中国三氟甲烷处置政策分析及建议

通过分析减排量核查报告,得出2014年政策实施带来了6078.20万t CO₂e的三氟甲烷（HFC-23）减排,占“十二五”氢氟碳化物（HFCs）累计减排目标的21.7%。此外,通过分析政策面临的问题,从监测方法学、政策设计和后续运行监管3个方面,对政策的后续运行及2020年后HFC-23的减排提出了建议。     

中国履行《蒙特利尔议定书(基加利修正案)》减排三氟甲烷的对策分析

2016年10月制定的《关于消耗臭氧层物质的蒙特利尔议定书（基加利修正案）》将三氟甲烷（HFC-23）纳入了其附件F第二类管控物质名单,并要求缔约国自2020年1月1日起以缔约方核准的技术对HFC-23进行销毁。伴随中国二氟一氯甲烷（HCFC-22）原料用途需求增长,其副产物HFC-23的产生量呈上升趋势,尽管HCFC-22生产工艺不断优化,HFC-23的副产率逐步下降,预测2050年HFC-23产生量将达到2.47万t（或365.56 Mt CO₂-eq),2020—2050年HFC-23累计产生量约56.3万t,折合约8332.40 Mt CO₂-eq。截至2015年,通过清洁发展机制以及国家发展和改革委员会减排专项的资助,中国以焚烧分解技术销毁HFC-23累计54585 t,为全球温室气体减排做出了重要贡献,但这一减排也花费了巨额资金投资焚烧设备和支付焚烧运行费用,提高了企业的生产成本、浪费了氟资源。研究显示,HFC-23资源化利用技术路线是可行的且中国相关技术专利正在逐步增加,鼓励和推进HFC-23资源化利用技术开发与应用是消除HFC-23排放可行的技术途径,也是未来中国加入并履行《基加利修正案》关键的技术路线选择。     

中国氟化工行业HFC-23减排潜力分析

我国是全球二氟一氯甲烷（HCFC-22）的主要生产国,在HCFC-22的生产过程中,会产生大量的温室气体--三氟甲烷（HFC-23）。通过分析我国11个HFC-23减排清洁发展机制（CDM）项目的监测数据,确定HFC-23的排放因子,估算我国2000-2010年HFC-23的排放量,并预测了2011-2020年HFC-23的排放量和减排潜力。预计到2020年,我国HFC-23的排放量将达到2.3亿t CO₂当量。如果HCFC-22企业能够实现自主减排,那么将为我国2020年CO₂排放强度下降40%～45%的减排目标贡献3.2%～3.6%。     

中国汽车空调行业HFC-134a需求和排放预测

 近年来HFC-134a作为中国汽车空调行业CFC-12制冷剂最主要的替代品,其消费量增长迅速,是中国消费量最大的HFCs（氢氟烃类物质）。以2005年为基线,通过制冷剂替代、技术进步、熟练操作和政策控制等情景假设,预测了中国汽车空调行业HFC-134a的需求量及排放量。结果表明：到2010和2015年,汽车空调HFC-134a的消费量将分别接近2.0万和3.5万t,排放量将分别接近1.6万和3.0万t,约折合排放21.0 和39.0 Mt CO₂当量。上述排放相对基线情景（即维持当前政策措施和不开展回收活动）,2010年和2015年减排温室气体分别为6.7 和13.0 Mt CO₂当量。     

中国汽车空调行业淘汰HFC-134a技术选择与政策建议

HFC-134a在中国汽车空调行业广泛使用,并已成为中国目前排放量最大的有意生产和使用的HFCs之一。欧盟和美国已经颁布相关法律法规控制包括HFC-134a在内的含氟温室气体的消费和排放。如果选择低全球变暖潜势（GWP）替代技术,中国汽车空调行业将具有巨大的温室气体减排潜力;伴随着汽车空调系统需求呈现的多样化,现有替代技术如HFO-124yf、HFC-152a、CO₂等各有优势和不足,需要综合考虑它们的经济成本、市场化可行性以及安全风险和环保标准;制定HFC-134a淘汰政策、积极推进替代技术的研究和应用,以积极响应国际社会加快淘汰HFC-134a的行动,也是落实2014年《中美气候变化联合声明》中提出的关于削减全球氢氟碳化物的行动。     

欧盟《气候与能源2030政策框架》要点分析与启示

通过分析《气候与能源2030政策框架》（以下简称《框架》）方案要点,认为欧盟2030年的减排目标相对2020年承诺目标更为积极,可再生能源目标略高于之前官方预期。由于东欧国家的参与,欧盟一方面获得了这些国家盈余的排放配额,帮助欧盟作为一个整体实现减排目标;另一方面,成员国经济发展水平差异增大,导致欧盟施行相对积极的环境政策阻力加大,未来大幅调整减排目标的可能性不大。《框架》目标将可能对2020年后国际碳市场需求预估产生影响,未来国际碳市场的健康运行,将不仅需要欧盟外的发达国家提出具有雄心的减排目标,也需要欧盟提高减排目标,增加其对于国际减排配额的需求;此外,欧盟辅助实现40%减排目标的相关生产标准和措施,可能对未来全球自由贸易产生影响,其他国家尤其是对外贸易依存度较高的发展中国家需要密切关注相关动向。《框架》方案所提出的以应对气候变化引领和促进经济发展、采用组合目标且针对不同目标采取不同实现形式、展现制定目标的透明度、充分考虑成员国差异等提法和操作方式值得中国借鉴。     

《灾害性天气预报警报指南》解读

2011年12月30日,国家质量监督检验检疫总局、国家标准化管理委员会批准发布了《灾害性天气预报警报指南》(GB/T 27966—2011)国家标准(中华人民共和国国家标准公告2011年第23号),自2012年3月1日起实施。标志着我国灾害性天气的预报警报有了规范性的标准。在面向政府、灾害处置机构、公众应对气象灾害时,将会扩大气象资源共享,保障灾害处置工作高效运转,提高灾害处置工作中气象服务能力和服务效益等方面发挥重要作用。     

《应急气象服务工作流程》解读

2011年12月30日,国家质量监督检验检疫总局、国家标准化管理委员会批准发布了《应急气象服务工作流程》（GB/T 27965—2011）国家标准（中华人民共和国国家标准公告2011年第23号）,自2012年3月1日起实施。     

巴黎协定背景下全球减排博弈模拟研究

构建了具有7个国家集团的全球多国家集团气候博弈集成评估模拟系统,针对《巴黎协定》背景下各国至2050年以及2100年的减排目标,分别对减排博弈的纳什均衡、博弈不确定性以及外部政策对减排博弈的影响展开了模拟分析。研究发现：在基准情景下,全球各国将在2030年后均选择不减排策略,全球至2100年升温达到2.62℃;而模型参数的不确定性也未能突破全球零减排的纳什均衡;而仅当在全球范围内对不减排采取惩罚措施时,全球零减排的纳什均衡点被打破。但在当前《巴黎协定》减排承诺下,为达到2℃的温控目标,加大2030—2050年的减排幅度至关重要,否则全球将在2040年左右突破2℃阈值。     

《京都议定书》第二承诺期森林管理基准线分析

基于各附件I缔约方2011年提交的年度国家温室气体排放清单、《京都议定书》第一承诺期森林管理活动的温室气体源/汇数据,以及森林管理活动的基准线数据,分析了森林管理活动在第一承诺期履约中的贡献,以及按各方提交的基准线,预计森林管理活动在未来承诺期履约中的作用。结果表明,《京都议定书》第一承诺期的最初两年（2008—2009年）,附件I缔约方可从合格的森林管理活动中获得年均2.46亿t CO2当量（CO2-eq）的信用额,相当于相应缔约方基准年（1990年）源排放的2.3%,对减限排目标的贡献率达53%,不合理的规则使一些缔约方在履约中可过度地利用森林管理的汇清除。各附件I缔约方提交的2013—2020年森林管理活动的基准线（约2.52亿t CO2-eq/a的净汇清除）远低于目前和过去的水平,使其可从中获得的用于抵消减排目标的信用额约为第一承诺期的4倍,对未来承诺期履约的贡献率将更大,一些缔约方提交的减排目标中的大部分可通过森林管理活动的信用额来抵消。因此,本文建议在未来的谈判中,要严格控制可用的森林管理活动的信用额,避免森林管理活动被滥用。     

Perverse incentives under the CDM: an evaluation of HFC-23 destruction projects

The clean development mechanism (CDM) under the Kyoto Protocol allows industrialized countries to use credits from greenhouse gas (GHG) abatement projects in developing countries. A key requirement of the CDM is that the emission reductions be real, measurable and additional. This article uses data from registered projects to evaluate the extent to which these objectives are met by projects that reduce hydrofluorocarbon-23 (HFC-23) emissions in the production of hydrochlorofluorocarbon-22 (HCFC-22). The data show that HCFC-22 plants produced significantly less HFC-23 during periods when no emission credits could be claimed compared with periods when HFC-23 destruction could be credited under the CDM. Moreover, the total amount of HCFC-22 produced appears to be determined mainly by CDM rules. This suggests that the claimed emission reductions may partly not be real and that the CDM provides perverse incentives to generate more HFC-23. The accelerated phase-out of HCFCs under the Montreal Protocol on Substances that Deplete the Ozone Layer could worsen this situation. To address these issues an ambitious emission benchmark for the baseline HFC-23 emissions is proposed.     

中国房间空调器行业淘汰HCFC-22的环境效益分析

中国是当前最大的HCFCs(含氢氟氯烃类物质)年生产和消费国家,而其中HCFC-22的生产量约占全部HCFCs的80%。2007年国际社会决定加速淘汰HCFCs,这将带来巨大的环境效益。为此,选择房间空调器行业对我国加速淘汰HCFC-22的环境效益进行了分析。通过淘汰情景和基线情景对比得出,采用HC-290(丙烷)替代制冷剂既可以直接实现温室气体减排,又可以节电从而间接减少温室气体排放。比较HFC-410A和HC-290两种替代淘汰情景,后者的环境效益显著高于前者。     

Estimate of Hydrofluorocarbon Emissions for 2012–16 in the Yangtze River Delta,China

Hydrofluorocarbons(HFCs) have been widely used in China as substitutes for ozone-depleting substances,the production and use of which are being phased out under the Montreal Protocol.China is a major consumer of HFCs around the world,with its HFC emissions in CO_2-equivalent contributing to about 18% of the global emissions for the period2012-16.Three methods are widely used to estimate the emissions of HFCs-namely,the bottom-up method,top-down method and tracer ratio method.In this study,the tracer ratio method was adopted to estimate HFC emissions in the Yangtze River Delta(YRD),using CO as a tracer.The YRD region might make a significant contribution to Chinese totals owing to its rapid economic growth.Weekly flask measurements for ten HFCs(HFC-23,HFC-32,HFC-125,HFC-134 a,HFC-143 a,HFC-152 a,HFC-227 ea,HFC-236 fa,HFC-245 fa and HFC-365 mfc) were conducted at Lin'an Regional Background Station in the YRD over the period 2012-16,and the HFC emissions were 2.4±1.4 Gg yr~(-1) for HFC-23,2.8±1.2 Gg yr~(-1) for HFC-32,2.2±1.2 Gg yr~(-1) for HFC-125,4.8±4.8 Gg yr~(-1) for HFC-134 a,0.9±0.6 Gg yr~(-1) for HFC-152 a,0.3±0.3 Gg yr~(-1) for HFC-227 ea and 0.3±0.2 Gg yr~(-1) for HFC-245 fa.The YRD total HFC emissions reached 53 Gg CO_2-e yr~(-1),contributing 34% of the national total.The per capita HFC CO_2-equivalent emissions rate was 240 kg yr-1,while the values of per unit area emissions and per million GDP emissions reached 150 Mg km~(-2)yr~(-1) and 3500 kg yr~(-1)(million CNY GDP)-1,which were much higher than national or global levels.     

Tropospheric transformation products of a series of hydrofluorocarbons and hydrochlorofluorocarbons

The products of the Cl-atom initiated reactions of a series of hydrofluorocarbons (HFCs) and hydrochlorofluorocarbons (HCFCs) in air have been investigated at 298 K and one atmosphere (740 Torr total pressure) of air. The products observed and quantified and their yields (%) were as follows: from CHF₂Cl (HCFC-22), C(O)F₂ (100%); from CHFCl₂ (HCFC-21), C(O)FCl (100%); from CH₂FCl (HCFC-31), HC(O)F (100%); from CH₃F (HFC-41), HC(O)F (100%); from CH₃CFCl₂ (HCFC-141b), C(O)FCl (100%); from CH₃CF₂Cl (HCFC-142b), C(O)F₂ (100%); from CH₃CHF₂ (HFC-152a), C(O)F₂ (92%); from CHCl₂CF₃ (HCFC-123), CF₃C(O)Cl (98%); from CHFClCF₃ (HCFC-124), CF₃C(O)F (101%); and from CHF₂CF₃ (HFC-125), C(O)F₂ (100%). The reaction mechanisms are discussed.     

A no cap but trade proposal for emission targets

One problem in international climate policy is the refusal of large developing countries to accept emission reduction targets. Brazil, China and India together account for about 20% of today's CO₂ emissions. We analyse the case in which there is no international agreement on emission reduction targets, but countries do have domestic targets, and trade permits across borders. We contrast two scenarios. In one scenario, Brazil, China and India adopt their business as usual emissions as their target. In this scenario, there are substantial exports of emission permits from developing to developed countries, and substantial economic gains for all. In the second scenario, Brazil, China and India reduce their emissions target so that they have no net economic gain from permit trade. Here, developing countries do not accept responsibility for climate change (as they bear no net costs), but they do contribute to an emission reduction policy by refusing to make money out of it. Adopting such break-even targets can be done at minor cost to developed and developing countries (roughly $2 bn/year each in extra costs and forgone benefits), while developing countries are still slightly better off than in the case without international emissions trade. This result is robust to variations in scenarios and parameters. It contrasts with Stewart and Wiener (2003) who propose granting ‘hot air’ to developing countries to seduce them to accept targets. In 2020, China and India could reduce their emissions by some 10% from the baseline without net economic costs.     

Determination of rate constants for reactions of some hydrohaloalkanes with OH radicals and their atmospheric lifetimes

Rate constants have been measured for the gas-phase reactions of hydroxyl radical with partly halogenated alkanes using the discharge-flow-EPR technique over the temperature range 298–460 K. The following Arrhenius expressions have been derived (units 10^–13 cm³ molecule^–1 s^–1): (8.1 _–1.2 ^+1.5 ) exp{–(1516±53)/T} for CHF₂Cl (HCFC-22); (10.3 _–1.5 ^+1.8 ) exp{–(1588±52)/T} for CH₂FCF₃ (HFC-134a); (11.3 _–1.6 ^+2.1 ) exp{–(918±52)/T} for CHCl₂CF₂Cl (HCFC-122); (9.2 _–2.0 ^+2.5 ) exp{–(1281±85)/T} for CHFClCF₂Cl (HCFC-123a).The atmospheric lifetimes for the substances have been estimated to be 12.6, 12.9, 1.05, and 4.8 years, respectively, and the accuracy of the estimates is discussed.