华南栖霞组灰岩—泥灰岩韵律层的成因

华南中二叠统栖霞组沉积了一套特殊的碳酸盐岩地层,该套地层富含有机质和硅质结核,是中国南方四套区域性海相烃源岩之一.在野外露头上,灰岩-泥灰岩韵律层因为其抗风化能力不同而受到广泛关注,其在整个华南栖霞组分布广泛.其中,灰岩层富含各种生物碎屑,主要包括钙藻、有孔虫和腹足,其次还有腕足,棘皮类和介形虫,偶尔见苔藓虫和三叶虫.灰岩层中较好的保存了易碎的钙质藻类,说明灰岩的胶结作用发生在成岩早期,没有明显压实作用的痕迹.泥灰岩以粒泥生物碎屑灰岩和黑色钙质泥岩为主,主要的生物碎屑以腕足和介形虫为主.生物碎屑都非常破碎,壳体大都平行层面,颗粒之间发育大量压溶缝,说明泥灰岩层经历过强烈的成岩压实作用.基于对灰岩-泥灰岩韵律层的生屑类型和成岩现象的分析,提出差异成岩作用来解释该套地层的形成过程:泥灰岩层中不稳定的文石在早期成岩过程中溶蚀,然后迁移到灰岩层中形成方解石胶结灰岩层;随后机械压实作用和化学压实作用主要发生在泥灰岩层中;最终灰岩-泥灰岩层由于差异成岩作用导致其抗风化能力不同而形成不同的露头特征.其中文石溶蚀发生在海水埋藏环境,有机质的分解为其提供了动力来源,这与栖霞期较高的原始生产力相符合.     

Differential Diagenesis of Limestone-Marl Alternations

灰岩-泥灰岩韵律层包括结核状灰岩到灰岩和泥灰岩互层,广泛分布在陆棚及深海环境中,出现于各地质时期,是研究高分辨率地层学和环境恢复的理想工具.但是成岩作用在灰岩-泥灰岩韵律层形成过程中的作用一直存在分歧,有的学者认为差异化学压实成岩作用加强了原始沉积的差异,有的学者认为成岩作用不仅能够强烈歪曲原始环境特征,还可以通过自身成岩作用形成与原始沉积特征类似的现象.灰岩-泥灰岩韵律层中的差异成岩作用是指泥灰岩中的不稳定碳酸盐矿物在海底成岩环境中经过溶解、迁移和在灰岩中再沉淀,导致灰岩层没有明显被压实,而泥灰岩层受到明显压实.本文重点评述了差异成岩作用发生的环境和过程,并对与之相关的胶结物来源问题和有机质在早期成岩过程中的作用进行了讨论.并以华南中二叠统栖霞组韵律层为例,探讨了差异成岩作用在其形成过程中的作用,最后对以后的研究方向进行了展望.     

鄂西峡口地区中二叠统栖霞组碳酸盐岩微相及相序

鄂西峡口地区在构造上属中扬子台地北缘,发育了一套比较完整的中、上二叠统海相碳酸盐岩沉积。采用微相分析的方法,对中二叠统栖霞组碳酸盐岩的生物组合、微相类型和沉积环境进行了研究,将峡口地区的栖霞组沉积归纳为7种微相:多类型生物碎屑粒泥灰岩、含大壳体有孔虫的生物碎屑粒泥-泥粒灰岩、粗枝藻粒泥-泥粒灰岩、破碎的生物碎屑粒泥灰岩、具定向排列的藻屑—腕足泥粒灰岩、含内碎屑的生物碎屑泥粒灰岩、含原地珊瑚和藻类的生物碎屑泥粒灰岩。碳酸盐岩微相类型的垂向序列指示了峡口地区的栖霞组形成于碳酸盐岩缓坡环境,其底部地层沉积于内缓坡局限海相,中上部地层为内缓坡边缘低能生物丘相与内缓坡开阔海相的交替沉积。     

灰岩-泥灰岩韵律层的差异成岩作用

灰岩-泥灰岩韵律层包括结核状灰岩到灰岩和泥灰岩互层,广泛分布在陆棚及深海环境中,出现于各地质时期,是研究高分辨率地层学和环境恢复的理想工具.但是成岩作用在灰岩-泥灰岩韵律层形成过程中的作用一直存在分歧,有的学者认为差异化学压实成岩作用加强了原始沉积的差异,有的学者认为成岩作用不仅能够强烈歪曲原始环境特征,还可以通过自身...     

武汉地区二叠系栖霞组灰岩—含泥灰岩韵律层生物产率

选取生物产率分析指标生源w(Ba)、生源w(Al)及w(Al)/w(Ti)比值,分析了武汉地区二叠系栖霞组灰岩-含泥灰岩韵律层的生物产率变化;同时用w(V)/w(V+Ni)、w(V)/w(Cr)及w(Mo)等指标分析了韵律层的古氧相特征.结果表明:武汉地区栖霞组灰岩-含泥灰岩韵律层灰岩部分的生物产率较低,形成于常氧环境;含泥质灰岩部分的生物产率明显较高,形成于缺氧环境.这种生物产率和沉积环境古氧相随韵律层规律性的变化,证实生物产率是导致栖霞组有机质质量分数变化的主要原因.     

安徽南部下二叠统结核状硅质岩和层状硅质岩的沉积学特征及其成因探讨

前言根据岩性特征和生物化石组合带,安徽南部下二叠统可划分为栖霞组和孤峰组。栖霞组主要为一套含硅质结核及硅质条带的灰岩建造。灰岩中含大量的藻类、(虫廷)、有孔虫、珊瑚、腕足和棘皮等浅海底栖型生物化石。孤峰组主要为一套薄层状硅质岩与薄层状泥页岩互层,组成硅—泥韵律沉积建造,含薄壳腕足、菊石、小有孔虫、硅质海绵和放射虫等浮游型生物化石。据两条主干部面(巢湖龟山、宿松坐山)统计,下二叠统碳酸盐岩占地层总厚的81.2％,     

塔里木盆地巴楚地区T_7~4界面生屑灰岩微相分析及成岩作用研究

前人对塔里木盆地巴楚地区T74界面的研究主要以在地震反射剖面中大的不整合面形式为基础进行的,对界面具体的岩性、微相和成岩作用研究较少。位于塔里木盆地巴楚县东北方向一间房地区的T74露头剖面为上奥陶统与中—下奥陶统的分界面,岩性以生物碎屑泥粒灰岩和粒泥灰岩为主。镜下分析表明:T74界面生屑灰岩中生物碎屑以棘皮动物(主要为海百合碎片)和介形虫为主,其他生物碎屑包括腕足动物、软体动物、三叶虫、钙球粒、粗枝藻、龙介虫、有孔虫、海绵和苔藓等。通过镜下微相、C-O同位素以及X射线荧光等多种分析方法,认为T74界面地层沉积相为较温暖的低能陆棚相,后期经历了埋藏压实成岩作用、地层抬升后的淡水成岩作用和风化剥蚀作用等。岩石的缝合线发育,孔渗性较好,利于地下流体的运移和渗透,对中—下奥陶统的岩溶发育起着控制作用。     

伊拉克鲁迈拉油田白垩系Mishrif组碳酸盐岩生物碎屑和成岩作用特点

中东地区白垩系Mishrif组主要由富含生物碎屑的颗粒泥晶灰岩及泥晶颗粒灰岩组成。基于薄片研究了伊拉克鲁迈拉油田Mishrif组碳酸盐岩中生物碎屑特征及其成岩作用的相异性特点,并总结了生屑成岩作用差异性特征对储层的影响。该区Mishrif组重要的生物碎屑有三大类,即双壳类、棘皮类和有孔虫类。这些生物碎屑主要经历了同生阶段的泥晶化和大气淡水溶蚀作用,中-浅埋藏期的压实压溶、充填胶结、新生变形等多期成岩作用。泥晶化作用主要发生在有孔虫壳体外壁;溶蚀作用更易发生在双壳类和有孔虫壳体中。胶结作用在不同类别生物碎屑上的表现形式不同,且对储层中早期孔隙的破坏强烈。不同类别生物碎屑的结构、大小、成分的差异造成了成岩作用的差异并进而影响储层物性。     

N油田A油组钙质隔夹层地质特征及成因分析

在油田开发过程中,隔夹层控制油气水运动规律,对于寻找剩余油具有重要控制作用。本文以N油田TF组2段A油组为研究对象,通过薄片、岩心测试、测井、碳氧同位素等资料综合分析,研究其钙质隔夹层的分布特征、岩石学特征、物性特征、测井识别特征,并从沉积环境、物质来源、成岩作用相结合的角度分析钙质隔夹层的成因。研究表明,A油组纵向上发育的三套钙质隔夹层主要发育在前滨滩坝沉积微相,顶钙与底钙的岩性以砂质生屑质灰岩为主,中钙为钙质砂岩;三套钙质隔夹层中生物碎屑主要以腕足、腹足、有孔虫为主,含少量棘皮、瓣鳃、红藻、介形虫、苔藓虫等;成岩作用主要为胶结作用,胶结物类型包含早期方解石胶结物、中期铁方解石胶结物、晚期铁白云石胶结物;碳氧同位素分析表明,隔夹层中碳主要来自于沉积过程中的海水,同时有少量来自于大气淡水和有机酸,Ca~(2+)主要来源于生物碎屑,其次为钙长石溶解、铝硅酸盐矿物的水化作用。     

西藏北部班戈地层分区下白垩统郎山组、康曲组和余穷组地层层序研究

在西藏自治区北部区域地质调查过程中 ,在班戈地层分区的下白垩统郎山组之上发现一套厚约 180 0 m的滨海—浅海相碳酸盐岩、陆源细碎屑岩岩石组合 ,该套组合不属于郎山组定义之内 ,且出露良好、层序稳定、标志清楚、厚度巨大、化石丰富 ,并具有很强的可填图性。因此 ,我们将整合于郎山组之上 ,岩性以杂色微—薄层状钙质泥岩、钙质 (粉 )砂岩与泥质生物灰岩的韵律产出为特征 ,产圆笠虫、腹足类、双壳类等化石的地层命名为康曲组 ;将整合于康曲组之上 ,下部以灰—深灰色中薄层状泥质生物灰岩、圆笠虫泥晶灰岩、钙质泥岩等韵律出现为特征 ,上部以灰色中—厚层状含硅质结核圆笠虫泥晶灰岩、圆笠虫泥晶灰岩夹灰绿色薄层状钙质砂岩为特征 ,富含圆笠虫、腕足类、腹足类、双壳类及海胆等化石的地层定名为余穷组。时代均置于早白垩世晚期     

Multiproxy approach to understanding the origin of Cretaceous pelagic limestone–marl alternations (DSDP site 391, Blake-Bahama Basin)

Limestone–marl alternations are usually directly interpreted to reflect cyclic palaeoenvironmental signals. However, uncertainty in such interpretations stems from the differential diagenesis that most limestone–marl alternations have undergone. Differential diagenesis results in markedly different alterations between limestones and marls and in the loss of comparability of many measurable parameters. For an unequivocal interpretation of the origin of rhythmic alternations, diagenetically robust parameters or parameters that clearly indicate the degree of diagenetic bias are required. The present study uses a multiproxy approach (independent biotic, sedimentary and geochemical parameters) in order to unravel the palaeoenvironmental signal recorded in Valanginian (Early Cretaceous) limestone–marl alternations from the Blake‐Bahama Basin (DSDP site 391). Using this approach, terrestrial and marine influences can be distinguished, changes in nutrient levels estimated and prediagenetic differences in the non‐carbonate fraction constrained. Surprisingly, no systematic variations in any of these parameters were observed between limestone and marl layers, implying that none of these was directly responsible for the formation of the rhythmic alternation. Hence, none of the current models of sedimentary formation of limestone–marl rhythmites is applicable here. Calcareous nannofossils are equally well preserved in limestone and marl layers, ruling out their dissolution in marl layers as a source of the calcite cement in the limestone beds. Sr values of 700–900 p.p.m. indicate that aragonite may have been present in the original, pelagic sediment. The assumption of fine‐grained sedimentary aragonite imported from nearby carbonate platforms as the source of the cement would explain a number of otherwise enigmatic features in these rhythmites, including the source of the calcite cement observed in the limestones, the equally good preservation of calcareous nannofossils in limestones and marls and the higher concentration of calcareous nannofossils in marl layers. The study demonstrates that examination of diagenetically inert parameters or parameters in which diagenetic effects can be filtered can yield unexpected results. Clearly, careful analysis of such parameters needs to be undertaken in order to make reliable palaeoenvironmental interpretations from rhythmite successions.     

Diagenesis of early Permian high‐latitude limestones,Lower Parmeener Supergroup,Tasmania

The Darlington (Sakmarian) and Berriedale (Artinskian) Limestones are neritic deposits that accumulated in high‐latitude environments along the south‐eastern margin of Pangea in what is now Tasmania. These rocks underwent a series of diagenetic processes that began in the marine palaeoenvironment, continued during rapid burial and were profoundly modified by alteration associated with the intrusion of Mesozoic igneous rocks. Marine diagenesis was important but contradictory; although dissolution took place, there was also coeval precipitation of fibrous calcite cement, phosphate and glauconite, as well as calcitization of aragonite shells. These processes are interpreted as having been promoted by mixing of shelf and upwelling deep ocean waters and enabled by microbial degradation of organic matter. In contrast to warm‐water carbonates where meteoric diagenesis is important, the Darlington and Berriedale Limestones were largely unaffected by meteoric diagenesis. Only minor dissolution and local cementation took place in this diagenetic environment, although mechanical compaction was ubiquitous. Correlation with burial history curves indicates that chemical compaction became important as burial depths exceeded 150 m, promoting precipitation of extensive ferroan calcite. This effect resulted from burial by rapidly deposited, overlying, thick, late Permian and Triassic terrestrial sediments. This diagenetic pathway was, however, complicated by the subsequent intrusion of massive Mesozoic diabases and associated silicifying diagenetic fluids. Finally, fractures most probably connected with Cretaceous uplift were filled with late‐stage non‐ferroan calcite cement. This study suggests that both carbonate dissolution and precipitation occur in high‐latitude marine palaeoenvironments and, therefore, the cold‐water diagenetic realm is not always destructive in terms of diagenesis. Furthermore, it appears that for the early Permian of southern Pangea at least, there was no real difference in the diagenetic pathways taken by cool‐water and cold‐water carbonates.     

黔南坳陷平塘甘寨二叠系茅口组沉积相与储层特征分析

通过铸体薄片、物性测试、扫描电镜等资料,对黔南坳陷平塘甘寨二叠系茅口组沉积相与储层特征进行深入分析,认为贵州平塘甘寨茅口组主要的岩石类型为亮晶-微晶生屑灰岩、生物灰岩、微晶灰岩、内碎屑亮晶灰岩、硅质岩、瘤状灰岩和含燧石灰岩等。茅口组生物种类较多,有介形虫、腹足、腕足、三叶虫、藻类、棘屑、蜒、珊瑚、海百合茎等。上述岩石学特征和生物组合指示平塘甘寨地区中二叠统茅口组为开阔碳酸盐台地沉积环境,包括台内滩和滩间两个亚相。储层特征分析结果表明,茅口组储集空间以晶间溶孔和晶间孔为主,具有明显的低孔低渗特征。局部溶蚀孔、构造裂缝相对较发育,对改造储层的孔渗性有重要的贡献。储层类型为碳酸盐岩裂缝-孔隙型储层,储层质量及发育部位受沉积相、成岩作用和构造活动多因素的控制。     

安徽无为-巢湖地区中下二叠统碳酸盐岩成岩作用

成岩作用控制孔隙演化,对油气开采具有重要的指示作用.安徽无为-巢湖地区中下二叠统碳酸盐岩广泛发育,有机质丰富,多年来主要集中在地层、古生物及沉积相方面的研究,成岩作用的工作较少.镜下鉴定显示研究区发育溶解作用、去白云化作用、压溶作用、破裂作用4种主要的建设性成岩作用和泥晶化作用、压实作用、胶结作用、白云化作用、硅化作用...     

湘鄂西奥陶纪宝塔组灰岩网纹构造成因及沉积环境探讨

网纹构造是宝塔组石灰岩地层中非常发育且分布广泛的一种构造形态 ,其成因一直存在争论和疑问。对湘鄂西地区宝塔组灰岩的研究表明 ,网纹构造的形成不是由于胶体凝缩、水下沉积物收缩或生物遗迹等原因 ,而是一种成岩早期形成的准同生变形构造。根据岩石性质及生物特征推断 ,宝塔组网纹状灰岩沉积于正常浪基面以下、风暴浪基面之上 (水深大约 5 0～ 15 0 m)的陆棚或台盆环境     

Facies controlled diagenetic evolution of the Delhi Group Sandstones,Bayana Basin,Rajasthan

The Bayana Basin forms the eastern most limit of north Delhi fold belt covering parts of northeastern Rajasthan. The deposition of sediments took place during middle Proterozoic in fluvial and shallow marine environments. The rocks are mainly clastics and include conglomerate, sandstone and shale. During mechanical compaction rearrangement of grains took place and point and long contacts were formed. The sandstones are cemented by iron oxide, silica, carbonate and barite. The porosity has developed due to dissolution of iron, carbonate cement and feldspar grains. Dissolution of quartz along grain boundaries and silica rich compaction pore water seems to be the main source of silica. These observations suggest progressive compaction which initiated at the sediment water interface and continued till deep burial diagenesis in a rapidly subsiding basin.     

Stratigraphy and facies development of the marine Late Devonian near the Boulongour Reservoir,northwest Xinjiang,China

Late Devonian to Early Carboniferous stratigraphic units within the ‘Zhulumute’ Formation, Hongguleleng Formation (stratotype), ‘Hebukehe’ Formation and the Heishantou Formation near the Boulongour Reservoir in northwestern Xinjiang are fossil-rich. The Hongguleleng and ‘Hebukehe’ formations are biostratigraphically well constrained by microfossils from the latest Frasnian linguiformis to mid-Famennian trachytera conodont biozones. The Hongguleleng Formation (96.8 m) is characterized by bioclastic argillaceous limestones and marls (the dominant facies) intercalated with green spiculitic calcareous shales. It yields abundant and highly diverse faunas of bryozoans, brachiopods and crinoids with subordinate solitary rugose corals, ostracods, trilobites, conodonts and other fish teeth. The succeeding ‘Hebukehe’ Formation (95.7 m) consists of siltstones, mudstones, arenites and intervals of bioclastic limestone (e.g. ‘Blastoid Hill’) and cherts with radiolarians. A diverse ichnofauna, phacopid trilobites, echinoderms (crinoids and blastoids) together with brachiopods, ostracods, bryozoans and rare cephalopods have been collected from this interval. Analysis of geochemical data, microfacies and especially the distribution of marine organisms, which are not described in detail here, but used for facies analysis, indicate a deepening of the depositional environment at the Boulongour Reservoir section. Results presented here concern mainly the sedimentological and stratigraphical context of the investigated section. Additionally, one Late Devonian palaeo-oceanic and biotic event, the Upper Kellwasser Event is recognized near the section base.     

Calcite cementation during bacterial manganese, iron and sulphate reduction in Jurassic shallow marine carbonates

Faunally restricted argillaceous wackestones from the Middle Jurassic of eastern England contain evidence of early diagenetic skeletal aragonite dissolution and stabilization of the carbonate matrix, closely followed by precipitation of zoned calcite cements, and precipitation of pyrite. Distinctive cathodoluminescence and trace element trends through the authigenic calcites, their negative δ¹³C compositions and the location of pyrite in the paragenetic sequence indicate that calcite precipitation took place during sequential bacterial Mn, Fe and sulphate reduction. Calcite δ¹⁸O values are compatible with cementation from essentially marine pore fluids, although compositions vary owing to minor contamination with ¹⁸O-depleted ‘late’cements. Mg and Sr concentrations in the calcites are lower than those in recent marine calcite cements. This may be a result of kinetic factors associated with the shallow burial cementation microenvironments. Bicarbonate for sustained precipitation of the authigenic calcites was derived largely from aragonite remobilization, augmented by that produced through anaerobic organic matter oxidation in the metal and sulphate reduction environments. Aragonite dissolution is thought to have been induced by acidity generated during aerobic bacterial oxidation of organic matter. Distinction of post-oxic metal reduction and anoxic sulphate reduction diagenetic environments in modern carbonate sediments is uncommon outside pelagic settings, and early bacterially mediated diagenesis in modern platform carbonates is associated with extensive carbonate dissolution. High detrital Fe contents of the Jurassic sediments, and their restricted depositional environment, were probably the critical factors promoting early cementation. These precipitates constitute a unique example of calcite authigenesis in shallow water limestones during bacterial Mn and Fe reduction.     

贵州平塘甘寨剖面二叠系茅口组沉积特征与层序地层

本文应用沉积学手段对贵州平塘甘寨剖面中二叠统茅口组进行详细的沉积特征和层序地层的研究。研究结果显示,茅口组主要的岩石类型有亮晶-微晶生屑灰岩、生物灰岩、微晶灰岩、亮晶内碎屑灰岩、硅质岩、瘤状灰岩和含燧石灰岩等,茅口组生物种类有介形虫、腹足、腕足、三叶虫、藻类、棘屑、蜒、珊瑚、海百合茎等。岩石学特征和生物组合指示,平塘甘寨地区中二叠统茅口组为开阔碳酸盐台地沉积环境,包括台内滩和滩间两个亚相。茅口组可划分出3个Ⅲ级层序PSQ1、PSQ2和PSQ3,均由海侵体系域（TST）与高水位体系域（HST）两部分组成。层序发育受到了海平面升降变化控制,层序之间的界面P2q/PSQ1、PSQ1/PSQ2、PSQ2/PSQ3皆为岩性-岩相转换面,层序界面P3l/PSQ3在茅口末期受到东吴运动的影响,为构造不整合面。