与火山活动有关的热水沉积锰矿——以贵州二叠纪锰矿为例

贵州产于中二叠统茅口组第二段的锰矿、铁锰矿、含锰菱铁矿,均分布在茅口晚期黔中台沟内。东部遵义一带为碳酸盐锰矿床,西部宣威—水城一带主要为锰帽型次生氧化锰矿床。笔者目的在于探讨黔中台沟锰矿成矿条件,以期扩大找矿远景。研究表明,区内各类锰矿石和矿胚层岩石都是在热水中生成的,证据是：①有大量热水沉积的标志性矿物;②常量、微量元素及稀土元素均具有热水沉积的特征;③流体包裹体均一温度达90～275℃等。锰矿的形成可能与峨眉地幔柱演化的中晚期阶段密切相关。茅口期玄武岩的喷出活动,有利于黔中台沟内硅灰泥锰质组合的形成。东部遵义一带的锰矿,被严格限制在热水喷发形成的硅质角砾岩分布区内,结合其他特征等,说明该区锰矿形成可能与强烈的热水活动有关。     

西藏羌塘中部独泉沟地区发现青藏高原首例富锰矿

独泉沟锰矿是青藏高原发现的首例富锰矿,成矿元素分析结果表明,矿石中Mn平均品位为41.95%,达到了Ⅰ级富锰矿石的品位标准。该锰矿体主要呈层状、似层状产出于上二叠统—下三叠统天泉山组复理石碎屑岩内;矿体地表部分为残坡积,残坡积范围宽20~30m,长约50m。根据产状及结构构造的差异,将研究区锰矿体分为层状锰矿体和脉状锰矿体,二者的矿石矿物皆是硬锰矿,脉石矿物以石英为主。初步研究认为,独泉沟锰矿是海相热水沉积型锰矿。作为青藏高原地区发现的首例富锰矿,独泉沟锰矿的发现填补了区内锰矿找矿工作的空白,对其成因的研究能为今后的找矿工作提供重要的线索和依据,在区域找矿方面具有一定的指示意义。     

Nonequilibrium thermodynamic model of manganese carbonate oxidation

Manganese carbonate can be converted to many kinds of manganese oxides when it is aerated in air and oxygen.Pure manganese carbonate can be changed into Mn3O4 and γ-MnOOH,and manganese carbonate ore can be converted to MnO2 under the air-aerating and oxygen-aerating circumstances.The oxidation process of manganese carbonate is a changing process of mineral association,and is also a converting process of valence of manganese itself.Not only equilibrium stat,but also nonequilibrium state are involved in this whole process,This process is an irreversible heterogeneous complex reaction,and oberys the nonequilibrium thermodynamic model,The oxidation rate of manganese cabonate is controlled by many factors,especially nonmanganese metallic ions which play an important role in the oxidation process of manganese carbonate.     

Effect of manganese tailings on capsicum growth

The impact of Mn in manganese waste rocks and electrolytic manganese residues on the growth of capsicum was studied via pot experiments. The product yield and manganese nutrition were mainly evaluated in this study. The results showed that the ingredients of manganese tailings were beneficial to the increase of chlorophyll contents in the capsicum. The chlorophyll contents were raised by 12.6%–28.7%, 7.18%–12.1% and 9.70%–13.7%, respectively, corresponding to the idiophase of flower bud, the initial florescence and the fruit expansion stage. Moreover, the additive significantly improved capsicum’s economic features, such as its height, stem width, fruit length and weight and the yield of fresh fruit. These parameters were raised by 11.9%–25%, 18.6%–25.6%, 20.7%–35.4%, 10.4%–27.6% and 11.4%–65.7%, respectively. At the meantime, the manganese taken up by stems and leaves of the capsicum also increased by 11.7%–23.4% and 33.9%–62.8%, respectively. The manganese which remained in the soil was less than that in the original soil due to plant absorption and rainfall loss in pot experiments. It is concluded that both manganese residues and the mixture of manganese waste rock and manganese residue could indeed be made full use of as a fertilizer which can provide Mn nutrition.     

湘西北锰矿床成矿模式研究——以湖南花垣民乐锰矿床为例

本文以湖南花垣民乐锰矿床为例,研究了矿床中火山碎屑物质的分布及特征,用硫同位素氧、碳同位素等成因地球化学特征阐明该区裂陷盆槽盆或地堑盆地中海底火山喷发对锰矿形成的重要意义,并提出了成矿模式,认为湘西北锰矿床属离火山喷发中心较远的海底火山喷发-沉积锰矿床。     

湖南省沉积型锰矿地质环境及成矿作用

湖南省沉积型锰成矿时代跨度大,最早由早元古代板溪群马底驿期至早二叠世孤峰期。其中,早南华纪大塘坡期、中奥陶世烟溪期及中二叠世孤峰期为三个最主要成锰集中期,并且大体呈现出朝东南方向成矿时代变新的趋势。成锰沉积盆地是锰矿床就位的重要场所,相应的岩相古地理环境为锰成矿创造了有利条件,即相对缺氧的、滞流的安静环境。这种环境在诸多古地理环境中都可以形成,导致了锰成矿岩相古地理环境的多样性,如浅海陆棚相、次深海棚缘盆地相、次深海台缘斜坡相及陆表次深海海盆相。三个主要成锰期锰成矿作用具有统一性,成矿作用与地壳拉张、海侵事件、缺氧事件等区域性重大地质事件关联密切。     

Evolution of Yanliao aulacogen in the Paleo-Mesoproterozoic and its control on manganese deposit

It is found that the bottom of Sangshu'an subgroup,which belongs to the Mesoproterozoic Gaoyuzhuang Formation located at the Yanliao aulacogen,is rich in manganese. Although there are still different viewpoints on the origin of manganese and the formation environment of manganese deposits,most scholars believe that the manganese is closely related with the extensive rifting background of the Yanliao aulacogen. In this paper,based on the analysis of exploration data on many manganese ores,the Qinjiayu manganese deposit located at Qianxi belonging to the Yanliao aulacogen,is selected. The manganese ore characteristics,ore types,and element geochemistry are analyzed. The results show that manganese mainly comes from submarine hydrothermal fluids. By analyzing the relationship between the distribution of main manganese deposits and the tectonic faults in the Yanliao aulacogen,it is found that the manganese ore of Gaoyuzhuang formation mainly concentrates at the intersections of the northeast-trending main fault and the northwest-trending transverse fault,and the relatively blocked,deep-water stagnant environment surrounded by faults,where the ore layers are thick and show a relatively high grade. It shows that the structure of the Yanliao aulacogen plays an important role in controlling the formation of Gaoyuzhuang manganese deposits. The syn-depositional faults act as channels for hydrothermal activity,providing a major source of minerals for the manganese-forming basins.     

甘孜—理塘结合带锰结核的发现及其地质意义

在甘孜—理塘结合带内理塘县中木拉乡附近发现锰结核。通过地质填图和综合研究,该锰结核产于结合带内瓦能蛇绿混杂岩组中的黑色粉砂质板岩中。其沉积层序为玄武岩→硅质岩→含锰结核粉砂质板岩。锰结核主量元素具有高Mn、低Fe、Si、Ca的特点,其中Mn含量为42.19%,高出大洋锰结核平均值1.83倍,Mn/Fe值较高,达8.1。锰结核中除Cr高于大洋锰结核平均值2～7倍外,多数微量元素低于大洋锰结核平均值。稀土元素具有较明显的Ce正异常,稀土总量、轻重稀土分异程度、Eu异常特征与混杂岩中的砂岩、硅质岩近似,而与玄武岩差别较大。该锰结核产出于大陆边缘构造环境,火山活动微弱,代表甘孜—理塘洋扩张到最大程度时的沉积。其时甘孜—理塘洋规模仍是有限的。     

燕辽坳拉槽古—中元古代裂谷盆地演化及其对锰矿沉积的控制作用*

燕辽坳拉槽中元古界高于庄组桑树鞍亚组底部为锰富集层段,虽然对于锰质来源、锰矿成因及形成环境存在认识分歧,但多数学者均认为高于庄组锰矿的形成与燕辽坳拉槽的盆地裂谷背景有着密不可分的联系。在搜集前人锰矿勘查资料的基础上,重点对典型锰矿床——迁西秦家峪锰矿进行了矿床地质特征、矿石类型及元素地球化学分析,结果显示其锰质主要来源于海底热液。通过分析主要锰矿点分布与燕辽裂谷盆地主要断裂之间的关系,发现在裂谷盆地内北东向主断裂与北西向传递断裂的交汇处,或被断裂所围限的闭塞、深水滞流环境,是高于庄组锰矿形成的最有利部位,矿层厚度大,品位相对较高。该研究表明燕辽坳拉槽裂谷盆地结构对高于庄组锰矿的形成具有重要的控制作用,且同沉积断裂作为热液活动的通道,为成锰盆地提供了主要的矿质来源。     

湖南省沉积型锰矿床地球化学特征

湖南省锰矿资源丰富,类型多样,沉积型锰矿是最重要的类型,主要沉积成锰期集中在早南华世大塘坡期、中奥陶世烟溪期及晚二叠世孤峰期。通过对三个主要成锰期代表性锰矿石电子探针分析显示,三个主要成锰期所成锰矿床,矿石组分类似,组成矿石的锰矿物主要为锰的碳酸盐,包括菱锰矿、钙菱锰矿、镁菱锰矿、锰白云石、锰方解石等。三个主要成锰期代表性锰矿石及地层稀土元素地球化学标准化参数与配分模式显示,各成矿期含锰地层与锰矿石之间无显著差异,暗示了它们是相似的沉积环境下形成的产物,为正常沉积与热水沉积的复合。一方面,各成矿期岩、矿石稀土元素总量中等偏高,表现为正常沉积物的稀土元素特征。另一方面,在北美页岩标准化配分曲线上,呈现出水平或重稀土相对富集的左倾配分曲线,Ce的负异常,又是典型热水沉积成因呈现出的稀土元素地球化学特征。δCe异常特征,指示了成锰作用处于波动的缺氧还原/氧化沉积环境。     

中国锰业存在的主要问题及对策建议

随着中国经济的发展,我国锰矿消费增长迅速,进口锰矿石量快速攀升,对外依存度已从2010年的47%攀升到2019年的82%,呈逐年上升的趋势。本文在系统收集并总结我国锰矿资源及开发利用现状、资源潜力及供需现状等资料的基础上,依据钢铁产量与锰矿消费之间的线性关系,对未来我国锰矿需求进行了预测,并对影响我国锰业安全的主要问题进行了梳理。针对存在的问题,提出了建立大中型锰矿资源基地、提高锰矿资源查明率、优化锰产业结构、降低锰资源消费、加大"走出去"力度,以及建立国家资源储备体系等对策建议,以此提高我国锰业安全保障程度,缓解我国锰矿资源供应不足的问题。在此基础上,在我国主要锰矿矿集区内,划分了重点勘查区,并提出了锰矿勘查工作部署建议。     

磁化率测量在沉积锰矿床中的应用

为研究磁化率在沉积锰矿床中的应用,对广西下雷锰矿床的钻孔岩心进行了磁化率测量试验。结果表明,含锰岩系中矿层磁化率与围岩磁化率明显不同,通常碳酸锰矿磁化率值比围岩要高出1~2个数量级,而围岩中硅质岩、灰岩、泥岩的磁化率无明显差异。磁化率可作为野外快速判别含锰岩系的代用指标。通过讨论下雷原生碳酸锰矿的磁化率异常,认为碳酸盐矿物磁性很低,对磁化率的贡献极小,磁化率异常高值指示与其伴生的铁质矿物;碳酸锰矿中含有磁性矿物,其磁性强弱决定了矿层磁化率的大小;黏土矿物中的绿泥石可吸附含铁的强磁性物质,绿泥石及其含量是影响碳酸锰矿磁化率的一个重要因素。     

四川观音梁子锰矿床地质特征及找矿意义

观音梁子锰矿赋存于寒武系邱家河组中,是龙门山中段在邱家河组中新发现的工业锰矿床。通过矿区勘探工作及室内观察、测试等手段,对矿区成矿地质背景、含锰岩系、矿体及矿石矿物特征、矿床成因、找矿前景等方面进行了初步总结分析。研究发现,观音梁子锰矿为典型的沉积型锰矿床,矿体呈层状产于邱家河组三段硅质白云岩中,延伸较稳定,严格受层位的控制;矿石类型为菱锰矿型,主要由菱锰矿、硫锰矿、水锰矿等组成。早寒武世,龙门山地区由于地壳拉张裂陷形成深海盆地,在还原环境下,锰元素与碳酸根直接结合形成碳酸锰矿物,稳定的物源、深海还原环境为锰矿富集提供了有利的成矿环境。观音梁子锰矿的发现,证实了龙门山北段邱家河组含锰层位的存在,为龙门山中段的锰矿找矿提供了契机,同时显示了寒武系邱家河组具有良好的找锰远景。     

Origin of high manganese concentrations in coal mine drainage, eastern Tennessee

The origin of high dissolved manganese concentrations in slightly acidic mine runoff from a surface mine operated by the Cumberland Coal Company in eastern Tennessee was investigated. Mineralogical and chemical analyses were performed on 31 samples of sandstone, shale, coal, and mudstone from the mine to identify the sources and stratigraphic distribution of high extractable manganese contents in the spoil materials. The samples were analyzed for their bulk mineral content by X-ray diffraction, net acid-base potential, and reaction to 2 or 4 chemical extraction procedures. A limited number of samples were analyzed for petrographic characteristics, clay mineral composition by X-ray diffraction, and mineral compositions by electron microprobe. Analysis of the data and consideration of the geochemical conditions at the mine were used to identify probable sources for the high extractable manganese contents.The results indicate 2 prominent, independent sources of extractable manganese. The first source is exchangeable manganese on clay minerals (mainly illite + muscovite and chlorite) and is concentrated in shale and mudstone rock types. The second and more significant source is manganese in siderite concretions and cement, mainly in shale and mudstone. Comparison to other coal-bearing strata indicates that manganese-rich siderite is common in fresh- to brackish-water subaqueous sediments that overlie coal. This is especially the case for coals formed in wet, tropical environments.Ratios of manganese to calcium and magnesium in mine runoff suggest that manganese from siderite is the major cause of the high dissolved manganese contents. A conceptual model is developed to explain the high manganese contents of the mine runoff. Oxidation of pyrite creates mildly acidic waters that are subsequently partially neutralized by reaction with impure siderite. Solubilized manganese remains dissolved in the slightly acidic runoff water, whereas dissolved iron precipitates as ferric hydroxide or goethite. Consideration of data from other coal mining regions suggests that similar reactions involving impure siderite may be responsible for high manganese concentrations in acidic to slightly acidic mine runoff. Geochemical reaction path modeling of pyrite and impure siderite with rainwater illustrate how resulting water compositions may vary depending on pyrite to siderite ratios in spoil materials. Spoil water compositions from the Cumberland mine are largely consistent with reaction of pyrite and impure siderite in proportions observed in the sediments; however, deviations may be explained by minor mixing with waters that reacted only with impure siderite or clay mineral exchange reactions.     

珠江三角洲地区地下水锰的分布特征及其成因

为了解珠江三角洲地区地下水中锰的含量及其成因,笔者采集并分析了352组地下水样和13组地表水样。结果表明:珠江三角洲地区地下水的锰含量在未检出至8.32mg/L之间,平均浓度为0.34mg/L,超标率达49.4%。在该区9个地级市范围都存在地下水锰超标现象。区内地下水的锰含量与总溶解固体(TDS)、化学需氧量(COD)以及HCO3ˉ都呈极显著的正相关关系,而与Eh呈极显著的负相关关系。珠江三角洲地区地下水中锰含量的分布与该地区的工业化程度以及所处的补、径、排条件密切相关。影响该地区地下水锰含量分布的因素主要有氧化还原环境、酸碱条件、地下水的总溶解固体、上覆盖层性质、地下水径流条件以及含水层介质等。     

滇东南地区斗南沉积型锰矿床矿物相变化及沉积模式

斗南锰矿是滇东南地区大型的沉积型锰矿床,对其沉积成因的研究可反映滇东南地区沉积型锰矿床的成矿模式。笔者对采自斗南锰矿床的条带状锰矿石样品,进行了系统的锰矿石物相分析和红外光谱分析。通过对锰矿石中锰矿类型与氧化还原界面关系的探讨,提出了由海平面变化引起的氧化还原界面波动所控制的沉积型锰矿的成矿模式。     

The control of cathodoluminescence in dolomite by iron and manganese

Variations in the cathodoluminescent properties of carbonates are usually attributed to differing proportions of manganese (Mn²⁺) as the most important activator, and iron (Fe²⁺) as the main inhibitor of luminescence. Interactions between manganese and iron concentrations and the luminescent properties of dolomite are demonstrated by petrographic and chemical analyses of 86 samples of dolomite representing a range of depositional environments and ages (Cambrian to Cretaceous) and a wide geographical distribution (North America and Europe). Iron and manganese are positively correlated in the dolomites, with the former showing a greater range of variation. Very small amounts of manganese are sufficient to activate the luminescence and as little as 100 ppm Mn²⁺ is present in highly luminescing samples. The intensity of luminescence is not proportional to the manganese concentration. Iron begins to quench luminescence as its concentration reaches 10,000 ppm. Above that level, luminescence is rapidly lost and total extinction occurs among samples containing more than 15,000 ppm Fe²⁺, regardless of the manganese concentration.     

滇东南地区石炭系锰矿找矿新发现

锰矿是我国重要的战略紧缺资源。本文通过对云南省大平-鸣就地区矿产地质调查研究,首次发现在石炭系顺甸河组中赋存有工业锰矿。通过对矿区的岩相古地理、地质特征、地球化学特征的研究分析,表明该锰矿是在贫氧的环境下,形成于古陆边缘的浅海,属于台地边缘浅滩相的产物。该发现和研究为今后在该层位中寻找锰矿提供了重要线索和依据,为锰矿找矿工作提供了新方向。     

云南省开远地区沉积型锰矿找矿前景分析

云南省开远地区位于南盘江克拉通盆地内,是滇东南地区传统的优质富锰矿产区。通过对云南省开远地区沉积型锰矿地质特征以及区内典型锰矿床研究,结合研究区遥感矿化蚀变信息特征、水系沉积物地球化学特征,系统总结了区内含锰岩系法郎组的成矿特征及找矿标志,在研究区内圈出了两个锰矿找矿远景区,通过地表山地工程验证,取得了较好的找矿成果,为在区内寻找锰矿指明了方向。     

Contributions to the mineralogy of authigenic manganese phases from marine manganese deposits

The formation of authigenic manganese minerals and ores in the pelagic regions of the ocean is related to oxidation of Mn²⁺ extracted from basalts and other rocks with heated seawater. For littoral parts of the ocean and lakes mobilization of Mn²⁺ and Fe²⁺ is admitted finding its way to the bottom sediments (along with the organic substances) from land in the form of Mn⁴⁺. The main manganese mineral of oceanic and continental basins is vernadite. Its deposition is considered a result of the activity of microorganisms.