春季中国东部气溶胶化学组成及其分布的模拟研究

本文利用区域空气质量模式RAQMS（Regional Air Quality Model System）,对2009年春季中国东部气溶胶主要化学成分及其分布进行了模拟研究。与泰山站观测资料的对比结果显示,模式能比较合理地反映气溶胶浓度的逐日变化特征。整体上,模式对无机盐气溶胶的模拟好,分别高估和低估黑碳和有机碳气溶胶浓度,其原因与排放源、二次有机气溶胶化学机制和模式分辨率的不确定性有关。模拟结果显示,春季气溶胶浓度高值主要集中于华北、四川东部、长江中下游等地区。受东南亚生物质燃烧和大气输送的影响,中国的云南和广西等地区有机碳浓度高于中国其他地区。中国西北部沙尘浓度较高,而且向东输送并影响到中国东部和南方部分地区。中国东部的华北、四川东部、长江中下游等地PM_2.5（空气动力学直径在2.5微米以下的颗粒物）污染严重,4月平均PM_2.5浓度超过了我国日平均PM_2.5浓度限值。中国东部泰山站的观测和模拟结果都显示近地面硝酸盐浓度超过硫酸盐,中国北部对流层中硝酸盐的柱含量也大于硫酸盐,而在中国南部则相反,这一方面与春季中国云量 南多北少的分布特征以及云内液相化学反应有关,另一方面也与南北温差对气溶胶形成的影响有关。就整个中国东部而言,虽然硫酸盐的柱含量（46 Gg）仍大于硝酸盐（42 Gg）,但比较接近,反映出我国氮氧化物排放迅速增加的趋势。春季中国地区对流层中PM₁₀（空气动力学直径在10微米以下的颗粒物）及其化学成分柱含量分别为:990.8 Gg（PM₁₀）,52.6 Gg（硫酸盐）,48.2 Gg（硝酸盐）,32.1 Gg（铵盐）,22.9 Gg（黑碳）和74.1 Gg（有机碳）,有机碳（OC）中一次有机碳（POC）和二次有机碳（SOC）分别占60%和40%,中国东部PM₁₀中人为气溶胶和沙尘分别占30%和70%,反映了春季沙尘对我国大气气溶胶的重要贡献。     

Present-day contribution of anthropogenic emissions from China to the global burden and radiative forcing of aerosol and ozone

The effect of anthropogenic emissions from China on global burdens of ozone, sulphate, organic carbon (OC) and black carbon (BC) aerosols is examined, using the three-dimensional chemistry transport model Oslo CTM2. Two model simulations were performed, the first with global present-day emissions and the second with the anthropogenic emissions from China set to their pre-industrial levels. The global radiative forcing for these species is then calculated. Industrial emissions from China are found to account for a 4–5% increase in the global burden of OC aerosol, the change in secondary organic aerosol being slightly less than that of primary organic aerosol. A 10% increase in the global sulphate aerosol burden is calculated, and the increase in BC is 23%. The global radiative forcing of aerosols from China was calculated to be −62, −3.7, −13 and 89 mW m⁻², for sulphate, secondary organic, primary organic and BC aerosols, respectively. The increase in ozone causes a forcing of 77 mW m⁻².     

Characteristics of Anthropogenic Sulfate and Carbonaceous Aerosols over East Asia： Regional Modeling and Observation

The authors present spatial and temporal characteristics of anthropogenic sulfate and carbonaceous aerosols over East Asia using a 3-D coupled regional climate-chemistry-aerosol model, and compare the simulation with the limited aerosol observations over the region. The aerosol module consists of SO2, SO4^2-, hydrophobic and hydrophilic black carbon （BC） and organic carbon compounds （OC）, including emission, advections, dry and wet deposition, and chemical production and conversion. The simulated patterns of SO2 are closely tied to its emission rate, with sharp gradients between the highly polluted regions and more rural areas. Chemical conversion （especially in the aqueous phase） and dry deposition remove 60% and 30% of the total SO2 emission, respectively. The SO4^2- shows less horizontal gradient and seasonality than SO2, with wet deposition （60%） and export （27%） being two major sinks. Carbonaceous aerosols are spatially smoother than sulfur species. The aging process transforms more than 80% of hydrophobic BC and OC to hydrophilic components, which are removed by wet deposition （60%） and export （30%）. The simulated spatial and seasonal SO4^2-, BC and OC aerosol concentrations and total aerosol optical depth are generally consistent with the observations in rural areas over East Asia, with lower bias in simulated OC aerosols, likely due to the underestimation of anthropogenic OC emissions and missing treatment of secondary organic carbon. The results suggest that our model is a useful tool for characterizing the anthropogenic aerosol cycle and for assessing its potential climatic and environmental effects in future studies.     

A GCM study of future climate response to aerosol pollution reductions

We use the global atmospheric GCM aerosol model ECHAM5-HAM to asses possible impacts of future air pollution mitigation strategies on climate. Air quality control strategies focus on the reduction of aerosol emissions. Here we investigate the extreme case of a maximum feasible end-of-pipe abatement of aerosols in the near term future (2030) in combination with increasing greenhouse gas (GHG) concentrations. The temperature response of increasing GHG concentrations and reduced aerosol emissions leads to a global annual mean equilibrium temperature response of 2.18 K. When aerosols are maximally abated only in the Industry and Powerplant sector, while other sectors stay with currently enforced regulations, the temperature response is 1.89 K. A maximum feasible abatement applied in the Domestic and Transport sector, while other sectors remain with the current legislation, leads to a temperature response of 1.39 K. Increasing GHG concentrations alone lead to a temperature response of 1.20 K. We also simulate 2–5% increases in global mean precipitation among all scenarios considered, and the hydrological sensitivity is found to be significantly higher for aerosols than for GHGs. Our study, thus highlights the huge potential impact of future air pollution mitigation strategies on climate and supports the need for urgent GHG emission reductions. GHG and aerosol forcings are not independent as both affect and are influenced by changes in the hydrological cycle. However, within the given range of changes in aerosol emissions and GHG concentrations considered in this study, the climate response towards increasing GHG concentrations and decreasing aerosols emissions is additive.     

耦合气溶胶气候模式FGOALS-f3-L模拟青藏高原地区气溶胶特性

基于新耦合气溶胶气候模式FGOALS-f3-L模拟分析了2002-2011年青藏高原地区气溶胶时空分布特征.结果表明:青藏高原地区,沙尘,硫酸盐,碳质气溶胶(包括黑碳,有机碳和混合碳)地表质量浓度分别占比为53.6％,32.2％,14.2％;在拉萨站点,模拟的气溶胶地表质量浓度被低估,尤其是黑碳和有机碳气溶胶;模拟的气溶胶光学厚度(AOD)时空分布与卫星观测结果较为一致,均方根误差和偏差分别为0.081和0.036;由于模式中沙尘排放参数化的不确定性,模式对AOD的模拟效果在夏季和秋季优于春季.     

Substitution of Natural Gas for Coal: Climatic Effects of Utility Sector Emissions

Substitution of natural gas for coal is one means of reducing carbon dioxide (CO₂) emissions. However, natural gas and coal use also results in emissions of other radiatively active substances including methane (CH₄), sulfur dioxide (SO₂), a sulfate aerosolprecursor, and black carbon (BC) particles. Will switching from coal to gas reduce the net impact of fossil fuel use on global climate? Using the electric utility sector as an example, changes in emissions of CO₂, CH₄,SO₂ and BC resulting from the replacement of coal by natural gas are evaluated, and their modeled net effect on global mean-annual temperature calculated. Coal-to-gas substitution initially produces higher temperatures relative to continued coal use. This warming is due to reduced SO₂ emissionsand possible increases in CH₄ emissions, and can last from 1 to 30years, depending on the sulfur controls assumed. This is followed by a net decrease in temperature relative to continued coal use, resulting from lower emissions of CO₂ and BC. The length of this period and the extent of the warming or cooling expected from coal-to-gas substitution is found to depend on key uncertainties and characteristics of the substitutions, especially those related to: (1) SO₂ emissions and consequentsulphate aerosol forcing; and (2) the relative efficiencies of the power plantsinvolved in the switch.     

Climate Responses to Direct Radiative Forcing of Anthropogenic Aerosols,Tropospheric Ozone,and Long-Lived Greenhouse Gases in Eastern China over 1951–2000

A unified chemistry-aerosol-climate model is applied in this work to compare climate responses to chang- ing concentrations of long-lived greenhouse gases(GHGs,CO2,CH4,N2O),tropospheric O3,and aerosols during the years 1951–2000.Concentrations of sulfate,nitrate,primary organic carbon(POA),secondary organic carbon(SOA),black carbon(BC)aerosols,and tropospheric O3 for the years 1950 and 2000 are obtained a priori by coupled chemistry-aerosol-GCM simulations,and then monthly concentrations are in- terpolated ...     

京津冀周边秸秆燃烧对PM2.5无机组分影响

华北平原是我国主要农作物产区,田间秸秆焚烧现象普遍存在,选取秋收季节（2014年10月）分析了秸秆燃烧的排放特征,利用区域化学传输模型WRF-Chem模拟研究了燃烧排放对气态前体物及其氧化产物的影响,以及最终导致的PM_2.5中硫酸盐、硝酸盐和铵盐的变化。研究表明:2014年秋收季节,河南和山东等省份的秸秆燃烧排放会在东南风的输送作用下影响京津冀地区;秸秆燃烧排放大量挥发性有机物（VOCs）,导致火点源及周边地区大气中主要氧化剂浓度上升,提升了区域大气氧化能力;当携带大量VOCs的秸秆燃烧烟羽与以化石燃料排放为主的城市气团相混合时,大气氧化性增强会加速城市地区人为源排放的NO_x和SO₂等气态前体物的氧化过程,提高硫酸盐和硝酸盐的形成速率、促进二次无机气溶胶的生成。     

Carbonaceous and inorganic species in PM<Subscript>10</Subscript> during wintertime over Giridih,Jharkhand (India)

Ambient concentrations of organic carbon (OC), elemental carbon (EC) and water soluble inorganic ionic components (WSIC) of PM₁₀ were studied at Giridih, Jharkhand, a sub-urban site near the Indo Gangatic Plain (IGP) of India during two consecutive winter seasons (November 2011–February 2012 and November 2012–February 2013). The abundance of carbonaceous and water soluble inorganic species of PM₁₀ was recorded at the study site of Giridih. During winter 2011–12, the average concentrations of PM₁₀, OC, EC and WSIC were 180.2?±?46.4; 37.2?±?6.2; 15.2?±?5.4 and 18.0?±?5.1 μg m^?3, respectively. Similar concentrations of PM₁₀, OC, EC and WSIC were also recorded during winter 2012–13. In the present case, a positive linear trend is observed between OC and EC at sampling site of Giridih indicates the coal burning, as well as dispersed coal powder and vehicular emissions may be the source of carbonaceous aerosols. The principal components analysis (PCA) also identifies the contribution of coal burning? +?soil dust, vehicular emissions?+?biomass burning and seconday aerosol to PM₁₀ mass concentration at the study site. Backward trajectoy and potential source contributing function (PSCF) analysis indicated that the aerosols being transported to Giridih from upwind IGP (Punjab, Haryana, Uttar Pradesh and Bihar) and surrounding region.     

Achievability of the Paris Agreement targets in the EU: demand-side reduction potentials in a carbon budget perspective

Limiting global warming to ‘well below’ 2°C above pre-industrial levels and pursuing efforts to limit the temperature increase even further to 1.5°C is an integral part of the 2015 Paris Agreement. To achieve these aims, cumulative global carbon emissions after 2016 should not exceed 940 – 390?Gt of CO₂ (for the 2°C target) and 167 – ?48?Gt of CO₂ (for the 1.5°C target) by the end of the century. This paper analyses the EU’s cumulative carbon emissions in different models and scenarios (global models, EU-focused models and national carbon mitigation scenarios). Due to the higher reductions in energy use and carbon intensity of the end-use sectors in the national scenarios, we identify an additional mitigation potential of 26–37 Gt cumulative CO₂ emissions up to 2050 compared to what is currently included in global or EU scenarios. These additional reductions could help to both reduce the need for carbon dioxide removals and bring cumulative emissions in global and EU scenarios in line with a fairness-based domestic EU budget for a 2°C target, while still remaining way above the budget for 1.5°C.

Key policy insights

• Models used for policy advice such as global integrated assessment models or EU models fail to consider certain mitigation potential available at the level of sectors.

• Global and EU models assume significant levels of CO₂ emission reductions from carbon capture and storage to reach the 1.5°C target but also to reach the 2°C target.

• Global and EU model scenarios are not compatible with a fair domestic EU share in the global carbon budget either for 2°C or for 1.5°C.

• Integrating additional sectoral mitigation potential from detailed national models can help bring down cumulative emissions in global and EU models to a level comparable to a fairness-based domestic EU share compatible with the 2°C target, but not the 1.5°C aspiration.

     

Aerosol characteristics over the Tibetan Plateau simulated with a coupled aerosol–climate model (FGOALS-f3-L) 耦合气溶胶气候模式FGOALS-f3-L模拟青藏高原地区气溶胶特性

This study presents the simulated aerosol spatiotemporal characteristics over the Tibetan Plateau (TP) with a newly developed coupled aerosol–climate model (FGOALS-f3-L). The aerosol properties are simulated over the TP for the period 2002–11. The results indicate that soil dust, sulfate, and carbonaceous aerosols (black carbon (BC), organic carbon (OC) and BC/OC) account for 53.6%, 32.2%, and 14.2% of the total aerosol mass over the TP, respectively. The simulated aerosol surface mass concentrations and aerosol optical depths (AODs) are evaluated with ground-based and satellite observations, respectively. Underestimations of the aerosol surface mass concentration are found at the Lhasa site, especially for BC and OC. The spatial distribution and interannual variation of AOD are consistent with MODIS observations, with the RMSE of 0.081 and bias of 0.036. Due to the uncertainty of the parameterization of dust emissions, the model's performance in summer and autumn is much better than that in spring.摘要基于新耦合气溶胶气候模式FGOALS-f3-L模拟分析了2002–2011年青藏高原地区气溶胶时空分布特征.结果表明:青藏高原地区, 沙尘,硫酸盐,碳质气溶胶 (包括黑碳,有机碳和混合碳) 地表质量浓度分别占比为53.6%, 32.2%, 14.2%;在拉萨站点, 模拟的气溶胶地表质量浓度被低估, 尤其是黑碳和有机碳气溶胶;模拟的气溶胶光学厚度 (AOD) 时空分布与卫星观测结果较为一致, 均方根误差和偏差分别为0.081和0.036;由于模式中沙尘排放参数化的不确定性, 模式对AOD的模拟效果在夏季和秋季优于春季     

Pollution by cereal waste burning in Spain

In this paper, the amount of cereal waste burned in Spain, which represents the most important source of biomass burning in this country, is estimated. During the period between 1980 and 1998, an average mass of 8 Tg of cereal waste was burned annually, with remaining 1 Tg of ash on the cereal fields after combustion. By using emission factors previously calculated by Ortiz de Zárate et al. [Ortiz de Zárate, I., Ezcurra, A., Lacaux, J.P., Van Dihn, P., 2000. Emission factor estimates of cereal waste burning in Spain. Atmos. Environ. 34, 3183–3193.], it is deduced that pollutant emissions linked to cereal waste-burning process reach values of 11 Tg CO₂, 80 Gg of TPM and 23 Gg of NO_x year⁻¹ during the cereal-burning period. These emissions represent 46% of total CO₂ and 23% NO_x emitted in Spain during the burning period that lasts 1 month after harvesting. Therefore, the relative importance of cereal waste burning as pollutant source in Spain almost during fire period becomes evident.Finally, our study allows to deduce that the production of 1 kg of cereal crop implies that 410 g of carbon and 3.3 g of nitrogen are going to be introduced into the atmosphere by this pollutant process. We estimate a total gaseous emission of 3.3 Tg of C and 25 Gg N as different pollutants by cereal waste burning.     

Costs and global impacts of black carbon abatement strategies

Abatement of particulate matter has traditionally been driven by health concerns rather than its role in global warming. Here we assess future abatement strategies in terms of how much they reduce the climate impact of black carbon (BC) and organic carbon (OC) from contained combustion. We develop global scenarios which take into account regional differences in climate impact, costs of abatement and ability to pay, as well as both the direct and indirect (snow-albedo) climate impact of BC and OC. To represent the climate impact, we estimate consistent region-specific values of direct and indirect global warming potential (GWP) and global temperature potential (GTP). The indirect GWP has been estimated using a physical approach and includes the effect of change in albedo from BC deposited on snow. The indirect GWP is highest in the Middle East followed by Russia, Europe and North America, while the total GWP is highest in the Middle East, Africa and South Asia. We conclude that prioritizing emission reductions in Asia represents the most cost-efficient global abatement strategy for BC because Asia is (1) responsible for a large share of total emissions, (2) has lower abatement costs compared to Europe and North America and (3) has large health cobenefits from reduced PM₁₀ emissions.     

Abatement of Greenhouse Gases: Does Location Matter?

Today's climate policy is based on the assumption that the location of emissions reductions has no impact on the overall climate effect. However, this may not be the case since reductions of greenhouse gases generally will lead to changes in emissions of short-lived gases and aerosols. Abatement measures may be primarily targeted at reducing CO₂, but may also simultaneously reduce emissions of NO_x, CO, CH₄ and SO₂ and aerosols. Emissions of these species may cause significant additional radiative forcing. We have used a global 3-D chemical transport model and a radiative transfer model to study the impact on climate in terms of radiative forcing for a realistic change in location of the emissions from large-scale sources. Based on an assumed 10% reduction in CO₂ emissions, reductions in the emissions of other species have been estimated. Climate impact for the SRES A1B scenario is compared to two reduction cases, with the main focus on a case with emission reductions between 2010 and 2030, but also a case with sustained emission reductions. The emission reductions are applied to four different regions (Europe, China, South Asia, and South America). In terms of integrated radiative forcing (over 100 yr), the total effect (including only the direct effect of aerosols) is always smaller than for CO₂ alone. Large variations between the regions are found (53–86% of the CO₂ effect). Inclusion of the indirect effects of sulphate aerosols reduces the net effect of measures towards zero. The global temperature responses, calculated with a simple energy balance model, show an initial additional warming of different magnitude between the regions followed by a more uniform reduction in the warming later. A major part of the regional differences can be attributed to differences related to aerosols, while ozone and changes in methane lifetime make relatively small contributions. Emission reductions in a different sector (e.g. transportation instead of large-scale sources) might change this conclusion since the NO_x to SO₂ ratio in the emissions is significantly higher for transportation than for large-scale sources. The total climate effect of abatement measures thus depends on (i) which gases and aerosols are affected by the measure, (ii) the lifetime of the measure implemented, (iii) time horizon over which the effects are considered, and (iv) the chemical, physical and meteorological conditions in the region. There are important policy implications of the results. Equal effects of a measure cannot be assumed if the measure is implemented in a different region and if several gases are affected. Thus, the design of emission reduction measures should be considered thoroughly before implementation.     

Aerosol characteristics during winter fog at Agra,North India

Simultaneous measurements on physical, chemical and optical properties of aerosols over a tropical semi-arid location, Agra in north India, were undertaken during December 2004. The average concentration of total suspended particulates (TSP) increased by about 1.4 times during intense foggy/hazy days. Concentrations of SO₄ ²⁻, NO₃ ⁻, NH₄ ⁺ and Black Carbon (BC) aerosols increased by 4, 2, 3.5 and 1.7 times, respectively during that period. Aerosols were acidic during intense foggy/hazy days but the fog water showed alkaline nature, mainly due to the neutralizing capacity of NH₄ aerosols. Trajectory analyses showed that air masses were predominantly from NW direction, which might be responsible for transport of BC from distant and surrounding local sources. Diurnal variation of BC on all days showed a morning and an evening peak that were related to domestic cooking and vehicular emissions, apart from boundary layer changes. OPAC (Optical properties of aerosols and clouds) model was used to compute the optical properties of aerosols. Both OPAC-derived and observed aerosol optical depth (AOD) values showed spectral variation with high loadings in the short wavelengths (<1 μm). AOD value at 0.5 μm wavelength was significantly high during intense foggy/hazy days (1.22) than during clear sky or less foggy/hazy days (0.63). OPAC-derived Single scattering albedo (SSA) was 0.84 during the observational period, indicating significant contribution of absorbing aerosols. However, the BC mass fraction to TSP increased by only 1% during intense foggy/hazy days and thereby did not show any impact on SSA during that period. A large increase was observed in the shortwave (SW) atmospheric (ATM) forcing during intense foggy/hazy days (+75.8 W/m²) than that during clear sky or less foggy/hazy days (+38 W/m²), mainly due to increase in absorbing aerosols. Whereas SW forcing at surface (SUF) increased from −40 W/m² during clear sky or less foggy/hazy days to −76 W/m² during intense foggy/hazy days, mainly due to the scattering aerosols like SO₄ ^2-.     

The danger of overvaluing methane’s influence on future climate change

Minimizing the future impacts of climate change requires reducing the greenhouse gas (GHG) load in the atmosphere. Anthropogenic emissions include many types of GHG’s as well as particulates such as black carbon and sulfate aerosols, each of which has a different effect on the atmosphere, and a different atmospheric lifetime. Several recent studies have advocated for the importance of short timescales when comparing the climate impact of different climate pollutants, placing a high relative value on short-lived pollutants, such as methane (CH₄) and black carbon (BC) versus carbon dioxide (CO₂). These studies have generated confusion over how to value changes in temperature that occur over short versus long timescales. We show the temperature changes that result from exchanging CO₂ for CH₄ using a variety of commonly suggested metrics to illustrate the trade-offs involved in potential carbon trading mechanisms that place a high value on CH₄ emissions. Reducing CH₄ emissions today would lead to a climate cooling of approximately ~0.5 °C, but this value will not change greatly if we delay reducing CH₄ emissions by years or decades. This is not true for CO₂, for which the climate is influenced by cumulative emissions. Any delay in reducing CO₂ emissions is likely to lead to higher cumulative emissions, and more warming. The exact warming resulting from this delay depends on the trajectory of future CO₂ emissions but using one business-as usual-projection we estimate an increase of 3/4 °C for every 15-year delay in CO₂ mitigation. Overvaluing the influence of CH₄ emissions on climate could easily result in our “locking” the earth into a warmer temperature trajectory, one that is temporarily masked by the short-term cooling effects of the CH₄ reductions, but then persists for many generations.     

Correlation between black carbon aerosols, carbon monoxide and tropospheric ozone over a tropical urban site

Black carbon aerosols plays an important role in the earth's radiative balance and little is known of their concentrations, distributions, source strength, and especially the aerosol chemistry of the developing world. The present study addresses the impact of back carbon aerosols on different atmospheric species like CO and tropospheric ozone over an urban environment, namely Hyderabad, India. Ozone concentration varies from 14 to 63 ppbv over the study area. Diurnal variations of ozone suggest that ozone concentration starts increasing gradually after sunrise, attaining a maximum value by evening time and decreasing gradually thereafter. Black carbon (BC) aerosol mass concentrations varies from 1471 to 11,175 ng m⁻³. The diurnal variations of BC suggest that the concentrations are increased by a factor of 2 during morning (06:00–09:00 h) and evening hours (18:00 to 22:00 h) compared to afternoon hours. Positive correlation has been observed between BC and CO (r²=0.74) with an average slope of 6.4×10⁻³ g BC/g CO. The slope between black carbon aerosol mass concentration and tropospheric ozone suggests that every 1 μg m⁻³ increase in black carbon aerosol mass concentration causes a 3.5 μg m⁻³ reduction in tropospheric ozone. The results have been discussed in detail in the paper.     

武汉市大气污染源排放清单及分布特征研究

以武汉市为研究区域,基于实地调查获得典型行业污染源活动水平,以大气污染物排放清单编制技术指南为参考,利用排放因子法建立2014年武汉市大气污染源排放清单,并结合经纬度、人口密度分布、土地利用类型、道路长度等数据将排放清单进行了3 km×3 km网格化处理.结果表明,2014年武汉市SO₂、NO_x、PM₁₀、PM_2.5、CO、BC、OC、VOCs和NH₃排放量分别为10.3、17.0、16.3、7.1、63.1、0.6、0.4、19.8和1.6万t.固定燃烧源为SO₂排放的主要来源,其贡献率约64%;移动源为NO_x的主要来源,其贡献率约51%;颗粒物排放主要来源于扬尘源和工艺过程源;CO和VOCs主要来源于工艺过程源,BC和OC排放均以移动源和生物质燃烧源为主,NH₃排放主要来自农业源.污染物排放主要集中在青山区至新洲区一带.     

不同污染条件下气溶胶对短波辐射通量影响的模拟研究

将高光谱分辨率的气溶胶光学参数化方案应用于高精度的辐射传输模式BCC_RAD（974带）中,研究不同污染状况下气溶胶在地表与近地层大气中造成的直接辐射强迫与辐射强迫效率。发现气溶胶在地表产生的直接辐射强迫为负,在近地层大气中产生的直接辐射强迫为正,且随气溶胶浓度的升高变大,说明大气气溶胶的含量越高,单位气溶胶光学厚度产生的直接辐射强迫越大。将短波划分为3个波段:紫外、可见光和近红外,发现在紫外、可见光和近红外波段中,不同污染状况下气溶胶在地表造成的直接辐射强迫范围分别为:-1.36—-13.66、-3.03—-32.41和-2.74—-28.62 W/m2,在近地层大气中产生的直接辐射强迫范围分别为0.44—4.26、0.99—9.80和0.93—8.87 W/m2。通过进一步对比自然和人为气溶胶的影响,发现人为气溶胶在地表和大气层顶产生的负直接辐射强迫以及对整层和近地面大气造成的正直接辐射强迫均大于自然气溶胶的影响,且上述两种排放源的气溶胶对整层大气辐射收支的影响主要集中在800 hPa高度以下的大气中。按照地表直接辐射强迫大小来分析不同种类气溶胶的影响,结果为硫酸盐>有机碳>黑碳>海盐>沙尘;按照近地层大气直接辐射强迫大小排序则为黑碳>有机碳>沙尘>海盐>硫酸盐。最后,通过分析散射型气溶胶与吸收型气溶胶对辐射通量的影响,还探究了大气中散射与吸收过程的异同。      

中国大陆黑碳气溶胶排放清单

The detailed high-resolution emission inventory of black carbon (BC) from China in the year 2000 was calculated. The latest fuel consumption data including fossil and biomass fuels, and socio-economic statistics used were obtained from government agencies, mostly at the county level, and some new emission factors (Efs) from local measurements were also used. National and regional summaries of emissions were presented at 0.2°×0.2°resolution. Total BC emission was 1499.4 Gg in 2000, mainly due to the burning of coal and biomass. The BC emission estimated here is higher than those in previous studies, mainly because the emissions from coal burning by rural industries and residences were previously underestimated. More BC aerosols were emitted from eastern China than western China. A strong seasonal dependence was observed for BC emissions, with peaks in January and December and low emissions in July and August; and this seasonality is mainly due to patterns in residential heating and the open burning of crop residues.