Alkali and Chlorine Photochemistry in a Volcanically Driven Atmosphere on Io

Observations of the Io plasma torus and neutral clouds indicate that the extended ionian atmosphere must contain sodium, potassium, and chlorine in atomic and/or molecular form. Models that consider sublimation of pure sulfur dioxide frost as the sole mechanism for generating an atmosphere on Io cannot explain the presence of alkali and halogen species in the atmosphere—active volcanoes or surface sputtering must also be considered, or the alkali and halide species must be discharged along with the SO₂ as the frost sublimates. To determine how volcanic outgassing can affect the chemistry of Io's atmosphere, we have developed a one-dimensional photochemical model in which active volcanoes release a rich suite of S-, O-, Na-, K-, and Cl-bearing vapor and in which photolysis, chemical reactions, condensation, and vertical eddy and molecular diffusion affect the subsequent evolution of the volcanic gases. Observations of Pele plume constituents, along with thermochemical equilibrium calculations of the composition of volcanic gases exsolved from high-temperature silicate magmas on Io, are used to constrain the composition of the volcanic vapor. We find that NaCl, Na, Cl, KCl, and K will be the dominant alkali and chlorine gases in atmospheres generated from Pele-like plume eruptions on Io. Although the relative abundances of these species will depend on uncertain model parameters and initial conditions, these five species remain dominant for a wide variety of realistic conditions. Other sodium and chlorine molecules such as NaS, NaO, Na₂, NaS₂, NaO₂, NaOS, NaSO₂, SCl, ClO, Cl₂, S₂Cl, and SO₂Cl₂ will be only minor constituents in the ionian atmosphere because of their low volcanic emission rates and their efficient photochemical destruction mechanisms. Our modeling has implications for the general appearance, properties, and variability of the neutral sodium clouds and jets observed near Io. The neutral NaCl molecules present at high altitudes in atmosph eres generated by active volcanoes might provide the NaX⁺ ion needed to help explain the morphology of the high-velocity sodium “stream” feature observed near Io.     

Lava lakes on Io: observations of Io's volcanic activity from Galileo NIMS during the 2001 fly-bys

Galileo's Near-Infrared Mapping Spectrometer (NIMS) obtained its final observations of Io during the spacecraft's fly-bys in August (I31) and October 2001 (I32). We present a summary of the observations and results from these last two fly-bys, focusing on the distribution of thermal emission from Io's many volcanic regions that give insights into the eruption styles of individual hot spots. We include a compilation of hot spot data obtained from Galileo, Voyager, and ground-based observations. At least 152 active volcanic centers are now known on Io, 104 of which were discovered or confirmed by Galileo observations, including 23 from the I31 and I32 Io fly-by observations presented here. We modify the classification scheme of Keszthelyi et al. (2001, J. Geophys. Res. 106 (E12) 33 025-33 052) of Io eruption styles to include three primary types: promethean (lava flow fields emplaced as compound pahoehoe flows with small plumes <200 km high originating from flow fronts), pillanian (violent eruptions generally accompanied by large outbursts, >200 km high plumes and rapidly-emplaced flow fields), and a new style we call “lokian” that includes all eruptions confined within paterae with or without associated plume eruptions). Thermal maps of active paterae from NIMS data reveal hot edges that are characteristic of lava lakes. Comparisons with terrestrial analogs show that Io's lava lakes have thermal properties consistent with relatively inactive lava lakes. The majority of activity on Io, based on locations and longevity of hot spots, appears to be of this third type. This finding has implications for how Io is being resurfaced as our results imply that eruptions of lava are predominantly confined within paterae, thus making it unlikely that resurfacing is done primarily by extensive lava flows. Our conclusion is consistent with the findings of Geissler et al. (2004, Icarus, this issue) that plume eruptions and deposits, rather than the eruption of copious amounts of effusive lavas, are responsible for Io's high resurfacing rates. The origin and longevity of islands within ionian lava lakes remains enigmatic.     

Galileo observations of volcanic plumes on Io

Io's volcanic plumes erupt in a dazzling variety of sizes, shapes, colors and opacities. In general, the plumes fall into two classes, representing distinct source gas temperatures. Most of the Galileo imaging observations were of the smaller, more numerous Prometheus-type plumes that are produced when hot flows of silicate lava impinge on volatile surface ices of SO₂. Few detections were made of the giant, Pele-type plumes that vent high temperature, sulfur-rich gases from the interior of Io; this was partly because of the insensitivity of Galileo's camera to ultraviolet wavelengths. Both gas and dust spout from plumes of each class. Favorably located gas plumes were detected during eclipse, when Io was in Jupiter's shadow. Dense dust columns were imaged in daylight above several Prometheus-type eruptions, reaching heights typically less than 100 km. Comparisons between eclipse observations, sunlit images, and the record of surface changes show that these optically thick dust columns are much smaller in stature than the corresponding gas plumes but are adequate to produce the observed surface deposits. Mie scattering calculations suggest that these conspicuous dust plumes are made up of coarse grained “ash” particles with radii on the order of 100 nm, and total masses on the order of 10⁶ kg per plume. Long exposure images of Thor in sunlight show a faint outer envelope apparently populated by particles small enough to be carried along with the gas flow, perhaps formed by condensation of sulfurous “snowflakes” as suggested by the plasma instrumentation aboard Galileo as it flew through Thor's plume [Frank, L.A., Paterson, W.R., 2002. J. Geophys. Res. (Space Phys.) 107, doi:10.1029/2002JA009240. 31-1]. If so, the total mass of these fine, nearly invisible particles may be comparable to the mass of the gas, and could account for much of Io's rapid resurfacing.     

Evolution of Io's volatile inventory

Using Voyager results, we have made crude estimates of the rate at which Io loses volatiles by a variety of processes to the surrounding magnetosphere for both the current SO₂-dominated atmosphere as well as hypothetical paleoatmospheres in which other gases, such as N₂, may have been the dominant constituent. Loss rates are strongly influenced by the surface pressure on the night side, the relationship between the exobase and the Jovian magnetospheric boundary, the exospheric temperature, and the peak altitudes reached by volcanic plumes. Several mechanisms make significant contributions to the prodigious rate at which Io is currently losing volatiles. These include: interaction of the magnetospheric plasma with volcanic plume particles and the background atmosphere; sputtering of ices on the surface, if the nightside atmospheric pressure is low enough; and Jeans' escape of O, a dissociation product of SO₂ gas. For paleoatmospheres, only the first two of these mechanisms would have been effective. However, they are capable of eliminating large amounts of N₂ and other volatiles from Io over the satellite's lifetime. Io could have also lost large amounts of water over its lifetime due to the extensive recycling of water between its upper and lower crust, with the partial dissociation of water vapor in silicate magma chambers initiating this loss process. Significant amounts of water may also have been lost as a result of the interaction of the magnetospheric plasma with water ice particles in volcanic plumes. Once an SO₂-dominated atmosphere becomes established, much water may have also been lost through the sputtering of surface water ice.     

Shield volcano topography and the rheology of lava flows on Io

Stereo and photoclinometry derived topography of shield-like volcanoes on Io indicate little relief (<3 km) and very low slopes (0.2° to 0.6°). Several shield volcanoes appear to be associated with broad rises of 1 to 3 km, but only 5 shield volcanoes have been identified with steep flank slopes (between 4° and 10°). These steep slopes are restricted to within 20-30 km of the summit, but where discernable, most of the lava flows observed on these edifices occur on the outer flanks where slopes are less than a degree. Despite their abundance, ionian shield volcanoes are among the flattest in the Solar System. The steepest volcanoes on Io are most comparable to large venusian shield volcanoes. Using simplistic Bingham rheologies we estimate the viscosity and yield strengths of ionian lavas. Yield strengths are estimated at 10¹-10² Pa, lower than most basaltic lavas. Viscosity estimates range from 10³ to 10⁵ Pa s, although these are probably upper limits. Actual values may have been as low as 10⁰ Pa s. Viscosity is sensitive to flow velocity, which is poorly known on Io. The best constraint on flow velocity comes from observations of the 1997 Pillan eruption, which bracket the eruptive phase to 132 day maximum, and more probably less than 50 days. Low slopes, long run-out distances and our estimated rheologic properties are consistent with (but not proof of) a low silica, low viscosity, high temperature composition for ionian lavas, supporting arguments for low-silica lava compositions such as basalt or komatiite. We cannot eliminate sulfur on rheologic grounds, however.     

High-Resolution Keck Adaptive Optics Imaging of Violent Volcanic Activity on Io

Io, the innermost Galilean satellite of Jupiter, is a fascinating world. Data taken by Voyager and Galileo instruments have established that it is by far the most volcanic body in the Solar System and suggest that the nature of this volcanism could radically differ from volcanism on Earth. We report on near-IR observations taken in February 2001 from the Earth-based 10-m W. M. Keck II telescope using its adaptive optics system. After application of an appropriate deconvolution technique (MISTRAL), the resolution, ∼100 km on Io's disk, compares well with the best Galileo/NIMS resolution for global imaging and allows us for the first time to investigate the very nature of individual eruptions. On 19 February, we detected two volcanoes, Amirani and Tvashtar, with temperatures differing from the Galileo observations. On 20 February, we noticed a slight brightening near the Surt volcano. Two days later it had turned into an extremely bright volcanic outburst. The hot spot temperatures (>1400 K) are consistent with a basaltic eruption and, being lower limits, do not exclude an ultramafic eruption. These outburst data have been fitted with a silicate-cooling model, which indicates that this is a highly vigorous eruption with a highly dynamic emplacement mechanism, akin to fire-fountaining. Its integrated thermal output was close to the total estimated output of Io, making this the largest ionian thermal outburst yet witnessed.     

Geologic mapping of the Amirani-Gish Bar region of Io: Implications for the global geologic mapping of Io

We produced the first geologic map of the Amirani-Gish Bar region of Io, the last of four regional maps generated from Galileo mission data. The Amirani-Gish Bar region has five primary types of geologic materials: plains, mountains, patera floors, flows, and diffuse deposits. The flows and patera floors are thought to be compositionally similar, but are subdivided based on interpretations regarding their emplacement environments and mechanisms. Our mapping shows that volcanic activity in the Amirani-Gish Bar region is dominated by the Amirani Eruptive Center (AEC), now recognized to be part of an extensive, combined Amirani-Maui flow field. A mappable flow connects Amirani and Maui, suggesting that Maui is fed from Amirani, such that the post-Voyager designation “Maui Eruptive Center” should be revised. Amirani contains at least four hot spots detected by Galileo, and is the source of widespread bright (sulfur?) flows and active dark (silicate?) flows being emplaced in the Promethean style (slowly emplaced, compound flow fields). The floor of Gish Bar Patera has been partially resurfaced by dark lava flows, although other parts of its floor are bright and appeared unchanged during the Galileo mission. This suggests that the floor did not undergo complete resurfacing as a lava lake as proposed for other ionian paterae. There are several other hot spots in the region that are the sources of both active dark flows (confined within paterae), and SO₂- and S₂-rich diffuse deposits. Mapped diffuse deposits around fractures on mountains and in the plains appear to serve as the source for gas venting without the release of magma, an association previously unrecognized in this region. The six mountains mapped in this region exhibit various states of degradation. In addition to gaining insight into this region of Io, all four maps are studied to assess the best methodology to use to produce a new global geologic map of Io based on the newly released, combined Galileo-Voyager global mosaics. To convey the complexity of ionian surface geology, we find that a new global geologic map of Io should include a map sheet displaying the global abundances and types of surface features as well as a complementary GIS database as a means to catalog the record of surface changes observed since the Voyager flybys and during the Galileo mission.     

Silicon tetrafluoride on Io

Silicon tetrafluoride (SiF₄) is observed in terrestrial volcanic gases and is predicted to be the major F-bearing species in low-temperature volcanic gases on Io [Schaefer, L., Fegley Jr., B., 2005b. Alkali and halogen chemistry in volcanic gases on Io. Icarus 173, 454-468]. SiF₄ gas is also a potential indicator of silica-rich crust on Io. We used F/S ratios in terrestrial and extraterrestrial basalts, and gas/lava enrichment factors for F and S measured at terrestrial volcanoes to calculate equilibrium SiF₄/SO₂ ratios in volcanic gases on Io. We conclude that SiF₄ can be produced at levels comparable to the observed NaCl/SO₂ gas ratio. We also considered potential loss processes for SiF₄ in volcanic plumes and in Io's atmosphere including ion-molecule reactions, electron chemistry, photochemistry, reactions with the major atmospheric constituents, and condensation. Photochemical destruction (t_chem ∼266 days) and/or condensation as Na₂SiF₆ (s) appear to be the major sinks for SiF₄. We recommend searching for SiF₄ with infrared spectroscopy using its 9.7 μm band as done on Earth.     

The final Galileo SSI observations of Io: orbits G28-I33

We present the observations of Io acquired by the Solid State Imaging (SSI) experiment during the Galileo Millennium Mission (GMM) and the strategy we used to plan the exploration of Io. Despite Galileo's tight restrictions on data volume and downlink capability and several spacecraft and camera anomalies due to the intense radiation close to Jupiter, there were many successful SSI observations during GMM. Four giant, high-latitude plumes, including the largest plume ever observed on Io, were documented over a period of eight months; only faint evidence of such plumes had been seen since the Voyager 2 encounter, despite monitoring by Galileo during the previous five years. Moreover, the source of one of the plumes was Tvashtar Catena, demonstrating that a single site can exhibit remarkably diverse eruption styles—from a curtain of lava fountains, to extensive surface flows, and finally a ∼400 km high plume—over a relatively short period of time (∼13 months between orbits I25 and G29). Despite this substantial activity, no evidence of any truly new volcanic center was seen during the six years of Galileo observations. The recent observations also revealed details of mass wasting processes acting on Io. Slumping and landsliding dominate and occur in close proximity to each other, demonstrating spatial variation in material properties over distances of several kilometers. However, despite the ubiquitous evidence for mass wasting, the rate of volcanic resurfacing seems to dominate; the floors of paterae in proximity to mountains are generally free of debris. Finally, the highest resolution observations obtained during Galileo's final encounters with Io provided further evidence for a wide diversity of surface processes at work on Io.     

X-ray probes of magnetospheric interactions with Jupiter's auroral zones, the Galilean satellites, and the Io plasma torus

Remote observations with the Chandra X-ray Observatory and the XMM-Newton Observatory have shown that the jovian system is a source of X-rays with a rich and complicated structure. The planet's polar auroral zones and its disk are both powerful sources of X-ray emission. Chandra observations revealed X-ray emission from the Io plasma torus and from the Galilean moons Io, Europa, and possibly Ganymede. The emission from the moons is due to bombardment of their surfaces by highly energetic magnetospheric protons, and oxygen and sulfur ions. These ions excite atoms in their surfaces leading to fluorescent X-ray emission lines. These lines are produced against an intense background continuum, including bremsstrahlung radiation from surface interactions of primary magnetospheric and secondary electrons. Although the X-ray emission from the Galilean moons is faint when observed from Earth orbit, an imaging X-ray spectrometer in orbit around one or more of these moons, operating from 200 eV to 8 keV with 150 eV energy resolution, would provide a detailed mapping of the elemental composition in their surfaces. Surface resolution of 40 m for small features could be achieved in a 100-km orbit around one moon while also remotely imaging surfaces of other moons and Jupiter's upper atmosphere at maximum regional resolutions of hundreds of kilometers. Due to its relatively more benign magnetospheric radiation environment, its intrinsic interest as the largest moon in the Solar System, and its mini-magnetosphere, Ganymede would be the ideal orbital location for long-term observational studies of the jovian system. Here we describe the physical processes leading to X-ray emission from the surfaces of Jupiter's moons and the properties required for the technique of imaging X-ray spectroscopy to map the elemental composition of their surfaces, as well as studies of the X-ray emission from the planet's aurora and disk and from the Io plasma torus.     

Photochemistry of a Volcanically Driven Atmosphere on Io: Sulfur and Oxygen Species from a Pele-Type Eruption

To determine how active volcanism might affect the standard picture of sulfur dioxide photochemistry on Io, we have developed a one-dimensional atmospheric model in which a variety of sulfur-, oxygen-, sodium-, potassium-, and chlorine-bearing volatiles are volcanically outgassed at Io's surface and then evolve due to photolysis, chemical kinetics, and diffusion. Thermochemical equilibrium calculations in combination with recent observations of gases in the Pele plume are used to help constrain the composition and physical properties of the exsolved volcanic vapors. Both thermochemical equilibrium calculations (Zolotov and Fegley 1999, Icarus141, 40-52) and the Pele plume observations of Spencer et al. (2000; Science288, 1208-1210) suggest that S₂ may be a common gas emitted in volcanic eruptions on Io. If so, our photochemical models indicate that the composition of Io's atmosphere could differ significantly from the case of an atmosphere in equilibrium with SO₂ frost. The major differences as they relate to oxygen and sulfur species are an increased abundance of S, S₂, S₃, S₄, SO, and S₂O and a decreased abundance of O and O₂ in the Pele-type volcanic models as compared with frost sublimation models. The high observed SO/SO₂ ratio on Io might reflect the importance of a contribution from volcanic SO rather than indicate low eddy diffusion coefficients in Io's atmosphere or low SO “sticking” probabilities at Io's surface; in that case, the SO/SO₂ ratio could be temporally and/or spatially variable as volcanic activity fluctuates. Many of the interesting volcanic species (e.g., S₂, S₃, S₄, and S₂O) are short lived and will be rapidly destroyed once the volcanic plumes shut off; condensation of these species near the source vent is also likely. The diffuse red deposits associated with active volcanic centers on Io may be caused by S₄ radicals that are created and temporarily preserved when sulfur vapor (predominantly S₂) condenses around the volcanic vent. Condensation of SO across the surface and, in particular, in the polar regions might also affect the surface spectral properties. We predict that the S/O ratio in the torus and neutral clouds might be correlated with volcanic activity—during periods when volcanic outgassing of S₂ (or other molecular sulfur vapors) is prevalent, we would expect the escape of sulfur to be enhanced relative to that of oxygen, and the S/O ratio in the torus and neutral clouds could be correspondingly increased.     

Numerical modeling of ionian volcanic plumes with entrained particulates

Volcanic plumes on Jupiter's moon Io are modeled using the direct simulation Monte Carlo (DSMC) method. The modeled volcanic vent is interpreted as a “virtual” vent. A parametric study of the “virtual” vent gas temperature and velocity is performed to constrain the gas properties at the vent by observables, particularly the plume height and the surrounding condensate deposition ring radius. Also, the flow of refractory nano-size particulates entrained in the gas is modeled with “overlay” techniques which assume that the background gas flow is not altered by the particulates. The column density along the tangential line-of-sight and the shadow cast by the plume are calculated and compared with Voyager and Galileo images. The parametric study indicates that it is possible to obtain a unique solution for the vent temperature and velocity for a large plume like Pele. However, for a small Prometheus-type plume, several different possible combinations of vent temperature and velocity result in both the same shock height and peak deposition ring radius. Pele and Prometheus plume particulates are examined in detail. Encouraging matches with observations are obtained for each plume by varying both the gas and particle parameters. The calculated tangential gas column density of Pele agrees with that obtained from HST observations. An upper limit on the size of particles that track the gas flow well is found to be ∼10 nm, consistent with Voyager observations of Loki. While it is certainly possible for the plumes to contain refractory dust or pyroclastic particles, especially in the vent vicinity, we find that the conditions are favorable for SO₂ condensation into particles away from the vent vicinity for Prometheus. The shadow cast by Prometheus as seen in Galileo images is also reproduced by our simulation. A time averaged frost deposition profile is calculated for Prometheus in an effort to explain the multiple ring structure observed around the source region. However, this multiple ring structure may be better explained by the calculated deposition of entrained particles. The possibility of forming a dust cloud on Io is examined and, based on a lack of any such observed clouds, a subsolar frost temperature of less than 118 K is suggested.     

Io: Heat flow from dark volcanic fields

Dark flow fields on the jovian satellite Io are evidence of current or recent volcanic activity. We have examined the darkest volcanic fields and quantified their thermal emission in order to assess their contribution to Io’s total heat flow. Loki Patera, the largest single source of heat flow on Io, is a convenient point of reference. We find that dark volcanic fields are more common in the hemisphere opposite Loki Patera and this large scale concentration is manifested as a maximum in the longitudinal distribution (near ∼200 °W), consistent with USGS global geologic mapping results. In spite of their relatively cool temperatures, dark volcanic fields contribute almost as much to Io’s heat flow as Loki Patera itself because of their larger areal extent. As a group, dark volcanic fields provide an asymmetric component of ∼5% of Io’s global heat flow or ∼5 × 10¹² W.     

Surface changes on Io during the Galileo mission

A careful survey of Galileo SSI global monitoring images revealed more than 80 apparent surface changes that took place on Io during the 5 year period of observation, ranging from giant plume deposits to subtle changes in the color or albedo of patera surfaces. Explosive volcanic activity was discovered at four previously unrecognized centers: an unnamed patera to the south of Karei that produced a Pele-sized red ring, a patera to the west of Zal that produced a small circular bright deposit, a large orange ring detected near the north pole of Io, and a small bright ring near Io's south pole. Only a handful of Io's many active volcanoes produced large scale explosive eruptions, and several of these erupted repeatedly, leaving at least 83% of Io's surface unaltered throughout the Galileo mission. Most of the hot spots detected from SSI, NIMS and ground-based thermal observations caused no noticeable surface changes greater than 10 km in extent over the five year period. Surface changes were found at every location where active plumes were identified, including Acala which was never seen in sunlight and was only detected through auroral emissions during eclipse. Two types of plumes are distinguished on the basis of the size and color of their deposits, confirming post-Voyager suggestions by McEwen and Soderblom [Icarus 55 (1983) 191]. Smaller plumes produce near-circular rings typically 150-200 km in radius that are white or yellow in color unless contaminated with silicates, and frequently coat their surroundings with frosts of fine-grained SO₂. The larger plumes are much less numerous, limited to a half dozen examples, and produce oval, orange or red, sulfur-rich rings with maximum radii in the north-south direction that are typically in the range from 500 to 550 km. Both types of plumes can be either episodic or quasi-continuous over a five year period. Repeated eruptions of the smaller SO₂-rich plumes likely contribute significantly to Io's resurfacing rate, whereas dust ejection is likely dominated by the tenuous giant plumes. Both types of plume deposits fade on time-scales of months to years through burial and alteration. Episodic seepages of SO₂ at Haemus Montes, Zal Montes, Dorian Montes, and the plateau to the north of Pillan Patera may have been triggered by activity at nearby volcanic centers.     

The variability of volcanic activity at Zamama, Culann, and Tupan Patera on Io as seen by the Galileo Near Infrared Mapping Spectrometer

Zamama, Culann, and Tupan Patera are three large, persistent volcanic centers on the jovian moon Io. As part of an ongoing project to quantify contributions from individual volcanic centers to Io’s thermal budget, we have quantified the radiant flux from all suitable observations made by the Galileo Near Infrared Mapping Spectrometer (NIMS) of these volcanoes, in some cases filling omissions in previous analyses. At Zamama, after a long period of cooling, we see a peak in thermal emission that corresponds with new plume activity. Subsequently, toward the end of the Galileo epoch, thermal emission from Zamama drops off in a manner consistent with a greatly reduced eruption rate and the cooling of emplaced flows. Culann exhibits possible episodic activity. We present the full Tupan Patera NIMS dataset and derive new estimates of thermal output and temporal behavior. Eruption rates at these three volcanoes are on the order of 30 m³ s⁻¹, consistent with a previous analysis of NIMS observations of Prometheus, and nearly an order of magnitude greater than Kilauea volcano, Hawai’i, Earth’s most active volcano. We propose that future missions to the jovian system could better constrain activity at these volcanoes and others where similar styles of activity are taking place by obtaining data on a time scale of, ideally, at least one observation per day. Observations at similar or even shorter timescales are desirable during initial waxing phases of eruption episodes. These eruptions are identifiable from their characteristic spectral signatures and temporal behavior.     

Near-surface flow of volcanic gases on Io

Significant near-surface flow of gas several hundred kilometers from Pele (Plume 1) on Io is indicated by a series of bright, elongate albedo markings. Particles produced at small, local vents are apparently carried as much as 70 km farther “downwind” from Pele. The gas densities and velocities necessary to suspend 0.1 to 10 μm particles at such a distance imply mass flow rates of 10⁷ to 10⁹ g/sec. Such flow rates are consistent with other estimates of mass transport by the plume. The large flow rates so far from the source allow an estimate of the rate of resurfacing of Io by lava flows and pyroclastics that is independent of estimates based on meteorite flux or on the amount of solids carried within the plumes themselves.     

Io: Energy constraints and plume volcanism

Observational and theoretical considerations, including near-surface energy constraints, suggest a model of Io that features a surface layer of sulfur overlying an active silicate crust. Such a model would imply frequent contact between silicate magma intrusions and the sulfur layer. This contact could produce volcanic plumes driven by high-temperature sulfur vapor. Plumes driven by sulfur vapor meet observationall constraint for a wide range of possible conditions, in contrast to the special conditions required for plume generation by SO₂. Characteristics of the two models are compared, and it is suggested that high-resolution infrared radiometry could identify the driving volatile.     

Impact-generated dust clouds surrounding the Galilean moons

Tenuous dust clouds of Jupiter's Galilean moons Io, Europa, Ganymede and Callisto have been detected with the in-situ dust detector on board the Galileo spacecraft. The majority of the dust particles have been sensed at altitudes below five radii of these lunar-sized satellites. We identify the particles in the duut clouds surrounding the moons by their impact direction, impact velocity, and mass distribution. Average particle sizes are between 0.5 and 1 μm, just above the detector threshold, indicating a size distribution with decreasing numbers towards bigger particles. Our results imply that the particles have been kicked up by hypervelocity impacts of micrometeoroids onto the satellites' surfaces. The measured radial dust density profiles are consistent with predictions by dynamical modeling for satellite ejecta produced by interplanetary impactors (Krivov et al., 2003, Planet. Space Sci. 51, 251-269), assuming yield, mass and velocity distributions of the ejecta from laboratory measurements. A comparison of all four Galilean moons (data for Ganymede published earlier; Krüger et al., 2000, Planet. Space Sci. 48, 1457-1471) shows that the dust clouds of the three outer Galilean moons have very similar properties and are in good agreement with the model predictions for solid ice-silicate surfaces. The dust density in the vicinity of Io, however, is more than an order of magnitude lower than expected from theory. This may be due to a softer, fluffier surface of Io (volcanic deposits) as compared to the other moons. The log-log slope of the dust number density in the clouds vs. distance from the satellite center ranges between −1.6 and −2.8. Appreciable variations of number densities obtained from individual flybys with varying geometry, especially at Callisto, are found. These might be indicative of leading-trailing asymmetries of the clouds due to the motion of the moons with respect to the field of impactors.     

Monte Carlo modeling of Io’s [OI] 6300 Å and [SII] 6716 Å auroral emission in eclipse

We present a Monte Carlo (MC) model of [OI] 6300 Å and [SII] 6716 Å emission from Io entering eclipse. The simulation accounts for the 3-D distribution of SO₂, O, SO, S, and O₂ in Io’s atmosphere, several volcanic plumes, and the magnetic field around Io. Thermal electrons from the jovian plasma torus are input along the simulation domain boundaries and move along the magnetic field lines distorted by Io, occasionally participating in collisions with neutrals. We find that the atmospheric asymmetry resulting from varying degrees of atmospheric collapse across Io (due to eclipse ingress) and the presence of volcanoes contributes significantly to the unique morphology of the [OI] 6300 Å emission. The [OI] radiation lifetime of ∼134 s limits the emission to regions that have a sufficiently low neutral density so that intermolecular collisions are rare. We find that at low altitudes (typically <40 km) and in volcanic plumes (Pele, Prometheus, etc.) the number density is large enough (>4 × 10⁹ cm⁻³) to collisionally quench nearly all (>95%) of the excited oxygen for reasonable quenching efficiencies. Upstream (relative to the plasma flow), Io’s perturbation of the jovian magnetic field mirrors electrons with high pitch angles, while downstream collisions can trap the electrons. This magnetic field perturbation is one of the main physical mechanisms that results in the upstream/downstream brightness asymmetry in [OI] emission seen in the observation by Trauger et al. (Trauger, J.T., Stapelfeldt, K.R., Ballester, G.E., Clarke, J.I., 1997. HST observations of [OI] emissions from Io in eclipse. AAS-DPS Abstract (1997DPS29.1802T)). There are two other main causes for the observed brightness asymmetry. First, the observation’s viewing geometry of the wake spot crosses the dayside atmosphere and therefore the wake’s observational field of view includes higher oxygen column density than the upstream side. Second, the phased entry into eclipse results in less atmospheric collapse and thus higher collisional quenching on the upstream side relative to the wake. We compute a location (both in altitude and latitude) for the intense wake emission feature that agrees reasonably well with this observation. Furthermore, the peak intensity of the simulated wake feature is less than that observed by a factor of ∼3, most likely because our model does not include direct dissociation-excitation of SO₂ and SO. We find that the latitudinal location of the emission feature depends not so much on the tilt of the magnetic field as on the relative north/south flux tube depletion that occurs due to Io’s changing magnetic latitude in the plasma torus. From 1-D simulations, we also find that the intensity of [SII] 6716 and 6731 Å emission is much weaker than that of [OI] even if the [SII] excitation cross section is 10³ times larger than excitation to [OI]. This is because the density of S⁺ is much less than that of O and because the Einstein-A coefficient of the [SII] emission is a factor of ∼10 smaller than that of [OI].     

The Zamama-Thor region of Io: Insights from a synthesis of mapping, topography, and Galileo spacecraft data

We have studied data from the Galileo spacecraft's three remote sensing instruments (Solid-State Imager (SSI), Near-Infrared Mapping Spectrometer (NIMS), and Photopolarimeter-Radiometer (PPR)) covering the Zamama-Thor region of Io's antijovian hemisphere, and produced a geomorphological map of this region. This is the third of three regional maps we are producing from the Galileo spacecraft data. Our goal is to assess the variety of volcanic and tectonic materials and their interrelationships on Io using planetary mapping techniques, supplemented with all available Galileo remote sensing data. Based on the Galileo data analysis and our mapping, we have determined that the most recent geologic activity in the Zamama-Thor region has been dominated by two sites of large-scale volcanic surface changes. The Zamama Eruptive Center is a site of both explosive and effusive eruptions, which emanate from two relatively steep edifices (Zamama Tholi A and B) that appear to be built by both silicate and sulfur volcanism. A ∼100-km long flow field formed sometime after the 1979 Voyager flybys, which appears to be a site of promethean-style compound flows, flow-front SO₂ plumes, and adjacent sulfur flows. Larger, possibly stealthy, plumes have on at least one occasion during the Galileo mission tapped a source that probably includes S and/or Cl to produce a red pyroclastic deposit from the same vent from which silicate lavas were erupted. The Thor Eruptive Center, which may have been active prior to Voyager, became active again during the Galileo mission between May and August 2001. A pillanian-style eruption at Thor included the tallest plume observed to date on Io (at least 500 km high) and new dark lava flows. The plume produced a central dark pyroclastic deposit (probably silicate-rich) and an outlying white diffuse ring that is SO₂-rich. Mapping shows that several of the new dark lava flows around the plume vent have reoccupied sites of earlier flows. Unlike most of the other pillanian eruptions observed during the Galileo mission, the 2001 Thor eruption did not produce a large red ring deposit, indicating a relative lack of S and/or Cl gases interacting with the magma during that eruption. Between these two eruptive centers are two paterae, Thomagata and Reshef. Thomagata Patera is located on a large shield-like mesa and shows no signs of activity. In contrast, Reshef Patera is located on a large, irregular mesa that is apparently undergoing degradation through erosion (perhaps from SO₂-sapping or chemical decomposition of sulfur-rich material) from multiple secondary volcanic centers.