辽宁农作物的生物地球化学分类

根据А．П．维诺格拉多夫的动植物体化学组成分类方法,对辽宁省４５种农作物及其立地土壤中的５２种化学元素进行了定量分析测试后,采用双指标法将元素的含量与生物吸收系数各分成三个数值段,从而将辽宁主要农作物化学元素划分成最富集元素、富集元素、贫乏元素及最贫乏元素４种类型,并作出农作物化学元素分类表,然后再将其转变成农作物生物地球化学分类表。表中列出了５２种化学元素在各种农作物中的含量及其生物吸收系数组合,并由此将辽宁主要农作物分为元素最富集作物、元素富集作物、元素贫乏作物和元素最贫乏作物四类。根据农作物的生物地球化学分类,人们可以科学地调整农业种植结构,可以均衡人体营养结构。它不仅可以为环境质量监测提供指示植物标志而且对植物地球化学探矿也具有重要的参考价值。     

Bertrand's Law and Weinberg's Principle and Their Extension

IntroductionThe topography and geomorphy controlled bythe geological structure of hydrogeological unit playdecisive roles not only in the distribution of surfaceand groundwater flow, the permeability of theaquifer but also in the hydrogeochemical reaction…     

Bertrand''s Law and Weinberg''s Principle and Their Extension

Bertrand's law that the plant can't live in lack of some indispensable element, appropriate amount of the element will make the plant thrive but excessive amount of it will make the plant poisoning and even die was obtained through the study on the biologic adaptability in laboratory for the indispensable element manganese by G. Bertrand. E. D. Weinberg developed Bertrand's law as that certain amount of manganese was appropriate for the growth of some bacteria but not for the form of bacteriophage.The double threshold contents of elements indispensable for the organisms and their physiological effects can be extended to different hydrogeochemical zones of hydrogeological unit. Some elements are lack in the hydrogeochemical zone, in which the elements leaching and transfer are very strong the biological physiological effect is negative to the elements content. However, in the elements enrichment area caused by leaching and concentrating by evaporation or environmental pollution, the biological physiological effects are positive to the element content. The elements content in other areas which are in between two above types is appropriate for the organisms.From the hydrogeochemical study in Liliu , Shanxi province we obtained that the rate of KBD, IDD and dental caries are resulted from deficiency of elements Se, I and F in water (soil), respectively, the rate of diseases above is inversely related with the element content, while in the zone with excessive fluorine caused by enrichment and leaching, the rate of endemic fluorosis is positive to the fluorine content.     

隧道富水程度遥感定量判释评估应用

本文列举分析了国内外由于未查明隧道水文地质条件给隧道施工和治理而产生问题的若干实例 ,指出水文地质勘测工作的重要性 ,叙述了利用遥感手段确定隧道富水程度与地面勘测方法的区别。重点介绍利用“遥感定量判释应用模式”评估隧道富水程度的思路 ,具体方法与步骤以及应用“隧道遥感富水程度估算经验公式”时应注意的问题。     

Geochemical features of sulfides from the Deyin-1 hydrothermal field at the southern Mid-Atlantic Ridge near 15°S

In this study, geochemical compositions of elements in sulfide samples collected from the Deyin-1 hydrothermal field near the 15°S southern Mid-Atlantic Ridge (SMAR) were analyzed by the X-ray fluorescence spectrometry (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) to examine the enrichment regulations of ore-forming elements and hydrothermal mineralization. These sulfide precipitates can be classified macroscopically into three types: Fe-rich sulfide, Fe-Cu-rich sulfide and Fe-Zn-rich sulfide, and are characterized by the enrichment of base metal elements along with a sequence of Fe>Zn>Cu. Compared with sulfides from other hydrothermal fields on MAR, Zn concentrations of sulfides in the research area are significantly high, while Cu concentrations are relatively low. For all major, trace or rare-earth elements (REE), their concentrations and related characteristic parameters exhibit significant variations (up to one or two orders of magnitude), which indicates the sulfides from different hydrothermal vents or even a same station were formed at different stages of hydrothermal mineralization, and suggests the variations of chemical compositions of the hydrothermal fluid with respect to time. The hydrothermal temperatures of sulfides precipitation decreased gradually from station TVG10 (st.TVG10) to st.TVG12, and to st.TVG11, indicating that the precipitation of hydrothermal sulfides is subjected to conditions changed from high temperature to low temperature, and that the hydrothermal activity of study area was at the late stage of a general trend of evolution from strong to weak. The abnormally low concentrations of REE in sulfides and their similar chondrite-normalized REE patterns show that REEs in all sulfides were derived from a same source, but underwent different processes of migration or enrichment, or sulfides were formed at different stages of hydrothermal mineralization. The sulfides collected from the active hydrothermal vent were mainly attributed to precipitating directly from the hydrothermal fluid, while those collected from the extinct hydrothermal chimney might have already been altered by the seawater. Generally, ore-forming elements in the sulfides can be divided into three groups: Fe-based element group, Cu-based element group and Zn-based element group. The first group includes Fe, Mn, Cr, Mo, Sn, Rb and bio-enriching elements, such as P and Si, reflecting the similar characteristics to Fe in the study area. And the second group contains Cu, W, Co, Se, Te and Bi, suggesting the similar behavior with Cu. Moreover, the third group includes Zn, Hf, Hg, Cd, Ta, Ga, Pb, As, Ag, Ni and Sb, which indicates the geochemical characteristics of most dispersed trace elements controlled by Zn-bearing minerals to some extent.     

南堡凹陷古近系沙河街组沉积环境和物源: 来自微量和稀土元素地球化学的证据

为深入认识南堡凹陷沙河街组富有机质泥页岩形成机理, 通过详细分析微量和稀土元素地球化学特征, 对其水体沉积环境及物源进行研究。结果表明: 微量元素Li, Cs, Bi较为富集; Cr, Sn较为亏损; 其他微量元素接近于上地壳元素含量。稀土元素总量变化范围宽泛, 接近或高于大陆上地壳的平均值, 指示陆源碎屑供给较为充足。REE分配模式表现为轻稀土元素富集, 分异程度较高; 重稀土元素相对亏损, 分异程度较低。铕元素异常值(δEu)负异常明显, 铈元素异常值(δCe)基本正常。根据锶丰度和锶/钡比值的变化, 反映出沙三段沉积时期湖泊水体具有一定的分隔性, 淡水、半咸水和咸水环境共存; 沙一段沉积时期湖泊水体的连通性增强, 以半咸水环境为主。根据V/(V+Ni)、Th/U比值及δCe、铈异常指数(Ce_anom)值特征, 反映出湖泊水体为分层较强的贫氧环境。源生Ba含量揭示出湖泊水体古生产力较高。通过稀土元素组合特征分析, 认为沙河街组物源主要来自燕山褶皱带于燕山期发育的花岗岩, 且混有少量沉积岩。南堡凹陷沙河街组泥页岩有机质富集程度与其古环境和古地理密切相关: 一是适宜的水体古盐度和丰富的水体营养物质适应多种浮游藻类的共同繁盛, 提高了湖泊水生有机质生产效率; 二是贫氧的水体环境减缓有机质在埋藏过程中的降解, 提高了沉积有机质保存效率。      

金属矿床氧化带中铁矿物的演化及其与金次生富集的关系

作为地壳中常见的主要变价元素—铁 ,它与金在内生成矿及表生再富集过程中的关系十分密切。铁在矿床中的分布及铁的硫化物矿物在氧化过程中演化的阶段性与环境的Eh值,pH值有着密切关系;进而影响和控制了金在表生演化过程中的地球化学行为。     

GEOCHEMICAL STUDY OF THE CORE S01 IN THE SOUTH CHINA SEA

Si, Ti, Al, Fe, Mn, Ca, Mg, K, Na, P and Sr, Ba, Rb, Ga, V, Zr, Cr, Ni, Co, Cu, Zn, Pb,Nb, Y, Th, La in the core S01 were analyzed and the pattems of their enrichment are discussed.Enrichment of Na, Fe, Mn, Ba, Cu elements in the core indicates volcanic material are an importantsoarce of the sediments in the area. The enrichment frequently varying with the deposition processshows bottom volcanism is frequent in the area and that the studied area is a margin basin with distinctoceanic characteristics. The abnormal enrichment of Mn at the layers(0-15 cm and 665-670 cm) of the core could beclosely related to and so, indicate, the wide deposition hiatus that have occurred in the West PacificOcean and adjacent margin seas since Late Pleistocene.     

平阴县土壤中重金属元素异常成因研究

通过对平阴县周边及其西部农田区采样调查，平阴县周边元素异常具有异常衬度较高，富集系数大等特征，西部农田区异常具有各元素套合关系好，多数异常衬度不高，富集系数小的特点。结果表明，西部农田区异常是以As，Cd为主要成分的异常，元素含量与SiO2，Al2O3，Fe2O3等常量组分间具有显著的相关性，随SiO2含量的增加而降低，随Al2O3，Fe2O3含量的增加而增加，说明土壤常量组分及其所决定的土壤质地是导致异常形成的主要因素；而平阴城区异常是以S，Hg，As，Zn，Mn等元素为主的异常，是典型的人为综合因素（化工烟尘、工厂污水、生活垃圾）产生的异常。     

Variations in rare earth elements with environmental factors in lake surface sediments from 17 lakes in western China

Numerous lakes in western China are excellent sites for understanding environmental change. However, what dominates rare earth element(REE) variations are still under debate in the lake environmental research. In this study, we selected 28 surface sediment samples from 17 lakes(i.e. largescale lakes, small water bodies, etc.) in the QinghaiTibet Plateau and Xinjiang area. These samples were analyzed to reveal the behavior of the REEs and major elements. These REE patterns are characterized by light rare earth element(LREE) enrichment, weak Ce anomaly(0.84-0.98, 0.94 on average) and negative Eu anomaly(0.53-1.00, 0.67 on average). The homogeneous REE patterns may reflect similar REE of the source lithologys. However, the REE abundances showed some significant differences. In this study, water chemistry data analyses inferred that the highly REE values appear possibly in the saltwater lake, and also related to carbonate mineral, whereas p H played a minor role in REE concentrations. In large-scale lakes(e.g. Lake Bosten and Lake Ulungur), the results showed that the relatively larger REE values are in the margins of lakes. Moreover, lower REE contents are towards the central region. Comprehensive study suggested that five major factors control the REE contents:(1) The REE tends to increase with the increase of the weathering intensity.(2) Likewise, heavy mineral(i.e. rutile, anatase, zircon, etc.) are probably primary in these sediments because they are highly enriched in the REE.(3) The contribution of Fe-Mn oxides is significant in sediments because their concentrations highly correlate with the REE.(4) The carbonate mineral(mainly calcite) played a significant role on the REE values in the lakes because the REEs are incorporated into the carbonate minerals generating the low REE concentrations.(5) Major element analysis, mineral analysis, and grain-size data analysis showed that the REE distribution is chiefly influenced by finer grain-size component of lake sediments due to the decreasing proportion of quartz and feldspar than coarser one. Moreover, the clay minerals in finer grain-size sediments can highly absorb the REE.     

伟晶岩型稀有金属矿床成矿作用研究进展

伟晶岩型矿床是世界上重要的稀有金属矿床类型之一，也是当前国际矿床学研究热点之一。近年来该类稀有金属矿床在分类、成矿流体及成矿物质来源、伟晶岩成岩方式和稀有金属富集机制等方面的研究取得了一些重要进展。伟晶岩通常与母质岩浆具有密切的时空关系，但不少也与母质岩浆无成因关系。伟晶岩稀有金属矿床成矿熔体/流体具有低黏度、富水、高分散性、富碱等性质，可导致P、F和B等元素在伟晶岩中的极端富集，使其与稀有金属组成各类络合物或化合物而迁移与富集。富含Li-Cs-Ta(LCT)型伟晶岩与S型花岗岩关系紧密，成矿物质主要起源于黑色页岩等海相沉积物质，而富含Nb-Y-F(NYF)型伟晶岩常与A型花岗岩联系紧密，属同源岩浆演化和矿化。花岗质岩浆分异结晶和地壳或地幔岩石的部分熔融是伟晶岩两种主要的形成方式。流体不混溶作用、富助熔组分花岗岩浆高度结晶分异和热液交代作用3种富集机制可用于解释伟晶岩型稀有金属矿床的形成。      

Possible relatedness between the outburst of the Diexi ancient dammed lake and ancient Chengdu's cultural change

The Diexi ancient dammed lake is in the upper reaches of the Minjiang River. Six terraces with lacustrine sediments occur at the base. These terraces are the products of the graded outburst of the Diexi ancient dammed lake. The outburst of the ancient dammed lake would certainly have had an impact on the Chengdu Plain in the lower reaches of the Minjiang River. In this paper, on-site sampling and laboratory analysis were used to analyze the sediments of the Diexi ancient dammed lake and the Jinsha site in Chengdu Plain, and the environmental indicators of each sediment layer were tested. Through a comparative analysis of the environmental indicators in the sediments at the two locations, the following results were obtained: the palaeoclimatic and palaeoenvironmental characteristics at the two locations generally show consistent changes. The most important finding is that the types and content of the major pollen taxa at the two locations are similar. The Pinus content strongly proves that the soil layers at the Jinsha site was sourced from the upper reaches of the Minjiang River. Considering that the demise of the ancient culture at the Jinsha site occurred close in time to the outburst of the ancient dammed lake, this similarity suggests that the cultural change at the Jinsha site may have been related to the outburst of the Diexi ancient dammed lake.     

西宁盆地地下热水的TDS分布特征及富集机理

西宁盆地大部分地下热水中TDS含量较高,极大限制了地热水的可利用性,研究盆地地下水TDS的成因机理,可为后期指导地热资源开发利用提供参考价值。通过对西宁盆地药水滩至盆地中心沿线地下水的常、微量组分的分析,探讨了区内TDS的分布特征及富集机理。结果表明:从盆地边缘到盆地中心,地下水由HCO₃-Ca·Mg型淡水逐渐向SO₄·Cl-Na、SO₄-Na型盐、卤水变化,地下水具有陆相沉积水特征,且变质程度逐渐增强;盆地内不同区域TDS的富集机理也有显著差异,盆地边缘以降水入渗、溶解混合作用为主,湟水中心区域以蒸发浓缩作用和混合、水-岩相互作用为主,而盆地中心区域则以深部沉积物质随热液上涌的混合作用和封闭环境下的水-岩相互作用为主。      

Concentration and Characterization of Colored Dissolved Organic Matter in the Surface Microlayer and Subsurface Water of the Yellow Sea and the East China Sea

The distribution and chemical properties of colored dissolved organic matter(CDOM) in the Yellow Sea and the East China Sea during December 2011-January 2012 were investigated. The input of freshwater and biological activities had an evident influence on the CDOM levels(characterized by the light absorption coefficient at the wavelength of 355 nm a_(355)) in the study area. The spatial distribution of CDOM levels displayed a gradually decreasing trend from the coastal waters(0.37 m~(-1)) to the open sea(0.18 m~(-1)). The spectral slope ratio(the slope ratio S_R defined as S_(275-295):S_(350-400)) during the cruise was correlated with salinity, and exhibited a large variation from inshore(average of 2.515) to offshore sites(average of 5.327) compared with the distribution of a_(355). The values of S_R were related to CDOM molecular weight(MW). The a_(355), S_R, and chlorophyll a in 37 samples collected from the surface microlayer were significantly correlated with those in the corresponding subsurface water samples, implying a strong exchange action between the microlayer and bulk water. The a_(355) and S_R of CDOM exhibited significant microlayer enrichment, with mean enrichment factors(EFs) of 1.72 and 1.62, respectively.     

马超营断裂带地质及地球化学特征

根据对马超营断裂带系统进行的地质—地球化学剖面研究，探讨了该带断裂构造活动及其元素地球化学迁移富集规律与构造地球化学分异之间的关系；分析了蚀变、矿化与成矿的关系，认为早期面型蚀变伴有成矿元素的活化和迁移，但无矿化富集，后期带状蚀变伴有金的富集成矿且以硅化、绢云母化为主要标志。从而，为马超营断裂带这一重要的以金为主成矿带的进一步工作、研究，提供了地球化学方面的依据。     

Sedimentary evolution since the late Last Deglaciation in the western North Yellow Sea

To decipher the sedimentary evolution and environmental changes since the late Last Deglaciation, two gravity cores were analyzed from the western North Yellow Sea (NYS). The two cores (B-L44 and B-U35) were sampled for grain size, clay minerals, detrital minerals, and 14C dating. They are comparable in lithofaies, and the observed succession was divided into four depositional units based on lithology and mineral assemblages, which recorded the postglacial transgression. Depositional unit 4 (DU 4) (before 11.5 ka) was characterized with enrichment in sand, and was interpreted as nearshore deposits in shallow water during the Younger Dryas Event. DU 3 (11.5-9.6 ka) displayed a fining-upward succession composed of sediments from local rivers, such as the Huanghe (Yellow) River, and from coastal erosion, which clearly were related to the Early Holocene transgression. Stable muddy deposition (DU 2) in NYS began to form at about 9.6 ka, which received direct supply of fine materials from the Shandong subaqueous clinoform. It is believed that the Yellow Sea circulation system played a major role in controlling the formation of fine sediment deposition in DU 1 (after 6.4 ka) after the sea level maximum.     

Hong kong direct investment in china’s mainland: A spatial study with special reference to the locational behaviour of investors

The study shows that the regional differentiation of Hong Kong direct investment (HKDI) in China was enlarged in the 1980s and has been reducing since 1991. The concentration of HKDI in the southern China and the coast has been replaced by the trend of moving northwards and inlandwards after 1989. But in terms of manufacturing sectors this trend has not clearly appeared until now. Those changing patterns are clearly related to the behaviour of Hong Kong industrial investors. The survey results suggest that “enjoying lower production cost” is the most important motive for their investment in China. In consequence, “close to Hong Kong”, “cheaper labour” and “favourable policy” are major factors for determining the investment locations. This behaviour, together with the lack of comparison study in location selection among most investors, explains that Guangdong absorbed most Hong Kong investment in the 1980s. As the production costs have been increasing in Guangdong, some companies have started to invest in non-Guangdong locations since the end of the 1980s. From the mental map of Hong Kong investors, however, only some of the non-Guangdong locations are practically attractive. Supported by National Natural Science Foundation of China and the University Graduates Association (Hong Kong). The author gratefully acknowledges the help from Professors Kam-hon Lee and Yue-man Yeung and Dr. David Chu at the Chinese University of Hong Kong, and Mr. Chai-ming Mak at Electricity Advisory Services Limited (HK) during the early stage of the study.     

沂南县贫水山区找水定井技术研究

综合分析沂南县气候、自然、地理,尤其是地质与水文地质条件,及2011年国土资源抗旱打井工作成果,结合沂南地下水含水岩组分布、赋存、地下水运移特征、构造对岩溶发育与地下水运动的控制等。得出沂南县岩溶地下水补给径流区的构造破碎带及其附近地下水相对富集。地下水富集特征可分为:构造带控水型、火成岩体阻挡富水型、断裂影响带强富水型及远离构造破碎带弱富水型等几种类型。根据岩溶地下水补给径流区地下水富集规律的分析研究,为今后贫水山区找水定井提供参考。     

新疆且末县米特河地区1:5万水系沉积物地球化学特征及找矿意义

根据1:5万水系沉积物地球化学测量工作成果,对采集的3138件样品中Cu,Pb,Zn,Au,Ag,W,Sn,Mo,Bi,As,Sb,Cr,Co,Ni共14种元素进行分析测试。研究结果表明,Au,Ag,Cu,Ni是区内最有找矿潜力的成矿指标元素;聚类分析所划分的4类元素簇群,主要与中低温成矿元素、阿尔金南缘断裂、蛇绿混杂岩相关,通过因子分析得到Ni-Cr-As-Sb-Cu-Bi,W-Bi-As-Cu,Bi-W,As,Ag-Zn-Pb,Cu-Bi-As共6类元素组合。其中Cr,Ni,Sb,Cu,As,Bi组合反映出与低温热液活动和断裂构造活动有关;Cr,Ni元素的富集主要与研究区内叶桑岗蛇绿混杂岩带关系密切;Ag,Pb,Zn组合则与地层低温热液元素局部富集和断裂构造活动密切相关。在综合异常分析和查证的基础上,结合区域成矿地质条件、区内矿产地质特征,圈定、划分出2个找矿远景区,并指出了研究区内以金、铜、银、镍为主要优势矿种,铅、锌为潜力矿种。     

贵州织金新华磷矿区风化磷块岩形成条件及风化淋滤富集机制初步研究

贵州织金新华磷矿是我国西南地区著名的超大型含稀土低品位磷矿床, 矿床平均品位w(P₂O₅)为17.22%, 已探明磷矿石储量13.48亿t, 稀土资源量350万t。近年研究发现, 新华磷矿矿石品位的波动变化与风化淋滤富集作用关系密切。为了进一步阐明风化淋滤作用对磷矿元素地球化学的影响及磷矿的次生富集规律, 以戈仲伍矿段为重点研究对象, 对含磷岩系开展了野外观察描述, 应用连续敲块法采集化学分析样品19件, 运用光学显微镜进行岩矿鉴定样品16件, 并对样品进行了岩石成分鉴定及综合研究工作。研究结果表明, 风化磷矿中w(P₂O₅)比原生磷矿提高了8%~18%, w(MgO)比原生磷矿降低了4%~7%, 风化强度处于弱到成熟阶段。织金新华风化磷矿的形成受到岩性条件、地质构造、水文条件等因素控制。本研究可以为深入研究该矿床的次生风化成矿作用对磷矿石化学成分的影响及为新的矿产研究提供资料, 为丰富我国风化淋积型磷矿床的成矿理论提供新认识, 为该矿区风化磷矿资源的合理开发利用提供理论指导。