The Dual Sources of Io's Sodium Clouds

Io's sodium clouds result mostly from a combination of two atmospheric escape processes at Io. Neutralization of Na⁺ and/or NaX⁺ pickup ions produces the “stream” and the “jet” and results in a rectangular-shaped sodium nebula around Jupiter. Atmospheric sputtering of Na by plasma torus ions produces the “banana cloud” near Io and a diamond-shaped sodium nebula. Charge exchange of thermal Na⁺ with Na in Io's atmosphere does not appear to be a major atmospheric ejection process. The total ejection rate of sodium from Io varied from 3×10²⁶ to 25×10²⁶ atoms/s over seven years of observations. Our results provide further evidence that Io's atmospheric escape is driven from collisionally thick regions of the atmosphere rather than from the exosphere.     

Photochemistry of a Volcanically Driven Atmosphere on Io: Sulfur and Oxygen Species from a Pele-Type Eruption

To determine how active volcanism might affect the standard picture of sulfur dioxide photochemistry on Io, we have developed a one-dimensional atmospheric model in which a variety of sulfur-, oxygen-, sodium-, potassium-, and chlorine-bearing volatiles are volcanically outgassed at Io's surface and then evolve due to photolysis, chemical kinetics, and diffusion. Thermochemical equilibrium calculations in combination with recent observations of gases in the Pele plume are used to help constrain the composition and physical properties of the exsolved volcanic vapors. Both thermochemical equilibrium calculations (Zolotov and Fegley 1999, Icarus141, 40-52) and the Pele plume observations of Spencer et al. (2000; Science288, 1208-1210) suggest that S₂ may be a common gas emitted in volcanic eruptions on Io. If so, our photochemical models indicate that the composition of Io's atmosphere could differ significantly from the case of an atmosphere in equilibrium with SO₂ frost. The major differences as they relate to oxygen and sulfur species are an increased abundance of S, S₂, S₃, S₄, SO, and S₂O and a decreased abundance of O and O₂ in the Pele-type volcanic models as compared with frost sublimation models. The high observed SO/SO₂ ratio on Io might reflect the importance of a contribution from volcanic SO rather than indicate low eddy diffusion coefficients in Io's atmosphere or low SO “sticking” probabilities at Io's surface; in that case, the SO/SO₂ ratio could be temporally and/or spatially variable as volcanic activity fluctuates. Many of the interesting volcanic species (e.g., S₂, S₃, S₄, and S₂O) are short lived and will be rapidly destroyed once the volcanic plumes shut off; condensation of these species near the source vent is also likely. The diffuse red deposits associated with active volcanic centers on Io may be caused by S₄ radicals that are created and temporarily preserved when sulfur vapor (predominantly S₂) condenses around the volcanic vent. Condensation of SO across the surface and, in particular, in the polar regions might also affect the surface spectral properties. We predict that the S/O ratio in the torus and neutral clouds might be correlated with volcanic activity—during periods when volcanic outgassing of S₂ (or other molecular sulfur vapors) is prevalent, we would expect the escape of sulfur to be enhanced relative to that of oxygen, and the S/O ratio in the torus and neutral clouds could be correspondingly increased.     

Silicon tetrafluoride on Io

Silicon tetrafluoride (SiF₄) is observed in terrestrial volcanic gases and is predicted to be the major F-bearing species in low-temperature volcanic gases on Io [Schaefer, L., Fegley Jr., B., 2005b. Alkali and halogen chemistry in volcanic gases on Io. Icarus 173, 454-468]. SiF₄ gas is also a potential indicator of silica-rich crust on Io. We used F/S ratios in terrestrial and extraterrestrial basalts, and gas/lava enrichment factors for F and S measured at terrestrial volcanoes to calculate equilibrium SiF₄/SO₂ ratios in volcanic gases on Io. We conclude that SiF₄ can be produced at levels comparable to the observed NaCl/SO₂ gas ratio. We also considered potential loss processes for SiF₄ in volcanic plumes and in Io's atmosphere including ion-molecule reactions, electron chemistry, photochemistry, reactions with the major atmospheric constituents, and condensation. Photochemical destruction (t_chem ∼266 days) and/or condensation as Na₂SiF₆ (s) appear to be the major sinks for SiF₄. We recommend searching for SiF₄ with infrared spectroscopy using its 9.7 μm band as done on Earth.     

Cassini observations of Io's visible aurorae

More than 500 images of Io in eclipse were acquired by the Cassini spacecraft in late 2000 and early 2001 as it passed through the jovian system en route to Saturn (Porco et al., 2003, Science 299, 1541-1547). Io's bright equatorial glows were detected in Cassini's near-ultraviolet filters, supporting the interpretation that the visible emissions are predominantly due to molecular SO₂. Detailed comparisons of laboratory SO₂ spectra with the Cassini observations indicate that a mixture of gases contribute to the equatorial emissions. Potassium is suggested by new detections of the equatorial glows at near-infrared wavelengths from 730 to 800 nm. Neutral atomic oxygen and sodium are required to explain the brightness of the glows at visible wavelengths. The molecule S₂ is postulated to emit most of the glow intensity in the wavelength interval from 390 to 500 nm. The locations of the visible emissions vary in response to the changing orientation of the external magnetic field, tracking the tangent points of the jovian magnetic field lines. Limb glows distinct from the equatorial emissions were observed at visible to near-infrared wavelengths from 500 to 850 nm, indicating that atomic O, Na, and K are distributed across Io's surface. Stratification of the atmosphere is demonstrated by differences in the altitudes of emissions at various wavelengths: SO₂ emissions are confined to a region close to Io's surface, whereas neutral oxygen emissions are seen at altitudes that reach up to 900 km, or half the radius of the satellite. Pre-egress brightening demonstrates that light scattered into Jupiter's shadow by gases or aerosols in the giant planet's upper atmosphere contaminates images of Io taken within 13 minutes of entry into or emergence from Jupiter's umbra. Although partial atmospheric collapse is suggested by the longer timescale for post-ingress dimming than pre-egress brightening, Io's atmosphere must be substantially supported by volcanism to retain auroral emissions throughout the duration of eclipse.     

Alkali and Chlorine Photochemistry in a Volcanically Driven Atmosphere on Io

Observations of the Io plasma torus and neutral clouds indicate that the extended ionian atmosphere must contain sodium, potassium, and chlorine in atomic and/or molecular form. Models that consider sublimation of pure sulfur dioxide frost as the sole mechanism for generating an atmosphere on Io cannot explain the presence of alkali and halogen species in the atmosphere—active volcanoes or surface sputtering must also be considered, or the alkali and halide species must be discharged along with the SO₂ as the frost sublimates. To determine how volcanic outgassing can affect the chemistry of Io's atmosphere, we have developed a one-dimensional photochemical model in which active volcanoes release a rich suite of S-, O-, Na-, K-, and Cl-bearing vapor and in which photolysis, chemical reactions, condensation, and vertical eddy and molecular diffusion affect the subsequent evolution of the volcanic gases. Observations of Pele plume constituents, along with thermochemical equilibrium calculations of the composition of volcanic gases exsolved from high-temperature silicate magmas on Io, are used to constrain the composition of the volcanic vapor. We find that NaCl, Na, Cl, KCl, and K will be the dominant alkali and chlorine gases in atmospheres generated from Pele-like plume eruptions on Io. Although the relative abundances of these species will depend on uncertain model parameters and initial conditions, these five species remain dominant for a wide variety of realistic conditions. Other sodium and chlorine molecules such as NaS, NaO, Na₂, NaS₂, NaO₂, NaOS, NaSO₂, SCl, ClO, Cl₂, S₂Cl, and SO₂Cl₂ will be only minor constituents in the ionian atmosphere because of their low volcanic emission rates and their efficient photochemical destruction mechanisms. Our modeling has implications for the general appearance, properties, and variability of the neutral sodium clouds and jets observed near Io. The neutral NaCl molecules present at high altitudes in atmosph eres generated by active volcanoes might provide the NaX⁺ ion needed to help explain the morphology of the high-velocity sodium “stream” feature observed near Io.     

S2O, polysulfuroxide and sulfur polymer on Io's surface?

To settle the question of disulfur monoxide and sulfur monoxide deposition and occurrence on Io's surface, we performed series of laboratory experiments reproducing the condensation of S₂O at low temperature. Its polymerization has been monitored by recording infrared spectra under conditions of temperature, pressure, mixing with SO₂ and UV-visible radiation simulating that of Io's surface. Our experiments show that S₂O condensates are not chemically stable under ionian conditions. We also demonstrate that SO and S₂O outgassed by Io's volcanoes and condensing on Io's surface should lead to yellow polysulfuroxide deposits or to white deposits of S₂O diluted in sulfur dioxide frost (i.e., S₂O/SO₂ < 0.1%). Thus S₂O condensation cannot be responsible for the red volcanic deposits on Io. Comparison of the laboratory infrared spectra of S₂O and polysulfuroxide with NIMS/Galileo infrared spectra of Io's surface leads us to discuss the possible identification of polysulfuroxide. We also recorded the visible transmission spectra of sulfur samples resulting from polysulfuroxide decomposition. These samples consist in a mixture of sulfur polymer and orthorhombic sulfur. Using the optical constants extracted from these measurements, we show that a linear combination of the reflectance spectra of our samples, the reflectance spectrum of orthorhombic S₈ sulfur and SO₂ reflectance spectrum, leads to a very good matching of Io's visible spectrum between 330 and 520 nm. We conclude then that Io's surface is probably mainly composed of sulfur dioxide and a mixture of sulfur S₈ and sulfur polymer. Some polysulfuroxide could also co-exist with these dominant components, but is probably restricted to some volcanic areas.     

Lava lakes on Io: observations of Io's volcanic activity from Galileo NIMS during the 2001 fly-bys

Galileo's Near-Infrared Mapping Spectrometer (NIMS) obtained its final observations of Io during the spacecraft's fly-bys in August (I31) and October 2001 (I32). We present a summary of the observations and results from these last two fly-bys, focusing on the distribution of thermal emission from Io's many volcanic regions that give insights into the eruption styles of individual hot spots. We include a compilation of hot spot data obtained from Galileo, Voyager, and ground-based observations. At least 152 active volcanic centers are now known on Io, 104 of which were discovered or confirmed by Galileo observations, including 23 from the I31 and I32 Io fly-by observations presented here. We modify the classification scheme of Keszthelyi et al. (2001, J. Geophys. Res. 106 (E12) 33 025-33 052) of Io eruption styles to include three primary types: promethean (lava flow fields emplaced as compound pahoehoe flows with small plumes <200 km high originating from flow fronts), pillanian (violent eruptions generally accompanied by large outbursts, >200 km high plumes and rapidly-emplaced flow fields), and a new style we call “lokian” that includes all eruptions confined within paterae with or without associated plume eruptions). Thermal maps of active paterae from NIMS data reveal hot edges that are characteristic of lava lakes. Comparisons with terrestrial analogs show that Io's lava lakes have thermal properties consistent with relatively inactive lava lakes. The majority of activity on Io, based on locations and longevity of hot spots, appears to be of this third type. This finding has implications for how Io is being resurfaced as our results imply that eruptions of lava are predominantly confined within paterae, thus making it unlikely that resurfacing is done primarily by extensive lava flows. Our conclusion is consistent with the findings of Geissler et al. (2004, Icarus, this issue) that plume eruptions and deposits, rather than the eruption of copious amounts of effusive lavas, are responsible for Io's high resurfacing rates. The origin and longevity of islands within ionian lava lakes remains enigmatic.     

The polar contribution to the heat flow of Io

Polar brightness temperatures on Io are higher than expected for any passive surface heated by absorbed sunlight. This discrepancy implies large scale volcanic activity from which we derive a new component of Io's heat flow. We present a ‘Three Component’ thermal background, infrared emission model for Io that includes active polar regions. The widespread polar activity contributes an additional ∼0.6 W m⁻² to Io's heat flow budget above the ∼2.5 W m⁻² from thermal anomalies. Our estimate for Io's global average heat flow increases to ∼3±1 W m⁻² and ∼1.3±0.4×10¹⁴ watts total.     

Relative contributions of sublimation and volcanoes to Io's atmosphere inferred from its plasma interaction during solar eclipse

We present a model that describes Io's delayed electrodynamic response to a temporal change in Io's atmosphere. Our model incorporates the relevant physical processes involved in Io's atmosphere-ionosphere-magnetosphere electrodynamic interaction to predict the far-ultraviolet (FUV) radiation as Io enters Jupiter's shadow and re-emerges into sunlight. The predicted FUV brightnesses are highly nonlinear as the strength of the electrodynamic interaction depends on the ratios of ionospheric conductances to the torus Alfvén conductance, but the former are functions of electrodynamics and the atmospheric density, which decays rapidly upon entering eclipse. Key factors governing the time evolution are the column density due to sublimation and the column density due to volcanoes, which maintain the background atmosphere during eclipse. The plasma interaction does not react instantaneously, but lags to a temporarily changing atmosphere. We find three qualitatively different scenarios with two of them including a post-eclipse brightening. The brightness ratio of in-sunlight/in-eclipse coupled with the existence of a sub-jovian equatorial spot constrains the volcanic column density to several times 10¹⁸ m⁻², based on the currently available observations. Thus in sunlight, the sublimation driven part of Io's atmosphere dominates the volcanically driven contribution by roughly a factor of 10 or more.     

The equilibrium of atmospheric sodium

We now have four examples of planetary objects with detectable sodium (and potassium) in their atmospheres—Earth, Io, Mercury and the Moon. After a summary of the observational data, this survey discusses proposed sources and sinks. It appears that Io's surface material is rich in frozen SO₂, but with around 1% of some sodium compound. The Io plasma torus contains ions of S, O and Na, also with at least one molecular ion containing Na. In turn, impact by these ions probably sustains the torus, as well as an extended neutral corona. A primary source for the Earth, Mercury and the Moon is meteoroidal bombardment; at Mercury and perhaps the Moon it may be supplemented by degassing of atoms from the regolith. Photoionization is important everywhere, although hot electrons are dominant at Io.     

Mid-infrared detection of large longitudinal asymmetries in Io's SO2 atmosphere

We have observed about 16 absorption lines of the ν₂ SO₂ vibrational band on Io, in disk-integrated 19-μm spectra taken with the TEXES high spectral resolution mid-infrared spectrograph at the NASA Infrared Telescope Facility in November 2001, December 2002, and January 2004. These are the first ground-based infrared observations of Io's sunlit atmosphere, and provide a new window on the atmosphere that allows better longitudinal and temporal monitoring than previous techniques. Dramatic variations in band strength with longitude are seen that are stable over at least a 2 year period. The depth of the strongest feature, a blend of lines centered at 530.42 cm⁻¹, varies from about 7% near longitude 180° to about 1% near longitude 315° W, as measured at a spectral resolution of 57,000. Interpretation of the spectra requires modeling of surface temperatures and atmospheric density across Io's disk, and the variation in non-LTE ν₂ vibrational temperature with altitude, and depends on the assumed atmospheric and surface temperature structure. About half of Io's 19-μm radiation comes from the Sun-heated surface, and half from volcanic hot spots with temperatures primarily between 150 and 200 K, which occupy about 8% of the surface. The observations are thus weighted towards the atmosphere over these low-temperature hot spots. If we assume that the atmosphere over the hot spots is representative of the atmosphere elsewhere, and that the atmospheric density is a function of latitude, the most plausible interpretation of the data is that the equatorial atmospheric column density varies from about 1.5×¹⁰¹⁷ cm⁻² near longitude 180° W to about 1.5×¹⁰¹⁶ cm⁻² near longitude 300° W, roughly consistent with HST UV spectroscopy and Lyman-α imaging. The inferred atmospheric kinetic temperature is less than about 150 K, at least on the anti-Jupiter hemisphere where the bands are strongest, somewhat colder than inferred from HST UV spectroscopy and millimeter-wavelength spectroscopy. This longitudinal variability in atmospheric density correlates with the longitudinal variability in the abundance of optically thick, near-UV bright SO₂ frost. However it is not clear whether the correlation results from volcanic control (regions of large frost abundance result from greater condensation of atmospheric gases supported by more vigorous volcanic activity in these regions) or sublimation control (regions of large frost abundance produce a more extensive atmosphere due to more extensive sublimation). Comparison of data taken in 2001, 2002, and 2004 shows that with the possible exception of longitudes near 180° W between 2001 and 2002, Io's atmospheric density does not appear to decrease as Io recedes from the Sun, as would be expected if the atmosphere were supported by the sublimation of surface frost, suggesting that the atmosphere is dominantly supported by direct volcanic supply rather than by frost sublimation. However, other evidence such as the smooth variation in atmospheric abundance with latitude, and atmospheric changes during eclipse, suggest that sublimation support is more important than volcanic support, leaving the question of the dominant atmospheric support mechanism still unresolved.     

Formation of mountains on Io: Variable volcanism and thermal stresses

Thermal stresses are potentially important drivers of Io's tectonics and mountain building. It has been hypothesized that sustained local or regional shut down of heat-pipe volcanism on Io could lead to deep crustal heating and large compressive stresses [McKinnon, W.B., Schenk, P.M., Dombard, A.J., 2001. Geology 29, 103-106]. Such large stresses would then be relieved by thrust faulting and uplifting of crustal blocks, producing mountains like those observed on Io. Here we analyze the tectonic consequences of the heat-pipe model in detail, considering both the initial thermal stress state of a basalt or peridotite crust created by heat-pipe volcanism, and relative roles of subsidence stresses (due to burial of preexisting layers) and thermal stresses arising from variable volcanism and changes in crustal (∼lithosphere) thickness. We limit the magnitude of the potential subsidence stresses in our study, because the magnitude of subsidence stresses can be quite large, if not dominant. Results indicate that for a fixed crustal thickness, the region of failure and faulting moves closer to the surface as eruption rate decreases and time increases. When the crust melts at its base as volcanism decreases (as might occur under steady state tidal heating), resulting in crustal thinning, the region of failure is brought even closer to the surface. Naturally, when compressive, subsidence stresses are included, the vertical extent of crust in brittle failure thickens to include most of the lithosphere. In contrast, increases in eruption rate cause the extent of the region in compressional failure to decrease and be driven very deep in the crust (in the absence of sufficient subsidence stress). Therefore, regions of declining volcanism are more likely to produce mountains, whereas regions of extensive or increasing volcanism are less likely to do so. This is consistent with the observation of a global anticorrelation between mountains and volcanic centers on Io. Finally, we find that the choice of crustal composition/rheology (dry basalt vs. dry peridotite) has little effect on our results implying that basalt, peridotite and komatiite are all similarly “stiff” in the Io environment.     

Formation of the sodium clouds and the regolith on Io by micrometeoroid impacts

The effects of the amount of sodium ions, their solar angles correlation, temperature and velocities, have been explained as consequences of the almost full penetration of the second mode of micrometeorite fluxes (M>10^–8 g) across the Io atmosphere to its surface, whereas volcanism may satisfy only the amount of sodium.Conclusions about the formation of fine grains on the Io surface, unflooded by lava, are presented. Due to its large specific surface (m² g^–1) the interaction of this topsoil and the Io atmosphere is no less important than the lava-atmosphere interaction.Paper presented at the European Workshop on Planetary Sciences, organised by the Laboratorio di Astrofisica Spaziale di Frascati, and held between April 23–27, 1979, at the Accademia Nazionale del Lincei in Rome, Italy.From September 1979.     

Nature of the iogenic plasma source in Jupiter's magnetosphere: II. Near-Io distribution

Three-dimensional calculations are presented for the distribution of the iogenic plasma source that is created near Io (i.e., within ∼24 satellite radii about Io) by O and S gases located in the volume above Io's exobase (i.e., corona and escaping extended neutral clouds, designated as the “Outer Region”) and are complementary to a preceding paper for calculations on a circumplanetary scale. The instantaneous pickup ion production rates for both electron impact and charge exchange have significant radial, north-south, and orbital-plane asymmetries beginning just inside and/or beyond Io's Lagrange sphere (5.81 Io radii) and, within the Lagrange sphere, are distributed nearly symmetrically about Io and are highly peaked about Io's exobase. The spatial natures of the corresponding pickup ion density, mass loading rates, and the pickup ion conductivity, current, and magnetic field are investigated. Spatially integrated rates are calculated for the corona volume and compared to larger Outer Region circumplanetary volumes and are also compared to estimates drawn from the scientific literature (but not modeled here) of the spatially integrated rates for pickup processes in the strongly perturbed “Inner Region” below the exobase. Within the corona volume, the spatially-integrated net-mass loading rate and total (electron impact and charge exchange) mass loading rate are only a factor of ∼3 and ∼5, respectively, smaller than those estimated for the Inner Region, whereas for the whole plasma torus, the Outer Region rates are larger or comparable to those estimated for the Inner Region. The total pickup ion gyration power supplied to the whole plasma torus is estimated to be significantly less than the power radiated by the plasma torus, indicating that an additional power source, likely a circumplanetary distribution of nonthermal electrons, is present.     

Impact of electron chemistry on the structure and composition of Io's atmosphere

Two-dimensional model calculations (altitude and solar zenith angle) are performed to investigate the impact of electron chemistry on the composition and structure of Io's atmosphere. The calculations are based upon the model of Wong and Smyth (2000, Icarus 146, 60-74) for Io's SO₂ sublimation atmosphere with the addition of new electron chemistry, where the interactions of the electrons and neutrals are treated in a simple fashion. The model calculations are presented for Io's atmosphere at western elongation (dusk ansa) for both a low-density case (subsolar temperature of 113 K) and a high-density case (subsolar temperature of 120 K). The impact of electron-neutral chemistry on the composition and structure of Io's atmosphere is confined primarily to an interaction layer. The penetration depth of the interaction layer is limited to high altitudes in the thicker dayside atmosphere but reaches the surface in the thinner dayside and/or nightside atmosphere at larger solar zenith angles. Within most of the thicker dayside atmosphere, the column density of SO₂ is not significantly altered by electrons, but in the interaction layer all number densities are significantly altered: SO₂ is reduced, O, SO, S, and O₂ are greatly enhanced, and O, SO, and S become comparable to SO₂ at high altitudes. For the thinner nightside atmosphere, the species number densities are dramatically altered: SO₂ is drastically reduced to the least abundant species of the SO₂ family, SO and O₂ are significantly reduced at all altitudes, and O and S are dramatically enhanced and become the dominant species at all altitudes except near the surface. The interaction layer also defines the location of the emission layer for neutrals excited by electron impact and hence determines the fraction of the total neutral column density that is visible in remote observation. Electron chemistry may also impact the ratio of the equatorial to polar SO₂ column density deduced from Lyman-α images and the north-south alternating and System III longitude-dependent asymmetry observed in polar O and S emissions.     

Nature of the iogenic plasma source in Jupiter's magnetosphere: I. Circumplanetary distribution

Three-dimensional calculations are presented for the circumplanetary nature of the iogenic plasma source (pickup ions produced by electron and charge exchange processes in the plasma torus) created by O and S gases located above Io's exobase in its corona and escaping extended neutral clouds (designated as the “Outer Region”). These calculations are undertaken using neutral cloud models for O and S with realistic incomplete collisional cascade source velocity distributions and rates at Io's exobase and realistic spacetime loss processes in the plasma torus. The resulting spatial distributions for O and S about Jupiter are highly peaked at Io but extend at much lower density levels all about the planet, particularly within Io's orbit where they may play a role in the pitch angle scattering and energy loss of radially inward diffusing energetic electrons for the synchrotron radiation belts of Jupiter, in producing bite-outs in the energy distribution of energetic heavy ions near Io's orbit, and in providing a charge exchange source for energetic neutral atoms (ENAs) detected both near and far from Jupiter. For the iogenic plasma source created by these neutrals, two-dimensional distributions produced by integrating the three-dimensional information along the magnetic field lines are presented for the instantaneous values of the pickup ion rates, the total- and net-mass loading rates, the mass-per-unit-magnetic-flux source rate, the pickup conductivity, the pickup radial current, and the pickup ion power (or energy rate). On the circumplanetary spatial scale, the instantaneous iogenic plasma source is highly peaked about Io's position on its orbit around Jupiter. The degree of orbital asymmetry and its physical origin are discussed, and overall spatially integrated rates are presented. The spatially integrated net-mass loading rate is 154 kg s⁻¹ and the total (electron impact and charge exchange) mass loading rate is 275 kg s⁻¹. Rough minimum estimates are made for the spatially integrated total-mass loading rate created by the “Inner Region” (spatial region below Io's exobase) and are at least ∼1 to 2.5 times larger than that for the Outer Region. Implications of the iogenic plasma source created by the Outer Region and the Inner Region are discussed.     

Alkali and halogen chemistry in volcanic gases on Io

We use chemical equilibrium calculations to model the speciation of alkalis and halogens in volcanic gases emitted on Io. The calculations cover wide temperature (500-2000 K) and pressure (10⁻⁶ to 10⁺¹ bars) ranges, which overlap the nominal conditions at Pele (T=1760 K, P=0.01 bars). About 230 compounds of 11 elements (O, S, Li, Na, K, Rb, Cs, F, Cl, Br, I) are considered. The elemental abundances for O, S, Na, K, and Cl are based upon observations. CI chondritic elemental abundances relative to sulfur are used for the other alkalis and halogens (as yet unobserved on Io). We predict the major alkali species in Pele-like volcanic gases and the percentage distribution of each alkali are LiCl (73%), LiF (27%); NaCl (81%), Na (16%), NaF (3%); KCl (91%), K (5%), KF (4%); RbCl (93%), Rb (4%), RbF (3%); CsCl (92%), CsF (6%), Cs (2%). Likewise the major halogen species and the percentage distribution of each halogen are NaF (88%), KF (10%), LiF (2%); NaCl (89%), KCl (11%); NaBr (89%), KBr (10%), Br (1%); NaI (61%), I (30%), KI (9%). We predict the major halogen condensates and their condensation temperatures at P=0.01 bar are NaF (1115 K), LiF (970 K); NaCl (1050 K), KCl (950 K); KBr (750 K), RbBr (730 K), CsBr (645 K); and solid I₂ (200 K). We also model disequilibrium chemistry of the alkalis and halogens in the volcanic plume. Based on this work and our prior modeling for Na, K, and Cl in a volcanic plume, we predict the major loss processes for the alkali halide gases are photolysis and/or condensation onto grains. Their estimated photochemical lifetimes range from a few minutes for alkali iodides to a few hours for alkali fluorides. Condensation is apparently the only loss process for elemental iodine. On the basis of elemental abundances and photochemical lifetimes, we recommend searching for gaseous KCl, NaF, LiF, LiCl, RbF, RbCl, CsF, and CsCl around volcanic vents during eruptions. Based on abundance considerations and observations of brown dwarfs we also recommend a search of Io's extended atmosphere and the Io plasma torus for neutral and ionized Li, Cs, Rb, and F.     

Photochemistry and Vertical Transport in Io's Atmosphere and Ionosphere

We present an updated model for the photochemistry of Io's atmosphere and ionosphere and use this model to investigate the sensitivity of the chemical structure to vertical transport rates. SO₂is assumed to be the dominant atmospheric gas, with minor molecular sodium species such as Na₂S or Na₂O released by sputtering or venting from the surface. Photochemical products include SO, O₂, S, O, Na, NaO, NaS, and Na₂. We consider both “thick” and “thin” SO₂atmospheres that encompass the range allowed by recent HST and millimeter-wave observations, and evaluate the possibility that O₂and/or SO may be significant minor dayside constituents and therefore likely dominant nightside gases. The fast reaction between S and O₂limits the column abundance of O₂to ∼10⁴less than that calculated by Kumar (J. Geophys. Res.87, 1677–1684, 1982; 89(A9), 7399–7406, 1984) for a pure sulfur/oxygen atmosphere. If a significant source of NaO₂or Na₂O were supplied by the surface and mixed rapidly upward, then oxygen liberated in the chemical reactions which also liberate free Na would provide an additional source of O₂. Fast eddy mixing will enhance the transport of molecular sodium species to the exobase, in addition to increasing the vertical transport rate of ions. Ions produced in the atmosphere will be accelerated by the reduced corotation electric field penetrating the atmosphere. These ions experience collisions with the neutral gas, leading to enhanced vertical ion diffusion. The dominant ion, Na⁺, is lost primarily by charge exchange with Na₂O and/or Na₂S in the lower atmosphere and by diffusion through the ionopause in the upper atmosphere. The atmospheric column abundance of SO, O₂, and the upper atmosphere escape rates of Na, S, O, and molecular sodium species are all strong functions of the eddy mixing rate. Most atmospheric escape, including that of molecular sodium species, probably occurs from the low density “background” SO₂atmosphere, while a localized high density “volcanic” SO₂atmosphere can yield an ionosphere consistent with that detected by the Pioneer 10 spacecraft.     

The Zamama-Thor region of Io: Insights from a synthesis of mapping, topography, and Galileo spacecraft data

We have studied data from the Galileo spacecraft's three remote sensing instruments (Solid-State Imager (SSI), Near-Infrared Mapping Spectrometer (NIMS), and Photopolarimeter-Radiometer (PPR)) covering the Zamama-Thor region of Io's antijovian hemisphere, and produced a geomorphological map of this region. This is the third of three regional maps we are producing from the Galileo spacecraft data. Our goal is to assess the variety of volcanic and tectonic materials and their interrelationships on Io using planetary mapping techniques, supplemented with all available Galileo remote sensing data. Based on the Galileo data analysis and our mapping, we have determined that the most recent geologic activity in the Zamama-Thor region has been dominated by two sites of large-scale volcanic surface changes. The Zamama Eruptive Center is a site of both explosive and effusive eruptions, which emanate from two relatively steep edifices (Zamama Tholi A and B) that appear to be built by both silicate and sulfur volcanism. A ∼100-km long flow field formed sometime after the 1979 Voyager flybys, which appears to be a site of promethean-style compound flows, flow-front SO₂ plumes, and adjacent sulfur flows. Larger, possibly stealthy, plumes have on at least one occasion during the Galileo mission tapped a source that probably includes S and/or Cl to produce a red pyroclastic deposit from the same vent from which silicate lavas were erupted. The Thor Eruptive Center, which may have been active prior to Voyager, became active again during the Galileo mission between May and August 2001. A pillanian-style eruption at Thor included the tallest plume observed to date on Io (at least 500 km high) and new dark lava flows. The plume produced a central dark pyroclastic deposit (probably silicate-rich) and an outlying white diffuse ring that is SO₂-rich. Mapping shows that several of the new dark lava flows around the plume vent have reoccupied sites of earlier flows. Unlike most of the other pillanian eruptions observed during the Galileo mission, the 2001 Thor eruption did not produce a large red ring deposit, indicating a relative lack of S and/or Cl gases interacting with the magma during that eruption. Between these two eruptive centers are two paterae, Thomagata and Reshef. Thomagata Patera is located on a large shield-like mesa and shows no signs of activity. In contrast, Reshef Patera is located on a large, irregular mesa that is apparently undergoing degradation through erosion (perhaps from SO₂-sapping or chemical decomposition of sulfur-rich material) from multiple secondary volcanic centers.     

High-Resolution Keck Adaptive Optics Imaging of Violent Volcanic Activity on Io

Io, the innermost Galilean satellite of Jupiter, is a fascinating world. Data taken by Voyager and Galileo instruments have established that it is by far the most volcanic body in the Solar System and suggest that the nature of this volcanism could radically differ from volcanism on Earth. We report on near-IR observations taken in February 2001 from the Earth-based 10-m W. M. Keck II telescope using its adaptive optics system. After application of an appropriate deconvolution technique (MISTRAL), the resolution, ∼100 km on Io's disk, compares well with the best Galileo/NIMS resolution for global imaging and allows us for the first time to investigate the very nature of individual eruptions. On 19 February, we detected two volcanoes, Amirani and Tvashtar, with temperatures differing from the Galileo observations. On 20 February, we noticed a slight brightening near the Surt volcano. Two days later it had turned into an extremely bright volcanic outburst. The hot spot temperatures (>1400 K) are consistent with a basaltic eruption and, being lower limits, do not exclude an ultramafic eruption. These outburst data have been fitted with a silicate-cooling model, which indicates that this is a highly vigorous eruption with a highly dynamic emplacement mechanism, akin to fire-fountaining. Its integrated thermal output was close to the total estimated output of Io, making this the largest ionian thermal outburst yet witnessed.