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中国西南典型地区酸雨形成过程研究 总被引:20,自引:1,他引:20
本文根据云水和雨水化学特性的观测和雨水酸化模式的模拟计算,研究了中国西南地区酸雨的形成过程。结果表明:在重庆和贵阳等重污染城市,云下过程对雨水的酸化起主要作用,在污染较轻的中小城镇和乡村地区,雨水酸度主要决定于云内过程。 但是云下过程对雨水中的主要酸碱离子浓度都有不可忽视的明显影响。雨水的酸化主要是由于SO2与H2O2和O3的氧化,气溶胶起较弱的缓冲碱化作用。在重庆和贵阳等地,当地SO2浓度已高达饱和,其值增减50%,都不会对该地雨水酸度有明显影响,起控制作用的是氧化剂浓度。 相似文献
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一次冰雹天气过程的云系发展演变及云物理特征研究 总被引:5,自引:1,他引:4
利用中尺度数值模式WRF(Weather Research and Forecasting)的数值模拟,结合NECP/FNL再分析资料、地面、探空、多普勒雷达基数据和卫星产品等观测资料,综合分析了2014年3月30日发生在贵州省西南部的一次冰雹天气过程。研究了有利于冰雹发生的环流特征和环境条件,分析了冰雹云系的发展演变特征、云微物理结构特征,初步分析了冰雹形成的云物理机制。结果表明:此次冰雹天气是典型的低压辐合线型降雹类型,地面降雹位置位于700 hPa切变线和近地面辐合线附近及南侧;发生此次冰雹过程的对流云系经历了对流云系的初生阶段、合并加强阶段、成熟降雹阶段和东移阶段。贵州地区上空对流云系的微物理结构具有混合相云特征,高层为冰晶、雪,中层为云水、霰,低层为雨水、冰雹。霰和云水是形成雨水和冰雹的主要来源,霰撞冻过冷云水和霰的自动转化是冰雹形成的主要微物理机制。 相似文献
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In this study, the results of four different field experiments concerning the speciation of iron and the concentrations of some other chemical compounds in cloudwater samples are compared to one-another. Hydrogen peroxide concentrations were higher during campaigns, conducted at sites not much influenced by anthropogenic emissions as compared to those conducted at more polluted areas. In contrast, percentages of S(IV) in the cloudwater were lowest at the rural sites and highest at the sites polluted by human activities, indicating a consumption of hydrogen peroxide in the oxidation reaction with S(IV). The concentration of dissolved iron was observed to correlate with the percentage of S(IV), which may be an essential point for the reductive dissolution of oxidic iron compounds of the aerosol particles. As far as the speciation of the dissolved iron is concerned, it became obvious that the percentage of Fe(III) is anticorrelated to the concentration of dissolved iron. This clearly shows the important effect of the chemical and/or photo reductive ways of dissolving the iron(III)-compounds from the aerosol particles. However, a correlation between the pH-value and hydrogen peroxide was observed. 相似文献
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1 INTRODUCTION Sitting in the central part of the Pearl River Delta, Guangzhou is one of the cities in China that are most polluted by acid rain. Broad attention has been brought to the problem. Since the early 1980s, a series of observation and studies h… 相似文献
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广州白云山风景区酸雨梯度分布 总被引:11,自引:4,他引:7
对1999年白云山风景区1~10月的降水pH 值、化学成分以及1月、6月大气低层的气溶胶进行了监测.分析结果表明(1)白云山3个测点降水的平均pH值最低为4.83,最高为5.29;酸雨频率最低58 %,最高91 %;强酸雨频率最低19 %,最高39 %.降水酸度和酸雨频率呈梯度变化,pH值随高度增高而减小,酸雨和强酸雨频率增加.(2)冬季近地层大气中偏碱性气溶胶在白云山的组成比较稳定,山上和山下测点气溶胶水溶性离子成分基本一致;而夏季山上、山下的成分有所不同,山上的SO42-比例明显增大.另外,尽管气溶胶中NO3-的含量极少,但降水中NO3-有明显的富集现象.(3)白云山降水离子成分中SO42-占阴离子的比例最大、NO3-次之;Ca2+占阳离子的比例最大、NH4+稍低.随高度上升SO42-和Ca2+在降水中的比例有所下降,而NO3-和NH4+比例明显增加,NO3-和NH4+对山上降水酸度的影响是相对增大的.(4)受附近公路交通的直接影响,白云山降水中的NO3-比例较大,NO3-/SO42-当量浓度比值平均达到0.4;NO3-对白云山降水酸度有较大的贡献,而且这一贡献随高度而增大. 相似文献
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G. P. Ayers N. Fukuzaki R. W. Gillett P. W. Selleck J. C. Powell H. Hara 《Journal of Atmospheric Chemistry》1998,30(2):301-310
Rainwater samples (wet-only; event samples) collected in Niigata in late autumn 1996 and springtime 1997 were used to assess the effectiveness of thymol as a biocide in Japanese rainwater. Upon collection each rainwater sample was divided into sub-samples, with thymol added to one sub-sample. Sub-samples with and without thymol were shipped to CSIRO, Australia, for chemical analysis. Comparison of analytical results for each pair of sub-samples proved the effectiveness of thymol in preventing biological action in this region where effects of rainwater microflaura and fauna on rainwater composition have not before been studied. Sub-samples without thymol exhibited lowered electrical conductivity, loss of the cations H+ and NH
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, and loss of the anions HCOO-, CH3COO-, C2O
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, CH3SO
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and PO
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. Nitrate showed no change in all but one of the samples, indicating that ammonia was the preferred source of nitrogen for the biological processes that consumed the rainwater organic acids and phosphate. These results suggest that thymol is a suitable rainwater biocide for use under Japanese conditions. 相似文献
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R. Cini F. Prodi G. Santachiara F. Porc S. Bellandi A. M. Stortini C. Oppo R. Udisti F. Pantani 《Atmospheric Research》2002,61(4):455
Cloudwater samples were collected from November 1992 to March 1995 in Vallombrosa, a mountain site of the Tuscan Apennines (central Italy). Chemical analyses show that all examined inorganic ions contributed significantly to the total ionic content (TIC). The ratio SO42−/NO4− ranged from 0.92 to 3.46 and was >1 for 86% of samples. There is a wide range in the chemical composition of the cloudwater. The total ionic content ranged from 640 to 7476 μeq l−1 and pH from 3.17 to 6.22. The liquid water content (LWC) ranged from 0.06 to 0.94 g m−3 and electrical conductivity from 47 to 485 μΩ−1. The total ionic content decreases while the liquid water content increases. Also analyzed were soluble trace metals (Fe, Pb, Cu, Mn, Cd, Al), synthetic anionic surfactants and the methanesulphonic acid. Chemical analyses evidenced in some cases a high concentration of organic matter. The meteorological analysis for a few samples of individual passages was carried out for the possibility of establishing a correspondence between meteorological events and chemical composition. The sources (marine, crustal and anthropogenic) of chemical components were deduced. 相似文献