藏南林周盆地林子宗火山岩的时代、成因及其地质意义：锆石U-Pb年龄和Hf同位素证据

本文对林子宗火山岩命名地-林周盆地内典中组最底部的英安质火山角砾岩和年波组下段的流纹质熔结凝灰岩进行了锆石U-Pb年代学和Hf同位素分析,结果显示前者形成于62.5±1.1Ma,而后者形成于56.4±1.2Ma,表明林子宗火山活动的起始时间略晚于K/T界限年龄。岩浆锆石的ε_(Hf)(T)值分别为 9.0～ 0.5和 11.0～ 4.8,显示亏损地幔的特征,与同时期冈底斯岩体的岩浆锆石相似,应为同源产物,源自于地幔楔的部分熔融。此外,典中组样品含有石炭纪年龄的捕获锆石,它们的ε_(Hf)(T)值介于-0.6～-3.2之间,具有中元古代的Hf同位素模式年龄,与附近念青唐古拉岩带花冈岩的捕获锆石相若,暗示拉萨陆块老地壳的混染在岩浆演化中亦扮演了角色。结合区域地质,我们认为在藏南拉萨陆块上的林子宗火山岩是印度与欧亚大陆碰撞之前到碰撞初期新特提斯海洋板块向北俯冲、拆离作用的结果。     

西藏冈底斯中段孔隆至丁仁勒地区林子宗群火山岩锆石SHRIMP年龄和地球化学特征的区域对比

本文对冈底斯中段孔隆-丁仁勒地区的林子宗群火山岩进行了地球化学和锆石SHRIMP定年测试,在年波组下部的英安质岩屑晶屑熔结凝灰岩(LZ06022-2)中获锆石SHRIMP年龄为59.64±0.72Ma,在典中组下部的安山质晶屑凝灰岩(LZ06017-4)中获锆石SHRIMP年龄为69.97±0.72Ma,这是目前为止林子宗群火山岩底部的最老年龄。结合前人资料,对冈底斯地区林子宗群火山岩的火山活动、地球化学及形成年代等进行了区域对比,结果显示整个冈底斯带林子宗群火山岩以喷溢相和爆发相为主,从早期到晚期爆发强度逐渐减弱,早期典中组以爆发相为主到晚期帕那组以喷溢相为主,且随着时间的演化火山活动强度表现为由强→弱,早期东段比中段和西段火山活动强,中期西段和中段比东段火山活动强,晚期均较弱,年波组火山活动强烈且频繁,持续时间长,从而形成了冈底斯中段林子宗群火山岩的独特性;岩石地球化学特征显示随着时间的演化具有从基性→中性→酸性岩浆演化的规律,全碱含量逐渐升高,岩石系列由钙碱性系列→高钾钙碱性系列→钾玄岩系列逐渐过渡;林子宗群火山岩具有陆缘弧火山岩的特征,是印度-亚洲大陆碰撞的产物,碰撞的起始时限在冈底斯带东、中、西段具有一定的差异,中段略早于东段和西段发生大陆碰撞。     

浙江丽水地区磨石山群火山岩时代归属

为查明浙江丽水地区中生代磨石山群火山岩的时代,在区域地质调查、火山机构划分的基础上,选择该群代表性火山岩进行锆石年龄测定。结果表明,大爽组底部流纹质晶屑熔结凝灰岩的SHRIMP锆石U-Pb年龄为154.9±5.5 Ma、LA-ICP-MS锆石U-Pb加权平均年龄为152.0±7.0 Ma,属晚侏罗世基默里奇阶;高坞组流纹质晶屑熔结凝灰岩SHRIMP锆石U-Pb年龄为131.6±2.7 Ma,两个火山机构的西山头组流纹质晶屑凝灰岩LAICP-MS锆石U-Pb加权平均年龄分别为128.6±1.7 Ma和139.5±2.5 Ma。认为浙南磨石山群火山岩时代:大爽组为晚侏罗世,高坞组、西山头组、茶湾组和九里坪组为早白垩世。     

冈底斯中段厅宫地区林子宗火山岩锆石U-Pb年龄和地球化学特征

林子宗火山岩事件是印度-亚洲大陆主碰撞过程的火山作用响应,对冈底斯带的构造演化具有重要意义。在冈底斯中段厅宫地区通过系统的LA-ICP-MS锆石U-Pb同位素测年,获得林子宗群典中组底部、年波组上部和帕那组顶部的火山岩锆石U-Pb年龄分别为(66.4±0.35)Ma、(53.6±1.5)Ma和(45±0.6)Ma。对林子宗火山岩的岩石地球化学分析表明,该火山岩具弧火山岩特征,早期表现出陆缘弧火山岩的特点,至中期年波旋回钾玄岩出现,标志着陆内岩浆作用的开始,到晚期帕那旋回则显示出陆壳重熔和地壳加厚的特征,记录了新特提斯洋消减俯冲到陆陆碰撞的地质信息。     

大兴安岭中段索伦地区白音高老组火山岩锆石U-Pb年龄、地球化学特征及构造意义

白音高老组火山岩位于大兴安岭中段科右前旗索伦地区,主要岩性为流纹岩和流纹质晶屑凝灰岩。LA-ICP-MS锆石U-Pb同位素分析表明,3组样品的锆石U-Pb年龄分别为127±2Ma、133±2Ma和123±1Ma,即白音高老组火山岩形成于133~123Ma,为早白垩世岩浆活动的产物。岩石学和岩石地球化学特征显示,白音高老组火山岩类似于高分异的I型花岗岩,有斜长石和少量角闪石部分熔融残留。锆石的~(176)Hf/~(177)Hf值介于0.282854~0.283026之间,ε_(Hf)(t)为较高的正值,变化于+5.5~+11.5之间,Hf二阶段模式年龄(T_(DM2))为828~439Ma,表明兴安地块地壳的主体增生年代为新元古代—显生宙。通过对比东北地区(以邻区为主)同时代岩浆-构造活动,研究区内白音高老组火山岩形成于伸展构造环境,这种伸展构造环境的形成可能与古太平洋板块俯冲于欧亚大陆之下的弧后伸展环境有关。     

青藏高原冈底斯带中部朱诺地区林子宗群火山岩锆石U-Pb年龄和地球化学特征

林子宗火山岩是发育在青藏高原南部冈底斯带的古近纪火山岩, 被认为代表了新特提斯洋俯冲消减结束过渡到印度—亚洲大陆碰撞过程的产物, 其确切的时代对于限制印度—亚洲大陆的碰撞时限具有重要意义.对冈底斯带中部朱诺地区的林子宗火山岩进行了系统的LA-ICP-MS锆石U-Pb年代学、元素和Sr-Nd同位素地球化学研究, 获得的林子宗火山岩的典中组、年波组和帕那组LA-ICP-MS锆石U-Pb年龄分别为64.8±1.6 Ma、59.7±1.8 Ma和48.9±0.8 Ma.元素和同位素地球化学结果表明, 朱诺地区各组特征与区域上特征相似, 其中典中组和年波组火山岩属于钙碱性和高钾钙碱性系列, 具有岛弧火山岩特点; 帕那组出现大量的钾玄岩, 属于同碰撞火山岩.证明前人提出的雅鲁藏布江地区洋盆闭合和印度—亚洲大陆碰撞开始时间为50 Ma左右的观点.      

西藏罗布真矿区林子宗群火山岩锆石U-Pb年龄、地球化学特征及其地质意义

罗布真铅锌多金属矿床位于冈底斯火山-岩浆活动带的中南部,矿区内广泛发育林子宗群火山岩,岩性为英安岩和流纹质晶屑凝灰岩。LA-ICP-MS锆石U-Pb定年结果显示,罗布真矿区内林子宗群英安岩的成岩年龄为(49.14±0.86) Ma,应属于帕那组火山岩地层,并非前人所认为的典中组。岩石具有高K、低Ti的特征,属于高钾钙碱系列;相对富集Rb、Th、U、K、Zr、Hf等元素,亏损Nb、Ta、P、Ti、Sr等元素,且轻重稀土分馏明显,具有明显的负铕(δEu=0.50~0.65)异常。在印度-亚洲大陆汇聚的过程中,新特提斯洋向欧亚大陆俯冲,约50 Ma发生了大规模的火山、岩浆作用,同时岩浆-热液成矿作用也进入高峰期,林子宗群火山岩的形成时代与该时代一致,形成于陆陆碰撞形成的板内环境。罗布真矿区林子宗群火山岩年龄的厘定,揭示了冈底斯带林子宗群帕那组火山岩具有赋矿潜力,对认识该地区林子宗群火山岩与热液脉型铅锌多金属矿化的关系具有指导意义。     

藏南米拉山地区林子宗火山岩LA-ICP-MS锆石U-Pb年龄和起源

大规模的林子宗火山岩呈带状展布于拉萨地体中南部地区,记录了新特提斯洋壳晚期俯冲和随后印度—欧亚大陆碰撞的重要信息,因而受到广泛关注,但迄今对区域性的林子宗火山岩仍然缺乏可靠的年龄数据约束。为此,本文对南部拉萨地体东部米拉山地区林子宗火山岩中的含角砾流纹岩样品进行了LA-ICP-MS锆石U-Pb定年和Hf同位素、全岩地球化学测试。获得了60.1±0.9Ma的锆石206Pb/238U年龄,与林周盆地典中组底部安山质岩浆活动的时代相当。测试样品以亏损中稀土元素和低的重稀土元素丰度为特征,锆石εHf(t)为正值(+8.5~+18.8),可能来源于较厚新生下地壳物质在角闪岩相/榴辉岩相过渡条件下的部分熔融。目前还很难论证呈带状分布的约60Ma林子宗火山岩稀土元素含量差异的构造含义。     

冈底斯西段麻木早白垩世岩浆岩岩石成因及地质意义

青藏高原冈底斯带发育有大量的岩浆岩,本文对中拉萨地块西段南缘革吉县西南麻木地区的花岗斑岩和流纹质晶屑凝灰岩进行了详细的岩石学、岩石地球化学、锆石微量元素和锆石Hf同位素研究,综合讨论了其岩浆成因及源区深部过程。麻木研究区内的花岗斑岩和流纹质晶屑凝灰岩属于早白垩世同期岩浆作用的产物,均属于钾玄质岩石,富集大离子亲石元素和轻稀土元素,亏损高场强元素和Eu,具有较高负值的εHf(t)值,分别为-9.57～-3.43和-8.79～-4.80,以及较古老的Hf同位素地壳模式年龄t_DM2,分别为1 774～1 388 Ma和1 727～1 477 Ma。研究区早白垩世岩浆岩源于古老下地壳物质的重熔,并有少量地幔物质的加入,经历了岩浆混合后角闪石、长石和黑云母等矿物的分离结晶,最终形成了花岗斑岩和流纹质晶屑凝灰岩。结合前人和本文的研究认为研究区早白垩世岩浆作用的主要诱发机制可能为南向俯冲的班公湖-怒江洋板片回转。     

冈底斯中段格达地区典中组火山岩锆石U-Pb年龄和地球化学特征

青藏高原南部广泛发育的林子宗火山岩蕴涵着新特提斯洋俯冲与印度—亚洲大陆碰撞过程的地质信息。为探讨冈底斯中段格达地区典中组火山岩的形成时代、岩浆源区及构造环境等特征,对其开展了LA-ICP-MS锆石U-Pb同位素测年和地球化学特征研究。研究结果表明: 该地区典中组火山岩锆石U-Pb年龄为(61.6±1.0) Ma; 典中组火山岩相对富集LILE和LREE、亏损HFSE,具典型岛弧火山岩的特征; 岩浆源区主要来源于地壳物质部分熔融,是俯冲岛弧构造环境下新特提斯洋北向俯冲消减过程的产物。     

Purification of the Beonite from Shangtianti,Henan Province,China

Bentonites consisting mainly of montmorillonite are widely utilized in various applications. However, natural bentonites contain many kinds of impurities such as quartz, cristobalite, feldspar, zeolite, calcite etc., which can decrease the performance of bentonite. Furthermore, quartz and cristobalite are carcinogenic. Therefore purification of bentonite is critical to its applications. Among the impurities in bentonite, cristobalite is the most difficult one to get rid of because of its tiny particle size and aggregation state.     

Relative geobarometry from high-pressure rocks of quartzofeldspathic composition from the Sesia Zone,Western Alps,Italy

In the Sesia Zone of the Western Alps, Italy, early Alpine blueschist to eclogite facies metamorphism of rocks of quartzofeldspathic composition has produced the same high-pressure assemblage of; quartz, Na-pyroxene, Na-amphibole, paragonite, phengite, zoisite, garnet, magnetite, sphene and Fe-sulphide (=the QFS assemblage) over an area (> 150 km². Relative gradients in pressure and temperature over this region are reflected in the variations in mineral chemistries of the individual phases of the quartzofeldspathic assemblage through continuous reactions. Mineralogical discontinuities do not occur in the QFS assemblage of this region. Increases in the Jadeite content of the pyroxenes (X _{Jd 0.48} to X _{Jd 0.93}) and in the glaucophane content of the amphiboles (X _{Gl 0.89} to X _{Gl 0.96}) occur from the southwest to the northeast of the region studied. Analysis of coexisting garnets and pyroxenes indicate that the compositional variation of amphiboles and pyroxenes is associated with a decrease in the grossular component of the coexisting garnet. Zoned pyroxenes and garnets, together with the regional trends in mineral chemistries suggest that the evolution of the QFS assemblage with increasing pressure may be modelled by pressure-sensitive continuous reactions in which amphibole, zoisite and the more jadeitic pyroxene constitute the high-pressure assemblage. Chemographic constraints permit the positioning in pressure/temperature space of the compositional isopleths of those model continuous reactions involving these phases which meet the textural and chemical criteria observed in the natural assemblages. The low dP/dT slope (–20 bars/° C) of these isopleths causes the continuous reactions to be useful for geobarometric calculations at pressures above the absolute breakdown of albite to jadeite plus quartz. In addition the pseudobinary loops for the other continuous reactions which are potentially useful geobarometers and involve either the NaAlCa_–1Mg_–1 exchange or the MgCa_–1 exchange are calculated. Comparison of mineral chemistries with the isopleths yields a relative barometric scheme for the localities studied. With these barometric observations, it is possible to show that the P-T path which the Sesia body travelled towards the final recorded state was one of increasing pressure. Other blueschist and eclogite occurrences from Syros and Sifnos which contain rocks of quartzofeldspathic composition are also examined.     

河北大庙Fe-Ti-P矿床中铁钛磷灰岩的成因: 来自磷灰石的证据

铁钛磷灰岩仅由磷灰石和铁钛氧化物组成,常赋存于岩体型斜长岩中,成因上有不混溶和分异堆晶两种不同的认识。本文从磷灰石角度讨论河北大庙铁钛磷灰岩的形成机制。大庙铁钛磷灰岩常产出于浸染状Fe—P矿体内部,有时与块状铁矿石交互出现形成韵律条带状矿石,为岩浆结晶分异的产物。铁钛磷灰岩中磷灰石呈浑圆状,含量变化于15％-34％。铁钛磷灰岩的全岩和磷灰石微量元素分析显示,磷灰石比全岩相对富集稀土元素达2．96—6．93倍,但两者的配分型式基本平行。质量平衡计算（Rocl／F）的结果表明,铁钛磷灰岩中几乎100％的稀土元素赋存于磷灰石中。综合上述特征,反映磷灰石为结晶分离的堆晶矿物,铁钛磷灰岩应为堆晶成因。因为如果磷灰石结晶于铁钛磷灰岩不混溶熔体,它的稀土元素分配系数也不会变化达2．3倍（变化于2．96—6．93）。计算出该磷灰石的母岩浆稀土元素组成,与浸染状Fe．P矿石最为相似,结合它与铁钛磷灰岩之间紧密共生的野外特征以及相似的全岩及磷灰石稀土元素配分型式,认为磷灰石最可能是在浸染状Fe．P矿浆中,经结晶分离作用形成铁钛磷灰岩。     

Metamorphic P-T paths from calcic pelitic schists from the Strafford Dome, Vermont, USA

Metamorphism of the Gile Mountain Formation and Waits River Formation in the Strafford Dome and Townshend-Brownington Syncline in east-central Vermont records two nappe-style events, D1 and D2, followed by doming. D1 formed a muscovite + biotite ± ilmenite schistosity subparallel to compositional layering, SO, and was followed by heating to garnet grade. The temperature and pressure at the end of D1 are estimated to be c . 450 C and 6-8 kbar. D2 variably crenulated and folded S1 during a nearly isothermal pressure increase of 1-2 kbar, calculated from compositions of garnet, which have inclusions trails with progressive crenulation and rotation of the S1 fabric. Similar P-T paths are computed for most of the area, suggesting that the later schistosity developed during emplacement of a regional nappe 3-6 km thick. There is a general lack of D3 (dome-stage) microstructures.
Near the Strafford-Willoughby Arch, staurolite and kyanite overgrew S2 in pelites, and plagioclase with increasing X _An overgrew S2 in calcic pelites, reflecting post-D2 heating to a maximum of 550-600 C. Metamorphic pressures at the end of D2 are fairly constant on the west side of the dome, indicating minor dome-stage uplift. In contrast, pressures at the thermal peak of metamorphism decrease by more than 4 kbar east of the dome. The observed pattern of isotherms and isobars is mainly the result of post-metamorphic, differential uplift and unroofing.
Finally, a minor, retrograde metamorphism produced the assemblage albite + epidote + K-feldspar + muscovite + chlorite, with grade increasing east toward the Connecticut River.     

A New Sauropod, Gongxianosaurus, from the Lower Jurassic of Sichuan, China

The paper describes an early and primitive sauropod dinosaur, Gongxianosaurus shibeiensis (gen. et sp. nov.), from the Dongyuemiao Member of the Lower Jurassic Ziliujing Formation in Shibei Township, Gongxian County, Sichuan Province, China, which is one of the 5 dinosaur fossils discovered in Gongxian in 1997. Except the skull which is incomplete, the fossils are well preserved. It has some features of both sauropods and prosauropods. It is an intermediate type in the evolution of dinosaurs from prosauropods to sauropods and provides materials for the study of the origin and evolution of the sauropod dinosaur fauna. The discovery of this new sauropod furnishes a way for the stratigraphic correlation between the Early Jurassic Ziliujing Formation in the Sichuan basin and the Lower Jurassic Lufeng Formation in the Central Yunnan basin.     

Nickenichite,a new arsenate from the Eifel,Germany

Summary Nickenichite is a new mineral found close to the village of Nickenich at the Nickenicher Sattel, Eifel, Germany. The chemical composition is Na_xCa_yCu_z(Mg, Fe, Al)₃(AsO₄)3, x 0.8, y 0.4, 0.4 and was derived by means of electron microprobe analyses and by a crystal structure investigation. The latter was determined from single-crystal X-ray data:a = 11.882(4)Å,b = 12.760(4)Å,c = 6.647(2)Å, = 112.81(2)°, space group C2/c,Z = 4;R = 0.053 andR _w = 0.033 from 984 observed data and 102 free variables. Nickenichite is structurally related to the minerals o'danielite and johillerite. The two crystallographically different octahedrally coordinated cation positionsMe = (Mg, Fe, Al) have averageMe-O distances of 2.108 Å and 2.056 Å, octahedra share edges to form zig-zag chains in ; the chains are interconnected by AsO₄ tetrahedra. In addition the compound is characterized by partially occupied Na^[4+4], Ca^[6+2] and Cu^[4] positions.

---

Nickenichit, ein neues Arsenat aus der Eifel, Deutschland

Zusammenfassung Nickenichit ist ein neues Mineral, das nahe dem Ort Nickenich, am Nickenicher Sattel, Eifel, Deutschland, gefunden wurde. Die chemische Formel ist Na_xCa_yCu_z, (Mg, Fe, Al)₃(AsO₄)₃, x 0,8, y 0,4, z 0,4 und wurde mittels Elektronenstrahl-Mikrosondenanalysen und einer Kristallstrukturuntersuchung ermittelt. Letztere wurde mit Einkristall-Röntgendaten durchgeführt:a = 11,882(4) Å,b = 12,760(4) Å,c = 6,647(2) Å, = 112,81(2)°, Raumgruppe C2/c,Z = 4;R = 0,053 undR _w = 0,033 für 984 beobachtete Daten und 102 freie Variable. Nickenichit zeigt enge strukturelle Beziehungen zu den Mineralen O'Danielit und Johillerit. Die zwei kristallographisch verschiedenen oktaedrisch koordinierten KationpositionenMe = (Mg, Fe, Al) haben mittlereMe-O-Abstände von 2,108 Å und 2,056 Å, die Oktaeder werden über Kanten zu zick-zack-artigen Ketten in verknüpft, diese werden untereinander über AsO₄-Tetraeder vernetzt. Des weiteren ist die Verbindung durch partiell besetzte Na^[4+4]-, Ca^[6+2]- und Cu^[4]-Positionen charakterisiert.

---

---

With 2 Figures     

Eclogites from the Obnazhennaya Kimberlite Pipe,Yakutia, Russia

Mineralogy and petrography of six eelogite xenoliths from the Obnazhennaya kimberlite pipe ar e described. Based upon modal and mineral compositions, these eclogites can be divided into Group A (five samples) and Group B (one sample), as per Coleman et al. (1965) and Shervais et al. (1988). Group-A eclogites are orthopyroxene-bearing, and their constituent minerals have high Mg# and Cr₂O₃ content. The clinopyroxenes in this type of eelogite have low jadeite component. The geochemical features of Group-A eclogites are similar to garnet pyroxenite, and e believed to be the product of high-pressure fractionates from an alkaline basaltic melt in thear upper mantle. Group-B eelogite (0-82/91) contains higher Al₂O₃ and FeO and lower MgO and Cr₂O₃; its composition is similar to a high-aluminum basalt or gabbro. This eelogite could have crystallized under high pressure in the upper mantle from a basaltic melt, without significant fractionation. Alternatively, it also could be the relict of subducted oceanic crust. However, no evidence exists at present that definitively indicates a crustal origin for this Group-B eelogite xenolith.     

Harkerite from the Alban Hills,Italy

Harkerite, found in metamorphic ejecta of the Alban Hills associated with cuspidine, grossular, phlogopite, vesuvian, biotite, and minor amounts of diopside, aegirinaugite, leucite, magnetite and calcito, shows cubic Laue symmetry m3m, possible space groups Fm3m, F432, F43m, a₀ = 14.82 Å.On the basis of isomorphous replacements suggested by the crystal structure analysis, chemical data may be represented by the formula: Ca₄₈Mg₁₆(AlSi₄O₁₆)₄(BO₃)₁₂(CO₃)₂₀ · 4H₂O. Refractive index n_D = 1.6490.The relations between harkerite from Albano, harkerite from Skye and other known harkerites and sakhaites are discussed.     

Surge dynamics of Aavatsmarkbreen,Svalbard, inferred from the geomorphological record

This study investigated the surge dynamics of Aavatsmarkbreen, a glacier in Svalbard and its geomorphological impact based on remote sensing data and field observations. The main objective was to analyse and classify subglacial and supraglacial landforms in the context of glacial deformation and basal sliding over a thin layer of thawed, water‐saturated deposits. The study also focused on the geomorphological evidence of surge‐related sub‐ and supraglacial crevassing and glacier front fracturing. From 2006 to 2013, the average recession of Aavatsmarkbreen was 363 m (52 m a⁻¹). A subsequent surge during 2013–2015 resulted in a substantial advance of the glacier front of over 1 km and an increase in its surface area of more than 2 km². The surface of Aavatsmarkbreen was severely fractured. Significant ice‐flow acceleration was noted whereby the highest surface velocity reached 4.9 m day⁻¹. The ephemeral water‐escape structures and mini‐flutings on the fine‐grained till surface that formed during the surge are indicative of high subglacial pore‐water pressure and enhanced basal sliding. Two genetic types of clast pavements occur in the marginal zone of Aavatsmarkbreen. The results of this study will help to constrain glaciological and geomorphological processes involved in surge phenomena. Understanding the scale and effects of these processes provides insight into the behaviour of fast‐flowing glaciers and ice streams and reveals their relationships with external factors.     

河北矾山杂岩体中单斜辉石的研究

河北矾山杂岩体属于二氧化硅不饱和的超钾质碱性-过碱性岩浆系列,由单斜辉石岩、辉石正长岩和碱长正长岩等不同类型岩石组成。各类型岩石主要组成矿物为单斜辉石、黑云母、石榴石和正长石。本文利用电子探针对单斜辉石进行了详细研究,发现所有单斜辉石属于高钙透辉石,随着岩浆的演化,主要表现为Fe²⁺对Mg²⁺的替代关系,结晶趋势为透辉石→钙铁辉石,这揭示矾山杂岩体岩浆体系的特点是高温、中等大小的氧逸度、贫硅、富碱（尤其是钾）。辉石中的Al^IV含量取决于岩浆的硅饱和度,硅越不饱和,Al^IV含量越高;Al^VI含量则与体系中的Al含量呈正相关关系。由Al对Si的替代引起的电荷不平衡主要由八面体位置的Fe³⁺来补偿,其次为少量的Ti⁴⁺和更少量的Al³⁺。体系中的Ti含量与体系的温度呈正相关关系,而Na含量则与辉石中的Ti和Fe³⁺含量成正相关关系。不同类型岩石中单斜辉石从核部到边部随着Mg^#的降低,Al、Ti含量呈现不同的演化趋势,这是因为它们于岩浆演化的不同阶段开始结晶,经历了不同的岩浆演化史。碱性岩中高钙辉石的出现和成分环带的普遍发育是由岩浆的贫硅富钾特征决定的。单斜辉石的成分不仅受控于结晶时的温度、压力条件,也受控于岩浆的总成分及其变异。