内蒙金厂沟梁金矿床流体包裹体的He-Ar同位素地球化学研究

金厂沟梁金矿床是华北陆台北缘大型脉状热液矿床，矿脉类型主要是黄铁矿-石英脉，其次是石英-黄铁矿脉和黄铁矿-黄铜矿石英脉。对其黄铁矿中的流体包裹体He、Ar同位素研究表明：黄铁矿-石英阶段的流体包裹体³He/⁴He比值为1.03～3.33 Ra，⁴⁰Ar/³⁶Ar比值为296~499；黄铁矿-黄铜矿-石英阶段的³He/⁴He比值为4.44~5.95Ra，⁴⁰Ar/³⁶Ar比值为288~312。这种特征揭示，该矿床流体包裹体的稀有气体组成是由地幔、大气水和地壳流体三端元构成；结合矿床地质特征和形成时代，得出该矿床的初始含矿流体源是MORB地幔和俯冲大洋板片，与岛弧/大陆边缘背景产生的玄武质岩浆基本一致,热流体上升到地壳浅部过程可能受到地壳流体和部分大气水混染。     

新疆坡北杂岩体西端镁铁-超镁铁质岩体成因的稀有气体同位素制约

新疆坡北镁铁-超镁铁质杂岩体由一个辉长岩体以及二十多个超镁铁质侵入体组成,其中坡一超镁铁质岩体稀有气体同位素组成揭示存在地幔柱的贡献。坡北杂岩体西端的坡一、坡四、坡十和坡十四等几个超镁铁质岩体的稀有气体同位素对比分析结果表明,岩浆矿物的³He/⁴He值（0.26~2.79Ra）分布于地壳与地幔值之间,较高的²⁰Ne/²²Ne和较低的²¹Ne/²²Ne值分布于Ne质量分馏线（MFL）和L-K线之间,⁴⁰Ar/³⁶Ar=295~598。³He/⁴He与⁴⁰Ar/³⁶Ar比值揭示坡北杂岩体西端不同超镁铁质岩体形成过程中地幔（柱）、地壳和大气组分的贡献不同,岩体成因也可能不同。其中,坡一岩体具有地幔柱作用的贡献,其他三个岩体的岩石圈地幔及地壳流体组分的贡献较大。岩浆地幔源区由深部地幔柱物质叠加俯冲流体交代的岩石圈地幔物质所组成,大气与地壳物质组分可能由俯冲再循环洋壳带入到岩浆地幔源区以及围岩物质的混入。     

广西栗木锡铌钽矿田成矿物质来源的惰性气体同位素示踪

文章利用黄铁矿流体包裹体惰性气体同位素,探讨了广西栗木锡铌钽矿田成矿流体的来源.黄铁矿流体包裹体的3He/4He比值为0.14～0.97 Ra,远远低于地幔流体的比值,接近饱和大气水的比值,并与地壳流体的比值处在相同的数量级上;40 Ar/36 Ar比值为555.98～ 855.11,平均705.55,显然偏离大气氩的同位素组成;40Ar*/4He比值为0.08～0.27,平均值为0.153,接近地壳值;20Ne/22 Ne=9.671～9.748和21Ne/22 Ne=0.0306～ 0.0330,具有饱和大气水的Ne同位素比值特征.结果表明,广西栗木锡铌钽矿田老虎头、牛栏岭和金竹源3个矿床的成矿流体是大气水和地壳流体的混合流体;水溪庙矿床的成矿流体也主要是大气水和地壳流体的混合流体,但可能有少量地幔流体的加入.     

桂西北丹池成矿带He、Ar同位素特征及其矿床成因指示

桂西北丹池成矿带是我国南方重要的有色金属矿业基地.本文对成矿带内芒场矿田马鞍山Pb-Zn矿和大山Sn-Zn矿、大厂矿田铜坑Sn多金属矿、五圩矿田箭猪坡Pb-Zn多金属矿等4个主要矿床矿石黄铁矿流体包裹体He、Ar同位素进行了研究.结果 表明,丹池成矿带内典型矿床成矿流体的3He/4He=0.79～5.32 Ra,介于地壳流体(0.01～0.05 Ra)与地幔流体(6～9 Ra)特征值之间,40Ar/36 Ar=273～351,接近或略高于大气40 Ar/36 Ar特征值(295.5),不同矿床成矿流体中均有幔源组分的参与,地幔流体参与成矿作用是一个区域性事件.结合区内泥盆纪喷流沉积作用、燕山晚期花岗质岩体及构造特征等综合研究认为,参与成矿作用的地幔组分主要来自壳幔相互作用过程中沿NW向深大断裂上升的深源地幔流体,丹池成矿带内成岩、成矿作用是燕山晚期同一构造-热事件产物,矿床成因属后生热液充填交代成矿.     

广西富贺钟钨锡多金属矿集区稀有气体同位素特征及其地质意义

桂东北富贺钟地区是广西重要的有色金属基地之一, 在姑婆山复式岩体的西南缘产出有新路、水岩坝和珊瑚3个主要钨锡多金属矿田。本文对不同矿田典型矿床分别开展了稀有气体同位素研究, 根据黄铁矿流体包裹体He、Ar、Ne同位素组成, 进一步讨论了区内钨锡成矿流体来源和壳-幔成矿作用过程。结果表明, 黄铁矿流体包裹体3He/4He=0.53~4.53 Ra、40Ar/36Ar=315.58~600.55、38Ar/36Ar=0.18688~0.19102、20Ne/22Ne=9.737~9.848、21Ne/22Ne=0.0291~0.0304, 显示成矿流体为地壳流体、幔源流体和饱和大气水的混合物, 成矿过程中有地幔物质的加入, 地幔He约占8.7%~75.7%。结合区内成岩、成矿的测年资料及岩石成因等综合分析认为, 区内中生代发生了多期次壳-幔相互作用, 且作用强度经历了强→弱→强的演化过程, 分别导致了姑婆山岩体主体岩性(165~160 Ma)和晚期细粒花岗岩(154~151 Ma)的侵位, 以及钨锡多金属成矿作用(136~100 Ma), 成矿与晚期的细粒花岗岩同位但不同时。     

湘南荷花坪锡多金属矿床成矿年代研究

荷花坪锡多金属矿床是本世纪初在南岭中段湘南地区新发现的一个大型矿床,区内的锡多金属矿化产在王仙岭岩体东南内、外接触带,已发现有Ⅰ、Ⅱ、Ⅲ和Ⅳ号4个主要锡多金属矿体。其中,Ⅰ、Ⅱ和Ⅳ号矿体由早期矽卡岩型和晚期蚀变碎裂岩型矿石组成,Ⅲ号矿体则由独立产出的蚀变碎裂岩型矿石组成,且包含有部分碎裂花岗斑岩。以往研究已对Ⅳ号矿体中的矽卡岩型矿石和Ⅲ号矿体中含矿斑岩脉分别采用辉钼矿Re-Os法和锆石SHRIMP U-Pb法进行了测年,获得的年龄分别为224.0±1.9Ma和142±2Ma。本文补充了晚期蚀变碎裂岩型矿石的~(40)Ar/~(39)Ar测年,结果显示,Ⅱ号矿体中蚀变碎裂岩型矿石白云母样品和石英样品的坪年龄分别为151.88±1.58Ma和155.39±7.04Ma;Ⅳ号矿体中蚀变碎裂岩型矿石石英样品的坪年龄为156.94±1.64Ma。结合前人研究资料综合分析,认为荷花坪矿区存在印支晚期(224Ma)、燕山早期(151~156Ma)和燕山晚期(142Ma)三期成矿作用,分别与区内印支期中粗粒含电气石黑云母花岗岩、燕山早期中粗粒黑云母花岗岩和燕山晚期花岗斑岩脉有关,不同期成岩、成矿作用的构造环境均为岩石圈的拉张伸展。湘南地区印支期(205~224Ma)基性岩浆活动及荷花坪矿床印支期成岩、成矿过程中均有幔源物质的参与,它们共同指示南岭地区中生代构造体制的转换或岩石圈伸展减薄可能始于印支主期(230~244Ma)之后的224Ma左右,即晚三叠世。     

赣南淘锡坑钨矿床He-Ar同位素地球化学研究

华南石英脉型黑钨矿的形成一直被认为是与地壳沉积物质重熔形成的S型花岗岩有关。然而,近年来对南岭中生代成岩成矿机制的研究发现,地幔组分可能参与了钨、锡成矿作用。本文对淘锡坑石英脉型钨多金属矿床与黑钨矿共生的黄铁矿和毒砂中流体包裹体的He、Ar同位素进行了研究。结果显示,上述矿物中流体包裹体的~3He/~4He值为0. 37～2. 11Ra(Ra为空气的~3He/~4He值,1Ra=1. 39×10~(-6)),介于地幔与地壳的~3He/~4He值之间;~(40)Ar/~(36)Ar值为309. 5～383. 6,平均335. 4,略高于大气的~(40)Ar/~(36)Ar比值(295. 5)。研究表明,成矿流体具有壳-幔两端元混合的特征。其中,地壳端元的流体为经过地下循环的低温饱和大气水,地幔端元的流体为矿区隐伏花岗岩体成岩过程中分异出的岩浆流体。结合前人研究成果,认为该矿床的形成与华南中生代燕山期发生的软流圈上涌、岩石圈减薄、地壳伸展等地球动力学作用有密切联系。这种动力学过程为地幔组分带来的热引起地壳沉积物质重熔形成钨多金属成矿花岗岩浆提供了条件。     

大水沟碲矿床成矿流体特征及其幔源性质

该文是大水沟碲矿床成矿流体研究的成果。经过进一步的稳定同位素、惰性气体同位素和流体包裹体研究,初步证明该碲矿床成矿流体主要来自地幔。由火山岩浆的多期次活动,中低温、高盐度的成矿流体,携带大量K、Na、Cl、F、CO₂、CH₄和H₂等深源物质,以富碱质、硅质为主的成矿交代作用,示意出成矿流体的深源性。氢、氧、碳、硫同位素组成均指示其成矿流体的地幔来源。惰性气体同位素测试:³He/⁴He为1.34~2.16 Ra; ⁴⁰Ar/³⁶Ar为385~1026,这进一步反应了大水沟碲矿床成矿流体来自原始地幔。     

雅鲁藏布江缝合带造山型金矿床成矿流体特征:来自He-Ar同位素的约束

雅鲁藏布江缝合带造山型金成矿带是近些年来在青藏高原新确立的碰撞造山型金成矿带,成矿流体是一套CO_2-H_2O-NaCl-CH_4-N_2体系,以变质水为主。为探讨地幔组分对成矿的影响,本文选取雅鲁藏布江缝合带内邦布矿床和念扎矿床两个大型的造山型金矿为研究对象,对与成矿相关的黄铁矿及胶黄铁矿进行He-Ar同位素分析。结果显示,邦布矿床含金石英脉中黄铁矿中流体包裹体的He和Ar的浓度变化范围较窄,~3He/~4He为0.59～0.70 Ra,~(40)Ar/~(36)Ar为365.1～423.1;2件胶黄铁矿样品的~3He/~4He为0.11 Ra及0.19 Ra,~(40)Ar/~(36)Ar为302.1和305.9;念扎矿床石英-多金属硫化物脉中黄铁矿的~3He/~4He为0.27～0.60 Ra,~(40)Ar/~(36)Ar为370.2～1777.9。雅鲁藏布江造山型金成矿带中造山型金矿成矿流体为壳幔源混合流体,地壳端元主要为变质水,地幔组分在邦布金矿和念扎金矿中的贡献率分别为12.8%～15.2%和5.7%～13.0%;这与藏南拆离系中的金锑成矿作用明显不用,藏南拆离系中的金锑矿床成矿流体主要表现为改造型饱和大气水的特征,未有地幔组分的贡献。     

湘南新田岭白钨矿床He,Ar同位素特征及Rb-Sr测年

新田岭白钨矿床是湘南W-Sn多金属矿集区中的一个大型矽卡岩型矿床,产于骑田岭岩体北接触带.本文对矽卡岩矿石中1件黄铁矿样品进行了流体包裹体He、Ar同位素测定,获得3He/4He值为4.08 Ra,40Ar/36Ar为342,反映了在矽卡岩矿床的成矿流体中亦有地幔流体的显著参与;运用石英Rb-Sr法获得成矿等时线年龄为(157.4±3.2)Ma(2σ)(MSWD=1.6),87Sr/86Sr初始值为0.71044±0.00012,该年龄值与柿竹园超大型钨多金属矿床及芙蓉大型锡矿等的成矿年龄在测试误差范围内基本一致,表明中侏罗世是湘南地区钨锡成矿的高峰期.     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.     

PALEONTOLOGY

正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)     

GEOCHEMICAL EXPLORATION

正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)     

MICROPALAEONTOLOGY

正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)     

PETROLOGY

正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,     

ENVIRONMENTAL GEOLOGY

正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an     

PROSPECTING EXPLORATION

正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of