五龙背热矿泉水化学特征

五龙背热矿泉水为高氟热水,除含有通常的地下水常规组分外,还含有F~-、SiO_2等特殊组分,水质类型为重碳酸钠型。气体成分有CO_2、O_2、N_2,其体积百分含量比仍在大气降水含量比范围内。地下热水中的F~-、Na~+、SiO_2、CO_3~(2-)、SO_4~(2-)、pH值、矿化度等与水温呈正相关;Ca~(2+)、Mg(2+)、HCO_3~-以及硬度与水温呈负相关。地下热水化学组分主要来源于围岩,即地下热水对围岩的溶解、水解、溶滤作用,使围岩化学组分进入地下热水中所致。在不同的温度条件下,或地下热水形成的不同阶段,存在着不同的水化学平衡。F~-、SiO_2可作为五龙背热矿泉型地下热水的水化学标志。     

辽宁南部菱镁矿和滑石矿陨落成因的认识

辽宁省南部菱镁矿—滑石矿床成因与硅镁质石陨石陨落作用有关,它们相互依存、相互制约,成群成带分布于早元古代大石桥组三岩段碳酸盐岩中,受同一含矿层位控制,具有品位高,厚度大,矿物成分简单的特点。根据地球化学热力学原理,组成矿床的主要成分SiO_2和MgO,主要来自硅镁质石陨石的镁橄榄石和顽火辉石。当石陨石陨落和撞击地壳时,在SiO_2—MgO—H_2O相系中生成滑石,在MgO—CaO—CO_2相系中生成白云石和菱镁矿。因此,辽宁南部菱镁矿—滑石矿床成矿物质来源于陨落;陨落作用提供了成矿能量;陨击坑或由陨落作用形成的洼陷区为成矿提供了空间成矿的场所。     

张家界地区寒武系底部钼、镍多元素富集层含矿岩系特征及成矿条件浅析

本文阐述了张家界地区寒武系底部钼、镍多元素富集层的赋存层位、含矿岩系的层序及各岩性层的特征,并对成矿物质来源、地层、岩相古地理、地球化学等成矿条件进行了探讨。     

广西大瑶山西侧层控矿床稳定同位素特征

本文通过对大瑶山西侧成矿带泥盆系层控矿床中的铅、硫、碳、氢、氧等稳定同位素组成特征研究,探讨了本区成矿物质的来源和含矿溶液性质。认为,铅主要源于上地壳泥盆系—寒武系岩石,后生阶段有部分印支—燕山期幔源铅(基性岩)加入:重晶石硫源于寒武—泥盆纪海水硫酸盐,而硫化物矿物硫源于细菌还原海水硫酸盐成的H_2S;矿物包裹体流体水的氢、氧同位素组成说明后生期含矿热液属于大气降水深循环形成的热囱水,部分碳、氧同位素组成反映了成矿带北段可能有岩浆期后热液的叠加。据此,将本区划为前泥盆纪、泥盆纪、印支期等三期成矿作用,形成了成岩、成岩—后生和后生层控矿床系列,具有多源、多期、多阶段特点。     

分散液液微萃取-气相色谱法测定环境水样中间甲苯酚

针对环境中痕量的间甲苯酚用一般仪器很难直接分析测定的问题,提出将分散液液微萃取技术与气相色谱联用测定环境水样中间甲苯酚的新方法.实验考察了影响分散液液微萃取效率的因素,包括萃取剂种类和用量、分散剂种类和用量、萃取时间、离心时间和盐度等,确定了最佳萃取条件为:200μL氯苯(萃取剂)和2.5mL丙酮(分散剂)混匀后,快速注入水样,室温静置8min,以3000r/min离心8min,吸取1μL沉积相进行气相色谱分析.实验结果为:在最佳的萃取条件下,间甲苯酚的富集倍数为98.7倍,方法的线性范围为0.05～ 50mg/L,检出限为4.2μg/L(S/N=3),相对标准偏差为5.64％.将方法用于实际水样的测定,水样的加标回收率在86％～122％,相对标准偏差(RSD)为3.3％～7.3％(n=3),实验表明该方法操作简便快速、成本低、环境友好,可用于实际水样的测定.     

分散液液微萃取-气相色谱法测定环境水样中间甲苯酚

针对环境中痕量的间甲苯酚用一般仪器很难直接分析测定的问题,提出将分散液液微萃取技术与气相色谱联用测定环境水样中间甲苯酚的新方法.实验考察了影响分散液液微萃取效率的因素,包括萃取剂种类和用量、分散剂种类和用量、萃取时间、离心时间和盐度等,确定了最佳萃取条件为:200μL氯苯(萃取剂)和2.5mL丙酮(分散剂)混匀后,快速注入水样,室温静置8min,以3000r/min离心8rain,吸取1μL沉积相进行气相色谱分析.实验结果为:在最佳的萃取条件下,间甲苯酚的富集倍数为98.7倍,方法的线性范围为0.05～50mg/L,检出限为4.2μg/L(S/N=3),相对标准偏差为5.64％.将方法用于实际水样的测定,水样的加标回收率在86％～～122％,相对标准偏差(RSD)为3.3％～7.3％(n=3),实验表明该方法操作简便快速、成本低、环境友好,可用于实际水样的测定.     

湖南凤凰铅锌矿床成矿流体特征及成矿机制

扬子地块东南缘是我国重要的铅锌成矿带,而其中凤凰矿田尚缺系统研究。以凤凰铅锌矿床为研究对象,运用流体包裹体地质学、同位素地球化学以及显微激光拉曼光谱等方法对成矿流体特征、流体来源及流体成分开展了系统研究。结果表明:矿床中闪锌矿和与成矿有关的脉石矿物中流体包裹体较发育;包裹体主要为气液两相,其均一温度介于111.2~177℃,盐度介于4.1%~25.2%,密度介于0.98~1.09 g/cm3,总体为低温、中高盐度、中等密度流体;石英、闪锌矿中单个包裹体成分拉曼光谱测试结果表明,气液两相包裹体中气相成分主要为CH₄,液相主要为H₂O,纯气相包裹体主要成分为CH₄;H-O同位素分析结果表明,成矿流体主要为建造水,表明来自盆地中的建造水萃取了深部地层中的成矿物质,并与沉积物中有机物干馏作用产生的CH₄等一起形成还原性成矿流体,沿同生断裂构造等通道向上运移,铅锌等成矿物质在浅部敖溪组白云岩中沉淀成矿。      

广西金牙金矿床石英的标型特征及其意义

本文通过对金牙金矿床石英的化学成分、包裹体、物理性质及稳定同位素等万面的矿物学特征研究,取得了有价值的成因信息和找矿标志。认为该矿床属浅成中低温地下热(卤)水渗滤型金矿床,成矿物质来源于地层围岩。还指出石英颗粒极细小,多为隐晶至微晶,自形程度低,呈白色或无色、透明;比重低,晶胞棱长a_o大而Co小、单位晶胞体积增大(与标准石英比);红外光谱有1个宽峰、4个吸收峰和2个强的特征峰的波段,具单峰或双峰发热光曲线(在50～350℃范围内);具结构铝,含Ca、Fe、Mn、Au、Ag、Co、Ni、Se、Te与∑REE等杂质元素,其中Au与Al成正相关,而Au与∑REE呈负相关;包裹体呈无色透明、个体细小且少,以液相为主.气液比低,且出现沸腾包体群,其含盐度低,无子矿物,Na、Ca较高,为富含CO_2,CH_4的Ca~(-2)-Na_a-HCO_3~1-Cl型地下热(卤-水(温度305～190℃、压力25669～16945kpa.深度小于1km);δ~(18)O、δ~(18)O_(H_2O)、δD值具大气降水特征,δ~(13)C值类似油田碳等特征,是找“金牙型”金矿的重要找矿标志。     

桂西北地区三条铷—锶等时线年龄

铷锶等时线法测定地质体年龄是目前普遍应用而准确度较高的方法之一,用该法测得金牙金矿床(JY金矿床)的成矿年龄为206Ma±12,为中三叠世晚期;含金黄铁矿、毒砂矿物包体年龄为276Ma±28,代表成矿物质来源地层的时代,和桂西基性岩时代相同。用铷锶等时线法测得桂西北地区辉绿岩时代为263.1Ma,和峨眉山玄武岩相当,属海西晚期。因此,有根据认为,金牙金矿床的硫砷金等成矿物质主要来自下伏晚二叠世基性岩和基性火山碎屑沉积岩。     

氢化物-原子荧光法测定三江源地表水中的铅含量

本文利用氢化物—原子荧光光度法,采用KOH+KHB4+K3Fe(CN)6做还原剂,对三江源地区地表水中铅的含量进行分析测定,通过实验找出最佳分析条件,为三江源地区水质普查提供快捷、准确的数据.     

Hydro-geochemistry evolution in Ordovician limestone water induced by mountainous coal mining: A case study from North China

This research aimed to investigate the changing mechanism of hydro-geochemistry in Ordovician limestone karst(OL) water induced by mountainous coal mining activities. Thus, the hydrogeochemistry evolution of OL water over 40 years within a typical northern mountainous coal mine named Fengfeng Mine was studied by using Piper diagram, Gibbs scheme, ions correlation and Principal component analysis(PCA) methods. Results showed that, except for HCO_3~-, the ions of Ca~(2+), Mg~(2+), SO_4~(2-),Na~++K~+, Cl~- and total dissolution solids(TDS) values all increased by years as mining continues. Different hydro-geochemical characteristics in different periods can reflect different water-rock interactions.Accordingly, sulfates dissolution gradually took place of carbonates in water-rock interaction. Especially,OL water-rock interactions in different periods were all affected by rock weathering and evaporationconcentration together. At last, evaporationconcentration co-effect dominated the hydrogeochemistry evolution slowly, along with significant cations exchange over years.     

吉林西部地区第四系潜水水质影响因素的R型因子分析

利用R型因子分析法对吉林西部地区第四系潜水样的水化学数据进行分析,识别出影响地下水化学组成的4个主因子。因子1以Na ,HCO3-和F-为主,揭示了土壤的溶滤作用对地下水化学成分的影响;因子2以Cl-,SO42-和Ca2 为主,反映蒸发浓缩作用对地下水化学成分的影响;因子3以K 和pH值为主,代表地下水的弱碱环境地球化学背景;因子4以NO3-为主,反映了人类活动(化肥和农药的广泛施用、大中城市的生活污水和工业污水的污染)对地下水化学成分的影响作用。     

Preliminary Results on Hydrological and Hydrochemical Features of Kartamak Glacier Area in Mt. Muztag Ata

The variations of the meltwater runoff draining from Kartamak Glacier in Mt. Muztag Ata in China were studied by using the measured hydrological data from 1 June to 25 August 2003. The meltwater runoff is mainly affected by ambient temperature and precipitation. Meltwater and precipitation samples were collected from 10 to 23 August 2003. Their pH, EC (electric conductivity) and the major ions (Na~ , K~ , Ca~(2 ), Mg~(2 ), Cl~-, NO_3~-, SO_~4~(2-)) were determined. pH values showed a positive correlation with EC values for all samples. Meltwater samples were slightly alkaline. Sulfate and calcium were the dominant anion and cation in the measured ions, respectively. All the ion concentrations had inverse relationships with runoff or water level. In order to discuss the origins of dissolved chemical substances in the glacial meltwater, a principal component analysis was carried out. The results showed that water-rock interaction determined the ion components of the meltwater.     

O_2和H_2O对脉冲电晕分解NO的影响

在脉冲电晕放电条件下,探讨了O2和H2O对NO分解反应过程的影响,并对复杂组分中NO的分解特性进行了实验研究。研究结果表明,脉冲电晕放电对NO分解反应具有一定的促进作用,可有效地分解模拟烟气中的NO,脱除效率随脉冲电压的增加而缓慢增加;受O2和H2O影响,NO分解转化率较N2氛围略有降低。     

宽甸石柱子花岗闪长岩体重砂爆裂普查法在找矿中的应用

通过对石柱子花岗闪长岩体重砂爆裂法研究，发现其轻组分爆裂频次（或活度）有明显差异．并确定区内重砂轻组分爆裂颇次异常下限值为４２００次，据此确定了８个重砂爆裂活度异常区，圈定并缩小了找矿靶区。同时重砂爆裂普查法还可以反映出岩体成矿的可能性，判别岩体的矿化程度．研究表明，重砂爆裂普查法对于发现热液盲矿体具有可行性，可为普查找矿提供信息．     

Deposition of atmospheric pollutant and their chemical characterization in snow pit profile at Dokriani Glacier,Central Himalaya

The uncertainty in assessing the numerous atmospheric pollutants transported via wind from arid and semi-arid regions is affecting the glacial ecosystem. In our study area due to the complexity of the system, a prominent seasonal difference noticed among major ions(Ca~(2+), Mg~(2+), SO_4~(2-), and NO_3~-). There is a need for understanding the ions cycling as a whole and the directionality of the feedback loops in the system. Therefore, we provide an appraisal of our current hypothesis for seasonal difference in major ion concentration from snow samples for two corresponding years(2013 and 2015) at Dokriani Glacier. A systematic study of chemical compositionsin the shallow snow pit from Dokriani Glacier was undertaken for the pre-monsoon season to understand the cycling of major ions from atmosphere to solute acquisition process. The intimating connections of ions cycling in snow and its temporal behavior was observed and analyzed through various statistical tests. Among major ions, the SO_4~(2-)has the highest concentration among anions on an average considered as 14.21% in 2013 and 29.46% in 2015. On the other side Ca~(2+) is the dominant cation contributing 28.22% in 2013 and 15.3% in 2015 on average. The average ratio of Na+/Cl-was higher in 2013 whereas lower in 2015. The backward trajectory analysis suggests the possible sources of the ions transported from Central Asia through the Western Disturbance(WD) as a prominent source of winter precipitation mainly in the Central Himalaya. Ionicconcentration of Ca~(2+) in cations was highly dominated while in anion SO_4~(2-)played the major role. Factor analysis and correlation matrix suggested that, the precipitation chemistry is mostly influenced by anthropogenic, crustal, and sea salt sources over the studied region. The elemental cycling through ocean, atmosphere and biosphere opens up new ways to understand the geochemical processes operating at the glacierized catchments of the Himalaya. Moreover, increasing the field-based studies in the coming decades would also have the certain advantage in overcoming the conceptual and computational geochemical modelling difficulties.     

重砂爆裂普查法填图在区调中的应用

重砂爆裂普查法填图,是一种新的矿物学普查找矿方法。方法原理是依据矿物中所含气液包体的多寡来判明被调查区域所受热液作用影响的程度。在以往矿区找矿应用此法取得成功的基础上,又将重砂爆裂普查法应用于区域地质调查中。实践表明,在区调工作中实施重砂爆裂法进行填图,所圈定的异常与地质、矿化、构造具因果关系。     

Sulfate-Methane Transition Depths and Its Implication for Gas Hydrate

The biological removal of CH_4 by methanotrophic(CH_4-oxidizing) archaea always occurs at a distinct zone which is known as sulfate-methane transition zone(SMTZ). It is an important indication for high methane flux and gas hydrate occurrence. In this study, we collected pore-water data from South China Sea, Carolina Rise and Blake Ridge to analyze the relationship between CH_4, SO_4~(2-) concentration and depth. We found that below the SMTZ, the methane concentration increases continuously with depth and sulfate concentration decrease linearly to zero. In addition, the geochemical data taken from all these sites show that SMTZ is relatively shallow(less than 20 m), which may indicate that these areas have high methane flux.