The chemical states of iron in marine sediments by means of Mössbauer spectroscopy in combination with chemical leachings

The chemical states of iron in near-shore and deep-sea sediments were investigated by means of⁵⁷Fe Mössbauer spectroscopy in combination with selective and nonselective chemical leachings. As far as a limited number of the sediments analyzed are concerned, Mössbauer spectra of near-shore sediments consist of high-spin paramgnetic ferrous (=1.13 mm/s, Eq=2.65 mm/s) and paramagnetic ferric (=0.35 mm/s, Eq=0.64 mm/s) components, while those of deep-sea sediments are composed of high-spin paramagnetic ferrous, paramagnetic ferrous, paramagnetic ferric and magnetic ferric (0.4 mm/s,H510 KG) components. The Fe²⁺/Fe³⁺ ratios of deepsea sediments are much smaller than those in near-shore sediments, while the total contents of iron in the former are much higher than those in the latter. This is principally due to the high contents of authigenic ferric oxides in deep-sea sediments. Further, in the aluminosilicate fraction, the Fe²⁺/Fe³⁺ ratios of deep-sea sediments are also smaller than those of near-shore sediments. This is probably attributed to high contents of clay minerals and authigenic aluminosilicates in deep-sea sediments relative to near-shore ones. The magnetic components in deepsea sediments are attributable to hematite, magnetite and/or maghemite.     

Offshore Occurrences of Heavy-Mineral Placers,Northwest Galicia,Spain

ABSTRACT

Results of offshore water-jet sediment sampling demonstrate the potential for interstadial placer deposits of industrial minerals in the shore-face to inner-shelf of Cape Ortegal, NW Spain. Placer deposition is interpreted to have occurred during glacial interstadials since the Last Glacial Maximum, and deposits sampled at 24 to 42 m. BSL were formed during the Younger Dryas, and subsequently preserved as a result of very rapid rising sea-levels. The sediments are almost entirely terrestrially derived with a particularly high heavy mineral content (Sp. Gr. >2.9), of more than 75% in all samples. Reworked garnet from earlier-sedimentary deposits constitutes an important fraction of the placer deposits identified but is generally absent in other sediments. Indications of the presence of +5 m-thick paleo-placer deposits with sections include:

• Placer garnet + spinel grades increase with depth in those sediments at 24 to 42 m BSL to the ocean-floor.

• The d50 of sediments with background grades decrease with depth while those of placer deposits do not display any significant trend.

• Garnets in non-mineralized sediments are almost entirely angular, whereas in placer enriched sediments they vary in form from well-rounded to angular. Some grains in the latter display surface morphologies typical of reworked sediment while none of the former do.

Sediments deposited during glacial interstadials at depths of up to 130 m BSL may represent important, undeveloped exploration targets for offshore placer deposits of industrial minerals. Industrial mineral exploration should extend the depths of investigations to those corresponding to major interstadial periods.     

A detailed geochemical and rock magnetic study of dredged basalt from the Sheba Ridge,Gulf of Aden

We report the results of petrological, geochemical and rock magnetic studies of basalt dredged from the eastern end of the west Sheba Ridge during cruise 11/1979 of R. R. S. Shackleton to the Western Gulf of Aden. The ridge is part of the Red Sea-Gulf of Aden spreading axis and the basalts are olivine tholeiites. The abundances of some elements are characteristic of normal MORB (mid-ocean ridge basalt) but other elemental abundances suggest affinites with transitional-type MORB.The observed magnetic properties are interpreted in terms of the composition, concentration and microstructure of the magnetic mineral fraction by recourse to the available data on synthetic analogues. The analysis has been carried out in greater detail than has been attempted in previous magneto-petrological studies. It appears that submarine weathering of the magnetic minerals (maghemitization) brings about not only the expected change in composition but also a fall in concentration of the magnetic fraction. This could result from the removal-of-iron oxidation mechanism operating in the submarine environment. It is also found that the fall in remanence with increasing degree of maghemitization is not explicable in terms of the change in composition and concentration of the magnetic minerals. A further influence—probably microstructural change—significantly reduces the remanence intensity.     

Mineralogical study of the core samples from the Indian Ocean,with special reference to the vertical distribution of clay minerals

The clay minerals in the 18 core samples collected from the northern, equatorial and southeastern Indian Ocean are illite, chlorite, montmorillonite and kaolinite. In the fraction finer than 2 in the surface layer (top to 5 cm deep) of each core, the relative abundance of clay minerals varies widely from area to area. Kaolinite possesses the maximum proportion of the clay mineral composition and chlorite has the minimum proportion.Kaolinite is particularly dominant in sediments near off the northwestern coast of Australia. In the factions finer and coarser than 2 of the surface layer, montmorillonite and kaolinite tend to be abundant in the fraction finer than 2, and chlorite and illite tend to be abundant in the fraction coarser than 2. In some cores, kaolinite-rich layers in sediments which are considered to have been transported by turbidity currents from the Bay of Bengal are found. Turbidity currents appear partly a role in transport of sediments to the equatorial Indian Ocean.As to the relation between the vertical change of clay mineral composition and geochronological data, montmorillonite and kaolinite tend to be more abundant in interglacial ages than in glacial ages, while illite and chlorite tend to exhibit opposite trend.Muscovite and biotite highly concentrated in the cores Ka-9 and Ka-15 collected from the equatorial Indian Ocean seem to originate from granite or gneiss of Ceylon and/or India.     

Occurrence of coprostanol, 24-ethylcoprostanol and 5α-stanols in the marine sediments

The present study deals with the elucidation of sterol composition of the marine sediments in Kagoshima Bay. The identification of each sterol was performed by gas-liquid chromatography, Ag⁺ impregnated column chromatography, mass spectrometry, and nuclear magnetic resonance spectrometry. The sediment obtained near the estuary of River Koutsuki contained large portions of 5-stanols such as coprostanol and 24-ethylcoprostanol basides 5-stanols such as cholestanol, 24-methylcholestanol, and 24-ethylcholestanol in the sterol fraction. These 5-stanols in the marine sediment may be derived from the fecal contamination by domestic sewages.     

山东省近海砂矿分类及其基本特征

根据砂矿产出的宏观海洋环境、矿种、形成时代、成矿作用和微地貌形态等要素,将山东省主要近海砂矿划分为2大类、13类、32亚类。初步探明具有工业价值的矿种有建筑用砂、石英砂、锆石、贝壳、球石、砂金等6个矿种,各类砂矿床约计86个。主要分布在莱州湾-荣成-青岛-岚山头一带的滨、浅海地区。近海砂矿资源将是山东省利用矿产资源的一个重要新领域。     

Combined magnetic,electrostatic, and gravity separation techniques for recovering strategic heavy minerals from beach sands

A combination of unit operations like gravity, magnetic, and electrostatic separation techniques were applied to separate strategic heavy minerals from bulk samples taken from two coastal stretches of Kappil-Varkala (KV) and Shanghumugham-Kovalam (SK) in Thiruvananthapuram, south Kerala, India. On processing the feed, the concentrate obtained contains 67.3% THM for KV and 65.15% THM for SK, out of which ilmenite predominantly exists with a yield of 45.55 and 43.6% in weight followed by other minerals like sillimanite, monazite, zircon, rutile, leucoxene, and garnet. Analysis indicates that judicious combination of unit operations like gravity, magnetic, and electrostatic separation techniques can efficiently recover heavy mineral species even from placers of smaller deposit.     

Practical Formulas for Intercoupling of Pressure and Depth in the Black Sea

On the basis of the generalization of the concept of standard ocean to the Black Sea, we deduce practical formulas for the conversion of pressure into depth and vice versa depending on the latitude of the place with regard for the equation of state for 1980. The error of these relations for the standard Black Sea (whose salinity is equal to 22.2 at a temperature of +9°C from the surface to the bottom) does not exceed ±0.2m and ±0.2dbar. The difference between the practical and actual depths in winter and summer periods does not exceed ±0.35m for depths varying within range 0–2000m. The proposed practical formulas enable one to simplify the procedure of rapid evaluation of depth (or pressure) in real time by excluding the procedure of integration over a specific volume.     

Global distribution and atmospheric transport of chlorinated hydrocarbons: HCH (BHC) isomers and DDT compounds in the Western Pacific,Eastern Indian and Antarctic Oceans

Concentrations of chlorinated hydrocarbons such as HCH isomers and DDT compounds were determined in air and surface water samples taken from the Western Pacific, Eastern Indian and Antarctic Oceans. The most interesting finding was their presence in measurable concentrations in the Antarctic Ocean. Chlorinated hydrocarbon pesticides are widely distributed in the open ocean environment over both the northern and southern hemispheres, and some characteristic distribution patterns of pesticide species in different oceanic regions were observed both in air and water samples. HCH residues found in the northern hemisphere were much higher in concentration than those in the southern hemisphere. On the other hand, higher concentrations of DDT residues were found in the tropical regions, but their levels were not so different between both the northern and southern hemispheres. HCH isomers found in the northern hemisphere had the following order of concentrations:-HCH> HCH>-HCH, while in the southern hemisphere-HCH was apparently dominant. DDT compound compositions were rather uniform in all the oceans surveyed, and more than 50% wasp,p-DDT. These facts can be explained by the world wide situation regarding pesticide use and the physicochemical properties of the pesticides such as their vapor pressures and water solubilities. In addition, the meridional circulation of the atmosphere, particularly the mass flows of the Hadley and Ferrel cells in the troposphere, also contributes to the atmospheric transport and global distribution of these pesticides.     

Parameterization of the dispersion relation of internal waves using the data of hydrological soundings in the Tropical Atlantic

Dependences have been determined which connect the parameters of the dispersion relation of the lowest mode of internal waves with the integral characteristics of the seasonal thermocline when 10 min30 min, 20 mh150 m, and 0·4 m²/s² Q5·2 m²/s².Translated by Mikhail M. Trufanov.     

Thermolability of dehydrogenases from a psychrophilic marine bacterium

The heat lability of succinic dehydrogenase, malic dehydrogenase and lactate dehydrogenase in cell-free extracts ofVibrio marinus MP-1 grown at 15C was compared for the tris buffer suspended enzymes and the NaCl suspended enzymes. The tris buffer suspended enzymes lost 50 percent activity at low thermal exposure between 5C and 27C. No activity was evident on thermal exposure between 32C and 39C. The enzyme extracts suspended in NaCl at 36 % were more heat stable, losing 50 percent activity after exposure between 16C and 40C. The enzymes lost all activity on thermal exposure between 33C and 42C in the presence of NaCl.     

Radioelement distribution in river,beach, and offshore areas and their significance to Chavara placer deposit,Southern Kerala Coast of India

The radioelement and heavy mineral distribution in river, beach and innershelf areas of the southern Kerala coast is related to placer mineral concentration on the beaches at Chavara. Southern Kerala rivers—Neyyar, Karamana and Vamanapuram—transport higher amounts of radioactive elements than the larger Kallada River due to higher radioactive minerals in the hinterland rocks. Coastal configurations and the seasonal longshore current pattern seems to control along-shore distribution of minerals. The proposed model for placer concentration suggests that the energy difference and seasonal current direction along this coast is important.     

Radiation balance and heat budget at the ocean/atmosphere interface in the western North Pacific

The downward short- and long-wave radiation fluxes at the sea surface (S, L) were measured aboard the R/VHakuho Maru, University of Tokyo, for the period of 117 days on six cruises from 1981 to 1985 in the western North Pacific near Japan. The upward fluxes of short- and long-wave radiation (S, L) were calculated by Payne's (1972) table and the Stefan-Boltzmann's law, respectively. The sensible and laten heat fluxes (Q _h ,Q _e ) were also estimated from an aerodynamic bulk method.From April to August, the daily mean value ofS varied with the amplitude of 100200 Wm^–2. The value ofS was estimated approximately 6% ofS in all seasons. The difference betweenL andL was so small that the net radiation flux (Q _n ) was dominated byS. In addition, the net heat flux at the sea surface was also dominated byS due to small values ofQ _h andQ _e , and then the ocean was warmed at the rate of 111 Wm^–2 in April and 63 Wm^–2 in August in the Oyashio Area, and 132 Wm^–2 in May and 164 Wm^–2 in June in the Kuroshio Area, respectively.From September to March, a remarkable negative correlation between the day to day variation ofS and that ofL was observed except when an intense cold air outbreak occurred. It was found that the correlation was caused by the cloud climatological feature of the western North Pacific in this period.S was not a dominant factor in the net heat flux. The value ofQ _h +Q _e in the Kuroshio Area ranged from 260 Wm^–2 to 630 Wm^–2, much larger thanQ _n which ranged from –8 Wm^–2 to 92 Wm^–2 in the leg mean values (each leg period was about 10 days). Then the ocean was cooled at the rate of –160–620 Wm^–2 during this period. The net heat flux in the Kuroshio Area averaged over five legs from late November to February was –473 Wm^–2. This value is 50100% larger than the climatological values reported so far.The temporal and spatial variability of radiation fluxes and heat fluxes during each leg was also discussed.     

Some characteristics of the development process of the wind-wave spectrum

The development process of wind-waves of which spectral peak distributes from 0.6 cps to 9.3 cps will be discussed on the basis of the wind tunnel experiments and of the field observations performed at Lake Biwa. The characteristics of power and slope spectra are here presented. The development process of these wind-waves is characterized by three stages;i.e. initial-wavelets, transition stage and sea-waves. In the wind tunnel experiments, the transition from the stage of the initial-wavelets to the transition stage occurs when the wave spectral peak arrives at the line 6.40×10^–4 k ^–2cm²·sec (wherek is wave number) or when the slope spectral density at the frequencyf _max becomes larger than 6.40×10^–4 sec. In the stage of sea-waves, the component wave of a wave-spectral peak is steepest in the component waves. And the wave spectral peak develops along the line 1.02×10² f ^–6 cm²·sec (wheref is the frequency corresponding to the wave numberk) untill it reaches the line 33.3f ^–4cm²·sec, and thereafter develops along the latter line, which indicates the constant density of slope spectrum. It is suggested that the nonlinearity of wind-waves must become stronger as wind-waves develop. The effective momentum flux _ws from the air flow to wind-waves in this stage is evaluated to be about 49% of the total stress ₀.     

Abundance and size composition of the summer phytoplankton communities in the western North Pacific Ocean,the Bering Sea,and the Gulf of Alaska

Chlorophylla concentrations (Chla) of size-fractionated phytoplankton samples were measured in the western North Pacific Ocean, the Bering Sea, and the Gulf of Alaska during the summer of 1986. Among samples collected in the upper 100 m (total of 210 samples), 207 samples were dominated by micro- (>10 m) or picoplankton (<2 m) and only three samples were represented by nanoplankton (2–10 m). These 207 samples were classified based on the total Chla content into three types: Type H (>1.0 g l^–1), Type M (0.5–1.0 g l^–1), and Type L (<0.5 g l^–1). These types further divided into two subtypes (-p and-m), depending upon dominancy of pico (-p) and microplankton (-m). The phytoplankton community was represented by Type L-p in the Gulf of Alaska, where 80% of the samples fell into this type. It was represented by Type M-p in the western North Pacific and the Oceanic Domain in the Bering Sea, where 53 and 41% of samples were identified as this type, respectively. In the Middle Domain of the Bering Sea, 68% of samples collected below the nitracline was Type H-m, which indicates blooms of microplanton. This type was also observed in the neritic waters near the Aleutian Islands. These types described above are consistent with a general trend that an increase in phytoplankton abundance is attributed to the growth of microplankton. An unusual type occurred above the nitracline of the Middle Domain, where microplankton prevailed, although the total Chla was less (Type L-m). This type represents a feature of late phase of an ice edge bloom. Another unusual type was found mainly in the Outer Domain of the Bering Sea, where the total Chla was high and picoplankton prevailed (Type H-p). The predominance of picoplankton seems to result from the heavy grazing intensity of large calanoid copepods upon microplankton but not upon picoplankton     

Kinetics of nitrate and ammonium uptake by the natural populations of marine phytoplankton in the surface water of the Oyashio region during spring and summer

The maximum uptake rate (_max) and affinity constant (K _s) for nitrate and ammonium were estimated in the surface water of offshore Oyashio in May (spring) and September (summer), 1990. The average _max/Chl.a for ammonium was 2.1 times larger than that of nitrate in both seasons. The average _max/Chl.a for both nitrogens were 3.5 times larger in summer than in spring. Water temperature and size composition of phytoplankton population were related to the seasonal difference in the _max/Chl.a. Phytoplankton population showed high affinity for both nitrogens in the spring and summer. In addition, the contribution of new production to total production was estimated by _max[_max–No₃/(_max–NO₃+_max–NH₄)]. The spring value was in the range of 0.26 to 0.45 (mean±SD=0.35±0.092), and the values in spring bloom were especially a little over 0.4. The summer value was in the range of 0.30 to 0.37 (0.34±0.04).     

The mechanism of the development of wind-wave spectra

The mechanism of the development of wind-waves will be proposed on the basis of the observed wave spectra in the wind tunnels and at Lake Biwa (Imasato, 1976). It consists of two aspects: One is that the air flow over the wind-waves transfers momentum concentratively to the steepest component waves and the other is that the upper limit of the growth of a wave spectral density is given by the ultimate value in the slope spectral density. The first aspect means that the wave field has the momentum transfer filter on receiving the momentum from the air flow. Wind-waves in the stage of sea-waves receive the necessary amount of momentum by the form drag,e.g. according to the Miles' (1960) inviscid mechanism, through a very narrow frequency region around a dominant spectral peak. On the other hand, wind-waves in the stage of initial-wavelets receive it according to the Miles' (1962a) viscous model through a fairly broad frequency region around the peak. The upper limit ofS _max developing according to viscous mechanism is given byS _max =6.40×10^–4 k _max ^–2cm²s andS _max =2.03C(f _max )^–2cm²s(S _max is the power density of the wave spectral peak with the frequencyf _max ,k _max is the wave number corresponding to the frequencyf _max andC is the phase velocity).From the second aspect, the upper limit of the growth of wave spectral density is given by 33.3f ^–4cm²s in the frequency region of late stage of sea-waves. Therefore, the spectral peak, which has the largest value in the slope spectral density in the component waves of the wave spectrum, rises high over the line 4.15f ^–5cm²s. The energy is transported from the spectral peak to the high frequency part and to the forward face of a wave spectrum by nonlinear wave-wave interaction. This nonlinearity is confirmed by the bispectra calculated from the observed wind-wave data. In the stage of sea-waves, nonlinear rearrangement of the wave energy comes from a narrow momentum transfer filter, and, in the stage of initial-wavelets, it comes mainly from small corrugations and small steepness of the wave field.     

Mean Vertical Distribution of the Dissipation Rate of Turbulent Energy in the Black Sea. Comparison with the Existing Models

We compare the results obtained by using theoretical and semiempirical models developed for the evaluation of the dissipation rate of turbulent energy in a stratified ocean with independent distribution of this quantity established by the authors for the active layer of the Black Sea (50–300 m) by using a one-dimensional model taking into account the balance of heat, salt, and fluid inside the layer. It is shown that, in a layer with gradual variation of the Väisälä–Brunt frequency N as a function of depth, the predominant sink of the energy of motion into dissipation N ² is ensured by the flow of energy through the spectrum of internal waves toward low frequencies and small vertical scales. On the contrary, in layers with abrupt drops of density as a function of depth (layers with jumps of density), an important role is played by the interface-type waves and the dependence of on N transforms into N .     

Morphology of largeHalimeda bioherms,eastern Java sea (Indonesia): A side-scan sonar study

The most extensive and thickestHalimeda bioherms reported from modern seas occur along both open and protected margins of Kalukalukuang Bank, eastern Java Sea (Indonesia). Seismic profiles suggest these features average 20 to 30 m thick (maximum 50 m) and developed over large areas by coalescence of individual mounds. Bioherm morphologies range from numerous small mounds ( 10–20 m diameter) through hay-stack features ( 100 m diameter) to broad swells. Some modern bank bioherms display surface forms that appear related to onbank flow from Makassar Strait. Upwelling of cold, nutritive water is likely responsible for unusualHalimeda productivity and large bioherm development.     

Intrusive Stratification of the Gulf-Stream Frontal Zone According to the Results of Investigations Performed during Cruise 43 of the R/V Akademik Vernadskii

We analyze the data of investigation of the intrusive structure of the Gulf-Stream frontal zone obtained in making frequent drift sections with the help of an MGI-8102 probing complex, study the regularities of variation of temperature, salinity, and density along separate intrusions, and present a series of results connected with the specific features of initiation and development of intrusions and the types of exchange processes determining their transformations. It is shown that the T-diagrams of all intrusions are well separated into segments with different slopes. Moreover, by comparing the slopes and locations of these segments with each other and with the T-diagrams of the Gulf Stream and slope waters, we can fairly reliably attribute the corresponding segments of intrusions to one of the following four types: initial dynamic folds of the frontal zone, layers of domestic water separating the intrusive segments of foreign water from each other, intrusive segments characterized by the penetration of ambient water, and segments not intrusive initially but getting the required slope as a result of interaction with upper and lower intrusive segments. For segments of the last two types, it is possible to specify the predominant type of exchange.