirs) and soil water contents (13 locations). The catchment was treated as ‘ungauged’ and the model was not calibrated against hydrometric measurements in order to determine the direct contribution of hydropedology on modelling efficiency. Streamflow was predicted well without calibration (NSE > 0.8; R² > 0.82) for both approaches at both weirs. The standard approach yielded slightly better streamflow predictions. The hydropedological approach resulted in considerable improvements in the simulation of soil water contents (R² increased from 0.40 to 0.49 and PBIAS decreased from 40% to 20%). The routing capacity of SWAT+ as employed in the hydropedological approach reduced the underestimation of wetland water regimes drastically and resulted in a more accurate representation of the dominant hydrological processes in this catchment. We concluded that hydropedology can be a valuable source of ‘soft data’ to reflect internal catchment structure and processes and, potentially, for realistic calibrations in other studies, especially those conducted in areas with limited hydrometric measurements.     

Isotope hydrology and water sources in a heavily urbanized stream

Complex networks of both natural and engineered flow paths control the hydrology of streams in major cities through spatio-temporal variations in connection and disconnection of diverse water sources. We used spatially extensive and temporally intensive sampling of water stable isotopes to disentangle the hydrological sources of the heavily urbanized Panke catchment (~220 km²) in the north of Berlin, Germany. The isotopic data enabled us to partition stream water sources across the catchment using a Bayesian mixing analysis. The upper part of the catchment streamflow is dominated by groundwater (~75%) from gravel aquifers. In dry summer periods, streamflow becomes intermittent in the upper catchment, possibly as a result of local groundwater abstractions. Storm drainage dominates the responses to precipitation events. Although such events can dramatically change the isotopic composition of the upper stream network, storm drainage only accounts for 10%–15% of annual streamflow. Moving downstream, subtle changes in sources and isotope signatures occur as catchment characteristics vary and the stream is affected by different tributaries. However, effluents from a wastewater treatment plant (WWTP), serving 700,000 people, dominate stream flow in the lower catchment (~90% of annual runoff) where urbanization effects are more dramatic. The associated increase in sealed surfaces downstream also reduces the relative contribution of groundwater to streamflow. The volume and isotopic composition of storm runoff is again dominated by urban drainage, though in the lower catchment, still only about 10% of annual runoff comes from storm drains. The study shows the potential of stable water isotopes as inexpensive tracers in urban catchments that can provide a more integrated understanding of the complex hydrology of major cities. This offers an important evidence base for guiding the plans to develop and re-develop urban catchments to protect, restore, and enhance their ecological and amenity value.