CO2地下埋存分布状况及环境影响的监测

CO₂的地质埋存处理是减缓温室效应的现实选择之一。要保证埋存的有效性、安全性和持久性,需要对钻井（主要包括注入井和废弃井）、CO₂地下分布运移状况以及因CO₂渗漏所造成的环境影响等方面实施严格的监测管理。通过对以上各方面文献的查阅和综合分析,系统阐述了世界范围内目前CO₂地质埋存过程中所采用的各项主要监测技术。     

基于生产与消费视角的CO2环境库茨涅兹曲线的实证研究

 基于生产和消费视角,对人均GDP和单位GDP的CO₂排放之间的内在关系进行了实证分析。对1990-2004年44个国家的人均GDP与生产型和消费型的单位GDP的CO₂排放进行面板数据的单位根检验和协整分析,在此基础上,对CO₂环境库茨涅兹曲线（EKC）进行模拟。结果显示：无论是从生产视角还是从消费视角,单位GDP的CO₂排放量都具有显著的倒"U"形状,符合环境库茨涅兹曲线特征。但对于多数发展中国家,消费型单位GDP的CO₂排放量总是低于生产型单位GDP的CO₂排放量,表明多数发展中国家在国际贸易中存在着内涵CO₂排放的净出口,这对从生产角度核算国家温室气体排放体系提出了挑战。最后,分析了CO₂环境库茨涅兹曲线对中国应对气候变化的启示。     

CO2倍增对我国东部极端降水的影响

 利用GFDL-CM2.1耦合模式控制试验和CO₂增长试验逐日降水输出结果,评估了CO₂浓度加倍对我国极端降水变化的影响。结果表明：CO₂浓度加倍导致我国东部地区年极端降水的强度增强、降水量显著增多及降水频次显著增加（除华北南部外）; CO₂浓度加倍对我国春夏季极端降水影响较大,导致东部多数地区春夏季极端降水频次增加,强度增强;而CO₂浓度加倍导致华北南部和长江中下游春夏季雨日减少以及小雨、中雨减少,从而导致年总降水量减少。     

基于生产与消费视角的CO2环境库茨涅兹曲线的实证研究

基于生产和消费视角,对人均GDP和单位GDP的CO₂排放之间的内在关系进行了实证分析。对1990-2004年44个国家的人均GDP与生产型和消费型的单位GDP的CO₂排放进行面板数据的单位根检验和协整分析,在此基础上,对CO₂环境库茨涅兹曲线（EKC）进行模拟。结果显示：无论是从生产视角还是从消费视角,单位GDP的CO₂排放量都具有显著的倒"U"形状,符合环境库茨涅兹曲线特征。但对于多数发展中国家,消费型单位GDP的CO₂排放量总是低于生产型单位GDP的CO₂排放量,表明多数发展中国家在国际贸易中存在着内涵CO₂排放的净出口,这对从生产角度核算国家温室气体排放体系提出了挑战。最后,分析了CO₂环境库茨涅兹曲线对中国应对气候变化的启示。     

CO2倍增对我国东部极端降水的影响

利用GFDL-CM2.1耦合模式控制试验和CO₂增长试验逐日降水输出结果,评估了CO₂浓度加倍对我国极端降水变化的影响。结果表明：CO₂浓度加倍导致我国东部地区年极端降水的强度增强、降水量显著增多及降水频次显著增加（除华北南部外）; CO₂浓度加倍对我国春夏季极端降水影响较大,导致东部多数地区春夏季极端降水频次增加,强度增强;而CO₂浓度加倍导致华北南部和长江中下游春夏季雨日减少以及小雨、中雨减少,从而导致年总降水量减少。     

温室效应引起的江淮流域气候变化预估

 选用英国Hadley中心的RCM-PRECIS模式进行江淮流域气候变化的数值模拟。在验证了PRECIS在江淮流域模拟能力的基础上,对未来CO₂增加后江淮流域的气候变化响应进行了预估。结果表明：在B2情景下,整个江淮流域都将继续增暖,到本世纪末（2071-2100年）区域年平均温度将增加2.9℃,夏季将可能出现更多的高温事件,而冬季极端低温事件减少;降水量呈增加趋势,强降水（尤其是120 mm以上的降水）日数也将增多。     

中国汽车空调行业HFC-134a需求和排放预测

 近年来HFC-134a作为中国汽车空调行业CFC-12制冷剂最主要的替代品,其消费量增长迅速,是中国消费量最大的HFCs（氢氟烃类物质）。以2005年为基线,通过制冷剂替代、技术进步、熟练操作和政策控制等情景假设,预测了中国汽车空调行业HFC-134a的需求量及排放量。结果表明：到2010和2015年,汽车空调HFC-134a的消费量将分别接近2.0万和3.5万t,排放量将分别接近1.6万和3.0万t,约折合排放21.0 和39.0 Mt CO₂当量。上述排放相对基线情景（即维持当前政策措施和不开展回收活动）,2010年和2015年减排温室气体分别为6.7 和13.0 Mt CO₂当量。     

CO2地下埋存分布状况及环境影啊的监测

CO2的地质埋存处理是减缓温室效应的现实选择之一。要保证埋存的有效性、安全性和持久性,需要对钻井（主要包括注入井和废弃井）、CO2地下分布运移状况以及因CO2渗漏所造成的环境影响等方面实施严格的监测管理。通过对以上各方面文献的查阅和综合分析,系统阐述了世界范围内目前CO2地质埋存过程中所采用的各项主要监测技术。     

海洋对人为CO2吸收的三维模式研究

文中用包含海洋化学过程和一个简单生物过程的三维碳循环模式模拟了海洋对大气CO₂的吸收,并分析了碳吸收的纬度分布。模拟工业革命以来海洋对大气CO₂的吸收表明:海洋碳吸收再加上大气CO₂的增加只占由化石燃料燃烧、森林砍伐和土地利用的变化而释放到大气中的CO₂的2/3。1980～1989年期间海洋年平均吸收2.05GtC。海洋人为CO₂的吸收有明显的纬度特征。模式计算的海洋CO₂的吸收在总量与纬度分布上与观测结果比较相符。     

江苏地区二氧化碳浓度时空分布特征分析

利用瓦里关和上甸子大气本底站观测的月平均CO₂浓度数据对GOSAT卫星反演的CO₂浓度数据进行验证,结果表明GOSAT产品与台站观测数据有较好的一致性.利用2009年6月—2011年5月GOSAT反演的CO₂浓度数据,分析了江苏地区CO₂浓度的时空变化特征,结果表明:1)975 hPa高度层CO₂浓度高于850 hPa高度层,CO₂浓度的水平变化要小于垂直变化;2)在季节变化上,CO₂浓度冬季最高,夏季最低,这可能与植被光合作用的强弱变化有关;比较前后两年的CO₂浓度数据,夏季和秋季的增速较快,冬季和春季的增速较慢;3)在日变化上,发现徐州和南京站02时CO₂浓度最高,14时CO₂浓度最低,这可能也与植被光合作用的强弱有关.     

Quality of geological CO2 storage to avoid jeopardizing climate targets

We explore allowable leakage for carbon capture and geological storage to be consistent with maximum global warming targets of 2.5 and 3 °C by 2100. Given plausible fossil fuel use and carbon capture and storage scenarios, and based on modeling of time-dependent leakage of CO₂, we employ a climate model to calculate the long-term temperature response of CO₂ emissions. We assume that half of the stored CO₂ is permanently trapped by fast mechanisms. If 40?% of global CO₂ emissions are stored in the second half of this century, the temperature effect of escaped CO₂ is too small to compromise a 2.5 °C target. If 80?% of CO₂ is captured, escaped CO₂ must peak 300?years or later for consistency with this climate target. Due to much more CO₂ stored for the 3 than the 2.5 °C target, quality of storage becomes more important. Thus for the 3 °C target escaped CO₂ must peak 400?years or later in the 40?% scenario, and 3000?years or later in the 80?% scenario. Consequently CO₂ escaped from geological storage can compromise the less stringent 3 °C target in the long-run if most of global CO₂ emissions have been stored. If less CO₂ is stored only a very high escape scenario can compromise the more stringent 2.5 °C target. For the two remaining combinations of storage scenarios and climate targets, leakage must be high to compromise these climate targets.     

Health, Safety and Environmental Risks of Underground Co2 Storage – Overview of Mechanisms and Current Knowledge

CO₂ capture and storage (CCS) in geological reservoirs may be part of a strategy to reduce global anthropogenic CO₂ emissions. Insight in the risks associated with underground CO₂ storage is needed to ensure that it can be applied as safe and effective greenhouse mitigation option. This paper aims to give an overview of the current (gaps in) knowledge of risks associated with underground CO₂ storage and research areas that need to be addressed to increase our understanding in those risks. Risks caused by a failure in surface installations are understood and can be minimised by risk abatement technologies and safety measures. The risks caused by underground CO₂ storage (CO₂ and CH₄ leakage, seismicity, ground movement and brine displacement) are less well understood. Main R&D objective is to determine the processes controlling leakage through/along wells, faults and fractures to assess leakage rates and to assess the effects on (marine) ecosystems. Although R&D activities currently being undertaken are working on these issues, it is expected that further demonstration projects and experimental work is needed to provide data for more thorough risk assessment.     

1975-2005年中国铁路机车的CO2排放量

基于我国铁路部门逐年统计数据,计算了1975-2005年我国铁路机车的CO₂排放量,分析了我国铁路机车CO₂排放强度及其变化特点。结果表明,由于蒸汽机车不断被内燃机车和电力机车所取代,我国蒸汽机车CO₂年排放量逐年降低,内燃机车的CO₂年排放量逐年上升,铁路机车CO₂总排放量由1975年的4223万t降至2005年的1640万t,CO₂排放强度呈现明显的降低趋势,年均降低2.4 g /换算吨公里。我国铁路机车的CO₂排放量占整个交通运输仓储和邮政行业CO₂排放量的比重也呈逐年降低趋势。     

基于多目标规划的中国二氧化碳减排的宏观经济成本估计

CO₂减排的宏观经济代价对处于不同发展阶段的国家有着巨大的差异,对此给出科学的估计具有重要的科学和现实意义。本文运用基于投入产出的多目标规划对中国CO₂减排的宏观经济成本进行了估算。结果表明：CO₂排放控制对我国经济的影响十分显著,在目前条件下,我国2010年CO₂减排的宏观经济成本为3100～4024元/t CO₂;而且减排的力度越大,相应的单位减排的宏观经济成本越高。采掘业、石油行业、化学工业、金属冶炼等行业和部门是CO₂的高排放部门,但同时也是实现减排较有潜力的部门。     

Enhanced climatic warming in the Tibetan Plateau due to doubling CO2: a model study

The National Center for Atmospheric Research (NCAR) regional climate model (RegCM2), together with initial conditions and time-dependent lateral boundary conditions provided by a 130-year transient increasing CO₂ simulation of the NCAR Climate System Model (CSM), has been used to investigate the mechanism of ground warming over the Tibetan Plateau (TP). The model results show that when CO₂ in the atmosphere is doubled, a strong ground warming occurs in the TP. Two regions within it with the largest warming are in the eastern TP (region I) and along the southwestern and western slopes (region II). Moreover, in region I the ground warming in the winter half year is stronger than that in the summer half year, but in region II the warming difference between the seasons becomes opposite to that in region I, i.e., the warming is strong in the summer half year and weak in the winter half year. There are indications that the summer monsoon enhances but the winter monsoon weakens when CO₂ is doubled. A strong elevation dependency of ground warming is found in region I for the winter half year, and in region II for both winter and summer half years at elevations below 5 km. The simulated characteristics of ground warming in the TP are consistent with the observations. In region I, when CO₂ is doubled, the cloud amount increases at lower elevations and decreases at higher elevation for the winter half year. As a consequence, at lower elevations the short wave solar radiation absorbed at the surface declines, and the downward long wave flux reaching the surface enhances; on the other hand, at higher elevations the surface solar radiation flux increases and the surface infrared radiation flux shows a more uniform increase. The net effect of the changes in both radiation fluxes is an enhanced surface warming at higher elevations, which is the primary cause of the elevation dependency in the surface warming. In the summer half year the cloud amount reduces as a result of doubling CO₂ in region I for all elevations, and there is no elevation dependency detected in the ground warming. Furthermore, there is little snow existing in region I for both summer and winter half years, and the impact of snow-albedo feedback is not significant. In region II, although the changes in the cloud amount bear a resemblance to those in region I, the most significant factor affecting the surface energy budget is the depletion of the snow cover at higher elevations, which leads to a reduction of the surface albedo. This reduction in turn leads to an enhancement in the solar radiation absorbed in the surface. The snow-albedo feedback mechanism is the most essential cause of the elevation dependency in the surface warming for region II.