大别造山带核部天堂寨和九资河花岗岩的成岩模拟

选用大离子亲石元素 Rb、Sr对大别造山带核部天堂寨和九资河花岗岩进行成岩模拟 ,结果表明 :( 1)天堂寨花岗岩主要与非平衡熔融有关 ,偏基性片麻岩可能是天堂寨花岗岩的主要原岩 ;( 2 )九资河花岗岩主要由片麻岩的平衡非实比批式熔融作用形成 ,但也不排除由偏基性片麻岩发生非平衡熔融形成九资河花岗岩的可能性 ;( 3 )天堂寨与九资河花岗岩熔融方式的差异可能反映了大别造山带燕山晚期不同地壳层次变质岩熔融方式的差别 ,即中下地壳以高温非平衡部分熔融为主 ,而中地壳以低温平衡熔融为主 ,并伴随有局部偏基性片麻岩的非平衡熔融     

冈底斯岩基中包体的初步研究

本文综合国内外研究成果对花岗岩中岩石包体进行成因归类,指出对其研究的理论和实际意义。以岩相学为基础,讨论冈底斯岩基中镁铁质包体的类型及形成机理,揭示冈底斯各单元岩浆作用初期的演化过程。     

江西印支期蔡江岩体中暗色微粒包体的发现及其地质意义

文章报道了江西蔡江花岗质岩体中发现暗色微粒包体,以及这些包体的地质、岩相学、LA-ICP-MS锆石U-Pb年代学和元素地球化学特征。包体多呈椭圆状,显示淬冷边和反向脉,具有典型的岩浆结构并含有针状磷灰石,有的包体含有长石捕虏晶。包体具有相对较低的SiO₂（低至57.05 wt%）和较高的MgO+Fe₂O₃（高达14.21 wt%）含量。LA-ICP-MS锆石U-Pb定年数据表明,包体形成于晚三叠世（224 Ma）,与寄主花岗岩（230~228 Ma）在误差范围内基本一致。上述特征表明,包体是离散的幔源偏基性岩浆团或者是幔源与寄主岩浆混合的产物。原始包体岩浆属于超钾质岩浆,可能是通过岩石圈地幔中交代成因的金云母辉石岩脉发生部分熔融而形成的。暗色微粒包体的发现为幔源岩浆底侵提供了直接证据,从而为蔡江花岗质岩石形成于较高温度提供佐证。该研究对于进一步探讨华南印支期花岗岩形成的热源机制具有意义。     

Significance of selective crystal entrainment and differential crystal-melt separation in petrogenesis of granites from the Tongbai orogen

Partial melting has been shown to be an important mechanism for intracrustal differentiation and granite petrogenesis. However, a series of compositional differences between granitic melt from experiments and natural granites indicate that the processes of crustal differentiation are complex. To shed light on factors that control the processes of crustal differentiation, and then the compositions of granitic magma, a combined study of petrology and geochemistry was carried out for granites (in the forms of granitic veins and parautochthonous granite) from a granulite terrane in the Tongbai orogen, China. These granites are characterized by high SiO₂ (>72 wt%) and low FeO and MgO (<4 wt%) with low Na₂O/K₂O ratios (<0.7). Minerals in these granites show variable microstructures and compositions. Phase equilibrium modelling using P–T pseudosections shows that neither anatectic melts nor fractionated melts match the compositions of the target granites, challenging the conventional paradigm that granites are the crystallized product of pure granitic melts. Based on the microstructural features of minerals in the granites, and a comparison of their compositions with crystallized minerals from anatectic melts and minerals in granulites, the minerals in these granitoids are considered to have three origins. The first is entrained garnets, which show comparable compositions with those in host granulites. The second is early crystallized mineral from melts, which include large plagioclase and K-feldspar (with high Ca contents) crystals as well as a part of biotite whose compositions can be reproduced by crystallization of the anatectic melts. The compositions of other minerals such as small grained plagioclase, K-feldspar and anorthoclase in the granites with low Ca contents are not well reconstructed, so they are considered as the third origin of crystallized products of fractionated melts. The results of mass balance calculation show that the compositions of these granites can be produced by mixing between different proportions of crystallized minerals and fractionated melts with variable amounts of entrained minerals. However, the calculated modal proportions of different crystallized minerals (plagioclase, K-feldspar, biotite and quartz) in the granites are significantly different from those predicted by melt crystallization modelling. Specifically, some rocks have lower modes of biotite and plagioclase, whereas others show lower K-feldspar modes than those produced by melt crystallization. This indicates that the crystallized minerals would be differentially separated from the primary magmas to form the evolved magmas that produce these granites. Therefore, the crystal entrainment and differential melt-crystal separation make important contributions to the composition of the target granites. Compared with leucogranites worldwide, the target granites show comparable compositions. As such, the leucogranites may form through the crystal fractionation of primary granitic magmas at different extents in addition to variable degrees of partial melting.     

赣西北小九宫-沙店白垩纪花岗岩的岩石成因及构造意义

赣西北-湘东北地区出露较多晚中生代花岗岩,并与中、下扬子地区晚中生代花岗岩组成一条NEE向岩浆岩带.通过对赣西北小九宫和沙店花岗岩进行系统的岩石学、年代学、元素地球化学、全岩Sr-Nd同位素研究,探讨其岩石成因及其构造意义.小九宫和沙店花岗岩的岩石类型主要为中粗粒斑状黑云二长花岗岩,LA-ICP-MS锆石U-Pb定年结果表明,其形成年龄分别为124±1 Ma和125±1 Ma,均为燕山晚期花岗岩.小九宫和沙店花岗岩均具有高钾、钙碱性、贫铁镁的含量特征,主要为弱过铝质花岗岩.两岩体具有相似的稀土元素分布型式和微量元素特征,表现为轻稀土富集的右倾型式,具有明显的Eu负异常（Eu/Eu*=0.17~0.50）,富集K、Rb、Th、U等大离子亲石元素,亏损Ba、Sr、P和高场强元素Nb、Ta、Ti等.主量、微量元素地球化学特征显示,两岩体为高钾钙碱性Ⅰ型花岗岩.小九宫和沙店花岗岩的ε_Nd（t）值分别为-8.06~-6.20、-6.51~-6.08,两阶段模式年龄（T_DM2）分别为1.42~1.57 Ga、1.42~1.45 Ga.Sr-Nd同位素组成和地球化学特征表明,两岩体主要来源于下地壳源区,其源岩可能为中元古代中性-基性火成岩.小九宫和沙店花岗岩体通过岩墙扩张作用方式被动侵位,结合区域构造背景,认为两岩体形成于伸展构造环境.地幔物质上涌可能为下地壳火成岩部分熔融提供持续的热源,岩浆在上升过程中经历明显的分离结晶作用.岩体中含有少量微粒包体及围岩捕虏体,反映岩浆在上升过程中可能受到较弱的混染作用.区域对比表明,从燕山早期到燕山晚期,赣西北-湘东北地区花岗质岩浆源区存在压力变小的趋势,可能反映了地壳的明显减薄.      

U-Pb ages and morphologies of zircon in microgranitoid enclaves and peraluminous host granite: evidence for magma mingling

 Granites of the S-type Wilson's Promontory Batholith (Lachlan Fold Belt, Australia) contain zircons which are euhedral and relatively large; their age is 395 Ma, which can be considered as the best available estimate of the crystallysation age of the granites. Contrary to their dominance in other S-type granites of the Lachlan Fold Belt, very few zircon cores give inherited ages, varying between 500 and 1700 Ma. Microgranitoid enclaves contained within the granites contain a zircon population that is dominated by relatively small, anhedral or elongated crystals. These give ages that are indistinguishable from the crystallisation age of the granite. Some enclaves, which are characterised by the presence of megacrysts, contain a proportion of larger, euhedral zircons. These zircons give inherited ages similar to the zircons from the granitic host rocks. The data are in agreement with a magma mingling origin for the microgranitoid enclaves. The large euhedral zircons are interpreted to have been introduced into the “enclave magma” during a hybridisation event which also introduced quartz and plagioclase megacrysts into the magma. The relatively high proportion of inherited cores within the “large” zircon population of the enclaves is related to the timing of mixing between “enclave” and host magma. This mixing event took place before the majority of the magmatic zircons crystallised in the granitic magma. The small, anhedral zircons within the enclaves crystallised during quenching of the globules of enclave magma against the cooler granitic magma. Received: 21 August 1995 / Accepted: 9 October 1995     

大别造山带东部燕山晚期区域变质－岩浆活动与区域构造抬升的同位素地质年代学证据

应用Ｒｂ－Ｓｒ同位素地质年代学方法，系统地研究了大别山东部两类不同构造环境（同构造花岗岩和非构造花岗岩）成因的花岗岩及大别杂岩混合二长片麻岩的冷却就位和构造－变质时代．结合区域上大别杂岩和花岗岩已有的同位素地质年代学成果分析，结果表明：（１）大别山东部燕山晚期区域变质－混合岩化－岩浆活动是同一构造－热事件的产物；（２）大别杂岩与中生代花岗岩具有相似的热历史，中下地壳大别杂岩的出露是燕山晚期区域构造抬升的结果     

浙东天台地区早白垩世花岗岩及暗色包体锆石U-Pb年龄、地球化学及其成因

在华南东部浙闽沿海一带普遍发育有大量晚中生代花岗质岩体及其中的暗色包体,这些岩体被认为是大规模壳幔相互作用和岩浆混合作用的产物。本文对浙东天台地区白鹤岩体中的寄主花岗岩及其中发育的暗色包体分别进行了LA-ICP-MS锆石U-Pb定年和详细的岩石地球化学研究,其锆石U-Pb年龄分别为(120.4±1.2)Ma和(120.6±1.1)Ma,属浙东燕山期侵入活动集中的早白垩世中晚期产物。岩石地球化学特征显示,寄主花岗岩为高硅、富碱、弱过铝质的高钾钙碱性花岗岩,具有较强的Eu负异常,富集Rb、Th、U、K,并有Sr、Ba、P、Ti、Nb、Ta等元素的亏损,岩石成因为高分异I型花岗岩;暗色包体多为低硅、富钠、偏铝质低钾拉斑玄武系列岩石,轻稀土富集、重稀土亏损,并具有弱的Eu正异常。锆石Hf同位素组成表现出不同物质来源(壳幔混源)花岗岩类岩石的特点。综合年代学及岩石地球化学特征,认为浙东地区早白垩世I型花岗岩及其暗色包体是在燕山期弧后碰撞伸展引张的构造背景下,由底侵的幔源岩浆与其诱发熔融的深部壳源岩浆经混合后,经过一定程度的分异演化,最后定位于浅成环境的产物。     

桐柏北部二朗坪蛇绿岩片中花岗岩:地球化学、成因及对地壳深部物质的指示

本文对产于桐柏北部二朗坪蛇绿岩片中加里东期桃园岩体和燕山期梁湾岩体花岗岩进行了系统的主量元素、微量元素和Sr-Nd-Pb 同位素地球化学研究。研究表明,桃园花岗岩与二朗坪基性岩具有相同的岩浆来源,两者均来自于亏损地幔源区,其中桃园花岗岩浆来自于基性岩浆的分异结晶,是与蛇绿岩共生的岩浆侵入单元,形成于与洋壳消减作用有关的弧后盆地环境,从而支持了二朗坪蛇绿岩属弧后盆地型蛇绿岩的认识。梁湾花岗岩的岩浆物质来自于南部(南秦岭)陆壳物质的部分熔融,指示在桐柏北部(北秦岭)的深部地壳中含有南秦岭陆壳物质,从而进一步证明了早期南秦岭陆壳向北俯冲叠置于北秦岭块体之下的认识。     

A Review of the Nature of Magmatism in Central Anatolia during the Mesozoic Post-Collisional Period

Magmatism in central Anatolia is characterized by petrographically and chemically distinct granitic and syenitic rocks. The granitic magmatism comprises C-type (crustal-derived) and H-type (hybrid) monzogranites and monzonites. Garnet-bearing C-type leucogranites represent the oldest magmatic phase, but younger hornblende ± biotite ± K-feldspar H-type plutons dominate the geology of the Central Anatolian Crystalline Complex (CACC). These typically include mafic microgranular enclaves. The granitic magmatism predates syenitic intrusions, among which quartz-bearing syenites were emplaced prior to feldspathoid-bearing ones.

The nature of magmatism in central Anatolia varies through time from peraluminous to metaluminous to alkaline. These different magma types reflect distinct stages of postcollisional magmatism, in which interaction between crust and mantle varied considerably. The C-type granites of the early stages of postcollisional magmatism were likely derived by partial melting of the lower continental crust induced by mafic magma underplating as a result of lithospheric delamination. The H-type granites and syenites of the mature and advanced stages of postcollisional magmatism indicate a significant contribution from mande-derived magma within a continuous or episodic extensional tectonic regime.     

花岗岩结晶分离作用问题——关于花岗岩研究的思考之二

岩浆结晶分离作用是一个古老的话题,很早就有学者指出,地球内部生成的岩浆大多是玄武质岩浆,大多数花岗岩是由玄武岩结晶分离形成的。本文在考察了岩浆结晶分离作用的制约因素、比较了不同性质岩浆结晶分离作用的特征之后指出:玄武质岩浆可以发生结晶分离作用,因为有与其相关的堆晶岩产出;安山质岩浆也可以发生结晶分离作用,因为也有与其相关的堆晶岩产出。但是,花岗质岩浆似乎不大可能发生结晶分离作用,因为,很少见到有与(富硅的)花岗质岩浆相伴的堆晶岩产出。花岗质岩浆之所以不大可能发生结晶分离作用的原因在于:(1)岩浆的黏性大,它不仅阻滞了矿物的结晶作用(使斜长石不能发育为自形晶),而且阻止了密度大的矿物(例如角闪石)下沉;(2)主要造岩矿物(例如斜长石)的密度与花岗质岩浆的密度相差无几,使结晶分离作用难以进行。本文详细考察了花岗质岩浆中斜长石的行为,指出在花岗质岩浆中斜长石结晶分离几乎是不可能的。那么,文献中大量充斥的花岗岩结晶分离作用的说法是依据什么呢?作者认为,文献中的许多说法可能主要是根据哈克图解得出的,而不是根据实际观察和理论研究得出的。作者认为,玄武岩和花岗岩不仅来源不同,成分不同,而且解释也不同。哈克图解中许多适合玄武岩的解释未必适合花岗岩。由于鲍文反应原理是结晶分离作用的理论基础,因此,文中也对鲍文反应原理进行了评述,并指出文献中存在的一些需要认真对待的问题,例如,从玄武岩-安山岩-英安岩-流纹岩的连续演化序列是不可能的;单元-超单元填图方法是不科学的;中国东部中生代大规模花岗岩不可能是玄武质岩浆结晶分离形成的等等。本文还以 Ajaji el ai.(1998)报道的摩洛哥 Tanncherfi 花岗岩为例,指出结晶分离作用的解释是不可能的。作者认为,花岗岩类的成分变化大,主要可能与源区组成、温度、压力、挥发分、部分熔融程度和过程、混合作用、岩浆分异及结晶分离作用有关。其中,源区组成可能是花岗岩多样性的最重要的原因,而结晶分离作用的影响可能是微乎其微的。本文认为,花岗岩结晶分离作用对于花岗岩成因的意义已经被大大地夸大了,我们应当重新思考结晶分离作用对于花岗质岩浆的意义。由于花岗岩的极端复杂性,许多问题还得不到比较合理的解释,本文的认识只是初步的。     

近代花岗岩研究的回顾

近代花岗岩实验和地球化学的研究使花岗岩研究走向一个最终成因和在地构造环境变迁结合的动力学方向。     

Evolution of the Proto-Tethys in the Baoshan block along the East Gondwana margin: constraints from early Palaeozoic magmatism

Zircon U–Pb ages and geochemical and isotopic data for Late Ordovician granites in the Baoshan Block reveal the early Palaeozoic tectonic evolution of the margin of East Gondwana. The granites are high-K, calc-alkaline, metaluminous to strongly peraluminous rocks with A/CNK values of 0.93–1.18, are enriched in SiO₂, K₂O, and Rb, and depleted in Nb, P, Ti, Eu, and heavy rare earth elements, which indicates the crystallization fractionation of the granitic magma. Zircon U–Pb dating indicates that they formed at ca. 445 Ma. High initial ⁸⁷Sr/⁸⁶Sr ratios of 0.719761–0.726754, negative ?_Nd(t) values of –6.6 to –8.3, and two-stage model ages of 1.52–1.64 Ga suggest a crustal origin, with the magmas derived from the partial melting of ancient metagreywacke at high temperature. A synthesis of data for the early Palaeozoic igneous rocks in the Baoshan Block and adjacent Tengchong Block indicates two stages of flare-up of granitic and mafic magmatism caused by different tectonic settings along the East Gondwana margin. Late Cambrian to Early Ordovician granitic rocks (ca. 490 Ma) were produced when underplated mafic magmas induced crustal melting along the margin of East Gondwana related to the break-off of subducted Proto-Tethyan oceanic slab. In addition, the cession of the mafic magmatism between late Cambrian-Early Ordovician and Late Ordovician could have been caused by the collision of the Baoshan Block and outward micro-continent along the margin of East Gondwana and crust and lithosphere thickening. The Late Ordovician granites in the Baoshan Block were produced in an extensional setting resulting from the delamination of an already thickened crust and lithospheric mantle followed by the injection of synchronous mafic magma.     

北秦岭西段早侏罗世A型花岗岩及其地质意义

本文通过岩相学、岩石地球化学、锆石U?Pb定年和Lu?Hf同位素组成分析等方法,对出露于北秦岭西段宝鸡岩体王家山一带的黑云母花岗岩和其中的包体进行了研究。结果表明,该花岗岩形成时代为187±2 Ma,属于高钾钙碱性—钾玄岩系列岩石,富集Rb、Th、U等大离子亲石元素以及Nb、Zr和Hf等高场强元素,亏损Ba、Sr和Eu,具有高的全岩锆石饱和温度(825℃~838℃),显示A型花岗岩特征,形成于造山后的板内环境,可能为秦岭岩群副变质岩与安山质岩石部分熔融的产物。暗色包体显示塑性流变特征,具有岩浆结构,发育针状磷灰石和具有复杂成分环带的更长环斑结构长石,是幔源岩浆注入酸性岩浆发生混合作用的产物,形成时代为191±2 Ma,其锆石Hf同位素组成变化范围较大,εHf(t)值介于-11.26~-2.51,主要为富集地幔部分熔融产物。综合本文及前人已有研究结果,认为~190 Ma的早侏罗世早期秦岭地区早中生代碰撞造山过程已经结束,区域开始逐渐进入板内伸展构造演化阶段。     

新疆准噶尔地区花岗岩中微粒闪长质包体特征及后碰撞花岗质岩浆起源和演化

新疆准噶尔地区也布山、庙儿沟两个晚古生代后碰撞准铝一过铝质花岗岩体中，广泛发育大量的暗色微粒闪长质包体。岩石学、矿物学、主量元素和微量元素地球化学研究表明，包体与其寄主岩存在明显的亲缘关系。东准噶尔也布山黑云母花岗岩体中的暗色微粒包体与寄主岩有相似的地球化学成分，表明它是与寄主花岗岩相同成因的同源包体，是来自上地幔的基性岩浆经过高度演化、结晶分异的产物；西准噶尔庙儿沟二长花岗岩体中含钾长石斑晶的微粒包体则主要是由幔源的下地壳基性岩部分熔融形成的残余体，被酸性岩浆携带并发生成分上的同化和混染，最后在上地壳侵位的产物。同准噶尔碱性花岗岩一样，载荷包体的准铝一过铝质花岗岩是晚古生代后碰撞阶段构造一岩浆活动的岩石类型之一，其形成和演化标志了准噶尔地区后碰撞幔源岩浆底侵作用导致大陆地壳垂向生长的过程。     

Magma Mingling/mixing vs. Magmatic Fractionation: Geneses of the Shirakawa Mo-mineralized Granitoids, Central Japan

Abstract. Leucocratic biotite granites are main components in the Hatogaya pluton and the Hirase stock in the Shirakawa region of central Japan. Molybdenite‐quartz vein mineralizations are widespread in and around the Hatogaya pluton and the Hirase stock, in which the largest is vein swarm of the Hirase mine. Mafic enclaves occur abundantly with granitic to granodi‐oritic matrix in the northern part of the Hatogaya pluton, while they are rare in the Hirase granitic stock. The enclaves with generally round shape have mostly diabasic to fine plutonic textures under the microscope, and show interfingering and lobate contacts with the felsic matrix. The enclaves are quartz monzodiorite in composition containing SiO>₂ mostly around 60 %. They have felsic blebs, thus are considered a mingled magma of basaltic compositions originated in depth and a felsic magma generated from the Hida metamorphic‐plutonic complexes or their basement. The mingled magma further mixed with and reacted with the felsic magma with SiO₂ 70 %, and then formed granodiorite‐granite of the high Na group (Na₂O higher than 4.25 %). Thus, compositional variation of the northern part of the Hatogaya pluton was caused by the magma mingling. The mingling happened to be deeper level produced homogeneous granodiorite of the Mihoro pluton. Biotite granite of the low Na group (less than 4.25 %) could have originated in a granitic magma generated also from the Hida metamorphic‐plutonic complexes or their basement. Most of the granites, occurring in the southern part of the Hatogaya pluton and Hirase stock, show high Rb/Sr ratio, strong Eu negative anomalies and flat REE patterns, and are thus considered as fractionated products of the SiO₂ 70 % original magma. The strong concentration of molybdenum in the Hirase stock can be explained by high degree of magmatic fractionation which produced MoS₂‐rich residual melts, suitable fractures developed at the latest Cretaceous time, and preservation of the mineralized fractures at the present level of erosion.     

广西大宁花岗闪长岩体中暗色微粒包体的地球化学及成因模式

本文通过对广西大宁花岗闪长岩体及其中的暗色微粒包体的岩石学、微量元素及稀土元素地球化学、Rb—Sr同位素及微量元素初始比值等研究,认为该岩体中的暗色微粒包体属于幔源物质,同时提出了包体与主体花岗岩成因的上地幔—地壳相互作用模式,强调了花岗岩浆形成过程中系统的开放性及上地幔基性岩浆参与的重要性。     

巴颜喀拉沉积盆地基底为扬子地台西缘的一部分：来自花岗岩的证据

侵入于巴颜喀拉沉积盆地中的扎加岩体，主要由高钾钙碱性的黑云母花岗岩组成，并出现有具岩浆结构的暗色微粒包体。花岗岩富集轻稀土（LREE）及大离子亲石元素（LILE），相对亏损重稀土（HREE）和高场强元素（HFSE），具Eu负异常（0．5～0．7）、较低的εNd（t）值（-3．5～-6．2）和中等的（^87Sr／^86Sr）初始比值（0．7088～0．7090），它们的亏损地幔Nd模式年龄tDM在1．1～1．3Ga之间。与寄主花岗岩相比，闪长质暗色微粒包体具有较低的SiO2，更低的Eu负异常（0．2～0．4）和εNd（t）值（-4．7～-6．1），更高的（^87Sr／^86Sr）初始比（0．7084～0．7124），以及稍老的tDM（1．4Ga）。岩石的地球化学资料表明，扎加花岗岩是在碰撞后构造环境下幔源岩浆上涌诱发下地壳岩石部分熔融的产物，其物源可能是苦海杂岩和万宝沟岩群的混合物。巴颜喀拉沉积盆地下面存在中元古代的基底，属于扬子地台西缘的一部分     

REE Mineralization of Weathered Crust and Clay Sediment on Granitic Rocks in the Sanyo Belt,SW Japan and the Southern Jiangxi Province,China

Rare earth element (REE) geochemistry and mineralogy have been studied in the weathered crusts derived from the Early Yanshanian (Jurassic) biotite granites of Dabu and Dingnan, as well as in the Indosinian (Permian) muscovite–biotite granite of Aigao in southern Jiangxi province, China, and the weathered crusts and clay sediments on biotite granites in the Sanyo belt, SW Japan, that is, Okayama, Tanakami, and Naegi areas. In all of the weathered crusts, biotite and plagioclase commonly tend to decrease toward the upper part of the profile, whereas kaolinite and residual quartz and K‐feldspar increase. The weathered crusts of the Dingnan granites and some Naegi granites, which are characterized by the enrichment in light REE (LREE) in C horizons, have higher total REE (ΣREE) content than the parent REE‐enriched granites. Weathering of LREE‐bearing apatite and fluorocarbonates in the Dingnan granites and allanite and apatite in some Naegi granites may account for the leaching of LREE at the B horizons. The leached LREE must result in subsequent enrichment of LREE in the C horizons. The enrichment is probably associated with mainly adsorption onto kaolinite and partly formation of possible secondary LREE‐bearing minerals. In Japan it was found that REE mineralization occurs not in the weathered granitic crusts but in reworked clay sediments, especially kaolinite‐rich layers, derived mainly from the weathering materials of REE‐enriched granitic rocks. The clay sediments are more enriched in LREE, which likely adsorbed onto kaolinite. Concentration of heavy REE within almost all the weathered crusts and clay sediments, however, may reflect mainly residual REE‐bearing minerals such as zircon, which originated in the parent granitic rocks. The findings of the present study support the three processes for fractionation of the REE during weathering: (i) selective leaching of rocks containing both stable and unstable REE‐bearing minerals; (ii) adsorption onto clay minerals; and (iii) presence of possible secondary LREE‐bearing minerals.     

中国东南部花岗岩成因与地壳演化

中国东南部不同时代花岗岩类的分布十分广泛 ,各类花岗岩的出露面积达 2 0 0 0 0 0km2 以上。其中 ,前侏罗纪花岗岩大部分具有较低的ε(Nd ,t)、较高的Ni(87Sr) /Ni(86Sr)和较古老的Nd模式年龄 ,相似于周围的前寒武纪基底变质岩。因此 ,它们的主体属壳源型 ,其成因可能主要同华夏地块与扬子地块之间的多次碰撞拼贴有关 ,由当时被加厚的地壳在降压条件下部分熔融形成。燕山期花岗岩在中国东南部分布最广。其中 ,呈东西向展布的燕山早期花岗岩 (南岭花岗岩 )被认为是与印支运动有联系的后造山花岗岩组合 ,多数具壳源型特征。而主要分布于东南沿海的燕山晚期花岗岩则不同 ,它们具有较高的ε(Nd ,t)、较低的Ni(87Sr) /Ni(86Sr)和相对年轻的Nd模式年龄 ,反映其源区中含有较多的地幔组分。它们的形成可能同太平洋板块俯冲、玄武岩浆底侵以及由此引起的地壳深熔和壳幔混合有关。根据花岗岩的Nd模式年龄以及地壳岩石中继承锆石U Pb年龄 ,认为中国东南部地壳具幕式生长特征 ,古—中元古代为主要的生长期。