改进重铬酸钾法快速测定水样CODcr

研究了用硫酸锰代替贵金属硫酸银作催化剂,在H2SO4-H3PO4介质中,重铬酸钾回流法测定水样中CODcr的新方法.通过实验,确定了最佳测定条件:MnSO4浓度为1×10-1mol.L-1;混酸溶液(H2SO4:H3PO4)=5:1(体积比);回流时间10min.并与标准方法进行了对比,准确度和精密度同标准法相近,大大节约了分析时间.     

利用GRACE监测中国区域干旱及其影响因素分析

利用2003-01~2012-12的GRACE时变地球重力场模型计算我国长江中下游平原、西南地区和华北平原陆地水储量变化的时间序列。结果表明，长江中下游平原和华北平原的陆地水储量变化量最低值在2011-05，西南地区最低值在2010-03。根据陆地水储量变化的水平衡原理计算3个区域地下水储量变化情况。结果表明，长江中下游平原和西南地区地下水储量呈缓慢增长的趋势，增长速率分别为0.54 mm/月和0.34 mm/月；华北地区呈缓慢减小的趋势，减小速率为0.33 mm/月。3个区域干旱时期地下水储量的亏损情况分别为：长江中下游平原-21.31 mm/月，华北平原-19.88 mm/月，西南地区-15.72 mm/月。最后，用NOAA发布的月降雨和气温数据对3个区域干旱期间的降雨量和蒸发量进行量化，分析3次干旱产生的原因。结果表明，西南地区2010年春季干旱的主要原因是气温异常，长江中下游平原和华北平原2011年干旱的主要原因是降雨量偏少。     

Influencing factors of seed long-distance dispersal on a fragmented forest landscape on Changbai Mountains,China

Seed long-distance dispersal(LDD) events are typically rare, but are important in the population processes that determine large-scale forest changes and the persistence of species in fragmented landscapes. However, previous studies focused on species dispersed via animal-mediated LDD, and ignored those dispersed by wind. The aim of this study was to assess the effects of canopy openness, edge, seed source, and patch tree density on the LDD of seeds by wind in forest. We collected birch seeds, a typical wind-dispersed species, throughout a larch plantation. We then assessed the relationship between birch LDD and each factor that may influence LDD of seeds by wind including distance to edge, canopy openness size, distance to mature forest, and the tree density of the larch plantation. We used univariate linear regression analysis to assess the influence of those factors on birch LDD, and partial correlations to calculate the contribution of each factor to LDD. The results showed that both canopy openness and edge had significant influences on birch LDD. Specifically, a negative relationship was observed between distance to edge and birch LDD, whereas there was a positive correlation between canopy openness size and LDD. In contrast, the distance to the mature forest was not correlated with birch LDD. Our results suggest that patch tree density could potently affect the probability of LDD by wind vectors, which provides novel and revealing insights regarding the effect of fragmentation on wind dynamics. The data also provide compelling evidence for the previously undocumented effect of habitat fragmentation on wind-dispersed organisms. As such, these observations will facilitate reasonable conservation planning, which requires a detailed understanding of the mechanisms by which patch properties hamper the delivery of seeds of wind-dispersed plants to fragmented areas.     

CHANGE OF NUTRIENT IMPORT AND EXPORT IN PROCESS OF RAINFALL IN AILAO MOUNTAIN OF YUNNAN PROVINCE

ＣＨＡＮＧＥ　ＯＦ　ＮＵＴＲＩＥＮＴ　ＩＭＰＯＲＴ　ＡＮＤ　ＥＸＰＯＲＴ　ＩＮ　ＰＲＯＣＥＳＳ　ＯＦ　ＲＡＩＮＦＡＬＬ　ＩＮ　ＡＩＬＡＯ　ＭＯＵＮＴＡＩＮ　ＯＦ　ＹＵＮＮＡＮ　ＰＲＯＶＩＮＣＥＧａｎＪｉａｎｍｉｎ（甘健民）；ＸｕｅＪｉｎｇｙｉ（薛敬意...     

Wet Canopy Evaporation Rate of Three Stands in Western Sichuan, China

The wet canopy evaporation rate (Er) was calculated by Penman-Monteith combination model based on three assumptions and with meteorological variables 2 m above the canopy in three stands, dominated by spruce (SF), fir (FF) and birch (BF) trees, respectively, in the subalpine forests in western Sichuan, China over a growing season. The total amount of the E was 44.5 mm for SF, 88.5 mm for FF and 57.8 mm for BF, accounting for 9.2%, 16.6% and 10.2% of the gross rainfall, respectively, in the measuring period. There was the highest average monthly Er and percentage of E to gross rainfall for FF compared with SF and BF.Mean Er was 0.097 mm h^-1 (ranging from 0.028 to0.487 mm h^-1), 0.242 mm h^-1 (from 0.068 to 0.711 mm h^-1) and 0.149 mm h^-1 (from 0.060 to 0.576 mm h^-1) for SF, FF and BF, respectively. The highest average monthly Er occurred in June was 0.120 mm h^-1 for SF, 0.317 mm h^-1for FF and 0.169 mm h^-1 for BF, and the lowest value in October was 0.083 mm h^-1 for SF, 0.187 mm h^-1 for FF and 0.101 mm h^-1 for BF, respectively. The averages of Er from 8:00 to16:00 were significantly higher than those from 0:00 to 8:00 and from 16:00 to 0:00 for the three stands. The marked daily and monthly differences of Er were contributable to the variations of solar radiation, air temperature and relative humidity above the canopy.     

中国长江流域洪涝灾害和持续性暴雨的发生特征及成因

主要综述了最近关于中国长江流域洪涝灾害和持续性暴雨发生特征和成因的研究。表明:长江流域洪涝灾害和持续性暴雨的发生频率非常高,并给经济造成了严重损失,长江流域洪涝灾害发生不仅具有准两年周期的年际变化,而且具有明显的年代际变化,从1977年之后,长江流域洪涝灾害和持续性暴雨增多;并且,表明了无论是长江中、下游地区或是长江上游的川东地区持续性暴雨都是在"鞍"型大尺度环流系统的配置下发生,这是由于这种大尺度环流系统的配置不仅利于水汽输送到长江中、下游地区或上游的川东地区,而且利于在"鞍"型中心地区产生垂直对流不稳定,从而引起暴雨中尺度系统的发展。此外,还综述了长江流域洪涝灾害和持续性暴雨发生的成因的研究,这些研究表明了长江流域洪涝灾害和持续性暴雨发生的年际和年代际变化是与大气-海洋-陆面耦合的东亚季风气候系统的变异密切相关。     

2011年春夏长江中下游旱涝急转的低频环流系统变化

为研究2011年春夏长江中下游地区旱涝急转现象与低频环流的关系,利用国家气象信息中心的753站逐日降水、NCEP/NCAR再分析资料和带通滤波的方法,得到如下结果：（1）2011年5-6月,长江中下游地区存在明显旱涝急转现象,5月的降水较同期偏少40％以上,6月的降水较同期偏多60％。（2）5-6月的旱涝急转前后,长江中下游地区的500hPa的垂直速度变化不仅与降水有很好的关系,而且其低频振荡的强度也显著加强,垂直速度由正（下沉运动）转负（上升运动）的转换时间几乎对应由旱转涝的时间。（3）对旱涝急转过程的500hPa低频变化垂直速度下沉运动最强、下沉运动向上升运动转换、上升运动最强3个位相的低频散度场分析发现,在5月干旱期间,长江中下游地区维持对流层低层（850hPa）辐散、高层（200hPa）辐合的低频环流系统,不利于降水。到6月强降水期,长江中下游地区则迅速转为对流层低层辐合、高层辐散的低频环流系统,有利于降水的发生。这种对流层低层-高层低频环流系统的变化是导致旱涝急转的重要原因之一。     

Deposition of atmospheric pollutant and their chemical characterization in snow pit profile at Dokriani Glacier,Central Himalaya

The uncertainty in assessing the numerous atmospheric pollutants transported via wind from arid and semi-arid regions is affecting the glacial ecosystem. In our study area due to the complexity of the system, a prominent seasonal difference noticed among major ions(Ca~(2+), Mg~(2+), SO_4~(2-), and NO_3~-). There is a need for understanding the ions cycling as a whole and the directionality of the feedback loops in the system. Therefore, we provide an appraisal of our current hypothesis for seasonal difference in major ion concentration from snow samples for two corresponding years(2013 and 2015) at Dokriani Glacier. A systematic study of chemical compositionsin the shallow snow pit from Dokriani Glacier was undertaken for the pre-monsoon season to understand the cycling of major ions from atmosphere to solute acquisition process. The intimating connections of ions cycling in snow and its temporal behavior was observed and analyzed through various statistical tests. Among major ions, the SO_4~(2-)has the highest concentration among anions on an average considered as 14.21% in 2013 and 29.46% in 2015. On the other side Ca~(2+) is the dominant cation contributing 28.22% in 2013 and 15.3% in 2015 on average. The average ratio of Na+/Cl-was higher in 2013 whereas lower in 2015. The backward trajectory analysis suggests the possible sources of the ions transported from Central Asia through the Western Disturbance(WD) as a prominent source of winter precipitation mainly in the Central Himalaya. Ionicconcentration of Ca~(2+) in cations was highly dominated while in anion SO_4~(2-)played the major role. Factor analysis and correlation matrix suggested that, the precipitation chemistry is mostly influenced by anthropogenic, crustal, and sea salt sources over the studied region. The elemental cycling through ocean, atmosphere and biosphere opens up new ways to understand the geochemical processes operating at the glacierized catchments of the Himalaya. Moreover, increasing the field-based studies in the coming decades would also have the certain advantage in overcoming the conceptual and computational geochemical modelling difficulties.     

Carbon storage capacity of different plantation types under sandstorm source control program in Hebei Province,China

Afforestation and reforestation are effective and ecological ways of mitigating elevated atmospheric carbon dioxide(CO2) concentration and increasing carbon(C) storage in terrestrial ecosystems. In this study, we measured the above-ground(tree, herbaceous plants and litter) and below-ground(root and soil) C storage in an aspen plantation(Populus davidiana) monoculture(PD), a larch plantation(Larix pincipis-rupprechtii) monoculture(LP), a pine plantation(Pinus tabulaeformis) monoculture(PT), a larch and birch mixed plantation(L. pincipis-rupprechtii and Betula platyphlla mixed)(MLB), and an apricot plantation(Armeniaca sibirica) monoculture(AS) under the Desertification Combating Program in Hebei Province, the northern China. The objective was to assess the effect of afforestation species on ecosystem C pools of different plantation types. Results showed that C storage of LP stand(258.0 Mg/ha) and MLB(163.4 Mg/ha) were significantly higher than the C storage in PD(45.5 Mg/ha), PT(58.9 Mg/ha) and AS(49.4 Mg/ha), respectively. Soil C was the main carbon pool of the ecosystem C storage in the five plantation stands, ranging from 31.4 Mg/ha to 232.5 Mg/ha, which accounted for 69.0%–90.1% of the total ecosystem C storage. The C storage in tree layer was about 5.2%–23.2% of ecosystem C storage. The herbaceous plants and litter layers contained 1.0%–6.0% and 1.5%–3.3% of ecosystem C storage, respectively. Our results suggest that tree species should be incorporated to accurately develop regional C budget of afforestation program, and also imply that substantial differences in ecosystem C stocks among plantation types can facilitate decision making on C management.     

离子色谱法测定地下水中有机氮

本文探讨了K_2S_2O_8氧化离子色谱法测定有机氮的实验条件,考察了淋洗剂离子价态及淋洗剂总离子强度对低浓度NO_3~-与高浓度SO_4~2-分离的影响;测定了11种含氮有机化台物有机氮的回收率。本法测定地下水中有机氮的结果与经典蒸馏法结果较为一致,具有操作简便、快速、准确,效率高的特点。     

用大气热源表征的东亚夏季风指数的研究

利用1965—2007年NCEP／NCAR再分析资料和同期的中国160站降水资料,在讨论大气热源的气候特征基础上,用整层积分的大气热源定义了一个东亚夏季风指数,并用该指数研究了东亚夏季风和中国气候的关系。研究表明：定义的大气热源季风指数能反映夏季风的异常变化,高（低）指数年对应的东亚夏季风偏强（弱）;该指数与长江中下游降水存在高度的同期负相关,对长江中下游夏季降水有较强的分辨能力。     

用大气热源表征的东亚夏季风指数的研究

利用1965—2007年NCEP／NCAR再分析资料和同期的中国160站降水资料,在讨论大气热源的气候特征基础上,用整层积分的大气热源定义了一个东亚夏季风指数,并用该指数研究了东亚夏季风和中国气候的关系。研究表明：定义的大气热源季风指数能反映夏季风的异常变化,高（低）指数年对应的东亚夏季风偏强（弱）;该指数与长江中下游降水存在高度的同期负相关,对长江中下游夏季降水有较强的分辨能力。     

东亚季风区石笋δ18O解译:基于夏季风与夏季风降雨的思考

近些年,对于东亚季风区石笋δ18O的气候环境指示意义的争论较多,主要在东亚季风区石笋δ18O代表夏季和风强度、夏季风降水还是水汽源变化。基于中国东部华北地区降水与长江中下游地区降水反相变化和长江中下游地区降水与菲律宾海降水反相变化(遥相关),从年际-年代际到千年-轨道尺度对石笋δ18O与夏季风降水、厄尔尼诺-南方涛动(ENSO)的相互关系进行了探讨分析。通过对比石笋δ18O记录与华北和梅雨区降水,发现石笋δ18O偏负对应华北降水增加,梅雨区降水减少;石笋δ18O偏正对应华北降水减少,梅雨区降水增加。这种对应关系不仅存在年际-年代际尺度,而且在千年-轨道尺度同样存在,石笋δ18O不仅反映夏季风强弱变化,同时与中国东部区域降水关系是明确对应的。通过降水的空间相互关系,发现ENSO活动主要通过影响中国东部降水的空间分布格局而作用于石笋δ18O。La Ni?a态导致南海及菲律宾海对流加强,西太副高位置偏北,长江中下游地区梅雨期缩短,华北夏季降水增加,东亚季风区石笋δ18O偏负。El Ni?o态,南海和菲律宾海对流受到抑制,西太副高位置南移,长江中下游地区梅雨期延长,华北夏季降水减少,东亚季风区石笋δ18O偏正。另外,水汽源分析发现,菲律宾海水汽输送对东亚季风区降水及降水δ18O贡献相对较小。因此,综合分析认为,东亚季风区石笋δ18O主要反映了亚洲夏季风的强弱变化。      

融合GPT2w模型与GNSS参数获取大气可降水量

针对GPT2w模型误差累积所导致的天顶对流层延迟(zenith tropospheric delay, ZTD)和大气可降水量(precipitable water vapor, PWV)精度不高的问题,利用2017年长三角地区7个探空站和2个GNSS站的实测数据检验GPT2w模型获取的气压、温度、水汽压、加权平均温度(Tm)和ZTD等参数的精度,并融合GNSS解算得到的ZTD(GNSS-ZTD)与GPT2w模型获取的气象参数,提高PWV反演精度。结果表明：1)近地面处的气压、温度和水汽压的bias分布在－3~4 mbar、－7~7 K和－9~2 mbar之间,精度较高;2)GPT2w模型获取的Tm在长三角地区适用性较好,年均bias和RMS分别为－1.21 K和6.89 K;3)基于GPT2w模型解算的ZTD的bias和RMS均值分别为1.4 cm和9.4 cm,精度明显低于基于实测气象数据获得的GNSS-ZTD;4)参数融合法计算的PWV与GNSS-PWV精度相当,该方法可用于无实测气象参数时实时获取PWV。     

Sulfate-Methane Transition Depths and Its Implication for Gas Hydrate

The biological removal of CH_4 by methanotrophic(CH_4-oxidizing) archaea always occurs at a distinct zone which is known as sulfate-methane transition zone(SMTZ). It is an important indication for high methane flux and gas hydrate occurrence. In this study, we collected pore-water data from South China Sea, Carolina Rise and Blake Ridge to analyze the relationship between CH_4, SO_4~(2-) concentration and depth. We found that below the SMTZ, the methane concentration increases continuously with depth and sulfate concentration decrease linearly to zero. In addition, the geochemical data taken from all these sites show that SMTZ is relatively shallow(less than 20 m), which may indicate that these areas have high methane flux.     

Effects of a flexible net barrier on the dynamic behaviours and interception of debris flows in mountainous areas

Flexible net barriers are a new type of effective mitigation measure against debris flows in valleys and can affect the kinematic energy and mass of debris flows. Here, ten flume tests were performed to study the dynamic behaviours of debris flows with differences in volumes, concentrations (solid volume fraction), and travel distances after interception by a uniform flexible net barrier. A high-speed camera was used to monitor the whole test process, and their dynamic behaviours were recorded. A preliminary computational framework on energy conversion is proposed according to the deposition mechanisms and outflow of debris flow under the effects of the flexible net barrier. The experimental results show that the dynamic interaction process between a debris flow and the flexible net barrier can be divided into two stages: (a) the two-phase impact of the leading edge of the debris flow with the net and (b) collision and friction between the body of the debris flow and intercepted debris material. The approach velocity of a debris flow decreases sharply (a maximum of 63%) after the interception by the net barrier, and the mass ratio of the debris material being intercepted and the kinetic energy ratio of the debris material being absorbed by the net barrier are close due to the limited interception efficiency of the flexible net barrier, which is believed to be related to the flexibility. The energy ratio of outflow is relative small despite the large permeability of the flexible net barrier.     

Assessment of soil organic carbon stock in the upper Yangtze River basin

Soil organic carbon is of great importance to terrestrial ecosystems.Studies on the amount and spatial distribution of soil organic carbon stock in various types of soil can help to better understand the role of soil in the global carbon cycle and provide a scientific basis for the assessment of the magnitude of carbon stored in a given area.Here we present estimates of soil organic carbon stock in soils in the upper reaches of the Yangtze River based on soil types as defined by Chinese Soil Taxonomy and recently compiled into a digital soil database.The results showed that the total soil organic carbon stock of the upper Yangtze River to a depth of 100 cm was 1.452×1013kg.The highest soil organic carbon stock was found in felty soils(2.419×1012kg),followed by dark brown soils(1.269×1012kg),and dark felty soils(1.139×1012kg).Chernozems and irrigation silting soils showed the lowest soil organic carbon stock,mainly due to the small total area of such soils.The soil organic carbon density of these major soil types ranged from 5.6 to 26.1 kg m-2.The average soil organic carbon density of the upper reaches of the Yangtze River was 16.4 kg m-2,which was higher than that of the national average.Soil organic carbon density indicated a distinct decreasing trend from west to east,which corresponds to the pattern of increasing temperature from cold to subtropical.     

Characteristics of diffuse pollution of nitrogen and phosphorous from a small town in the hilly area of the central Sichuan Basin,China

Hydrological and hydro-chemical monitoring of nitrogen (N) and phosphorus (P) in a small urbanized catchment was conducted in the hilly area of the central Sichuan Basin, China, from 2010 through 2011. The diffuse N and P loadings in different forms of total nitrogen (TN) and phosphorus (TP), dissolved nitrogen (DN) and phosphorus (DP), as well as particulate nitrogen (PN) and phosphorus (PP) were calculated based on runoff discharges and chemical analyses. The results revealed that the diffuse pollution concentrations of TN, DN, PN, TP, DP and PP exhibited large variations during rainfall events, with peak concentrations occurring during the initial period. For all of the measured parameters, the event mean concentrations (EMCs) were observed to clearly vary among rainfall events. The EMCs of TN, DN, PN, TP, DP and PP (for all of the observed rainfall events) were 10.04, 6.62, 3.42, 1.30, 0.47 and 0.83 mg/L, respectively. The losses of diffuse N and P exhibited clear seasonal patterns and mainly occurred during the period from July through September, when the losses totaled 99.3 and 9.6 kg/ha for TN and TP, respectively, accounting for 75% and 74% of the total annual loadings. The mean annual loadings of TN and TP were 124.6 and 12.9 kg/ha, respectively. The results indicate that residential areas in the hilly area of the central Sichuan Basin are subject to high diffuse N and P loadings, posing a serious risk to the receiving water quality. Ecological buffering belts are recommended to incorporate into the urbanized catchment to reduce diffuse pollution.     

中国历史山洪灾害分布特征研究

中国山洪灾害发生频繁,区域分布差异性明显且难以预报,关于山洪灾害分布特征的研究对于山洪灾害预警、山洪灾害防治区规划等具有重要意义。本文以历史山洪灾害点为基础数据,以6个一级地貌大区（东部平原低山丘陵大区（Ⅰ）、东南低山丘陵平原大区（Ⅱ）、华北-内蒙东中山高原大区（Ⅲ）、西北高中山盆地高原大区（Ⅳ）、西南中低山高原盆地大区（Ⅴ）、青藏高原高山极高山盆地谷地大区（Ⅵ））为基本分析单元,统计对比不同地貌区域内山洪灾害数目、密度,并进一步分析山洪灾害随高程、高程标准差以及50年一遇6 h雨量（H6-50）的分布情况,从而获得中国历史山洪灾害的主要分布特征。结果表明：山洪灾害集中分布于东南低山丘陵平原大区及西南中低山高原盆地大区,占全国山洪灾害的60%左右。6 h雨量（H6-50）处于240~280 mm区域山洪灾害密度最大。高程标准差小于30 m区域山洪灾害密度较大。东南低山丘陵平原大区高程处于10~50 m间,高程标准差小于30 m,雨量（H6-50）在150~270 mm间地区山洪灾害密度较大;西南中低山高原盆地大区山洪灾害集中分布于高程600 m以下,高程标准差小于50 m,雨量（H6-50）大于120 mm地区。以地貌区划结果为基本分析单元相对于行政界线而言更有助于分析山洪灾害分布特征。     

基于洪峰模数的山洪灾害雨量预警指标研究

山洪灾害预警是防御山洪的重要非工程措施,雨量预警指标是山洪灾害预警的关键。目前的雨量预警指标计算方法对水文气象资料条件以及模型建模率定都有很高的要求,并不适用于基层防汛人员。因此,本文基于全国山洪灾害调查评价成果数据,提出了一种运用洪峰模数计算雨量预警指标的简便、易用的方法。该方法以小流域洪水计算推理公式为基础,将公式中流量与流域面积的比值用洪峰模数表示,得到基于洪峰模数的临界雨量估算公式,并考虑流域土壤含水量等因素,分析临界雨量变化阈值,最终得到雨量预警指标。本文以云南省绥江县双河小流域为例,计算结果显示不同时段（1 h、3 h、6 h）净雨量和预警时段呈线性关系。降雨损失计算中洼地蓄水和植被截留在不同时段相同,土壤下渗在不同的时段不相同。在此基础上,计算不同土壤含水量条件下,不同时段的雨量预警指标。最后,对临界流量、降雨损失和预警指标进行了合理性分析,结果显示预警指标和调查评价结果及实测降雨都比较接近,计算的预警指标合理。本研究为基层山洪灾害预警提供了一种快速、便捷的预警指标计算方法,为预警指标计算提供技术支持。