Ages and Sources of Ore‐Related Porphyries at Yongping Cu–Mo Deposit in Jiangxi Province,Southeast China

Whole‐rock geochemistry, zircon U–Pb and molybdenite Re–Os geochronology, and Sr–Nd–Hf isotopes analyses were performed on ore‐related dacite porphyry and quartz porphyry at the Yongping Cu–Mo deposit in Southeast China. The geochemical results show that these porphyry stocks have similar REE patterns, and primitive mantle‐normalized spectra show LILE‐enrichment (Ba, Rb, K) and HFSE (Th, Nb, Ta, Ti) depletion. The zircon SHRIMP U–Pb geochronologic results show that the ore‐related porphyries were emplaced at 162–156 Ma. Hydrothermal muscovite of the quartz porphyry yields a plateau age of 162.1 ± 1.4 Ma (2σ). Two hydrothermal biotite samples of the dacite porphyry show plateau ages of 164 ± 1.3 and 163.8 ± 1.3 Ma. Two molybdenite samples from quartz+molybdenite veins contained in the quartz porphyry yield Re–Os ages of 156.7 ± 2.8 Ma and 155.7 ± 3.6 Ma. The ages of molybdenite coeval to zircon and biotite and muscovite ages of the porphyries within the errors suggest that the Mo mineralization was genetically related to the magmatic emplacement. The whole rocks Nd–Sr isotopic data obtained from both the dacite and quartz porphyries suggest partial melting of the Meso‐Proterozoic crust in contribution to the magma process. The zircon Hf isotopic data also indicate the crustal component is the dominated during the magma generation.     

鄂东南地区程潮大型矽卡岩型铁矿区岩体成因探讨

湖北程潮铁矿是鄂东南矿集区内最大的矽卡岩型铁矿床。为了系统研究矿区内不同侵入体的成因,对程潮矿区内不同时代的侵入体进行了矿物学、地球化学和Sr-Nd-Pb同位素研究。矿区内花岗岩、石英二长斑岩、闪长岩中的黑云母成分特征暗示它们均为壳幔物质混合成因的镁质黑云母;与成矿相关的花岗岩、石英二长斑岩中原生黑云母矿物学成分显示出原始岩浆具有高氧逸度的特征,高氧逸度为磁铁矿的形成提供了有利条件。岩石地球化学特征研究表明,不同类型的岩石都具有富钾和准铝质的特征,富集Rb、Ba、K等大离子亲石元素和轻稀土元素,亏损Nb、Ta、Ti等高场强元素。矿区岩石的(⁸⁷Sr/⁸⁶Sr)_i值为0.705 0~0.709 1,ε_Nd(t)值为-14.16~-6.95,²⁰⁶Pb/²⁰⁴Pb值为17.636~18.919,²⁰⁷Pb/²⁰⁴Pb值为15.451~15.613,²⁰⁸Pb/²⁰⁴Pb值为37.833~39.556。矿物学、地球化学、Sr-Nd-Pb同位素特征暗示矿区岩体为富集地幔发生部分熔融并同化混染了不同比例下地壳物质的产物,早期闪长岩（（140±1） Ma）比晚期花岗岩和石英二长斑岩（（128±1） Ma）的源区有更多的地幔成分,花岗岩和石英二长斑岩与闪长岩具有相近的锆石饱和温度（平均值分别为783、788、765℃）。     

青藏高原拉萨地块西部亚热南复式岩体年代学与地球化学

青藏高原拉萨地块发育着中新世斑岩,该后碰撞时期的斑岩因与斑岩型Cu-Mo矿床有着密切关系已被前人做过大量研究。然而对于拉萨地块西部未成矿斑岩岩体的年代学、地球化学报道研究较少。本文对拉萨地块西部亚热南复式岩体识别出的两类侵入岩进行了锆石LA-ICP-MS U-Pb定年和岩石地球化学研究表明,亚热南复式岩体主要由始新世黑云母二长花岗岩(年龄49.4±0.9Ma)和中新世花岗斑岩(年龄16.3~16.5Ma)组成。始新世黑云母二长花岗岩属钾玄岩系列准铝质-弱过铝质,具有低的Sr/Y、(La/Yb)N值高Y、YbN值具有典型的岛弧岩浆岩性质;中新世花岗斑岩为钾玄岩系列、准铝质,具有类埃达克质特征。这两种岩性所反映的源区亦存在差别,始新世黑云母二长花岗岩源区为地幔楔混染过的中下地壳;而具有埃达克性质的花岗斑岩则可能是源于古老地壳部分熔融。结合年代学及构造背景,推论出始新世黑云母二长花岗岩的岩石成因为新特提斯洋板片断离引发混染过的中下地壳发生熔融并结晶分异形成;而中新世花岗斑岩则形成于某种动力学机制引发的古老下地壳熔融后侵位于上地壳。     

Origin of the Newly Discovered Zhunuo Porphyry Cu-Mo-Au Deposit in the Western Part of the Gangdese Porphyry Copper Belt in the Southern Tibetan Plateau, SW China

The newly discovered Zhunuo porphyry Cu-Mo-Au deposit is located in the western part of the Gangdese porphyry copper belt in southern Tibet, SW China. The granitoid plutons in the Zhunuo region are composed of quartz diorite porphyry, diorite porphyry, granodiorite porphyry, biotite monzogranite and quartz porphyry. The quartz diorite porphyry yielded zircon U-Pb ages of 51.9±0.7 Ma(Eocene) using LA-ICP-MS, whereas the diorite porphyry, granodiorite porphyry, biotite monzogranite and quartz porphyry yielded ages ranging from 16.2±0.2 to 14.0±0.2 Ma(Miocene). CuMo-Au mineralization is mainly hosted in the Miocene granodiorite porphyry. Samples from all granitoid plutons have geochemical compositions consistent with high-K calc-alkaline series magmatism. The samples display highly fractionated light rare-earth element(REE) distributions and heavy REE distributions with weakly negative Eu anomalies on chondrite-normalized REE patterns. The trace element distributions exhibit positive anomalies for large-ion lithophile elements(Rb, K, U, Th and Pb) and negative anomalies for high-field-strength elements(Nb and Ti) relative to primitive mantlenormalized values. The Eocene quartz diorite porphyry yielded εNd(t) values ranging from-3.6 to-5.2,(~(87)Sr/~(86)Sr)i values in the range 0.7046–0.7063 and initial radiogenic Pb isotopic compositions with ranges of 18.599–18.657 ~(206)Pb/~(204)Pb, 15.642–15.673 ~(207)Pb/~(204)Pb and 38.956–39.199 ~(208)Pb/~(204)Pb. In contrast, the Miocene granitoid plutons yielded ε_(Nd)(t) values ranging from-6.1 to-7.3 and(87Sr/86Sr)i values in the range 0.7071–0.7078 with similar Pb isotopic compositions to the Eocene quart diorite. The Sr-Nd-Pb isotopic compositions of the rocks are consistent with formation from magma containing a component of remelted ancient crust. Zircon grains from the Eocene quartz diorite have ε_(Hf)(t) values ranging from-5.2 to +0.9 and two-stage Hf model ages ranging from 1.07 to 1.46 Ga, while zircon grains from the Miocene granitoid plutons have ε_(Hf)(t) values from-9.9 to +4.2 and two-stage Hf model ages ranging from 1.05–1.73 Ga, indicating that the ancient crustal component likely derives from Paleo- to Mesoproterozoic basement. This source is distinct from that of most porphyry Cu-Mo-Au deposits in the eastern part of the Gangdese porphyry copper belt, which likely originated from juvenile crust. We therefore consider melting of ancient crustal basement to have contributed significantly to the formation Miocene porphyry Cu-Mo-Au deposits in the western part of the Gangdese porphyry copper belt.     

Discriminating characters of ore-forming intrusions in the super-large Chalukou porphyry Mo deposit,NE China

The Chalukou porphyry Mo deposit, located in the Great Hinggan Range, is the largest Mo deposit in northeast China, although the age and genesis of the associated magmatic intrusions remain debated.Here we report zircon U-Pb ages and trace elements, whole rock geochemistry and Sre Nd isotope data with a view to understand the relationship between the magmatism and molybdenum mineralization.Zircon U-Pb analysis yield an age of 475 Ma for rhyolite in the older strata, 168 Ma for the premineralization monzogranite, and 154 Ma for the syn-mineralization granite porphyry. The granite porphyry and quartz porphyry are considered as the ore-forming intrusions. These rocks are peraluminous, alkali-calcic, and belong to high-K to shoshonitic series with a strong depletion of Eu. They also display characteristics of I-type granites. The rocks exhibit wide variations of(87 Sr/86 Sr)iin the range of 0.705426 -0.707363, and ε_(Nd)(t) of -3.7 to 0.93. Zircon REE distribution patterns show characteristics between crust and the mantle, implying magma genesis through crust-mantle interaction. The Fe_2O_3/FeO values(average 1) for the whole rock and EuN/Eu*Nvalues(average 0.45), Ce~(4+)/Ce~(3+) values(average 301)for zircon grains from the granite porphyry are higher than those from other lithologies. These features suggest that the ore-forming intrusions(syn-mineralization porphyry) had higher oxygen fugacity conditions than those of the pre-mineralization and post-mineralization rocks. The Chalukou Mo deposit formed in relation to the southward subduction of the Mongol-Okhotsk Ocean. Our study suggests that the subduction-related setting, crust-mantle interaction, and the large-scale magmatic intrusion were favorable factors to generate the super-large Mo deposits in this area.     

内蒙古小东沟斑岩型钼矿床的成矿时代及成矿物质来源

小东沟斑岩型钼矿床位于大兴安岭南段,距北部的西拉木伦河大断裂仅25 km。对小东沟岩体进行了Sr-Nd同位素和铅同位素分析,87Sr/86Sr(t)为0.705 0~0.705 5,εNd(t)为-2.4~-2.8;对主要钼矿体的6件辉钼矿样品进行了铼-锇同位素分析,所获同位素等时线年龄为(138.1±2.8)M a,表明小东沟钼矿床形成于早白垩世。铅同位素分析结果表明小东沟斑岩型钼矿床的成岩成矿物质具有不同来源,成岩物质来自俯冲洋壳衍生的新生地壳物质,而成矿物质来自地幔分异的产物(流体),属于壳源岩浆+幔源流体的组合。结合区域构造演化历史,对小东沟斑岩型钼矿的成因做出如下解释:在早白垩世,大兴安岭开始隆升,岩石圈拆沉,软流圈(层)物质上涌、基性岩浆的底侵以及地幔流体的加入,引起下地壳岩石的熔融,随后更多的地幔含矿流体进入到岩浆房。岩浆携带来自地幔的含矿流体,沿着区域性的EW、NE向深大断裂上侵定位,并在此过程中演化形成富硅、富钾质的花岗岩,最后沿近NS向的断裂侵位到二叠纪地层中,沉淀形成矿床。     

新疆阿尔泰小土尔根铜矿区岩体地球化学及其地质意义

小土尔根是近年来诺尔特地区新发现的斑岩铜矿。矿区内发育花岗斑岩、花岗闪长斑岩、黑云母二长花岗岩,其中与成矿作用密切相关的岩体为花岗闪长斑岩。为了确定矿区侵入岩成因及其与铜矿化的内在关系,对矿区内发育的岩体开展了岩相学和地球化学研究。结果表明,所有岩石富硅和碱,铝含量中等,属高钾钙碱性和钾玄质系列岩石。所有样品富集Rb、Ba等大离子亲石元素和轻稀土元素,相对亏损Nb、Ta、Ti、P、Sr和重稀土元素,指示其为同源岩浆分异演化的产物,形成于陆缘弧环境。结合区域地质背景,推测这些岩体是俯冲洋壳发生部分熔融并交代上覆地幔楔后,在上升过程中经分离结晶作用后的产物。与典型的还原性斑岩型铜矿形成条件进行对比研究后,认为小土尔根地区有形成斑岩型矿床的潜力。     

Collision-related genesis of the Sharang porphyry molybdenum deposit,Tibet: Evidence from zircon U–Pb ages,Re–Os ages and Lu–Hf isotopes

Sharang is a low-fluorine, calc-alkaline porphyry Mo deposit hosted mainly in a granite porphyry of a multi-stage plutonic complex in the northern Gangdese metallogenic belt, largely with stockwork and ribbon-textured mineralization. The observed age estimates suggest that the formation of the magmatic host complex (52.9–51.6 Ma) and the ore deposit itself (52.3 Ma) occurred during the main stage of the India–Asia collision. The host rocks are characterized by lower zircon ε_Hf(t) values than those of the pre-ore and post-ore rocks. This suggests that the Lhasa terrane basement might play an important role in the formation of Sharang ore-forming intrusions. In view of the framework of magmatic–metallogenic events we suggest that slab roll-back may have induced melting of juvenile crust and ancient continental complexes during the India–Asia collision. This proposal focuses exploration for additional molybdenum deposits on the collision zone.     

Geochronology and fluid source constraints of the Songligou gold‐telluride deposit,western Henan Province,China: Analysis of genetic implications

The Songligou gold‐telluride deposit, located in Songxian County, western Henan Province, China, is one of many gold‐telluride deposits in the Xiaoqinling‐Xiong'ershan district. Gold orebodies occur within the Taihua Supergroup and are controlled by the WNW F101 Fault, and the fault was cut across by a granite porphyry dike. Common minerals in gold orebodies include quartz, chlorite, epidote, K‐feldspar, calcite, fluorite, sericite, phlogopite, bastnasite, pyrite, galena, chalcopyrite, sphalerite, tellurides, gold, bismuthinite, magnetite, and hematite, and pyrite is the dominant sulfide. Four mineralization stages are recognized, including pyrite‐quartz stage (I), quartz‐pyrite stage (II), gold‐telluride stage (III), and quartz‐calcite stage (IV). This work reports the Rb–Sr age of gold‐telluride‐bearing pyrite and zircon U–Pb age of granite porphyry, as well as S isotope data of pyrite and galena. The pyrite Rb–Sr isochron age is 126.6 ± 2.3 Ma (MSWD = 1.8), and the average zircon U–Pb age of granite porphyry is 166.8 ± 4.1 Ma (MSWD = 4.9). (⁸⁷Sr/⁸⁶Sr) _i values of pyrite and δ³⁴S values of sulfides vary from 0.7104 to 0.7105 and ?11.84 to 0.28‰, respectively. The obtained Rb–Sr isochron age represents the ore formation age of the Songligou gold‐telluride deposit, which is much younger than the zircon U–Pb age of the granite porphyry. Strontium and S isotopes, together with the presence of bastnaesite, suggest that the ore‐forming fluid was derived from felsic magmas with input of a mantle component and subsequently interacted with the Taihua Supergroup. Tellurium was derived from metasomatized mantle and was related to the subduction of the Shangdan oceanic crust and Izanagi plate beneath the North China Craton (NCC). This deposit is a part of the Early Cretaceous large‐scale gold mineralization in east NCC and formed in an extensional tectonic setting.     

江西九龙嶂和相山火山-侵入杂岩岩石地球化学的对比研究

九龙嶂和相山火山-侵入杂岩是中国华南地区与铀矿有关的中生代流纹英安质火山-侵入杂岩。相山火山-侵入杂岩是华南地区最大的火山岩型铀矿赋矿围岩,其主体岩石为流纹质碎斑熔岩,浅成-超浅成侵入岩有英安斑岩、花岗斑岩等;九龙嶂火山-侵入杂岩的铀资源潜力尚待评价,主体岩石为流纹质熔结凝灰岩,浅成-超浅成侵入岩有英安斑岩、石英二长斑岩等。两地区的火山-侵入杂岩的岩石化学成分及其变化特点极为相近,微量元素蛛网图和稀土配分型式也基本一致,它们具有相似的岩浆过程和统一的活动陆缘构造背景;同时,从早期火山岩浆活动到晚期浅成-超浅成岩浆侵入活动,其w(SiO₂)和w(Rb)/w(Sr)的值降低,而w(MgO)以及w(K)/w(Rb)、w(Ba)/w(Rb)和w(LREE)/w(HREE)的值增高,晚期浅成-超浅成侵入岩与早期火山岩没有直接的分异演化关系。     

新疆东天山多头山铁-铜矿区花岗岩类的年代学、地球化学、岩石成因及意义

多头山矿床是东天山阿奇山?雅满苏成矿带铁铜矿床的典型代表,矿床成因与区内岩浆岩有紧密联系。矿区出露的侵入岩主要有花岗斑岩、二长花岗岩、钾长花岗岩及英安玢岩。LA-ICP-MS锆石U-Pb年代学研究获得花岗斑岩、二长花岗岩及英安玢岩的年龄分别为316.3±8.1 Ma、318.3±3.0 Ma和197.2±3.5 Ma。花岗斑岩A/CNK介于0.82~1.01之间,显示偏铝质特征,为Ⅰ型花岗岩;同时样品富集大离子亲石元素Th、U、Pb,亏损高场强元素Nb、Ta、Ti,显示弧岩浆特征。钠质蚀变导致了花岗斑岩显示出富Na、贫K、Rb、Ca、Sr的特征。钠化花岗斑岩Nb/Ta为12.4~16.0,具有较高的ε_(Nd)(t)(5.76~6.24)值和较低的I_(Sr)值(0.70353~0.70532),与安第斯中生代岩基地球化学特征相似,结合样品中出现古老锆石的捕掳晶,表明其源区为新生的下地壳,混合有少量幔源物质,并伴随有地壳混染。二长花岗岩与钠化花岗斑岩具有相近的形成年龄和相似的地球化学特征,如Nb/Ta比值(14.2),亏损高场强元素、富集大离子亲石元素,同为准铝质(A/CNK=0.97)弧岩浆,暗示它们可能具有相似的源区。而早侏罗世的英安玢岩具有高Sr(552×10~(-6))含量和较高的Sr/Y(73.6)比值,显示出钙碱性埃达克岩的特征,同时样品具有较高的K_2O(3.27%)含量、Mg~#指数(55),表明其来源于拆沉下地壳的熔融并混有少量幔源岩浆。综合区域研究资料、年代学、地球化学及同位素特征,我们认为多头山所在的阿奇山?雅满苏成矿带可能是晚古生代洋壳向南俯冲至中天山地块之下形成的大陆边缘弧。     

Petrogenesis of Late Jurassic granitoids and relationship to polymetallic deposits in southern China: The Huangshaping example

ABSTRACT

Southern Hunan Province, located in the Cathaysia Block where the Shi–Hang zone and Nanling belt meet, is characterized by extensive Mesozoic magmatism and coeval polymetallic mineralization. The Huangshaping W–Mo–Pb–Zn–(Cu) deposit is representative in this area. However, the petrogenesis of the granitoids associated with the Huangshaping deposit, and their relationships with mineralization, remain undetermined. In this paper we focus on zircon U–Pb dating, whole-rock geochemistry, and Sr–Nd–Pb–Hf isotopic compositions in order to further our understanding of these issues, as well as their regional implications. The Huangshaping granitoids are characterized by two pulses of intrusive activity: a first-stage quartz porphyry and a second-stage felsite and granite porphyry, our new data show that the quartz porphyry and felsite formed at 160.5 ± 1.3 and 156.6 ± 1.4 Ma, respectively, representing a period of Late Jurassic magmatism. Granitic enclaves within the quartz porphyry crystallized at 160.2 ± 1.6 Ma, and zircons and apatites from the enclaves exhibit Hf isotopic and geochemical compositions that suggest a Palaeoproterozoic lower crustal melt as one end-member of the magma that formed the quartz porphyry, whereas another likely end-member was coeval mantle-derived magma, as indicated by the geochemistry and Sr–Nd–Pb–Hf isotopes. However, both the felsite and granite porphyry were probably derived from the melting of metamorphic basement rocks in the upper crust. The felsite clearly formed as a result of the rapid ascent and cooling of magma, whereas the granite porphyry underwent fractional crystallization. The magma sources and evolution of the granitoids, as well as their association with the Huangshaping mineralization, suggest that melting of upper crustal components controlled the W–Mo and Pb–Zn mineralization, whereas dehydration of a subducted slab provided the Cu mineralization in southern Hunan Province.     

Geochemistry,zircon U–Pb analysis,and fluid inclusion 40Ar/39Ar geochronology of the Yingchengzi gold deposit,southern Heilongjiang Province,NE China

The Yingchengzi gold deposit, located 10 km west of Shalan at the eastern margin of the Zhangguangcai Range, is the only high commercially valuable gold deposit in southern Heilongjiang Province, NE China. This study investigates the chronology and geodynamic mechanisms of igneous activity and metallogenesis within the Yingchengzi gold deposit. New zircon U–Pb data, fluid inclusion ⁴⁰Ar/³⁹Ar dating, whole‐rock geochemistry and Sr–Nd isotopic analysis is presented for the Yingchengzi deposit to constrain its petrogenesis and mineralization. Zircon U–Pb dating of the granite and diabase–porphyrite rocks of the igneous complex yields mean ages of 471.7 ± 5.5 and 434 ± 15 Ma respectively. All samples are high‐K calc‐alkaline or shoshonite rocks, are enriched in light rare earth elements and large ion lithophile elements, and are depleted in high field strength elements, consistent with the geochemical characteristics of arc‐type magmas. The Sr–Nd isotope characteristics indicate that the granite formed by partial melting of the lower crust, including interaction with slab‐derived fluids from an underplated basaltic magma. The primary magma of the diabase–porphyrite was likely derived from the metasomatized mantle wedge by subducted slab‐derived fluids. Both types of intrusive rocks were closely related to subduction of the ocean plate located between the Songnen–Zhangguangcai Range and Jiamusi massifs. However, fluid inclusion ⁴⁰Ar/³⁹Ar dating indicates that the Yingchengzi gold deposit formed at ~249 Ma, implying that the mineralization is unrelated to both the granite (~472 Ma) and diabase–porphyrite (~434 Ma) intrusions. Considering the tectonic evolution of the study area and adjacent regions, we propose that the Yingchengzi gold deposit was formed in a late Palaeozoic–Early Triassic continental collision regime following the closure of the Paleo‐Asian Ocean. In addition, the Yingchengzi deposit could be classified as a typical orogenic‐type gold deposit occuring in convergent plate margins in collisional orogens, and unlikely an intrusion‐related gold deposit as reported by previous studies. Copyright © 2015 John Wiley & Sons, Ltd.     

大兴安岭北部岔路口斑岩钼矿床岩浆岩锆石U Pb年龄及其地质意义

黑龙江省岔路口超大型斑岩钼矿床位于大兴安岭北部,是目前我国东北地区最大的钼矿床,矿体赋存于中酸性杂岩体及侏罗系火山-沉积岩内,其中花岗斑岩、石英斑岩、细粒花岗岩与钼矿化关系密切.本文采用LA-ICP-MS锆石U-Pb定年方法,获得了矿区内二长花岗岩、花岗斑岩、石英斑岩、细粒花岗岩、流纹斑岩、闪长玢岩及安山斑岩的结晶年龄分别为162±1.6 Ma、149±4.6 Ma、148±1.6 Ma、148±1.2 Ma、137±3.3 Ma、133±1.7Ma和132±1.6 Ma.岔路口矿区内至少存在3期岩浆活动,其顺序为侏罗纪火山-沉积岩、二长花岗岩→晚侏罗世花岗斑岩、石英斑岩、细粒花岗岩→早白垩世流纹斑岩、闪长玢岩、安山斑岩.岔路口矿床成矿时代为晚侏罗世,是东北亚大陆内部构造-岩浆活化的产物,形成于古太平洋板块俯冲作用引起的挤压向伸展构造体制转折背景,与我国东部大规模钼矿化爆发期相对应.     

云南澜沧老厂隐伏花岗斑岩体地球化学特征及构造环境

详细阐述了老厂隐伏花岗斑岩的地球化学特征,利用图解判别了其形成的构造环境,并初步探讨其成因机制。老厂花岗斑岩SiO2含量(68.09%~73.48%)与中国花岗岩平均值基本相当,富碱(Na2O+K2O为7.73%~8.51%),富钾(K2O/Na2O为1.85~25.8),属酸性偏铝质高钾钙碱性系列岩浆岩。轻稀土元素中等富集,重稀土元素相对亏损,(La/Yb)N=12.01~24.85,δEu=0.79~0.99(为弱负异常),稀土元素分布曲线为平滑的右倾曲线。通过花岗斑岩地球化学特征、图解判别、锆石标型特征等的综合研究,认为老厂隐伏花岗斑岩体是以壳源为主的壳幔源混合成因花岗斑岩,形成于青藏高原新生代碰撞造山主碰撞阶段区域挤压机制下的主碰撞构造环境。碰撞激发深部地幔局部熔融,使熔融体沿穿透性构造发育的早期裂谷带轴部上涌,成为构造-岩浆-热事件的主要驱动力;地幔物质涌入,向下地壳注入新生物质,诱发下地壳物质熔融,形成壳幔混合源富钾含矿岩浆。     

苏门答腊岛苏利特河—苏里安铜成矿带埃达克质侵入岩和矽卡岩地球化学特征及成因意义

本文旨在通过分析苏门答腊岛苏里安斑岩型铜矿至苏利特河矽卡岩型铜矿成矿带中埃达克质侵入岩及矽卡岩的岩石学和地球化学特征,探讨其成因意义。该成矿带是巴东地区辛卡拉克湖以东地球化学异常带的主体部分,其绝大多数侵入岩浆体皆为为Ⅰ-型花岗岩复合体,相当于印支晚期同碰撞火山弧和燕山早期碰撞后岩浆侵入活动的产物。该成矿带内的埃达克质花岗岩和闪长斑岩(早侏罗世和早白垩世)具有低的Y、Yb含量、高的ΣREE含量和Eu正异常,在构造环境判别图上落在活动大陆边缘(ACM)火山弧环境中。埃达克质岩浆来源于俯冲洋壳板片部分熔融。然而,矽卡岩主量元素与岩浆岩侵入体相比,其CaO含量增多,SiO2、Al2O3、K2O以及Na2O含量降,REE普遍表现为Eu负异常。该成矿带内矿化矽卡岩与侵入岩的微量元素模式在蛛网图上显示某些相似性,但是二者的REE配分模式却不尽相同。矽卡岩的微量元素和稀土元素具有低Rb、Ba含量和K、Sr、P、Ti低谷,主要继承了原始岩浆和母岩埃达克质岩的共同特征。矽卡岩化是引起Ti、Yb、Y和REE总量降低的主导控制作用。     

Long-lived,stationary magmatism and pulsed porphyry systems during Tethyan subduction to post-collision evolution in the southernmost Lesser Caucasus,Armenia and Nakhitchevan

The composite Meghri–Ordubad and Bargushat plutons of the Zangezur–Ordubad region in the southernmost Lesser Caucasus consist of successive Eocene to Pliocene magmatic pulses, and host two stages of porphyry Cu–Mo deposits. New high-precision TIMS U–Pb zircon ages confirm the magmatic sequence recognized by previous Rb–Sr isochron and whole-rock K–Ar dating. A 44.03 ± 0.02 Ma-old granite and a 48.99 ± 0.07 Ma-old granodiorite belong to an initial Eocene magmatic pulse, which is coeval with the first stage of porphyry Cu–Mo formation at Agarak, Hanqasar, Aygedzor and Dastakert. A subsequent Oligocene magmatic pulse was constrained by U–Pb zircon ages at 31.82 ± 0.02 Ma and 33.49 ± 0.02 Ma for a monzonite and a gabbro, and a late Miocene porphyritic granodioritic and granitic pulse yielded ages between 22.46 ± 0.02 Ma and 22.22 ± 0.01 Ma, respectively. The Oligo-Miocene magmatic evolution broadly coincides with the second porphyry-Cu–Mo ore deposit stage, including the major Kadjaran deposit at 26–27 Ma.Primitive mantle-normalized spider diagrams with negative Nb, Ta and Ti anomalies support a subduction-like nature for all Cenozoic magmatic rocks. Eocene magmatic rocks have a normal arc, calc-alkaline to high-K calc-alkaline composition, early Oligocene magmatic rocks a high-K calc-alkaline to shoshonitic composition, and late Oligocene to Mio-Pliocene rocks are adakitic and have a calc-alkaline to high-K calc-alkaline composition. Radiogenic isotopes reveal a mantle-dominated magmatic source, with the mantle component becoming more predominant during the Neogene. Trace element ratio and concentration patterns (Dy/Yb, Sr/Y, La/Yb, Eu/Eu*, Y contents) correlate with the age of the magmatic rocks. They reveal combined amphibole and plagioclase fractionation during the Eocene and the early Oligocene, and amphibole fractionation in the absence of plagioclase during the late Oligocene and the Mio-Pliocene, consistent with Eocene to Pliocene progressive thickening of the crust or increasing pressure of magma differentiation. Characteristic trace element and isotope systematics (Ba vs. Nb/Y, Th/Yb vs. Ba/La, ²⁰⁶Pb/²⁰⁴Pb vs. Th/Nb, Th/Nb vs. δ¹⁸O, REE) indicate that Eocene magmatism was dominated by fluid-mobile components, whereas Oligocene and Mio-Pliocene magmatism was dominated by a depleted mantle, compositionally modified by subducted sediments.A two-stage magmatic and metallogenic evolution is proposed for the Zangezur–Ordubad region. Eocene normal arc, calc-alkaline to high-K calc-alkaline magmatism was coeval with extensive Eocene magmatism in Iran attributed to Neotethys subduction. Eocene subduction resulted in the emplacement of small tonnage porphyry Cu–Mo deposits. Subsequent Oligocene and Miocene high-K calc-alkaline and shoshonitic to adakitic magmatism, and the second porphyry Cu–Mo deposit stage coincided with Arabia–Eurasia collision to post-collision tectonics. Magmatism and ore formation are linked to asthenospheric upwelling along translithospheric, transpressional regional faults between the Gondwana-derived South Armenian block and the Eurasian margin, resulting in decompression melting of lithospheric mantle, metasomatised by sediment components added to the mantle during the previous Eocene subduction event.     

Petrogenesis of Ore‐Related Granodiorite Porphyry in the Jiande Copper Deposit,SE China: Implications for the Tectonic Setting and Mineralization

Adakitic rocks and related Cu–Au mineralization are widespread along eastern Jiangnan Orogen in South China. Previous studies have mainly concentrated on those in the Dexing area in northeastern Jiangxi Province, but information is lacking on the genesis and setting of those in northwestern Zhejiang Province. The Jiande copper deposit is located in the suture zone between the Yangtze and Cathaysia blocks of South China. This paper presents systematic LA–ICP–MS zircon U–Pb dating and element and Sr–Nd–Hf isotopic data of the Jiande granodiorite porphyry. Zircon dating showed that the Jiande granodiorite porphyry was produced during the Middle Jurassic (ca. 161 Ma). The Jiande granodiorite porphyry is characterized by adakitic geochemical affinities with high Sr/Y and La_N/Yb_N ratios but low Y and Yb contents. The absence of a negative Eu anomaly, extreme depletion in Y and Yb, relatively low MgO contents, and relatively high ²⁰⁷Pb/²⁰⁴Pb ratios, indicated that the Jiande granodiorite porphyry was likely derived from partial melting of the thickened lower continental crust. In addition, the Jiande granodiorite porphyry shows arc magma geochemical features (e.g., Nb, Ta and Ti depletion), with bulk Earth‐like ε_Nd (t) values (?2.89 to ?1.92), ε_Hf (t) values (?0.6 to +2.8), and initial ⁸⁷Sr/⁸⁶Sr (0.7078 to 0.7105). However, a non‐arc setting in the Middle Jurassic is indicated by the absence of arc rocks and the presence of rifting‐related igneous rock associations in the interior of South China. Combined with the regional Neoproterozoic Jiangnan Orogeny, it indicates that these arc magma geochemical features are possibly inherited from the Neoproterozoic juvenile continental crust formed by the ancient oceanic crust subduction along the Jiangnan Orogen. The geodynamic environment that is responsible for the development of the Middle Jurassic Jiande granodiorite porphyry is likely a localized intra‐continental extensional environment along the NE‐trending Jiangshan‐Shaoxing Deep Fault as a tectonic response to far‐field stress at the margins of the rigid South China Plate during the early stage of the paleo‐Pacific plate subduction. In terms of Cu mineralization, we suggest that the metal Cu was released from the subducted oceanic slab and reserved in the juvenile crust during Neoproterozoic subduction along the eastern Jiangnan Orogen region. Partial melting of the Cu rich Neoproterozoic juvenile crust during the Middle Jurassic time in the Jiande area caused the formation of adakitic rocks and the Cu deposit.     

Lithogeochemical,Re–Os and U–Pb Geochronological,Hf–Lu and S–Pb Isotope Data of the Ga'erqiong‐Galale Cu–Au Ore‐Concentrated Area: Evidence for the Late Cretaceous Magmatism and Metallogenic Event in the Bangong‐Nujiang Suture Zone,Northwestern Tibet,China

The Ga'erqiong‐Galale skarn–porphyry copper–gold ore‐concentrated area is located in the western part of the Bangong‐Nujiang suture zone north of the Lhasa Terrane. This paper conducted a systematic study on the magmatism and metallogenic effect in the ore‐concentrated area using techniques of isotopic geochronology, isotopic geochemistry and lithogeochemistry. According to the results, the crystallization age of quartz diorite (ore‐forming mother rock) in the Ga'erqiong deposit is 87.1 ± 0.4 Ma, which is later than the age of granodiorite (ore‐forming mother rock) in the Galale deposit (88.1 ± 1.0 Ma). The crystallization age of granite porphyry (GE granite porphyry) in the Ga'erqiong deposit is 83.2 ± 0.7 Ma, which is later than the age of granite porphyry (GL granite porphyry) in the Galale deposit (84.7 ± 0.8 Ma).The quartz diorite, granodiorite, GE granite porphyry and GL granite porphyry both main shows positive ε_Hf(t) values, suggesting that the magmatic source of the main intrusions in the ore‐concentrated area has the characteristics of mantle source region. The Re–Os isochron age of molybdenite in the Ga'erqiong district is 86.9 ± 0.5 Ma, which is later than the mineralization age of the Galale district (88.6 ± 0.6 Ma). The main intrusive rocks in the ore‐concentrated area have similar lithogeochemical characteristics, for they both show the relative enrichment in large‐ion lithophile elements(LILE: Rb, Ba, K, etc.), more mobile highly incompatible lithophile elements(HILE: U, Th) and relatively depleted in high field strength elements (HFSE: Nb, Ta, Zr, Hf, etc.), and show the characteristics of magmatic arc. The studies on the metal sulfides' S and Pb isotopes and Re content of molybdenite indicate that the metallogenic materials of the deposits in the ore‐concentrated area mainly come from the mantle source with minor crustal source contamination. Based on the regional tectonic evolution process, this paper points out that the Ga'erqiong‐Galale copper–gold ore‐concentrated area is the typical product of the Late Cretaceous magmatism and metallogenic event in the collision stage of the Bangong‐Nujiang suture zone.     

Petrological and Geochemical Characteristics of Intrusive Rocks Related to Porphyry Copper Mineralization and the Implications for the Genesis of Deposits in the Namosi area, Viti Levu, Republic of the Fiji Islands

In the Namosi district, of Viti Levu Island, Republic of the Fiji Islands, we conducted chemical analysis on intrusive rocks and attempted to clarify the relationship between petrological characteristics and mineralization. Samples were collected from the Waisoi copper deposit, Waivaka corridor, Waisomo, Wailutelevu and Wainabama Southwest localities. The intrusive rocks in the district show the overall characteristics of calc-alkaline magnetite series. Using the normative composition diagram for granite classification, most of the intrusive rocks plot in the tonalite, granodiorite, quartz monzodiorite and quartz diorite fields. Rare earth element (REE) analysis revealed that at Waisoi the intrusive rocks tend towards an Eu positive anomaly, whereas most of those at Waisomo tend to have a negative anomaly. The (Ce_cn/Yb_cn)/Yb_cn ratio shows that the intrusive rocks in the Namosi district may be derived from a mantle origin magma possibly contaminated by crustal materials. Waisoi rocks have less contamination with continental crust and show higher gold content compared to those of the Waivaka corridor. The observed differences between Waisoi and Waivaka corridor in the Cu/Au ratio might also be caused by varying amounts of contamination by crustal materials. There is no clear correlation between the La/Yb ratio and K–Ar ages, however, the La/Yb ratio of the Waivaka corridor rocks has a wide range, suggesting a variable amount of crustal contamination of the magma from 7 to 5 Ma. The less crustal contamination and generation of relatively high silica contents under relatively oxidized conditions in the Waisoi magmas is correlated with Au-rich porphyry copper mineralization and in contrast more crustal contamination produced Au-poor porphyry copper mineralization at the Waivaka Corridor in the Namosi district.