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1.
碧口群火山岩性质及形成环境   总被引:1,自引:0,他引:1  
中元古代—新元古代碧口群火山岩系分布在扬子地块北缘、秦岭造山带南侧。碧口群火山岩系具大陆裂谷火山岩特点,形成于大陆裂谷作用构造环境。火山岩系特征为:① 具双峰式火山岩组合,火山岩系由基性火山岩(细碧岩及细碧质凝灰岩)及酸性火山岩(石英角斑岩及石英角斑质凝灰岩)组成。② 基性火山岩包括两个岩浆系列的岩石,即碱性玄武岩浆系列及拉斑玄武岩浆系列。③ 火山岩富集LREE及LIL。微量元素及同位素(SmNd,RbSr)研究表明,基性火山岩形成于相似于洋岛玄武岩源的地幔柱源,酸性火山岩为地壳重熔的产物。扬子地块北缘分布有碧口群、西乡群等中元古代—新元古代大陆火山岩系,表明在这一时期大陆裂谷拉张火山作用发育,成为秦岭地壳的主要增生成壳期。  相似文献   

2.
湖南中—新元古代火山—侵入岩地球化学及成因意义   总被引:11,自引:2,他引:11  
江南造山带西段湖南中、新元古代火山-侵入岩具有截然不同的地球化学特征。中元古代火山-侵入岩金属亚碱性玄武岩类,MgO,Ni,Cr含量及Al2O3/TiO2比值高,稀土元素分馏形式多样,更多地具有岛弧火山岩的特征,新元古代中基性火山-侵入岩MgO,Ni,Cr含量较低;其中的基性岩大多属碱性玄武岩类,并较富TiO2,Al2O3/TiO2比值较低,HFSE明显富集,微量元素标准化曲线与OIB类似,具有裂谷玄武岩的特征。中元古代南桥玄武岩εNd(t)为6.86-8.98,具有明显的N-MORB特征,是俯冲带附近的古洋壳残片,为九岭古岛弧提供了新的证据。中元古代的益阳玄武岩εNd(t)为1.56-1.76,Nb,Ti,Zr亏损,Th相对富集,具俯冲带火山岩的地球化学特征,同时这些玄武岩具有高MgO、高Al2O3/TiO2比值和Ni,Cr含量,具科马提质玄武岩的特性,可能是局部地幔柱-弧相互作用的产物。新元古代早期益阳安山质集块岩Th,La,Sm和Nd富集,Nb,Ti,Zr和Hf亏损,εNd(t)值为-0.53--1.05,是格林威尔造山运动的产物。新元古代黔阳,古丈、高桥火山-侵入岩原始地幔标准化曲线近似于OIB,具裂谷玄武岩的特征,黔阳,古丈基性岩εNd(t)值在1.09-1.69,来源于软流圈地幔,湖南这些中-新元古代火-侵入岩的地球化学特征记录了Radinia超大陆在该区从拼合到裂解的演化踪迹。  相似文献   

3.
刘超辉  刘福来 《岩石学报》2015,31(10):3107-3128
华北克拉通存在三个主要的中元古代裂谷带,从南到北分别为熊耳裂谷带、燕辽裂谷带以及渣尔泰-白云鄂博-化德裂谷带。其中熊耳群中火山岩的峰期年龄为1780~1750Ma,其上还有形成于被动大陆边缘的五佛山群、汝阳群以及官道口群。中北部的燕辽裂谷带包括长城系、蓟县系和青白口系,其中长城系团山子组和大红峪组火山岩的年龄分别为~1640Ma和1626~1622Ma,蓟县系高于庄组、雾迷山组和铁岭组凝灰岩的年龄分别为1560Ma、1485Ma和1437Ma,而下马岭组凝灰岩年龄为1366~1380Ma。北缘渣尔泰-白云鄂博-化德裂谷带中渣尔泰群书记沟组玄武岩年龄为1743Ma,阿古鲁沟组酸性火山岩年龄为~810Ma,白云鄂博群尖山组中基性火山岩年龄为1728Ma,化德群比鲁特组火山碎屑岩年龄为1515Ma。中元古代岩浆事件除了裂谷带中的火山作用外,还包括三期基性岩墙群(~1780Ma太行-吕梁岩墙群、~1730Ma密云岩墙群和~1620Ma泰山岩墙群)以及1.76Ga到1.65Ga非造山岩浆组合(斜长岩-环斑花岗岩体-A型花岗岩)。中元古代中期,华北克拉通北缘发育了基性岩席(墙)、A型花岗岩以及碳酸岩脉,双峰式岩浆作用说明华北北缘在中元古代中期经历了裂谷作用,与哥伦比亚超大陆的最终裂解有关,并且与白云鄂博巨型REE-Nb-Fe矿床的形成具有成因上的联系。华北克拉通北部两个裂谷带中的地层具有可以对比的层序以及时代,而中元古代中期辉绿岩墙、A型花岗岩以及碳酸岩脉可以与其它克拉通同时期的非造山岩浆作用对比,证明华北克拉通经历了哥伦比亚超大陆的最终裂解。古地磁数据已经证明在哥伦比亚超大陆时期Siberia、Laurentia、Baltica、Amazion以及华北克拉通是连接在一起的,而北缘中元古代中期大陆裂谷相关岩浆岩的发现也说明它是与另一个古大陆相连的。华北克拉通南缘熊耳火山岩的构造背景到底是大陆裂谷还是大陆边缘弧则关系着其是与另一个克拉通相连还是面向大海,这需要我们进一步深入研究。  相似文献   

4.
南秦岭元古宙板内火山作用特征及构造意义   总被引:18,自引:2,他引:18  
南秦岭元古宙火山岩主要由两大类岩石构成,一类为SiO245%-57%的基性火山岩系,另一类为SiO267%-78%的酸性火山岩系,主要岩石类型为细碧岩、玄武岩和石英角班岩、流纹岩。基性火山岩整体上属拉斑玄武岩系列,酸性火山岩属钙碱系列。火山岩强烈富集稀土元素,尤其是轻稀土元素,酸性火山岩和基性火山岩有相似的稀土元素特征,显示了源区特征的不同。基性火山岩富集强不相容元素,相对亏损Nb和Ti, 成于大陆裂谷环境,具有大陆拉斑玄武岩的特征。同位素特征表明基性火山作用与地幔柱活动密切相关。南秦岭的中、晚元古代大陆拉张及由古地幔柱活动所引发的陆裂火山岩浆活动是古秦岭洋打开的先兆。  相似文献   

5.
碧口群火山旋回及其地质构造意义   总被引:13,自引:2,他引:11  
通过详细的野外剖面观察和室内岩石地球化学研究,将碧口碧火山岩划分为3个火山旋回,每个旋回下部为基性火山岩(细碧岩及细碧质凝灰岩),上部为酸性火山岩(石英角斑岩或石英角斑质凝灰岩)。基性火山岩富集LREE及LIL。第一旋回基性火山岩属碱性系列,第二、三旋回基性火山岩属拉斑玄武岩系列。基性火山岩浆形成于与洋岛玄武岩类似的地幔柱源,其中第三旋回基性火山岩浆晚期受岩石圈地幔混染;酸性火山岩为地壳重熔作用的产物。碧口群火山岩属大陆裂谷双峰式火山岩系,是中一新元古代扬子地块北缘大陆拉张作用的产物。这种拉张作用是秦岭造山带从震旦纪开始的大规模扩张作用的先兆。  相似文献   

6.
通过详细的野外剖面观察和室内岩石地球化学研究,将碧口群火山岩划分为3个火山旋回,每个旋回下部为基性火山岩(细碧岩及细碧质凝灰岩),上部为酸性火山岩(石英角斑岩或石英角斑质凝灰岩).基性火山岩富集LREE及LIL.第一旋回基性火山岩属碱性系列,第二、三旋回基性火山岩属拉斑玄武岩系列.基性火山岩浆形成于与洋岛玄武岩类似的地幔柱源,其中第三旋回基性火山岩浆晚期受岩石圈地幔混染;酸性火山岩为地壳重熔作用的产物.碧口群火山岩属大陆裂谷双峰式火山岩系,是中一新元古代扬子地块北缘大陆拉张作用的产物.这种拉张作用是秦岭造山带从震旦纪开始的大规模扩张作用的先兆.  相似文献   

7.
西天山昭苏北部早石炭纪大哈拉军山组火山岩由碱性橄榄玄武岩和少量的拉斑玄武岩组成。火山岩TiO2(1.10~1.99%)和P2O5(0.22~0.70%)含量较高,富集大离子亲石元素(Rb,Ba,K)并强烈亏损高场强元素(Nb,Ta,Ti)((Nb/La)N=0.20~0.36),轻重稀土分异,其地球化学特征总体上与美国盆岭地区新生代(中新世中期之前)火山岩以及中美洲和南美洲的弧后“过渡型”基性火山岩相似,但与典型火山弧岩浆岩有些不同。大量元古代继承锆石的出现以及主量、微量元素和Nd同位素地球化学特征均表明火山岩经历了相当程度的结晶分异和陆壳混染(AFC)。与碱性玄武岩相比,拉斑玄武岩的SiO2含量和K2O/Na2O比值较高,而εNd(t),MgO和Mg^#值较低,可能由碱性玄武岩浆经AFC演化形成。碱性橄榄玄武岩中含富Fe,Ti贫Si的火山岩夹层(Fe-Ti玄武岩),是碱性玄武质岩浆依Fenner趋势发生较高程度结晶分异的产物。火山岩的元素地球化学特征指示岩浆源区可能为俯冲流体交代富集的岩石圈地幔,然而,Fe-Ti玄武岩的出现以及地球化学特征随时间的规律性变化均指示它们形成于拉张的构造环境。我们提出,昭苏北部大哈拉军山组火山岩可能形成于具有元古代陆壳基底的活动大陆边缘弧后拉张环境。这一认识与前人提出的大哈拉军山组火山岩为地幔柱活动影响的大陆裂谷岩浆岩的认识有所不同。  相似文献   

8.
闽中地区马面山群东岩组变质岩形成的古构造环境研究   总被引:9,自引:0,他引:9  
闽中地区马面山群东岩组地层主要为绿片岩为主的一套古火山沉积建造。其主要岩性类型包括各种成分的绿片岩、大理岩、石英片岩及变粒岩类。绿片岩显示海底火山喷发特征,变粒岩原岩为中酸性岩类。东岩组变质岩岩石化学研究表明,绿片岩的原岩应为玄武岩类。变粒岩类主要属于英安岩及流纹岩。这些特征反映东岩组具双峰式火山岩特征,形成于大陆内部张性环境。绿片岩稀土元素特征也显示和大陆拉张环境中的火山岩类稀土特征非常相似,属大陆拉斑玄武岩;微量元素分布显示出该组变质岩原岩类似于大洋岛和大陆裂谷的板内碱性玄武岩。因此闽中地区中元古代可能处于板内古裂谷环境。  相似文献   

9.
新的同位素年代学、岩石学与地球化学研究表明云南前寒武纪各岩群普遍由跨越古、中和新元古代不同时代的构造片岩组成。哀牢山群和瑶山群是相连接的同一地层单元 ,主体岩石形成于 130 0~ 16 0 0Ma。昆阳群下亚群泥质碳酸盐沉积岩Pb Pb等时年龄在 170 0~ 16 0 0Ma之间 ,上亚群大营盘组为 12 6 0Ma。苍山群的变拉斑系列形成于岛弧环境 ,其钕模式年龄值在 15 0 0~ 2 0 0 0Ma ,Sm Nd等时年龄近于为 16 5 0Ma ,εNd(t) =+ 7.4。形成于板内环境的碱性系列玄武岩 ,钕模式年龄值在 10 0 0~ 110 0Ma。苴林群变拉斑玄武岩钕模式年龄为 16 0 0~ 170 0Ma ,εNd(t) =+ 6 .6 ;变碱性玄武岩样品为 80 0~ 10 0 0Ma ,可与苍山群相比较。钕模式年龄和Pb同位素填图表明昆阳群与大红山群 ,苴林群与苍山群分别归属于扬子和印支块体的准同时地层。成矿年龄测定表明前寒武纪地层中成矿作用表现为 70 0~ 90 0Ma的改造成矿 ,与大规模从基性到酸性的岩浆活动密切相联系。90 0~ 10 0 0Ma板内环境碱性玄武岩的广泛出现 ,标致着大陆裂解的开始。晋宁期花岗岩活动从早期 (80 0~ 830Ma)的偏中酸性到晚期 (6 80~ 780Ma)的酸性 ,表明构造环境从拉张向挤压环境发展 ,体现了Rodinia超大陆形成、裂解到冈瓦纳大陆形成的过程  相似文献   

10.
辽东地区早元古代火山岩特征及其形成的动力学背景   总被引:3,自引:0,他引:3  
辽东地区早元古代火山岩是下元古界辽河群地层的重要组成部分,它们由酸性和基性两套火山岩组成。前者形成于辽河裂谷发育早期的拉张裂陷阶段,属于壳源岩浆成因;后者形成于辽河裂谷发育中晚期的强烈拉张裂陷阶段,属于幔源岩浆成因。重点讨论了基性火山岩的岩石学、矿物学、岩石化学和地球化学特征,结果表明,这些基性火山岩主要为一套海底喷发的基性枕状熔岩,具有大陆拉斑玄武岩和大洋拉斑玄武岩的双重特征,是辽河裂谷由大陆壳向大洋壳演化过程中的产物。火山岩形成的动力学背景与早元古代时期热地幔对流形式的出现以及郯-庐断裂带发生右旋平移剪切活动密切相关。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

18.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

19.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

20.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

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