Geodynamic Indications on Igneous Rocks of Transitory Geologic Setting during the Late Hercynian in North Tarim Basin

Basic and intermediate-acidic igneous rocks were developed during the late Hercynian in North Tarim basin.The geochemistry characteristics of the rocks show that basic volcanic rock has K2O/Na2O = 0.18-0.61 < 1 and falls into a category of basalt of sodium system.The rocks contain enriched large-ion lithophile elements (LILE) (K,Rb,Ba,Th) and high-field strength elements (HFSE) (Nb,Ta,Ti,Zr,P),with the magmatic material from the upper mantle.The intermediate-acidic volcanic rocks have σ = 1.91-2.96 < 3.3,K2O/Na2O =1.25-1.59 > 1,as well as the enriched LILE and depleted HFSE (Nb,Ta,Ti,P),presenting the same trace element compositions and characteristics as in the granitic rocks of South Tianshan Mt.; they are either shoshonitic igneous rocks or high-K calc-alkaline igneous rocks,with a distinct crust-derived component feature.The comprehensive analyses on the characteristics of the trace elements,the graphic tectonic discrimination,and the distribution features of the two types of igneous rocks show that they were formed under different tectonic settings and geodynamic environments:the basalt was formed in the active rifting period when the active mantle upwelling caused the thinning of lithosphere; the intermediateacidic volcanic-intrusive rock was formed in the island arc area of the active continental margin in North Tarim; the formation is associated with the plate subduction during the course of South Tianshan Ocean closure-the subduction of Middle Tianshan Mountain toward the Tarim plate.The basic and intermediate-acidic igneous rocks reveal a tectonic regime of extension-extrusion transition,which is significant in determining the key tectonic revolution period of North Tarim basin.     

内蒙古东北部额尔古纳地区上护林-向阳盆地中生代火山岩LA-ICP-MS锆石U-Pb年龄和地球化学特征

LA-ICP-MS锆石U-Pb测年结果表明,研究区中生代火山岩可分为2期,分别是早白垩世早期（约144Ma）吉祥峰组流纹岩类和早白垩世晚期（约125Ma）上库力组流纹岩类与梅勒图组玄武岩类。早白垩世早期吉祥峰组流纹岩富硅、富碱、富钾（K2O/Na2O〉1）,富集轻稀土元素和Rb、Th、U等元素,亏损重稀土元素、高场强元素（Nb、Ta、Ti）及Sr、P,具有A型流纹岩的特征,暗示其形成于伸展环境。早白垩世晚期火山岩显示双峰式岩石组合特征,基性端元富碱、高钾,富含轻稀土元素和Rb、Ba,亏损重稀土元素和高场强元素（Nb、Ta、Ti、Y）,类似于钾玄质玄武岩,酸性端元显示A型流纹岩的特征。双峰式火山岩组合的存在暗示其形成于陆内拉张的构造环境。结合区域上中生代火山岩的空间分布规律,认为早白垩世早期火山岩的形成与蒙古-鄂霍次克缝合带的演化有关,早白垩世晚期双峰式火山岩的形成与古太平洋板块向欧亚大陆下的俯冲作用相联系。     

内蒙古东北部额尔古纳地区上护林-向阳盆地中生代 火山岩LA-ICP-MS锆石U-Pb年龄和地球化学特征

LA-ICP-MS锆石U-Pb测年结果表明,研究区中生代火山岩可分为2期,分别是早白垩世早期(约144Ma)吉祥峰组流纹岩类和早白垩世晚期(约125Ma)上库力组流纹岩类与梅勒图组玄武岩类。早白垩世早期吉祥峰组流纹岩富硅、富碱、富钾(K2O/Na2O>1),富集轻稀土元素和Rb、Th、U等元素,亏损重稀土元素、高场强元素(Nb、Ta、Ti)及Sr、P,具有A型流纹岩的特征,暗示其形成于伸展环境。早白垩世晚期火山岩显示双峰式岩石组合特征,基性端元富碱、高钾,富含轻稀土元素和Rb、Ba,亏损重稀土元素和高场强元素(Nb、Ta、Ti、Y),类似于钾玄质玄武岩,酸性端元显示A型流纹岩的特征。双峰式火山岩组合的存在暗示其形成于陆内拉张的构造环境。结合区域上中生代火山岩的空间分布规律,认为早白垩世早期火山岩的形成与蒙古-鄂霍次克缝合带的演化有关,早白垩世晚期双峰式火山岩的形成与古太平洋板块向欧亚大陆下的俯冲作用相联系。     

四川攀枝花二叠纪双峰式火山岩地球化学特征及其地质意义

攀枝花二叠纪火山岩发育有玄武岩和粗面岩的基性和碱性两个端元,区域上明显缺失中间过渡类型。玄武岩SiO_2含量处于45.65%~49.32%范围内,粗面岩SiO_2含量介于64.39%~69.17%之间,构成经典的"双峰式"火山岩特征组合。两者均具有富Na、贫K、轻稀土富集、轻重稀土明显分馏的特征。特征微量元素Nb/Ta、Th/Ta、Th/U比值变化相对较小,玄武岩分别为15.16、2.70和4.13,粗面岩分别为15.40、2.55和4.12,显示两者具有相似的地球化学属性。微量元素特征显示,除了Ti和Y等少数高场强元素不协调以外,玄武岩与粗面岩绝大多数微量元素变化规律相似,且Rb、Ce、Y、Nb、Hf、Ta等元素与洋岛玄武岩(OIB)特征一致,说明它们具有地幔柱构造系统下的岩浆属性,岩浆源于石榴石二辉橄榄岩岩石圈地幔的部分熔融。结合前人资料,攀枝花二叠纪双峰式火山岩的厘定,不仅暗示了岩浆形成于拉张的裂谷构造环境,也为西南地区二叠纪峨眉山大火成岩地幔柱成因提供支撑。     

Geochronology,petrogenesis, and tectonic setting of Mesozoic volcanic rocks,southern Manzhouli area,Inner Mongolia

We have undertaken major and trace element analyses of volcanic rocks in Northeast China, as well as U–Pb dating and Hf isotopic analysis of their zircons, in order to determine the petrogenesis and tectonic setting of the volcanics. Mesozoic volcanism in the southern Manzhouli area occurred in two stages: Middle to Late Jurassic (164–147 Ma) and Early Cretaceous (142–123 Ma). The first stage is represented by the Tamulangou, Jixiangfeng, and Qiyimuchang formations. The Jixiangfeng Formation (162–156 Ma) is a rhyolite–trachyte dominated unit that lies between two basalt units, namely the underlying Tamulangou (164–160 Ma) and overlying Qiyimuchang (151–147 Ma) formations. The second igneous stage is dominated by rhyolitic lavas and tuffs of the Shangkuli Formation and basaltic rocks of the Yiliekede Formation, and they yield zircon U–Pb ages of 142–125 and 135–123 Ma, respectively. Basaltic rocks of the Tamulangou and Yiliekede formations have a wide range of MgO contents (1.64–9.59 wt%), but are consistently depleted of Nb and Ta and enriched with incompatible trace elements such as large ion lithophile elements (LILEs) and light rare earth elements (LREEs). Trachytes and rhyolites of the Jixiangfeng and Shangkuli formations are characterized by enrichment in LILEs and LREEs relative to HFSEs and HREEs, and with negative Nb, Ta, P, and Ti anomalies and positive ? _Hf(t) values (3.49–9.98). These data suggest that basaltic volcanic rocks in southern Manzhouli were generated by fractional crystallization of a common parental magma, which was derived by partial melting of metasomatized (enriched) lithospheric mantle, whereas the trachytic and rhyolitic magmas were produced by the melting of lower crustal mafic and felsic granulites, respectively. Geochronological data indicate that Mesozoic volcanism in southern Manzhouli was initiated in the Middle to Late Jurassic and continued into the Early Cretaceous. It was mainly induced by lithospheric extension after the closure of the Mongol–Okhotsk Ocean.     

庐枞盆地中生代火山岩的起源、演化及形成背景

庐枞中生代火山盆地位于长江中下游断陷带内,地处扬子板块的北缘.庐枞盆地内火山岩分布广泛,为一套包括粗玄岩-玄武粗安岩-粗面岩的富碱橄榄安粗岩系,划分为龙门院、砖桥、双庙和浮山等四个喷溢堆积旋回.盆地内火山岩浆活动起止时间约为136～124Ma,均为早白垩世火山活动.地球化学特征显示,庐枞盆地4个旋回火山岩岩浆具有同源关系,源于性质接近于EMI型富集地幔的交代地幔;各旋回火山岩岩浆演化过程中存在结晶分异作用,同时还受到了一定的地壳物质混染;火山岩由早到晚(龙门院旋回→砖桥旋回→双庙旋回→浮山旋回)具有向高钾、负Eu异常增强、结晶分异作用增强、岩浆分异程度增高方向的演化规律;庐枞盆地早白垩世存在由挤压-拉张过渡背景转为典型张性背景的构造转换,转换时间约为130.5Ma左右,龙门院、砖桥旋回火山岩形成于挤压-啦张过渡的构造背景,双庙、浮山旋回火山岩形成于典型的拉张构造背景.     

Geochronology and geochemistry of late Carboniferous volcanic rocks from northern Inner Mongolia,North China: Petrogenesis and tectonic implications

Zircon U–Pb ages, geochemical and Sr–Nd isotopic data are presented for the late Carboniferous Baoligaomiao Formation (BG Fm.) and Delewula Formation (DW Fm.) volcanic rocks, widely distributed in northern Inner Mongolia, in the northern part of the Xing'an–Mongolia Orogenic Belt (XMOB). The BG Fm. rocks mainly consist of basaltic andesites and andesites while the DW Fm. rocks include dacites, trachytes, rhyolites, pyroclastic rocks and minor andesites. New LA-ICPMS zircon U–Pb analyses constrain their eruption to late Carboniferous (317–322 Ma and 300–310 Ma, respectively). The BG Fm. volcanic rocks are characterized by enriched large ion lithophile elements (LILE) and depleted high field strength elements (HFSE), with initial ⁸⁷Sr/⁸⁶Sr ratios of 0.70854–0.70869 and negative εNd(t) (− 2.1 to − 2.4) values. They have low La/Ba (0.03–0.05), high La/Nb (2.05–3.70) ratios and variable Ba/Th (59.5–211) ratios. Such features suggest that they are derived from melting of heterogeneous sources including a metasomatized mantle wedge and Precambrian crustal material. The DW Fm. volcanic rocks are more depleted in HFSE with significant Nb, Ta, P, Ti anomalies. They have high initial ⁸⁷Sr/⁸⁶Sr ratios (0.72037–0.72234) and strong negative εNd(t) (− 11 to − 11.6) values which indicate those igneous rocks were mainly derived from reworking of the Paleoproterozoic crust. The late Carboniferous volcanic rocks have geochemical characteristics similar to those of the continental arc rocks which indicate the northward subduction of the Paleo Asian Ocean may have continued to the late Carboniferous. The volcanic association of this study together with the early Permian post-collisional magmatic rocks suggests that a tectonic transition from subduction-related continental margin arc volcanism to post-collisional magmatism occurred in the northern XMOB between the late Carboniferous and the early Permian.     

安徽庐枞火山岩盆地橄榄玄粗岩系的地球化学特征及其对下扬子地区晚中生代岩石圈减薄机制的约束

庐枞盆地内的中生代火山-潜火山岩具高钾和相对富碱为特性,属典型的橄榄玄粗岩系列。它们在地球化学上表现出明显富集Rb、Th、U、K等强不相容元素和轻稀土元素,亏损高场强元素Nb和Ta的特征。Nd、Sr同位素组成总体位于富集型的扬子克拉通岩石圈地幔的范围内或其附近,显示其母岩浆主要是由富集型地幔部分熔融形成的。火山-潜火山岩的成分变异趋势显示橄榄玄粗质幔源岩浆在高压下(斜长石稳定压力之下,1.5GPa)经历过以单斜辉石和钛铁氧化物为主的矿物分离结晶作用。低压下矿物的分离结晶作用及上地壳物质的混染则不明显。这套火山-潜火山岩的部分地球化学性质(如Ce/Yb比值)类似于大洋岛弧内的橄榄玄粗岩,可能意味着区内由于岩石圈的减薄,软流圈地幔上涌到了岩石圈相对较浅的部位,控制源区部分熔融的主要是尖晶石相地幔岩。虽然局部(如靠近郯庐断裂的盆地西缘)可能存在着明显的热侵蚀,但"突发性的"机械拆沉是区内(乃至整个长江中下游地区)岩石圈减薄的主要机制。在整个晚中生代岩石圈减薄的过程中,这两种机制可能一直相互促进着。     

Petrogenesis of Cretaceous adakitic and shoshonitic igneous rocks in the Luzong area, Anhui Province (eastern China): Implications for geodynamics and Cu–Au mineralization

Both adakitic and shoshonitic igneous rocks in the Luzong area, Anhui Province, eastern China are associated with Cretaceous Cu–Au mineralization. The Shaxi quartz diorite porphyrites exhibit adakite-like geochemical features, such as light rare earth element (LREE) enrichment, heavy REE (HREE) depletion, high Al₂O₃, MgO, Sr, Sr / Y and La / Yb values, and low Y and Yb contents. They have low ε_Nd(t) values (− 3.46 to − 6.28) and high (⁸⁷Sr / ⁸⁶Sr)_i ratios (0.7051–0.7057). Sensitive High-Resolution Ion Microprobe (SHRIMP) zircon analyses indicate a crystallization age of 136 ± 3 Ma for the adakitic rocks. Most volcanic rocks and the majority of monzonites and syenites in the Luzong area are K-rich (or shoshonitic) and were also produced during the Cretaceous (140–125 Ma). They are enriched in LREE and large-ion lithophile elements, and depleted in Ti, and Nb and Ba and exhibit relatively lower ε_Nd(t) values ranging from − 4.65 to − 7.03 and relatively higher (⁸⁷Sr / ⁸⁶Sr)_i ratios varying between 0.7057 and 0.7062. The shoshonitic and adakitic rocks in the Luzong area have similar Pb isotopic compositions (²⁰⁶Pb / ²⁰⁴Pb = 17.90–18.83, ²⁰⁷Pb / ²⁰⁴Pb = 15.45–15.62 and ²⁰⁸Pb / ²⁰⁴Pb = 38.07–38.80). Geological data from the Luzong area suggest that the Cretaceous igneous rocks are distributed along NE fault zones (e.g., Tanlu and Yangtze River fault zones) in eastern China and were likely formed in an extensional setting within the Yangtze Block. The Shaxi adakitic rocks were probably derived by the partial melting of delaminated lower crust at pressures equivalent to crustal thickness of > 50 km (i.e., 1.5 GPa), possibly leaving rutile-bearing eclogitic residue. The shoshonitic magmas, in contrast, originated mainly from an enriched mantle metasomatized by subducted oceanic sediments. They underwent early high-pressure (> 1.5 GPa) fractional crystallization at the boundary between thickened (> 50 km) lower crust and lithospheric mantle and late low-pressure (< 1.5 GPa) fractional crystallization in the shallow (< 50 km) crust. The adakitic and shoshonitic rocks appear to be linked to an intra-continental extensional setting where partial melting of enriched mantle and delaminated lower crust was probably controlled by lithospheric thinning and upwelling of hot asthenosphere along NE fault zones (e.g., Tanlu and Yangtze River fault zones) in eastern China. Both the shoshonitic and adakitic magmas were fertile with respect to Cu–Au mineralization.     

四川盐源地区晚二叠纪双峰式火山岩的厘定及其地质意义

四川省盐源县柏林山一带广泛分布着一套基性岩、酸性岩的火山岩组合,两类火山岩在时空上紧密伴生,二者之间缺失中性火山岩,构成典型的双峰式火山岩组合。通过对区内双峰式火山岩的空间分布调查,基性岩主要为致密块状玄武岩、斑状玄武岩,酸性火山岩主要为碱流岩,碱流岩位于玄武岩顶部,为晚二叠纪峨眉山大火成岩省的组成部分。在地质背景、岩石学、地球化学等方面研究的基础上,对区内双峰式火山岩的成因和形成环境进行了探讨,表明玄武岩的原始岩浆来自富集型地幔源区,为地幔橄榄岩小程度部分熔融的产物,形成于洋岛构造环境,碱流岩主要为玄武岩浆极度分离结晶后的酸性残余岩浆形成,形成于陆内拉张构造环境。柏林山地区晚二叠纪双峰式火山岩的发现和厘定为峨眉山玄武岩的演化提供了新的线索和依据,为区域成矿研究以及稀有稀土找矿提供了新的启示。     

Neoproterozoic subducted materials in the generation of Mesozoic Luzong volcanic rocks: Evidence from apatite geochemistry and Hf-Nd isotopic decoupling

A combined study including apatite geochemistry, zircon U-Pb, Lu-Hf isotopes and whole-rock geochemistry including Nd isotopes was carried out for the late Mesozoic volcanic rocks from the Luzong Basin, in the lower Yangtze River region, South China. Whole-rock geochemistry indicates the enrichments of large ion lithophile elements (LILE) and light rare earth elements (LREE) as well as depletions of Nb, Ta and Ti. The extremely low Cl contents in apatites strongly contrast with the rather high-K contents in whole rocks. Potential loss of Cl during syn- and post-magmatic processes having been ruled out, Cl-K decoupling is attributed to be a feature inherited from the primary magma, which indicates the involvement of highly dehydrated sediments and altered oceanic crust in the mantle source. A calculation based on apatite and whole-rock geochemistry further illustrates that the source was composed of four end-members in the perspective of Cl/K, Cl/Nb and F/K ratios. The Hf-Nd isotopes are decoupled for the basaltic trachytes from the lower volcanic sequences in the Luzong Basin, with rather low ε_Hf(t) values (mean = − 10.3) and inconsistent Hf-Nd model ages (Hf ~ 1.8 Ga, Nd ~ 1.3 Ga), which indicate the “zircon effect” that in turn requires the incorporation of continental detritus in the source via subduction. However, Hf and Nd isotopes are nearly coupled for the rocks from the upper volcanic sequences in the Luzong Basin. Late-Mesoproterozoic two-stage Hf and Nd model ages (ca. 1.2 Ga) of rocks from the upper volcanic sequences in the Luzong Basin are similar to those of the Neoproterozoic igneous rocks from the Jiangnan orogen, suggesting their relationship with the same subduction event. Based on the combined apatite geochemistry and Hf-Nd isotopes, this work suggests that the source of Luzong volcanic rocks might incorporate Neoproterozoic subducted slab fragments and detrital sediments that had been blocked in the deep lithospheric mantle below the Luzong area since the Neoproterozoic assembly between the Yangtze and Cathaysia blocks. The partial melting may be triggered by the back-arc lithospheric extension related to the subduction of Paleo-Pacific plate in the late Mesozoic.     

酒西盆地南缘旱峡早白垩世火山岩地球化学特征及其构造意义

酒西盆地旱峡和红柳峡等地有基性火山岩产出,它们曾一度被认为是新生代构造运动的产物。旱峡火山岩作为夹层产于早白垩世新民堡群下沟组地层中,火山岩气孔、杏仁构造发育。局部发育枕状构造,具明显的水下喷发特征。旱峡火山岩SiO2相对较低,K2O+Na2O不高,但钾相对较高。稀土总量为(211．875～237．454)×10^-6,轻稀土富集,(La/Yb)N为12．47—13．79;稀土配分曲线右倾、平滑,Ce为弱的负有异常,无Eu异常。在原始地幔标准化的微量元素蛛网图上,各元素均表现为相对富集,大离子亲石元素富集程度最高．有Nb,Ta槽,但相对于原始地幔不亏损;曲线表现为整体上隆的特征,表明其源区为富集地幔。旱峡火山岩与红柳峡粗玄质熔岩的稀土和微量元素的配分模式几乎完全相同,表明它们同源同期：运用多个玄武岩大地构造环境判别图解,最终确定洒西盆地早白垩世火山岩形成于大陆拉张环境。这与酒西盆地及其周围地区(酒泉盆地群)下白垩统构造特征和盆地群热演化特征一致。对酒西盆地火山岩形成构造背景的研究,对于深化酒西盆地构造演化特征有较为重要的意义。     

东南沿海中生代火山岩带地球化学特征

中国东南沿海位于太平洋板块和欧亚板块的结合处,广泛分布着中生代火山岩,并伴随有大规模的成矿作用。酸性火山岩占绝对优势,基性中性火山岩仅零星出露。酸性和中性火山岩为一套富碱、富钾、富铝、低钛的高钾钙碱性系列,基性火山岩为一套富硅贫碱的高钾和中钾钙碱性系列。从基性到酸性火山岩稀土分馏和铕的负异常逐渐加剧。基性火山岩贫Nb、Zr、Y,弱富集Ba、Hf、Th、Ce。中性火山岩和酸性火山岩贫Ba、Ti、P、Nb、Zr、Ta、Sr,强烈富集Pb。通过主量、微量和稀土元素的研究认为,基性火山岩和酸性火山岩为独立的岩浆起源,在中生代,东南沿海广泛存在着玄武岩的底侵作用,给下地壳提供了大量的热源,从而诱发了下地壳重熔,形成了大量的酸性火山岩。中性火山岩由酸性和基性岩浆混合形成,其地球化学特征主要受酸性岩浆的制约。     

西天山伊宁县北琼阿希河谷火山岩地球化学特征及构造背景探讨

对西天山伊宁县北琼阿希河谷出露的火山岩进行了地球化学特征研究,结果表明,该地区火山岩属于钙碱性火山岩系列,LREE强烈富集[(La/Yb)N介于2.76~7.03之间],具有弱的Eu负异常,样品的强不相容元素(Cs、Rb、Ba、Th、U)LILE均明显富集,总体在原始地幔的10倍以上,显示了岛弧火山岩的Nb-Ta负异常特征。但是,其(Th/Nb)N、(La/Nb)N的比值远远大于1,Ba/Nb、La/Nb的变化范围较大,Zr/Nb、Zr/Hf接近N-MORB的比值,Ta/Nb却接近上地壳的比值,暗示该地区的火山岩岩浆在上升过程中受到一定程度的地壳混染,所有样品均显示为中钾-高钾系列,这种钾质类型的优势地位也反映了陆壳基质在岩浆活动中占有重要的地位。样品的Zr均大于300、Zr/Y均大于4,显示了板内玄武岩的成分特征,在Zr-Zr/Y判别图解中,大多数样品投到板内玄武岩的构造环境区域内。结合区域上的地质特征,认为该地区在泥盆世一直处于抬升阶段,在石炭纪时碰撞结束并进入碰撞后伸展阶段,局部地区产生一定的裂谷化特征。琼阿希河谷的火山岩的Nb-Ta负异常特征应为地壳混染引起,火山岩的形成环境为碰撞后伸展的构造环境。     

大兴安岭北段呼中西部塔木兰沟组火山岩年代学、岩石地球化学特征及其构造意义

呼中火山岩位于大兴安岭北段,塔木兰沟组是其喷发较早的一期中基性火山岩。锆石U-Pb年代学研究表明,呼中火山岩形成于(154±1)Ma,属晚侏罗世。呼中火山岩SiO_2为49.80%~55.96%、Al_2O_3为16.70%~18.93%、Na_2O+K_2O为6.35%~9.11%,属中基性高铝碱性岩石。微量元素特征显示,呼中火山岩富集大离子亲石元素Ba,亏损高场强元素Nb、Ta,Nb/Ta=12.44~15.58。呼中火山岩元素含量及其比值的变化显示了本区塔木兰沟组玄武岩浆在分离结晶作用过程中受到了壳源物质的影响,其形成环境为板块边缘岛弧造山带环境,由古亚洲洋和(或)蒙古—鄂霍茨克洋板块俯冲形成。     

大兴安岭嫩江地区中生代双峰式火山岩锆石U-Pb定年、地球化学特征及其地质意义

本文对嫩江地区中生代双峰式火山岩进行了锆石LA-ICP-MSU-Pb年代学和岩石地球化学研究。测年结果显示嫩江地区中生代双峰式火山岩形成于127.5Ma的早白垩世晚期。岩石地球化学研究表明,早白垩世晚期火山岩具有双峰式组合特点,基性端员富碱,富含轻稀土元素和大离子亲石元素,亏损重稀土元素和高场强元素（Nb、Ta、Ti、Y）,形成于富集的岩石圈地幔的部分熔融和分离结晶作用,形成的过程可能含有少量的陆壳混染。酸性端员显示A型流纹岩的特征,为幔源岩浆底侵,使中下地壳岩石发生部分熔融的成因。双峰式火山岩组合的存在暗示其形成于陆内拉张的构造环境。结合区域上中生代火山岩的空间展布特征,嫩江地区早白垩世晚期双峰式火山岩的形成应与太平洋板块向欧亚大陆的俯冲作用有关。     

长江中下游庐枞火山岩盆地南侧钾质侵入岩带的成因

庐枞火山岩盆地南侧的钾质侵入岩带由正长岩-石英正长岩-正长花岗岩组成,以石英正长岩为主。它们的形成时间介于123"130 Ma之间,峰值约为126 Ma,其中正长岩和石英正长岩的形成时间稍早,而正长花岗岩的形成时间略晚。整个钾质侵入岩带的侵位时间晚于庐枞盆地内的橄榄玄粗质火山作用约4"7 Ma,也是长江中下游地区除最东段的宁镇地区外中生代最晚的岩浆活动产物之一。地球化学上,该钾质侵入岩带以高钾、富碱、富集Rb、Th、U、K等强不相容元素和轻稀土元素、亏损高场强元素Nb、Ta和Ti为特征。它们的母岩浆主要是由富集型上地幔部分熔融形成的,从正长岩经石英正长岩到正长花岗岩的演化主要受矿物的分离结晶作用控制,地壳物质同化所起的影响不大。但与同样来自富集型上地幔部分熔融的庐枞盆地内火山杂岩的母岩浆相比,前者的母岩浆来源深度可能更大些或其中包含了更多来自软流圈地幔的组分。两者的演化路径也完全不同,钾质侵入岩带的母岩浆除经历过高压下的分离结晶作用外,晚期在低压下还经历过长石为主,可能还有黑云母的分离结晶,甚至上地壳物质一定程度的混染作用;而盆地内火山杂岩的母岩浆低压下矿物的分离结晶作用及上地壳物质的混染都不明显。庐枞盆地南缘的富钾侵入岩与盆地内的火山杂岩一样,地球化学上都具有明显的大陆弧的特征,暗示它们的岩浆源区可能形成于俯冲带环境,意味着扬子地块北缘先前(推测为古元古代晚期)曾发生过俯冲作用,上地幔的交代富集可能就与这次的俯冲作用有关。     

吐--哈盆地及周缘早二叠世火山岩地球化学特征及大地构造环境探讨

长期以来对吐—哈盆地及其周缘地区早二叠世构造环境的归属存在较大异议.通过对盆地早二叠世火山岩地球化学特征的研究,进一步厘定了火山岩的产出环境.研究表明,区内火山岩以玄武岩、玄武安山岩和流纹岩为主,具双峰式火山岩特征,大部分玄武岩相对MORB强烈富集LILE和LREE,HFSE适度富集,Th/Ta比值>5,Ta、Nb的适度亏损和陆壳的混染有关,少量玄武岩带有与消减作用有关的地球化学信息,与造山期后伸展环境下的火山岩地球化学特征相似.结合区域地质特征及邻区研究结果,认为吐—哈盆地早二叠世火山岩为造山期后伸展背景下裂谷环境的产物.     

滇东南建水火山岩LA-ICP-MS锆石U-Pb测年、地球化学特征及地质意义

滇东南建水地区位于师宗-弥勒构造带的南段,区内出露一套玄武岩–安山岩–英安岩–流纹岩组合。研究这套火山岩的形成时间和形成环境对认识滇东南构造格局有着重要意义。本文首次对建水火山岩进行LA-ICP-MS锆石U-Pb测年,获得两个样品的年龄分别为261.9±2.2 Ma(MSWD=0.80)、264.8±1.7 Ma(MSWD=1.12),属中二叠世晚期,代表建水火山岩的形成时间。建水玄武岩与安山岩具有低TiO_2含量(0.50%~0.88%)、高Mg~#(52.0~64.5)、弱富集LREE((La/Yb)_N=1.42~3.44)、富集LILE(Rb,Th,U,Pb)、轻微亏损HFSE(Nb,Ta,Ti)的特点,具典型岛弧玄武岩的特征;英安岩和流纹岩高ΣREE含量(139.5×10~(–6)~313.6×10~(–6))、富集LREE((La/Yb)N=4.16~9.78)和LILE(Rb,Ba,Th,U)、亏损HFSE(Nb,Ta)、强亏损Sr、Ti、Y等元素的特点与典型的岛弧流纹岩相似,但高钾(K_2O含量平均7.73%)、钙碱性(δ=0.93~2.94)、强过铝质(A/CNK=1.13~2.10)的特点使之区别于一般岛弧酸性火山岩,而具有一些上地壳部分熔融形成的S型花岗岩的特点。综合建水火山岩岩石组合、地球化学和区域地质背景,认为建水火山岩形成于活动大陆边缘的弧后盆地伸展环境,是地幔部分熔融形成的玄武质岩浆结晶分异与上地壳混染作用的共同结果,与滇桂交界处岛弧火山岩、两广交界处岛弧玄武岩等同为哀牢山洋向北俯冲的产物。     

西天山乌孙山地区大哈拉军山组火山岩LA-ICP-MS锆石U-Pb年龄及其构造环境

西天山乌孙山地区大哈拉军山组由玄武岩、安山岩、英安岩、流纹岩及相应的火山碎屑岩组成,安山岩和流纹岩分布最广。LA-ICP-MS锆石U-Pb定年结果表明,火山活动喷发的安山岩与安山质晶屑凝灰熔岩分别形成于353.9Ma±6.5Ma和356.3Ma±4.4Ma,属于早石炭世早期。通过区域对比,西天山大哈拉军山组的火山岩浆作用显示从伊犁中天山板块南北缘向伊犁盆地内部逐渐变年轻的特点,且火山岩喷发时代差别不大(约40Ma)。岩石地球化学研究表明,火山岩属钙碱性系列,富集轻稀土元素,相对亏损重稀土元素。中性火山岩富集大离子亲石元素(如Cs、Rb、Th、U),而相对亏损高场强元素,具有明显的Nb、Ta、Ti负异常,显示出岛弧火山岩的特征;酸性火山岩相对富集Rb、Th、U、Ta等元素,具有明显的Ba、Sr、P、Eu、Ti等元素的负异常。综合伊犁-中天山板块南缘的构造演化特征,认为大哈拉军山组形成于活动大陆边缘环境,产在板块俯冲-碰撞的最后阶段。