铅锌矿尾砂重金属污染物对不同土地利用类型土壤性质影响的典范对应分析

广西阳朔思的村铅锌矿尾矿砂坝坍塌造成了大面积农田污染,已往报道多集中在金属矿山开采过程中产生的废液及大量固体废弃物堆砌而造成的环境污染,较少关注因尾矿砂坝坍塌所造成的这种土壤重金属特殊污染模式。本文运用典范对应分析(CCA)研究铅锌矿尾砂坝坍塌对不同土地利用类型(玉米地、柑橘园、水稻田)造成的重金属(铅、锌、铜、镉)污染以及对土壤理化性质(有机碳、碱解氮、速效磷、速效钾、阳离子交换量、碳氮比、pH值)的影响。CCA分析结果表明,研究区污染以铅、锌、镉为主,铜次之,其中锌和镉的空间分布格局受土地利用类型的影响更明显,并且镉对水稻田产生的环境风险最高。此外,在土壤中尾矿砂分布不均的前提下,土地利用类型是造成土壤重金属污染空间分布不同的重要驱动力,受土壤质地和矿砂性质的影响,重金属污染引起的酸化效应在供试土壤中不明显,使得CCA图中pH值所代表的点远离重金属箭头连线;阳离子交换量距重金属连线较近,受重金属影响明显并随重金属污染的加剧而减小;碱解氮、速效磷、速效钾等速效养分受重金属污染的影响并不显著,但与施肥配比和农业管理密切相关;有机碳与重金属箭头连线分布象限相同且包裹于其中,与重金属质量分数呈正相关关系,相较于玉米地和柑橘园,水稻田中有机碳积累量更大,达到18.14 g/kg,可能因稻田中微生物的碳源代谢利用能力明显降低,土壤中有机碳的矿化分解受阻,导致水稻土中有机碳的积累。此外,尾矿砂作为土壤重金属的持续性释放源,尽管对土壤的基本理化性质尤其是速效养分的影响并不明显,但能够通过影响土壤微生物群落间接影响土壤碳循环。     

小秦岭金矿区土壤重金属生物有效性与影响因素

土壤中重金属生物有效性与影响因素分析是土壤重金属风险管控的关键问题。通过实地调查、现场采样、实验测试、综合分析等方法,分析了研究区100km2内Hg、Pb、Cd、Cr、As、Cu、Zn七种重金属元素的有效态含量特征,研究了这些重金属有效态含量之间、有效态含量与全量、有效态与土壤pH、有机质含量、粒度等基本理化参数之间的相关性,分析了重金属污染来源。结果表明,土壤中Hg、Pb、Cd、Cr、As、Cu、Zn七种重金属有效态的平均含量分别为2.29mg/kg、594mg/kg、2.52mg/kg、6.30mg/kg、2.16mg/kg、48.14mg/kg、50.21mg/kg,其变异系数大小为:HgPbCuZnCdAsCr。Hg的变异系数最大,是由于金矿选矿活动采用混汞法提金排放的尾矿堆(库)分布不均。Hg、Pb、Cd、Cu、Zn有效态量与全量之间均存在显著的相关性;土壤有机质与重金属有效态之间存在显著的相关性;土壤pH与有效态重金属之间存在显著的负相关性;土壤粒度对重金属有效态的累积影响不明显。     

合肥市土壤重金属元素异常及其生态效应

通过对合肥市及其周边地区表层土壤重金属元素异常空间分布特征的分析，查明了生活和工业排污是形成Hg、Cd、Pb、Zn异常的主要原因；相对于深层土壤，表层土壤具有明显的富集特征，自地表向下重金属元素含量呈迅速下降趋势。探讨了土壤重金属元素全量与有效量、土壤pH值的关系，土壤重金属元素有效度大小排序为：Cd〉Pb〉Zn〉Hg，Cd、Pb有效量与全量相关性显著，且与pH值呈负相关，随着土壤cd、Pb元素全量的增加以及土壤不断酸化，其生态风险将显著增大。异常区土壤重金属的累积已造成部分蔬菜重金属超标，进而影响到蔬菜食用安全性，因此，加强土壤环境质量保护，对保证合肥市社会经济可持续发展具有重要意义。     

福建沿海地区土壤-稻谷重金属含量关系与影响因素研究

福建沿海地区土壤Pb含量远高于我国其他地区及全国背景值,其对农产品安全、生态环境的影响值得关注。本文采集该地区典型耕作区58套土壤-水稻样品,查明Pb、Cd等重金属元素含量特征及其关键控制因素。研究表明从水稻根→茎叶→稻谷,重金属元素含量和富集系数呈现明显的下降趋势,有害重金属As、Pb等的递减速率远大于植物营养元素Cu、Zn,指示水稻根部对重金属元素具有一定的阻截作用。土壤-稻谷间Pb具有显著正相关性,显示土壤Pb是稻谷Pb的重要来源;稻谷Pb含量与土壤有机碳呈显著负相关关系,与土壤pH呈弱负相关关系,说明富含有机碳、相对碱性的土壤环境可降低土壤Pb的生物有效性,减少稻谷对土壤Pb的吸收富集。土壤理化条件对稻谷Cd富集系数有显著影响,富含有机碳、Al₂O₃、Fe₂O₃、CaO、MgO、S的土壤条件有利于阻断稻谷对土壤Cd的吸收,降低土壤Cd污染的生态风险。本项研究为开展水田土壤重金属污染治理修复、预测稻谷食用安全提供了重要的依据。     

基于典范对应分析的会仙岩溶湿地土壤理化性质与土壤酶活性关系研究

为揭示湿地退化过程中土壤理化性质与土壤酶活性关系,文章以广西桂林市会仙岩溶湿地系统中的湿地、稻田和旱地三种土地利用类型的表层土壤为研究对象,运用描述性分析、相关性分析和典范对应分析(Canonical Correspondence Analysis,CCA)等方法来探讨它们之间的内在联系。结果表明:土壤理化性质除有效磷、速效钾外,土壤有机碳、全氮、碱解氮、阳离子交换量、交换性钙、交换性镁的质量分数均表现为湿地稻田旱地,说明岩溶湿地在维持土壤碳库以及营养元素方面具有重要的作用。会仙湿地中有效磷、速效钾的质量分数低于稻田和旱地,根本原因在于人类活动以及农业活动的影响。除蛋白酶外,脲酶、蔗糖酶、碱性磷酸酶和纤维素酶的质量分数均在湿地中最高,与土壤理化性质的质量分数在湿地中较高相吻合,并表现出较强的空间异质性。进一步分析典范对应分析图,可知会仙岩溶湿地受人类活动影响较大,湿地首先被开垦为稻田,随着土壤自然肥力的下降最后被开垦成旱地,因此在生态演替不可逆转的条件下,将稻田作为人工湿地加以保护是维持湿地生态环境最佳的土地利用方式。     

应用毒性淋溶提取法评价天津市某工业用地及周围农田土壤中重金属生态风险

毒性淋溶提取法(TCLP)是美国法定的一种生态环境风险评价方法,通过提取土壤中的重金属有效态判断土壤重金属污染状况和评估污染区域生态风险。本文应用TCLP法提取天津市某工业园区内及周围农田土壤中的有效态Cu、Pb、Zn、Cd,采用电感耦合等离子体质谱法和原子吸收光谱法分别测定重金属全量和有效态,结合单项污染指数和内梅罗综合污染指数评价了重金属生态风险。结果表明:研究区Zn是首要污染物,主要来源于镀锌厂、金属制品厂和电镀厂,其次是Pb和Cu污染,Cd无污染;Pb、Zn可能具有同源性或伴生关系;大部分土壤处于安全水平,重金属污染率不到30%,但农田土壤出现了Zn的轻度污染。重金属全量是影响重金属有效态含量较大的因素,当Zn全量大于环境质量标准限值(300 mg/kg),Pb全量大于80mg/kg时,有效态Zn、Pb与其全量均呈正相关。因此,可以使用TCLP法将土壤重金属全量与有效态进行量化评价重金属生态风险。     

岩溶铅锌矿区土壤重金属污染特征

以DX、DW铅锌矿区土壤为研究对象,利用原子吸收光谱法（AA800）、原子荧光光谱法（AF-640）测定土壤中铅、铬、镉、铜、锌、镍、汞和砷等重金属的含量,利用单因子污染指数法、N.L.Nemerow综合污染指数法对比分析土壤中重金属的污染特征,采用PCC统计学方法分析矿区土壤中重金属之间的相关性。结果表明:两矿区土壤中除Cu、Cr外,其余重金属均已对土壤造成单一或复合污染,其中Cd污染最为严重,对综合污染贡献最大。DX、DW矿区土壤重金属的Nemerow指数分别为27.61、63.54,均达到极强污染水平,且DW矿区污染较为严重。DX矿区,除Ni外,Pb、Cr等7种重金属元素之间存相关性;DW矿区,除Cr外,Pb、Ni等7种重金属元素之间存相关性,这可能与二矿区均属多金属伴生、共生矿床有关;土壤中各重金属总含量与pH值没有显著的相关性。研究结果将为合理制定矿区土壤污染的修复和治理措施提供依据。      

广西某铅锌矿区废水汇集洼地土壤重金属污染调查与评价

对某铅锌矿废水汇集的岩溶洼地土壤重金属镉、铜、铅、锌、铬、砷和汞的含量进行调查分析,运用单项污染指数与综合污染指数相结合的方法对土壤环境质量状况和采用Hakanson潜在生态指数法对土壤重金属污染潜在生态风险进行评价。结果表明,该区块土壤受到重金属镉、锌、汞、铅的严重污染,其污染指数均大于1,尤其是镉污染指数高达88.4,其后依次为锌和汞,铅最小;剖面上,A、B、C层,即0~30 cm、30~60 cm和60~90 cm土壤,均已受到不同程度的重金属污染,而且污染程度A层>B层>C层,其综合污染指数分别为67.0、11.9和8.8,各自的潜在生态风险指数分别为2 921.0、543.4、421.2,对应的潜在生态风险程度分别为极强、强、强。由此可见,该岩溶洼地土壤不仅镉、锌、汞、铅污染严重,而且其生态风险也很大,但土壤中基本没有受铜、铬、砷污染。在该洼地土壤重金属污染物没有清除前,建议禁止种植食用农产品,而改为种植非食用型经济作物。      

廊坊地区土壤重金属存在形态及有效性分析

通过对廊坊39个样点根系土中As、Cd、Cr、Hg、Pb共5种重金属元素各形态含量的统计与分析,总结出该区根系土重金属元素形态组成特征,初步分析了各重金属元素在土壤中的地球化学行为。运用相关性分析方法,对5种重金属元素有效态含量与全量及土壤pH、TOC的相关性进行分析。根据分析结果,重金属元素有效态含量的高低不仅受其全量的影响,而且与土壤pH、TOC亦有着密切关系。该结论为评估廊坊表层土壤重金属元素污染程度提供了理论依据。     

四川省沐川县典型土壤剖面重金属分布特征和生态风险评价

根据全国土壤污染状况调查显示，全国土壤的环境状况总体不容乐观，耕地土壤环境质量令人担忧，已对粮食安全构成威胁。已有的研究工作多集中于土壤重金属的空间分布特征及污染源分析、重金属污染风险评估以及评估方法，但对于不同土壤深度重金属在耕地中的积累与剖面分布的变化及其生态风险分析相对较少。为研究四川省沐川县土壤剖面重金属分布特征和生态风险，本文在研究区选择三个不同地质背景区采集了土柱剖面样品开展相关工作。结果表明：样品中As、Cd、Hg、Pb、Ni、Cu、Zn七项指标中，除了Cu外，其余重金属元素含量都高于国家和四川省土壤背景值，表明这些元素在土壤中呈现不同程度地富集。土壤中7种重金属的浓度与土壤养分(氮、磷、钾)，土壤有机碳和pH值存在相关性，如在玉米地剖面中，氮和磷与Cd呈显著正相关，相关系数分别为0.845、0.747。大量研究表明，磷肥中含有一定量的重金属。磷肥中重金属含量高低与磷矿及其来源有关，磷肥能够增加土壤Cd含量。土壤有机碳与Cd呈显著正相关，相关系数为0.934，其原因是土壤有机质对重金属的吸附作用，有机碳对土壤中重金属的保留起了重要作用。pH值与Cd呈显著负相关，相关系数为...     

Gamma-ray bursts as a result of the interaction of a shock from a supernova and a neutron-star companion

A supernova explosion in a close binary system in which one of the components is a compact magnetized object (neutron star or white dwarf) can form a narrow “tail” with length l _t ～10⁹ cm, width h _t ～10⁸ cm, and magnetic field B _t ～10⁶, due to the resulting shock wave flowing around the magnetosphere of the compact object. The energy released by the reconnection of magnetic field lines in this tail can accelerate electrons to relativistic speeds (γ≈10⁴), creating the conditions required for powerful synchrotron radiation at energies from hundreds of keV to several MeV, i.e., for a gamma-ray burst (GRB). The duration of this radiation will depend on the power of the shock that forms during the supernova. If the shock is not sufficiently powerful to tear off the magnetosphere tail from the compact object, the duration of the GRB will not exceed l _t /V _A ≤1 s, and the conditions necessary for an “afterglow” at softer energies will not arise. If the shock is more powerful, the tail can be torn from the magnetosphere, forming a narrow ejection, which is perceived in its relativistic motion toward the observer(Γ～10⁴) as an afterglow whose duration grows from tens of seconds at gamma-ray energies to tens of days in the optical. This may explain why afterglows are observed only in association with long GRBs (T ₉₀>10 s). Very short GRBs (T ₉₀<0.1 s) may be local, i.e., low-power, phenomena occurring in close pairs containing compact, magnetized objects, in which there is again an interaction between the magnetosphere of the compact object and a shock wave, but the shock is initiated by a flare on the companion, which is a red-dwarf cataclysmic variable, rather than by a supernova.     

Coupled consolidation of a porous medium with a cylindrical or a spherical cavity

This paper presents a theoretical approach to analyse coupled, linear thermoporoelastic fields in a saturated porous medium under radial and spherical symmetry. The governing equations account for compressibility and thermal expansion of constituents, heat sink due to thermal dilatation of water and thermal expansion of the medium, and thermodynamically coupled heat–water flow. It has been reported in the literature that thermodynamically coupled heat–water flows known as thermo-osmosis and thermal filtration have the potential to significantly alter the flow fields in clay-rich barriers in the near field of a underground waste containment scheme. This study presents a mathematical model and examines the effects of thermo-osmosis and thermal-filtration on coupled consolidation fields in a porous medium with a cavity. Analytical solutions of the governing equations are presented in the Laplace transform space. A numerical inversion scheme is used to obtain the time-domain solutions for a cylindrical cavity in a homogeneous or a non-homogeneous medium. A closed form time-domain solution is presented for a spherical cavity in a homogeneous medium. Selected numerical solutions for homogeneous and non-homogeneous media show a significant increase in pore pressure and displacements due to the presence of thermodynamically coupled flows and a negligible influence on temperature. © 1998 John Wiley & Sons, Ltd.     

Physical properties of a horizon of a white hole and a Kruskal wormhole

The possible application of a Rindler type reference frame for studies of physical processes near the horizons of black and white holes is considered. New similar reference frames inside black and white holes in the region T of a Kruskal wormhole are introduced.     

Propagation of a shear crack in a compressed plane with a circular hole

The problem of the equilibrium of a plane with a circular hole and a shear crack is considered to model failure of an excavation (borehole or circular opening) in rocks weakened by discontinuities (planes of weakness). It is assumed that sliding occurs in a part of the plane of weakness when the Mohr–Coulomb friction criterion is satisfied due to the stress redistribution caused by the excavation. The method of singular integral equations is employed to solve the boundary value problem. Geomechanical problems concerning borehole breakout and rockburst caused by fault-opening interaction are discussed. © 1998 John Wiley & Sons, Ltd.     

Scattering of a plane wave by a lined cylindrical cavity in a poroelastic half-plane

The focus of this contribution is to develop a complex variable function method to solve the two-dimensional scattering of plane waves by a lined cylindrical cavity in the poroelastic half-plane. The poroelastic half-plane is based on Biot’s dynamic theory, and the governing equations are solved by reduction to three Helmholtz equations. The lining structure can be treated as an elastic material and decoupled into two Helmholtz equations. Here, the large circle assumption is applied to simulate the half-plane boundary. By using appropriate boundary conditions and continuity conditions, the unknown coefficients in the potentials can be determined. Selected numerical results are presented in this paper.     

On a controversial method for modeling a coregionalization

This paper reviews two alternative approaches for modeling the (cross) variograms in a coregionalization: (1) fitting the traditional linear model of coregionalization. or (2) deducing the crossvariogram model as a linear combination of prior direct (auto) variogram models while checking the Cauchy-Schwarz inequalities. We show that the second approach has no practical advantage over the traditional one and may not be valid if more than two variables are involved. In such case. Cauchy-Schwarz inequalities are necessary but not sufficient conditions for validity of a coregionalization model.     

The Behaviour of a Reinforced Soil Mattress Spanning a Cavity Modelled in a Geotechnical Centrifuge

Sinkholes can occur on land underlain by dolomite and cause substantial damage to buildings and even loss of life. More than four million people work or reside on dolomite land in South Africa and it is therefore important to be able to construct safely on dolomite land and to minimise the risk of damage to infrastructure and loss of life. Compacted soil mattresses are often used to found structures on areas underlain by dolomite. This study investigated the effect of tensile reinforcement on the behaviour of a soil mattress spanning an underlying water filled cavity designed to impose a cover subsidence sinkhole. Three small-scale models, each consisting of a soil mattress with a cover subsidence sinkhole forming underneath, were constructed and tested in a geotechnical centrifuge. In the first test, an unreinforced soil mattress was tested and in two more tests, reinforced soil mattresses with different reinforcement strengths were tested. The settlement of the unreinforced soil mattress was initially less than that of the reinforced soil mattresses up to the point at which it failed suddenly. Neither of the reinforced soil mattresses failed suddenly, but both experienced large surface settlements that would have led to substantial damage to an overhead structure.     

Impact force to a rigid obstruction from a granular mass sliding down a smooth incline

The impact force to a rigid obstruction from a granular mass sliding down a smooth incline provides insights into the solid-like and fluid-like behaviors of granular avalanches and useful information for risk assessment and engineering design against landslides. In this study, a series of 2-D flume tests were performed to systematically investigate the effects of inclination angle, sliding distance, and initial relative density on the flow front velocity and impact force on a rigid obstruction. The experimental results show that for inclination angles smaller than the critical state friction angle of sand, an increase in the sliding distance and/or initial relative density results in smaller impact forces; for higher inclination angles, the trend is reversed. Based on the experimental results, an analytical equation is proposed to estimate the flow front velocity and an empirical approach is presented to estimate the maximum impact force based on elastic solid and hydrodynamic methods. The proposed equations are found to provide more accurate predictions for the maximum impact force than similar equations in the literature.     

露头处具有淤泥层的滨海含水层系统中海潮引起的水头波动

滨海地区社会与经济的发展引发了各种各样的水文地质问题, 因此对滨海地区的水文地质条件, 尤其是地下水与海水之间的水力联系的研究尤为重要.本文考察了海底露头处具有淤泥层的滨海含水层系统中由海潮引起的水头波动.该系统由潜水含水层、承压含水层和介于其间的弱透水层构成.建立了该系统的数学模型, 得到了该模型的解析解.该解析解包含2个无量纲参数: 弱透水层的相对越流系数和淤泥层的相对透水系数.解析解表明, 淤泥层使各处的水头波幅被缩小了一个常数倍(波幅缩减因子), 并使各处的波动相位产生了一个不超过45°的正位移常数(时滞).该时滞对半日潮不超过1.5h, 对全日潮不超过3h.波幅缩减因子和正位移常数只与弱透水层的相对越流系数和淤泥层的相对透水系数有关.当这两个无量纲参数取某些特殊值时, 本次研究的解和前人考虑的几种较简单情形所对应的解一致.承压含水层中水头波幅随着淤泥层的相对透水系数的递增而严格递增, 随弱透水层的相对越流系数的递增而严格递减; 波动相位随着这2个无量纲参数的递增均严格递减.分析表明弱透水层的越流和淤泥层的存在均对承压含水层水头波动有显著影响.      

Locating a point on a spherical surface relative to a spherical polygon of arbitrary shape

An algorithm for determining if any given point,P, on the surface of a sphere is located inside, outside, or along the border of an arbitrary spherical polygon,S, is described. The polygon is described by specifying coordinates of its vertices, and coordinates of some pointX which is known to lie withinS. The algorithm is based on the principle that an arc joiningX andP will cross the border ofS an odd number of times ifP lies outsideS, and an even number of times ifP lies withinS. The algorithm has been implemented as a set of FORTRAN subroutines, and a listing is provided. The algorithm and subroutine package can be used with spherical polygons containing holes, or with composited spherical polygons.