岩溶区土壤有机碳和团聚体的关系研究——以重庆市中梁山岩溶槽谷为例

研究了重庆市中梁山岩溶槽谷不同土地利用方式对土壤有机碳和团聚体稳定性的影响,在此基础上引入通径分析方法探讨有机碳与各粒径团聚体之问的关系.研究表明,土地利用方式对土壤有机碳、团聚体稳定性指数和团聚体保存几率影响明显:坡耕地有机碳含量仅为17.544(g/kg),分别比灌丛、橘林地、草地和菜地低61.14%、71.66%、74.43%和100.83%;团聚体稳定性指数依次为草地(2.394)>灌丛(2.383)>橘林地(2.085)>坡耕地(1.953)>菜地(0.865);团聚体稳定性与有机碳含量的相关性与土地利用方式有关,在灌丛和草地中明显正相关,在橘林地和菜地中呈负相关,而在坡耕地中相关性不明显;大粒径团聚体保存几率是决定有机碳含量的主要园子,5～10mm和3～5mm粒级的土壤团聚体对有机碳累积与稳定的决定系数分别为0.61和0.50.      

石漠化地区土地利用方式对土壤团聚体稳定性及有机碳的影响

以典型高原山地喀斯特石漠化6种土地利用方式土壤为研究对象,探讨不同生态恢复条件下,坡耕地转变为林地、草地及林草套种地后对表层土壤结构稳定性及其有机碳含量的影响。结果表明:在坡耕地实施石漠化治理措施,造林种草后,>0.25 mm团聚体含量显著增加,以人工林、次生林居多,坡耕地较少。在干湿筛处理下,采用平均质量直径（MWD）、几何平均直径（GMD）、分形维数（D）、>0.25 mm团聚体含量等指标来表征的团聚体稳定性显示,人工林和次生林土壤团聚体稳定性较强,坡耕地和林草套种地土壤团聚体稳定性较弱。总体上不同土地利用方式均以小粒级团聚体有机碳含量最高,>5 mm和2~5 mm水稳性团聚体有机碳对土壤有机碳的贡献率最大（除农耕地）;土壤大团聚体对土壤有机碳的固定起主要作用。石漠化坡耕地退耕还林种草有利于促进土壤表层土壤结构的稳定及有机碳的积累。      

三江平原典型湿地剖面有机碳分布特征与积累现状

研究了三江平原3类典型湿地（泥炭沼泽、腐殖质沼泽和沼泽化草甸）沉积物剖面有机碳的组分与分布特征。结果表明,泥炭沼泽、腐殖质沼泽和沼泽化草甸剖面有机碳分布具有明显的储碳层和淀积层。储碳层厚度分别约为110、60和15 cm,有机碳平均含量分别为295、280和60 g/kg（干物质重）。泥炭沼泽和腐殖质沼泽储碳层内,有机碳主要组分为分解程度低的轻组碳（约占总有机碳的70%以上）,沼泽化草甸的储碳层内轻组碳约为16%。储碳层以下淀积层的有机碳含量都 < 30 g/kg,轻组碳含量很少。3种类型湿地剖面轻组碳与总有机碳之间有着极显著的正相关关系（[WTBX]P[WT]=0.01）。初步建立了湿地有机碳储量的估算方法,得到3种类型湿地剖面1 m内的有机碳储量分别为6.62×104、4.90×104和1.44×104 t/km2,2 m内分别为8.16×104、6.81×104和2.24×104 t/km2。     

土壤碳固定与生物活性:面向可持续土壤管理的新前沿

土壤碳固定研究是近10年土壤学研究的重要前沿,而可持续管理的土壤固碳是当前应对气候变化和全球土壤退化的重大需求。从土壤有机碳的生态系统功能及服务出发,分析了土壤碳固定与土壤功能及生物活性的关联,评述了当前土壤碳固定与微生物活性变化的认识,探讨了土壤团聚体尺度土壤固碳与生物活性的关系,并以水稻土为例讨论了土壤碳固定中团聚体过程及其有机碳—微生物—生物活性的演进关系,提出了土壤碳库稳定性与生物活性的协同关系及其表征问题,特别是如何通过有机质—微生物—酶活性的团聚体分布揭示土壤碳固定的本质,以及良好管理下土壤固碳与生态系统功能的协同特征及其管理途径等优先科学问题。借助非破坏团聚体分组技术和现代微域原位观察分析技术,土壤学已经能从团聚体尺度深入研究土壤固碳与生物活性的土壤机制,这将全面地揭示土壤固碳对于生态系统过程、功能及服务的影响特质,进而为可持续土壤固碳和农田有机质提升,为固碳减排与农田生产力提升及土壤环境服务改善协同发展提供科学依据和管理的政策依据。     

桂林毛村岩溶区自然植被土壤团聚体中腐殖质组成初步研究

探索土壤有机碳物理保护与化学保护的关系,有助于揭示土壤固碳和培肥机理,明确不同粒级团聚体和不同腐殖物质组分对土壤固碳和肥力的贡献。本研究对岩溶区自然植被土壤团聚体中腐殖质含量进行了研究,结果表明:(1)灌丛和林地土壤团聚体中有机碳含量总体上均表现为随着土层深度的增加逐渐下降,而在不同土层深度随着团聚体粒径范围的变化则有机碳含量的变化规律则不同,无明显一致的规律;(2)两种土地利用方式各粒径团聚体中胡敏酸和富里酸均比全土小。这可能是由于在湿筛分离团聚体的过程中溶于水的那部分胡敏酸和富里酸成分被损失掉;(3)各腐殖质组分随着团聚体粒径范围的减小在两种自然植被上均无明显一致的规律,但胡敏酸和富里酸总量则基本表现为随着团聚体粒径范围的减小而逐渐升高,即在0.25mm和0.5~0.25mm粒径范围团聚体中最大;(4)两种自然植被土壤各土层中和各团聚体中胡敏酸/富里酸(HA/FA)基本上表现为小于1,这主要是因为研究区温度相对较高,湿度较大,植被覆盖度大,微生物降解作用强所致。     

石漠化区植被恢复过程凋落叶分解特征及其对土壤有机碳/氮的影响——以重庆中梁山为例

运用凋落物分解袋及样品室内分析的方法,研究了石漠化脆弱生态区植被恢复不同阶段主要建群种凋落叶分解及有机碳、氮释放动态及其与土壤团聚体有机碳、氮之间的关系。结果表明:(1)各植被恢复阶段凋落叶分解系数介于0.73～1.33之间,不同阶段之间表现为,草地<灌丛<乔木林<灌乔林,人工樟树林介于乔木林与灌乔林之间。(2)各植被恢复阶段凋落叶有机碳、氮净释放率介于58.5%～72.9%与21.2%～63.9%之间,有机碳在分解期间表现为净释放,有机碳、氮释放率随植被恢复年限的延长呈增加的趋势。(3)凋落叶分解与养分释放对土壤有机碳、氮含量的提高有促进作用。其中,凋落叶分解系数与0.25～1 mm、<0.25 mm粒径团聚体轻组有机碳、氮之间关系密切。在植被恢复过程中,凋落叶分解速率及有机碳、氮释放率随恢复年限延长而呈增加趋势,凋落叶分解对土壤有机碳、氮有重要影响,轻组有机碳、氮优先向小粒径团聚体输入,小粒径团聚体在土壤有机碳、氮积累中有重要作用。凋落叶分解一方面能为植物生长提供养分,同时也促进土壤有机质的形成与积累,植被恢复过程中应加强水土保持、提高土壤层的养分保蓄与抗水土流失能力。      

辽宁西部沿海地区土壤碳库构成及变化规律研究

基于辽宁西部沿海地区多目标地球化学调查获得的表层和深层土壤碳含量数据,计算了研究区表层（0~20 cm）、中层（0~100 cm）和深层（0~180 cm）的土壤碳密度及储量,探讨了不同分类单元的土壤碳库构成特征及固碳潜力,并对近40年来土壤有机碳变化规律进行研究.结果显示：1）研究区土壤碳库构成以有机碳为主,无机碳储量随深度增加有所增大.表层、中层和深层土壤有机碳密度分别为2.14、7.59和11.27 kg/m²,低于全国多目标调查区平均值和环渤海地区.2）不同分类单元土壤碳库构成具有一定差异：表层土壤元古宇和中生界单元的碳密度较大,而中层和深层表现为古生界土壤碳密度较大;山地土壤碳密度大于丘陵和平原;褐土土壤碳密度最高,潮土最低;林草地土壤碳密度最高,耕地和园地较低.3）研究区表层、中层和深层固碳潜力分别为33.91、103.32和129.37 Mt,其中有机碳的固碳潜力大于无机碳.4）近40年间,土壤有机碳总体呈增加态势,其中,耕地和园地的表层土壤总体表现为碳源效应,释放有机碳量0.29 Mt.棕壤分布区和林地分布区对土壤有机碳的输入贡献最大.     

石灰岩发育土壤团聚体形成机制研究

土壤团聚体是土壤最基本的结构单元。为了解岩溶地区石灰岩发育土壤团聚体的形成机制,选择贵阳市花溪区花溪水库石灰岩所发育的土壤为材料,采用干、湿筛法,分析团聚体颗粒的分级情况,并比较拆分有机质与钙镁铁铝离子间连接后四种离子含量的变化以及团聚体各粒级含量的变化。结果显示:团聚体是由细小颗粒在胶结物质有机质与钙镁铁铝离子结合下形成微团聚体,进一步形成更大粒级的团聚体,最后在分子力的作用下粘结土粒或者其他团聚体形成完整的团聚体结构;有机质与钙离子的结合是团聚体形成的主要胶结物质,其次为有机质与镁铁离子的结合,有机制与铝离子的结合作用不大,这与石灰岩矿物主要是碳酸钙有关;研究区发育土壤大粒级水稳性团聚体含量相对较高,土壤抗蚀性好,抵抗侵蚀能力强。      

广东省普宁市土壤硒的分布特征及影响因素研究

开展了广东省普宁市区域土壤硒调查研究,采集了413个表层土壤样品(0～20 cm)和103个深层土壤样品(> 150 cm),测定了土壤全硒含量,据此研究土壤硒分布特征及其影响因素。结果表明,普宁市土壤全硒含量变化于0. 16～2. 01 mg/kg,平均值为0. 63 mg/kg,总体上处于中硒及高硒水平,不存在缺硒和硒过剩土壤。砂页岩风化形成的赤红壤全硒含量较高,平均值达0. 86 mg/kg,以侏罗系页岩母质发育的土壤全硒含量最高,平均值达0. 89 mg/kg;三角洲第四系沉积物发育形成的水稻土全硒含量最低,平均值为0. 41 mg/kg。回归分析表明,土壤全硒含量与铁铝含量、有机碳含量具有极显著正相关,与p H呈极显著负相关。影响普宁市土壤硒含量的主要因素是成土母质,土壤p H、有机碳和铁铝含量及土地利用方式对土壤全硒含量分布与富集也有一定的影响。     

基于文献可视化分析的土壤团聚体研究进展

从时间和空间尺度梳理了土壤团聚体的发展历程,通过分析发文时间、发文国家和地区以及关键词等把握土壤团聚体的研究方向、热点和发展趋势。近10年来,土壤团聚体的研究方向主要集中在气候变化背景下土壤有机碳对土壤团聚体稳定性的影响机制,以及土壤团聚体在缓解土壤侵蚀、风蚀和重金属污染等方面的作用。土壤团聚体研究的热点是不同土地管理制度或者不同土地利用方式对土壤团聚体稳定性的影响机制,以及土壤团聚体在碳循环中的作用。同时发现对土壤团聚体的研究高度集中在中低纬度、中低海拔地区,而对高纬度、高海拔地区关注不够。未来土壤团聚体的研究仍会在气候变化背景下展开：(1)研究其与土壤有机碳的相互作用机制,充分发挥其固碳潜力;(2)研究其与土壤水分的关系,探究其对不同尺度水循环的影响;(3)在高纬度、高海拔地区进一步开展深层次和外延性的研究。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。