渤海湾西南岸古黄河三角洲全新世地层层序和演化过程

对渤海湾西南岸6个钻透全新统的钻孔进行了详细的沉积学研究和年代测定,利用160个粒度和94个微体古生物样品共同确定沉积相,并利用22个泥炭的常规14C年代,依据层序地层学原理划分了全新世地层层序,恢复了演化过程.渤海湾西南岸全新世黄河三角洲地层主要包括海侵层序、高海面层序和加积层序,海侵层序包括滨海沼泽、滨海砂坝和下切河谷,时代为8.5ka B.P.至全新世底界;高海面层序下段西部为滨海湖沼和积水洼地等滨海相,东部为潮成沙脊、前三角洲和潮下带等海相,时代为7.6～8.5kaB.P.;高海面层序上段西部为河间洼地、沼泽和分支河道等泛滥平原相,东部为河口砂坝、潮间带和潮成沙脊,时代为3.0～7.1ka B.P.;加积层序主要为分支河道、决口扇和河间洼地等沉积相,时代为3.0ka B.P.至今.渤海湾西南岸在9.0ka B.P.开始受海水影响,形成滨海湖沼;7.1～7.6ka B.P.达到最大海侵,位于旧城和盐山之间;海岸线于5.6ka B.P.时位于黄骅苗庄贝壳堤一带,于3.0ka B.P.时位于YS4和NP3孔之间,于2.0ka B.P.时形成现今岸线.古黄河于8.5～9.0ka B.P.时经YS3孔和NP1孔入海;于7.6～8.5ka B.P.时经YS4和NP3孔入海,于1.9～2.6kaB.P.时经YS7和NP1孔入海.5.6～7.1ka B.P.时期,研究区为当时古黄河三角洲的侧翼,形成河口砂坝,废弃之后形成潮成沙脊和苗庄贝壳堤.1.9ka B.P.至今,黄河在研究区外侧入海.     

渤海南部莱州湾晚更新世以来沉积演化特征

晚更新世以来渤海南部莱州湾发生了3次重要海侵-海退事件及沉积演化过程,渤海南部多源河流三角洲对莱州湾沉积环境改变作用明显。本文选择莱州湾剖面进行沉积地层对比,结合调查资料和测试数据,初步建立莱州湾沉积地层格架,分析晚更新世以来莱州湾沉积演化过程。研究发现,渤海南部中小河流与黄河泥沙为莱州湾沉积物的共同物质来源,二者在不同阶段分别对莱州湾沉积演化起主导作用。提出本区沉积地层具有分期性、分段性和相关性规律。在124.6~72.0 ka B.P.,60.0~24.4 ka B.P.和10.2~4.0 ka B.P.出现过3次暖湿期,分别对应沧州海侵、献县海侵和黄骅海侵,主要发育滨浅海相沉积,向南退积为三角洲/潮坪—河流沉积;由陆向海,短源河流沉积贡献降低,黄河沉积贡献增加。在72.0~60.0 ka B.P.和24.4~10.2 ka B.P.出现2次冷干期,分别对应玉木早冰期和玉木晚冰期,河流相发育,三角洲进积。受海陆交互作用影响,晚更新世以来渤海南部莱州湾大致经历了浅海相—三角洲—潮坪—浅海相—三角洲—陆相的沉积演化。     

钱塘江北岸晚第四纪沉积与古环境演变

通过钱塘江北岸第四系钻孔岩心的岩石学、年代学以及孢粉带、有孔虫化石组合的综合分析,认为HQB7孔全新世沉积始于孔深35.7 m处(年代约为10.4 ka B.P.),其下至孔深71.1 m属晚更新世沉积,并将该孔31.2 ka B.P.以来的古环境演变划分为5个发展阶段.系统阐述了各阶段的古植被、古气候与古地理特征,指出第2阶段(20.1～10.4ka B.P.)处于低海面时期,气候凉冷干燥,其早期可能对应于末次盛冰期(LGM);第4阶段(7.5～2.5 ka B.P.)为高海面时期,气候温热潮湿,相当于与全球变化相一致的全新世气候适宜期.本区晚第四纪3万年以来的气候变化特点与中国南方的深圳湾地区有很好的可比性.     

渤海西南岸6000年古海岸线重建及影响因素解析

全新世大暖期的海平面上升对全球海陆变迁产生了重大影响,重建这一时期的古海岸线对研究古海岸环境演化及预测未来海岸线变迁都具有重要意义,特别是在沿海低洼地带.本文以渤海西南沿岸为典型区域,收集具有完整测年的6ka B.P.左右的51个钻孔埋深数据,内插得到区域沉积层厚度图;再对已有文献中的钻孔高程数据重新订正,根据构造分区拟合出不同区域的相对海平面变化曲线;最后结合区域陆地现代数字高程模型(DEM),利用已有的古海岸线重建模型,构建了6ka B.P.的DEM,进一步分析全球海平面变化及构造运动作用在海岸线变迁中的影响.结果表明,全新世最大海侵时期,渤海西南岸陆地面积减少了2.08× 104km2,0m等高线深入内陆最远达约129km,在构造抬升或稳定区域,到达现在海岸6m高程附近,而快速下沉区则可达到8～10m等高线附近.沿岸相对海平面变化自菜州湾东岸向渤海湾西南岸逐渐降低,最高在现代海平面以上4m多,最低处略高于现代海平面,受构造升降作用影响明显.基于雷达剖面进一步估算,全球海平面变化在相对海平面变化的贡献量为上升1.52m,构造作用的影响为,莱州湾东岸3m,莱州湾南岸0.37m,现代黄河三角洲地区-0.36m,渤海湾西南岸-0.70m.     

青藏高原全新世1月和7月气温序列重建

青藏高原自然环境受人类干扰相对较小,为利用古孢粉记录重建气候因子提供了可能,高原过去气候因子的重建对于预测未来气候变化趋势有重要意义.通过选取的29条高原化石孢粉记录,利用现代类比法和化石孢粉点与高原气温的函数关系,把化石孢粉点古气温转化为青藏高原古气温,重建了高原全新世1月和7月古气温序列.结果表明：对于1月和7月气温而言,全新世早期（11.5～8.5 ka BP）为气温波动上升期;全新世中期（8.5～4.6 ka BP）为全新世大暖期,气温整体高于现代;全新世晚期（4.6 ka BP～至今）又可分为两个阶段,一个是4.6～2.4 ka BP,在此阶段1月和7月气温都有减小的趋势,另一个阶段则是2.4 ka BP至今,气温出现反常的趋势.     

晚冰期以来青藏高原降水序列集成重建

选取青藏高原36条(34个地点)由孢粉已重建的降水序列(8条)和化石孢粉谱(28条),分别采用直接提取和现代类比法获得1852个具有年代的定量降水数据,以高原4个分区为单位,建立青藏高原晚冰期以来古降水数据集。构建分区古降水空间模拟-多区面积加权的集成方法,即借助GIS分析,基于现代高原降水空间分布的地理因子模拟,集成重建晚冰期以来高原古降水序列。结果表明:16~12 ka B.P.,高原总体降水量较少,其中16 ka B.P.不到200 mm,约为现代降水量的一半,15~13 ka B.P.后降水显著增长,较前期上升70 mm;13~12 ka B.P.,又跌至220 mm,较现代低100 mm。进入全新世后,降水量迅速增长,降水在全新世早期的9.2~8.7 ka B.P.即达到最大值,高出现代70 mm,9.2~5.0 ka B.P.为全新世湿润期,平均高出现代50 mm;5 ka B.P.之后,降水波动较小,与现代基本持平。集成降水与其他高低分辨率环境记录有很好的可比性,说明集成序列有很好的代表性和一定的准确性。此外,高原降水变化区域差异明显,全新世最大降水呈现出西早东晚,西南季风(ISM)区早于东南季风(EASM)区的特点,高原西部和南部全新世早期9 ka B.P.左右即达极大值,而高原东缘迟至全新世中期的8.0~7.5 ka B.P.;降水增加最为明显的是高原西北部,最盛期降水约高出为现代的1倍,高原东部和南部现季风控制区域,只比现代高出0.2倍。     

渤海西南岸全新世最大海侵界线及其地貌特征

结合钻孔与探地雷达探测古海相层尖灭点的测量方法与图像处理原则,本研究在沿渤海西南岸分布的8个相关钻孔附近开展了探测,经图像处理、与钻孔对比分析以及在特征位置钻探浅钻的方式,获得了5处最大海侵尖灭点的位置、地层剖面形态以及高程等信息.结合6ka B.P.、2ka B.P.左右和现代黄河流路变迁史及沿岸贝壳堤分布情况,揭示了最大海侵时期小清河向北至漳卫新河范围主要为古黄河形成的广阔三角洲潮滩地貌,海侵线远离海岸线深入内陆,其上的贝壳堤形成主要与黄河流路变迁相关;而渤海湾西南岸黄骅、沧州附近及以北主要为沼泽-潟湖-沙坝海岸地貌特征,海侵线由潟湖的陆侧边缘向海逐渐推进,沿岸分布的6ka B.P.左右贝壳堤的形成则是基于沿岸堤,并伴随风暴作用发育而来.莱州湾南岸依据埋藏古河道古湖泊的分布情况,推断该区全新世最大海侵前后具有与现代相似的海岸地貌特征,海侵时,海水直抵当时最大高潮线附近,使得海岸线与海侵线几乎相当.依据剖面地形校正结果可知,最大海侵时,海水侵入内陆至现代地表高程5.8～ 10.3m范围,后期新构造运动造成的隆起与下沉的区域差异,使得不同区域海侵层高程发生相应的变化,该结果为进一步估算海平面变化提供重要基础.     

黄河源区距今13万年来古气候演化

综合分析黄河源区-青海玛多地区斗格涌盆地钻孔剖面的孢粉及易溶盐等气候代用指标,揭示了该区130ka B P以来的古气候演变规律。即:130.0-110.0ka B P寒冷干旱;110.0-82.0ka B P寒温较湿;82.0-10.4ka B P寒冷干旱;10.4ka B P至现代(即全新世)温湿冷干交替。全新世古气候又可划分为3期:早全新世升温期(10.4-7.5ka B P)(Anathermal);中全新世大暖期(7.5-3.5ka B P)(Megathermal);晚全新世降温期(3.5ka B P至今)(Katathermal)。本区古气候总的规律是:冷期长且比全球其它地方提前,暖期短且开始时期滞后。全新世以来气候波动具有千年尺度的振荡规律,晚全新世至今,气温有逐渐降低,湿度逐渐变干的趋势。      

渤海湾西岸BT113孔35ka以来的沉积环境演化与海陆作用

根据渤海湾西岸有孔虫和介形虫与年代学(AMS14C和OSL测年)研究,将该段岩心自下而上划分为6个沉积单元(U1—U6),它们依次形成于晚更新世的河流及全新世的潮滩、浅海、前三角洲、三角洲前缘和三角洲平原沉积环境,结束于约35 ka的U1单元的陆相环境,证实晚更新世低海面时渤海湾西岸未受海水影响。U1和U2单元之间,存在历时约27 ka的沉积间断(35～8.5 ka cal BP),研究区因此缺失早全新世沉积。U2单元的潮滩环境指示全新世海侵于8.5 ka cal BP到达渤海湾西岸,当时相对海平面为-16.7 m。U3单元为浅海环境,约6 ka cal BP时相对海平面上升到-6.8～-1.8 m。8.5～6 ka cal BP期间的海面上升速率是0.4～0.6 cm/a,可能与MWP1C事件有关。U4—U5单元,转为三角洲环境,沉积速率增大,反映自3.7 ka cal BP河流输入影响加强,约1.3 ka cal BP时成陆,形成U6单元。晚更新世35 ka以来的陆海环境演化,总体上是对气候变化控制下的海面变化的响应。     

渤海湾西岸全新世海面变化

在讨论海面标志点基本定义的基础上,从渤海湾西岸534个原始数据中获得了136个指示高水位、潮间带或低水位的海面变化标志点,并重建了它们的相对海平面时空分布,进而获得了渤海湾西岸全新世相对海平面变化带.约10cal.ka B.P.时,相对海平面变化带达到-25m,以约6m/1000a(即约6mm/a)的平均速率上升,在6cal.ka B.P.前后达到现代海面的高度;6cal.ka B.P.至今,变化带的高度介于+1m～-2m之间,未发现中全新世相对高海面.再搬运海相贝类和陆相泥炭类样品的14C年龄,分别存在约600年和660年的驻留时间.经过驻留时间校正的新海面变化年代学序列,将渤海湾相对海平面达到现代高度的时间点确定为约6cal.ka B.P.,从而与全球海面变化的对比更为准确.渤海湾盆地的长期稳定下沉和沉积自重压实的共同作用,可能抵消了冰川均衡调整(GIA)引起的中全新世数米高的相对高海面.     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.